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Torner, Judit; Cacho, Isabel; Stoll, Heather M; Moreno, Ana; Grimalt, Joan O; Sierro, Francisco Javier; Fornós, Joan J; Cheng, Hai; Edwards, R Lawrence (2025): Stable Isotope Records and Mg/Ca Ratios of the RAT Speleothem from Menorca Island (387–209 ka) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.986464

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Published: 2025-10-10DOI registered: 2025-11-08

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Abstract:
This dataset comprises speleothem carbon and oxygen isotope records, Mg/Ca ratios results from the RAT speleothem. The data were used to reconstruct past climate variability in the western Mediterranean region over the interval 387 to 209 ka, encompassing several glacial terminations (TIV, TIII, and TIIIa). The speleothem was collected in winter 2011 from Murada Cave, located on Menorca Island (39°57′58″N; 3°57′53″E). Stable isotope analyses (δ¹³C and δ¹⁸O) were performed with 50 µg of carbonate powder using isotope ratio mass spectrometry (IRMS), and Mg/Ca ratios were measured by inductively coupled plasma mass spectrometry (ICP-MS) at the Scientific and Technological Centres of the University of Barcelona. Analytical uncertainties were ≤ 0.04‰ VPDB for δ¹³C and ≤ 0.08‰ VPDB for δ¹⁸O, NBS19 international standard (Coplen, 1996) was used for calibration.
Keyword(s):
glacial terminations; isotopes; Mediterranean; Paleoclimate; Speleothems; trace elements
Related to:
Torner, Judit; Cacho, Isabel; Stoll, Heather M; Moreno, Ana; Grimalt, Joan O; Sierro, Francisco Javier; Fornós, Joan J; Cheng, Hai; Edwards, R Lawrence (2025): New age constraints for glacial terminations IV, III, and III.a based on western Mediterranean speleothem records. Climate of the Past, 21(2), 465-487, https://doi.org/10.5194/cp-21-465-2025
Torner, Judit; Cacho, Isabel; Stoll, Heather M; Moreno, Ana; Grimalt, Joan O; Sierro, Francisco Javier; Fornós, Joan J; Cheng, Hai; Edwards, R Lawrence (2025): U–Th Dating of the RAT Speleothem from Menorca Island (387–209 ka) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.986506 (Age dating)
References:
Coplen, Tyler B (1996): New guidelines for reporting stable hydrogen, carbon, and oxygen isotope-ratio data. Geochimica et Cosmochimica Acta, 60(17), 3359-3360, https://doi.org/10.1016/0016-7037(96)00263-3
Funding:
Agencia Estatal de Investigación (AEI), grant/award no. CTM2013-48639-C2-1-R: OPERA - Forzamiento oceánico en la variabilidad de precipitaciones sobre Iberia y respuesta de ecosistemas marinos al CO2 antropogénico
Agencia Estatal de Investigación (AEI), grant/award no. PID2022-138010OB-I00: MORIA - Extensión e impacto de las aguas mediterráneas en el Atlántico Norte: variabilidad presente y pasada usando isótopos de neodimio
Coverage:
Latitude: 39.950967 * Longitude: 3.950883
Date/Time Start: 2011-11-03T14:54:00 * Date/Time End: 2011-11-03T14:54:00
Minimum DEPTH, sediment/rock: 0.0000 m * Maximum DEPTH, sediment/rock: 0.5275 m
Event(s):
RAT_collection * Latitude: 39.950967 * Longitude: 3.950883 * Date/Time: 2011-11-03T14:54:00 * Elevation: 80.0 m * Location: Murada Cave, Menorca, Spain * Method/Device: Speleothem sample (SPS)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1DEPTH, sediment/rockDepth sedmTorner, JuditGeocode
2Age, datedAge datedka BPTorner, Juditsee reference(s)
3Age, error to olderAge e +ka BPTorner, Judit
4Age, error to youngerAge e -ka BPTorner, Judit
5Age, uncertainty maximum/oldAge unc maxkaTorner, Judit
6Age, uncertainty minimum/youngAge unc minkaTorner, Judit
7Magnesium/Calcium ratioMg/Cammol/molTorner, JuditInductively coupled plasma-mass spectroscopy (ICP-MS), Agilent, 7500-ceMg(24)/Ca(43)
8Magnesium/Calcium ratio, standard deviationMg/Ca std dev±Torner, Judit
9δ13C, carbonateδ13C carb‰ PDBTorner, JuditMass spectrometer, Thermo Finnigan MAT 252 with Kiel III automated carbonate preparation deviceAnalytical uncertainty ≤0.04 ‰ VPDB
10δ18O, carbonateδ18O carb‰ PDBTorner, JuditMass spectrometer, Thermo Finnigan MAT 252 with Kiel III automated carbonate preparation deviceAnalytical uncertainty ≤0.08 ‰ VPDB
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2821 data points

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