<?xml version="1.0" encoding="UTF-8"?><resource xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.3/metadata.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4"><identifier identifierType="DOI">10.1594/PANGAEA.989435</identifier><creators><creator><creatorName>Arnold, T Elliott</creatorName><givenName>T Elliott</givenName><familyName>Arnold</familyName></creator></creators><titles><title>Hydrogen isotopes of n-alkane biomarkers and brGDGT temperatures from Lake Tulane, Florida, USA</title></titles><publisher>PANGAEA</publisher><publicationYear>2026</publicationYear><subjects><subject>Branched GDGTs</subject><subject>Hydrogen isotopes</subject><subject>Lake core</subject><subject>Lake Tulane</subject><subject subjectScheme="Parameter">Event label</subject><subject subjectScheme="Parameter">Latitude of event</subject><subject subjectScheme="Parameter">Longitude of event</subject><subject subjectScheme="Parameter">Date/Time of event</subject><subject subjectScheme="Parameter">Core</subject><subject subjectScheme="Parameter">Device type</subject><subject subjectScheme="Parameter">AGE</subject><subject subjectScheme="Parameter">Temperature, water</subject><subject subjectScheme="Parameter">δ Deuterium, n-alkane C23</subject><subject subjectScheme="Parameter">δ Deuterium, n-alkane C27</subject><subject subjectScheme="Parameter">δ Deuterium, n-alkane C29</subject><subject subjectScheme="Parameter">δ Deuterium, n-alkane C31</subject><subject subjectScheme="Parameter">δ Deuterium, n-alkane C33</subject><subject subjectScheme="Parameter">δ Deuterium, n-alkane C35</subject><subject subjectScheme="Parameter">ε</subject><subject subjectScheme="Method">Core</subject><subject subjectScheme="Method">Reconstructed, using branched GDGTs</subject><subject subjectScheme="Method">See Device type column</subject></subjects><dates><date dateType="Collected">2018-08-11T00:00:00</date></dates><resourceType resourceTypeGeneral="Dataset">Dataset</resourceType><relatedIdentifiers><relatedIdentifier relatedIdentifierType="DOI" relationType="References">10.1016/j.gca.2023.08.019</relatedIdentifier></relatedIdentifiers><sizes><size>269 data points</size></sizes><formats><format>text/tab-separated-values</format></formats><rightsList><rights rightsURI="https://creativecommons.org/licenses/by/4.0/" schemeURI="https://spdx.org/licenses/" rightsIdentifierScheme="SPDX" rightsIdentifier="CC-BY-4.0">Creative Commons Attribution 4.0 International</rights></rightsList><descriptions><description descriptionType="Abstract">This dataset includes temperatures derived from branched glycerol dialkyl glycerol tetraethers (brGDGTs) and regional hydrology changes reconstructed from hydrogen isotope ratios (δ2H) of n-alkanes extracted from a lacustrine sediment core from Lake Tulane, Florida, USA. In 1994, 8 cores from 6 locations (2 complete overlaps) were acquired from a transect along the north basin of Lake Tulane. Cores were taken with a 7.5-cm diameter Wright square-rod piston corer from an anchored raft. Separately, a single surface-water interface core was acquired from the north basin of Lake Tulane in 2010. brGDGTs and n-alkanes were extracted from archived core sections at 8-10 cm intervals in August of 2018 and from the surface-water interface core at 5 cm intervals in August of 2019. The archived core interval spanned Heinrich Stadials 4-2 (41,000-17,000 BP) and the surface-water interface core spanned 78-0 BP. brGDGT distributions from both cores were measured via atmospheric pressure chemical ionization high-performance liquid chromatography-mass spectrometry (APCI/HPLC–MS), and hydrogen isotope ratios of n-alkanes were measured on a Thermo Trace GC Ultra coupled to a Thermo Electron Delta V Advantage IRMS with an Isolink combustion furnace. The brGDGT data was converted to degrees Celsius (°C) following the open-sourced code provided in O'Beirne et al. (2023, doi:10.1016/j.gca.2023.08.019). Hydrogen isotope results are given in the conventional δ-notation. A proxy for seasonal precipitation and aridity (ε(C29-C23)) was created, which reflects the difference between the δ2H values of aquatic n-alkanes (δ2HC23) and terrestrial leaf wax δ2H values (δ2HC29) using the following equations: (1) α = (1000 + 𝛿2HC29)/(1000 + 𝛿2HC23), and (2) ε(C29-C23) = (α -1) x 1000.</description></descriptions><geoLocations><geoLocation><geoLocationPoint><pointLongitude>81.500361</pointLongitude><pointLatitude>27.585833</pointLatitude></geoLocationPoint></geoLocation><geoLocation><geoLocationPlace>Florida, USA</geoLocationPlace></geoLocation></geoLocations></resource>