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Paul, Sophie Anna Luise (2025): Dissolved rare earth element and yttrium and manganese concentrations in pore water from the Pacific [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.982624, In: Paul, Sophie Anna Luise; Scholz, Florian; Fröhberg, Nico; Schmidt, Katja (2025): Neodymium isotope compositions, rare earth element concentrations and ancillary geochemical data for sediment cores, pore water and bottom seawater from the Atlantic and Pacific Oceans [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.981262

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Published: 2025-08-26DOI registered: 2025-09-24

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Abstract:
The Neodymium (Nd) isotopic signature (εNd) has been widely used as a proxy to reconstruct past ocean circulation. Recently it has been increasingly questioned which archives can be reliably used to extract authigenic εNd used for the reconstruction of past ocean circulation and under which environmental conditions bottom seawater εNd are altered and the original water mass signature is overprinted. Pore waters of marine sediments are the key environment in which early diagenetic exchange processes between seawater-derived Nd and terrigenous solid phases take place. This dataset contains dissolved rare earth element and yttrium (REY) and manganese (Mn) concentrations of pore water and MUC overlying bottom water from the abyssal Pacific Ocean.
Samples were collected during cruises SO239 in 2015, SO240 in 2015, and SO268 in 2019. Pore waters were sampled from MUC liners and for some samples several liners were pooled to acquire sufficient volume for REY analyses. Sediments were centrifuged and the supernatant (i.e., the pore water) and the MUC bottom water were filtered through 0.2 µm pore size by different techniques (polyethersylfone (PES) syringe filters, cellulose acetate (CA) syringe filters, CA membrane filters using a water jet pump). These different filtration methods lead to comparable results. Pore water was preserved by acidification to ~ pH 1.8 with concentrated suprapure or ultrapure HCl.
REY and Mn were preconcentrated offline using a seaFAST (Elemental Scientific Inc., Nebraska, USA) with a 10 mL sample loop and using a NOBIAS PA-1 resin column. Samples were spiked with 100 ppt Tm and In to monitor yields and all REY were Tm corrected at the end of the data evaluation. Correction was usually within 5-15%. Preconcentrated samples were measured on a Thermo Fisher Element HR-ICP-MS (GEOMAR, Kiel) coupled to a CETAC Aridus 2 desolvating nebulizer for increased sensitivity and decreased oxide formation.
Funding:
German Research Foundation (DFG), grant/award no. 458637508: Early diagenetic alteration of rare earth element and yttrium (REY) signals in marine sediments and impact on the use of REY as tracers in past and present marine environments
Coverage:
Median Latitude: 12.981316 * Median Longitude: -121.211723 * South-bound Latitude: 11.818830 * West-bound Longitude: -125.924517 * North-bound Latitude: 14.112867 * East-bound Longitude: -117.017317
Date/Time Start: 2015-03-30T10:35:00 * Date/Time End: 2019-05-08T06:52:59
Minimum DEPTH, sediment/rock: 0.00 m * Maximum DEPTH, sediment/rock: 0.29 m
Event(s):
SO239_66-1  * Latitude: 11.818830 * Longitude: -117.552170 * Date/Time: 2015-03-30T10:35:00 * Elevation: -4314.8 m * Location: North Pacific Ocean * Campaign: SO239 * Basis: Sonne_2 * Method/Device: Multicorer with television (TVMUC)
SO240_18-1  * Latitude: 13.118500 * Longitude: -118.127670 * Date/Time: 2015-05-12T17:48:00 * Elevation: -4319.2 m * Location: North Pacific Ocean * Campaign: SO240 * Basis: Sonne_2 * Method/Device: MultiCorer (MUC)
SO268/1_5-1 (MUC-01)  * Latitude: 11.931200 * Longitude: -117.026467 * Date/Time: 2019-02-28T15:52:24 * Elevation: -4081.5 m * Location: Clarion-Clipperton Fraction Zone, North East Pacific Ocean * Campaign: SO268/1 * Basis: Sonne_2 * Method/Device: Multicorer with television (TVMUC) * Comment: GER Trial; TV-MUC
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1431 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Date/Time

Latitude

Longitude

Station

Depth sed [m]

Depth top [m]

Depth bot [m]

Sample label
10 
Filter
11 
Y [µg/kg]
12 
La [µg/kg]
13 
Ce [µg/kg]
14 
Pr [µg/kg]
15 
Nd [µg/kg]
16 
Sm [µg/kg]
17 
Eu [µg/kg]
18 
Gd [µg/kg]
19 
Tb [µg/kg]
20 
Dy [µg/kg]
21 
Ho [µg/kg]
22 
Er [µg/kg]
23 
Yb [µg/kg]
24 
Lu [µg/kg]
25 
Mn [µg/kg]
SO268/1_18-1 2019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.000.000.0018MUC bw REYPES syringe filter0.026220.007860.001060.001420.006310.001390.000380.002040.000320.002330.000600.001950.002200.00036
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.060.020.1018MUC 2-10 cm REYPES syringe filter0.022860.009350.001180.001630.007040.001630.000390.002180.000340.002280.000550.001760.002000.00034
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.000.000.0018MUC bw TMPES syringe filter0.024380.007660.000930.001410.006290.001340.000340.001990.000300.002120.000550.001850.002050.00032
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.010.000.0218MUC 0-2 cm TMPES syringe filter0.032600.013370.001680.002200.010340.002320.000640.003280.000500.003460.000830.002690.003060.00054
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.030.020.0418MUC 2-4 cm TMPES syringe filter0.032730.013180.002750.002130.009630.002330.000660.003280.000510.003610.000840.002760.003410.00060
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.050.040.0618MUC 4-6 cm TMPES syringe filter0.023610.009950.001080.001660.007080.001590.000430.002260.000330.002420.000550.001800.002060.00035
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.070.060.0818MUC 6-8 cm TMPES syringe filter0.022900.011010.002050.001960.008600.001930.000460.002500.000370.002330.000560.001730.001950.00030
SO268/1_18-12019-03-03T09:33:0711.9242-117.0173SO268 18MUC0.090.080.1018MUC 8-10 cm TMPES syringe filter0.023380.012000.004220.002360.009770.002160.000550.002760.000390.002710.000580.001920.001920.00030
SO268/1_5-1 2019-02-28T15:52:2411.9312-117.0265SO268 005TVMUC0.000.000.00005TVMUC bw TMPES syringe filter0.017580.005840.001120.001070.004730.001050.000250.001430.000210.001520.000370.001310.001300.00023
SO268/1_5-12019-02-28T15:52:2411.9312-117.0265SO268 005TVMUC0.010.000.02005TVMUC 0-2 cm TMPES syringe filter0.030070.011620.001280.001870.008370.001810.000540.002680.000420.003080.000750.002430.002690.00047
SO268/1_5-12019-02-28T15:52:2411.9312-117.0265SO268 005TVMUC0.030.020.04005TVMUC 2-4 cm TMPES syringe filter0.028310.010530.001850.001800.008020.001860.000500.002630.000410.002920.000660.002250.002570.00045
SO268/1_5-12019-02-28T15:52:2411.9312-117.0265SO268 005TVMUC0.050.040.06005TVMUC 4-6 cm TMPES syringe filter0.021830.009170.000940.001480.006530.001330.000350.001870.000280.002070.000480.001680.001780.00030
SO268/1_5-12019-02-28T15:52:2411.9312-117.0265SO268 005TVMUC0.070.060.08005TVMUC 6-8 cm TMPES syringe filter0.024150.009600.001330.001710.007460.001630.000490.002250.000330.002290.000540.001770.001940.00031
SO268/1_5-12019-02-28T15:52:2411.9312-117.0265SO268 005TVMUC0.090.080.10005TVMUC 8-10 cm TMPES syringe filter0.018840.008100.000980.001460.006140.001300.000320.001730.000260.001900.000430.001420.001500.00024
SO268/2_171-1 2019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.000.000.00171MUC bw liner 3 TMPES syringe filter0.025000.007840.001530.001420.006130.001390.000360.001820.000290.002240.000540.001860.001920.00033
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.000.000.00171MUC bw liner 10 TMPES syringe filter0.030560.009050.001530.001820.008560.001900.000510.002560.000410.002900.000700.002380.002510.00041
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.010.000.02171MUC 0-2 cm TMPES syringe filter0.036870.014050.003920.002540.011420.002710.000730.003680.000590.004030.000930.003110.003750.00068
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.030.020.04171MUC 2-4 cm TMPES syringe filter0.027210.012250.003100.002080.008930.001850.000540.002670.000390.002820.000660.002080.002280.00038
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.050.040.08171MUC 4-6 cm TMPES syringe filter0.022790.010730.001430.001750.007550.001580.000450.002120.000340.002250.000530.001750.001820.00029
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.080.060.10171MUC 6-10 cm TMPES syringe filter0.019720.009020.001250.001540.006630.001380.000360.001830.000270.001850.000460.001380.001490.00023
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.160.140.18171MUC 14-18 cm TMPES syringe filter0.020020.009480.002500.001810.007820.001710.000430.002130.000330.002180.000490.001500.001590.00025
SO268/2_171-12019-05-08T03:41:3011.8500-117.0554SO268 171MUC0.200.180.22171MUC 18-22 cm cm TMPES syringe filter0.050770.031190.047740.008650.036390.008420.002110.009340.001380.008390.001610.004790.004500.00068
SO268/2_172-1 2019-05-08T06:52:5911.8408-117.0552SO268 172MUC0.000.000.00172MUC bw REYPES syringe filter0.022640.007100.001570.001340.005850.001280.000390.001740.000290.001950.000510.001700.001710.00029
SO268/2_172-12019-05-08T06:52:5911.8408-117.0552SO268 172MUC0.010.000.02172MUC 0-2 cm REYPES syringe filter0.036890.012070.001910.002200.010050.002270.000680.003390.000550.003850.000910.003180.004070.00073
SO268/2_172-12019-05-08T06:52:5911.8408-117.0552SO268 172MUC0.060.050.08172MUC 4-8 cm REYPES syringe filter0.022040.009960.001360.001680.007200.001500.000420.002050.000310.002170.000470.001570.001690.00028
SO268/2_172-12019-05-08T06:52:5911.8408-117.0552SO268 172MUC0.100.080.12172MUC 8-12 cm REYPES syringe filter0.019140.008980.002100.001690.006990.001530.000410.002000.000300.002040.000460.001400.001550.00025
SO268/2_172-12019-05-08T06:52:5911.8408-117.0552SO268 172MUC0.140.120.16172MUC 12-16 cm REYPES syringe filter0.021070.010190.002470.002110.009060.002150.000510.002340.000370.002430.000540.001700.001660.00026
SO268/2_172-12019-05-08T06:52:5911.8408-117.0552SO268 172MUC0.180.160.20172MUC 16-20 cm REYPES syringe filter0.019500.008900.002100.001780.007570.001670.000440.002010.000310.002180.000490.001470.001590.00023
SO268/1_67-1 2019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.000.000.0067MUC bw REYPES syringe filter0.022370.010960.006120.001580.007110.001500.000400.001950.000320.002330.000550.001800.001930.00032
SO268/1_67-12019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.000.000.0067MUC bw TMPES syringe filter0.025130.008400.001570.001720.007660.001700.000460.002290.000370.002710.000630.002090.002310.00038
SO268/1_67-12019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.010.000.0267MUC 0-2 cm TMPES syringe filter0.025810.010600.001660.001860.008050.001850.000530.002710.000420.003040.000700.002300.002820.00049
SO268/1_67-12019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.030.020.0467MUC 2-4 cm TMPES syringe filter0.020580.010230.001630.001840.007900.001640.000470.002260.000350.002400.000540.001660.001840.00030
SO268/1_67-12019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.050.040.0667MUC 4-6 cm TMPES syringe filter0.018740.009780.001650.001780.007860.001630.000450.002180.000330.002230.000500.001600.001620.00026
SO268/1_67-12019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.070.060.0867MUC 6-8 cm TMPES syringe filter0.022600.012390.002440.002410.010190.002320.000560.002850.000430.002880.000630.001910.001830.00029
SO268/1_67-12019-03-18T11:51:4914.1049-125.8613SO268 67MUC0.090.080.1067MUC 8-10 cm TMPES syringe filter0.023330.013160.002710.002680.011410.002530.000690.003130.000470.003110.000650.001980.001980.00030
SO268/1_65-1 2019-03-18T05:05:2414.1129-125.8716SO268 65MUC0.000.000.0065MUC bw TMPES syringe filter0.020380.006790.001070.001330.005880.001320.000380.001680.000280.002050.000500.001630.001880.00030
SO268/1_65-12019-03-18T05:05:2414.1129-125.8716SO268 65MUC0.010.000.0265MUC 0-2 cm TMPES syringe filter0.021300.009480.001040.001610.006950.001490.000420.002070.000340.002400.000570.001810.002150.00036
SO268/1_65-12019-03-18T05:05:2414.1129-125.8716SO268 65MUC0.030.020.0465MUC 2-4 cm TMPES syringe filter0.021840.010390.001230.001840.007970.001740.000470.002340.000350.002560.000570.001810.001900.00032
SO268/1_65-12019-03-18T05:05:2414.1129-125.8716SO268 65MUC0.050.040.0665MUC 4-6 cm TMPES syringe filter0.019470.010180.001180.001790.007590.001660.000440.002120.000320.002240.000510.001610.001650.00026
SO268/1_65-12019-03-18T05:05:2414.1129-125.8716SO268 65MUC0.070.060.0865MUC 6-8 cm TMPES syringe filter0.018760.010200.001460.001750.007610.001590.000420.002040.000310.002140.000480.001440.001490.00024
SO268/1_65-12019-03-18T05:05:2414.1129-125.8716SO268 65MUC0.090.080.1065MUC 8-10 cm TMPES syringe filter0.021380.011660.002110.002230.009170.002040.000560.002590.000390.002580.000580.001700.001640.00027
SO268/1_79-1 2019-03-21T09:38:3914.0365-125.9245SO268 79MUC0.000.000.0079MUC bw TMPES syringe filter0.021400.006760.001370.001370.006050.001300.000380.001770.000300.002180.000520.001730.001950.00031
SO268/1_79-12019-03-21T09:38:3914.0365-125.9245SO268 79MUC0.010.000.0279MUC 0-2 cm TMPES syringe filter0.028750.010760.001600.002040.009120.002090.000610.002950.000480.003480.000780.002690.003140.00056
SO268/1_79-12019-03-21T09:38:3914.0365-125.9245SO268 79MUC0.030.020.0479MUC 2-4 cm TMPES syringe filter0.024610.010810.001240.001820.007880.001820.000530.002510.000410.002860.000670.002100.002330.00038
SO268/1_79-12019-03-21T09:38:3914.0365-125.9245SO268 79MUC0.050.040.0679MUC 4-6 cm TMPES syringe filter0.023060.011390.001440.001910.008320.001930.000530.002490.000400.002730.000600.001930.002060.00033
SO268/1_79-12019-03-21T09:38:3914.0365-125.9245SO268 79MUC0.070.060.0879MUC 6-8 cm TMPES syringe filter0.022400.011750.002440.002020.009060.001840.000510.002560.000370.002690.000590.001890.001930.00032
SO268/1_79-12019-03-21T09:38:3914.0365-125.9245SO268 79MUC0.090.080.1079MUC 8-10 cm TMPES syringe filter0.022560.011960.001630.002070.008810.001920.000520.002570.000370.002550.000580.001810.001820.00029
SO268/2_136-1 2019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.000.000.00136MUC bw TM liner 2PES syringe filter0.027330.009220.001600.001840.008340.001790.000500.002500.000410.002840.000670.002310.002500.00041
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.000.000.00136MUC bw TM liner 12PES syringe filter0.018760.006650.001330.001340.005700.001260.000350.001630.000250.001870.000460.001500.001710.00026
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.000.000.00136MUC bw TM liner 15PES syringe filter0.025760.008380.000980.001630.007370.001600.000430.002090.000360.002550.000620.002120.002450.00038
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.010.000.02136MUC 0-2 cm TMPES syringe filter0.029300.011720.002990.002260.010020.002370.000640.003160.000490.003590.000780.002730.003270.00058
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.030.020.04136MUC 2-4 cm TMPES syringe filter0.024300.012200.002540.001960.008520.001790.000510.002570.000380.002810.000600.002030.002150.00035
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.050.040.06136MUC 4-6 cm TMPES syringe filter0.023180.011850.001610.001960.008200.001740.000540.002490.000380.002540.000590.001940.001990.00032
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.080.060.10136MUC 6-10 cm TMPES syringe filter0.021950.011960.002330.001970.008470.001820.000490.002490.000360.002500.000560.001730.001900.00029
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.120.100.14136MUC 10-14 cm TMPES syringe filter0.022060.012430.003480.002160.009220.002110.000540.002580.000410.002650.000580.001770.001760.00027
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.160.140.18136MUC 14-18 cm TMPES syringe filter0.022070.012260.005950.002170.009100.001970.000520.002640.000400.002710.000590.001900.001840.00029
SO268/2_136-12019-04-18T12:02:5914.0251-125.9206SO268 136MUC0.200.180.22136MUC 18-22 cm TMPES syringe filter0.017850.009880.008400.001730.007430.001640.000410.002070.000310.002140.000470.001460.001590.00024
SO268/2_139-1 2019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.000.000.00139MUC bw REYPES syringe filter0.019470.006500.001150.001300.005810.001270.000340.001730.000270.002090.000470.001600.001620.00028
SO268/2_139-12019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.010.000.02139MUC 0-2 cm REYPES syringe filter0.027050.010890.001790.001960.008680.002030.000550.002760.000460.003270.000740.002500.003050.00053
SO268/2_139-12019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.030.020.04139MUC 2-4 cm REYPES syringe filter0.022720.010360.001460.001800.007910.001740.000470.002370.000360.002570.000590.001900.001970.00034
SO268/2_139-12019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.060.040.08139MUC 4-8 cm REYPES syringe filter0.020530.010720.002250.001790.007400.001570.000440.002090.000320.002210.000510.001610.001650.00026
SO268/2_139-12019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.100.080.12139MUC 8-12 cm REYPES syringe filter0.022350.012750.003600.002410.010260.002190.000600.002780.000410.002780.000610.001860.001800.00028
SO268/2_139-12019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.140.120.16139MUC 12-16 cm REYPES syringe filter0.020500.012630.003280.002140.009060.001840.000520.002520.000370.002480.000520.001550.001610.00024
SO268/2_139-12019-04-19T11:48:2914.0316-125.9167SO268 139MUC0.180.160.20139MUC 16-20 cm REYPES syringe filter0.020730.012370.004600.002380.009830.002100.000550.002800.000390.002580.000560.001660.001650.00024
SO240_18-1 2015-05-12T17:48:0013.1185-118.1277SO240 18MUC0.000.000.00SO240 18MUC bwCA membrane filter0.031780.008860.004960.001710.007430.001730.000420.002400.000380.002700.000670.002330.002540.000421.746
SO240_18-12015-05-12T17:48:0013.1185-118.1277SO240 18MUC0.010.000.02SO240 18MUC 0-2 cmCA syringe filter0.069170.028510.015060.006940.030090.007100.001850.008670.001340.008810.001920.006080.006580.001122.588
SO240_18-12015-05-12T17:48:0013.1185-118.1277SO240 18MUC0.080.070.09SO240 18MUC 7-9 cmCA syringe filter0.044340.023970.011510.005180.021570.004960.001220.005820.000850.005200.001090.003330.003070.000483.691
SO240_18-12015-05-12T17:48:0013.1185-118.1277SO240 18MUC0.150.140.16SO240 18MUC 14-16 cmCA syringe filter0.056380.032840.010620.007150.029080.006210.001560.007680.001100.006700.001400.004200.003650.000560.960
SO240_18-12015-05-12T17:48:0013.1185-118.1277SO240 18MUC0.220.210.23SO240 18MUC 21-23 cmCA syringe filter0.050190.028700.017270.006780.027890.006490.001560.007400.001090.006740.001350.004050.003610.000550.851
SO240_18-12015-05-12T17:48:0013.1185-118.1277SO240 18MUC0.290.280.30SO240 18MUC 28-30 cmCA syringe filter0.079470.045070.026510.012270.050410.012300.003030.013450.001950.011650.002320.006690.005820.000900.289
SO239_66-1 2015-03-30T10:35:0011.8188-117.5522SO239 66MUC0.000.000.0066MUC bwCA membrane filter0.030910.008110.003530.001500.006790.001480.000410.002160.000370.002600.000640.002280.002450.00041
SO239_66-12015-03-30T10:35:0011.8188-117.5522SO239 66MUC0.010.000.0266MUC 0-2 cmCA syringe filter0.039310.014660.003140.002760.011830.002850.000770.003990.000610.004190.000930.003110.003530.00057
SO239_66-12015-03-30T10:35:0011.8188-117.5522SO239 66MUC0.080.070.0966MUC 7-9 cmCA syringe filter0.025350.013950.002960.002200.009220.002040.000520.002690.000400.002520.000550.001780.001650.00027
SO239_66-12015-03-30T10:35:0011.8188-117.5522SO239 66MUC0.150.140.1666MUC 14-16 cmCA syringe filter0.025510.014480.003860.002450.010010.002190.000560.002790.000420.002590.000570.001800.001640.00026
SO239_66-12015-03-30T10:35:0011.8188-117.5522SO239 66MUC0.220.210.2366MUC 21-23 cmCA syringe filter0.026920.015230.004790.002650.010720.002290.000580.003010.000440.002730.000590.001890.001640.00026