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Arinaitwe, Kenneth; Khoo, Siao Jean; Beck, Aaron; Greinert, Jens; Achterberg, Eric Pieter (2025): Munition compound data for water samples collected from German and Danish waters of Baltic Sea during ALKOR cruise AL603 in October 2023 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.982508

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Published: 2025-11-18DOI registered: 2025-12-17

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Abstract:
This dataset consists of munition compound data from the analysis of water samples collected along a cruise track that went through German and Danish waters of the western Baltic Sea in October 2023 during ALKOR cruise AL603. The cruise track started and ended in the Bay of Kiel, via the Little Belt, Bay of Aarhus, Great Belt and Bay of Mecklenburg. Water column samples were collected from 99 stations. Surface and deep-water samples were collected using a rosette of Niskin bottles. A CTD sensor package was also mounted on the the Niskin rosette frame. Samples (1L) were extracted onboard onto solid phase extraction (SPE) columns. Munition compounds were eluted from the SPE columns using acetonitrile, concentrated and reconstituted in 50% methanol/water. The samples were analyzed by ultra high-performance liquid chromatography and high-resolution, atmospheric pressure chemical ionization mass spectrometry.
Keyword(s):
Baltic Sea; Dumped munitions; Marine environment; Marine Pollution; Munition compounds; World War II
Supplement to:
Arinaitwe, Kenneth; Khoo, Siao Jean; Raupers, Björn; Kampmeier, Mareike; Beck, Aaron; Gledhill, Martha; Greinert, Jens; Achterberg, Eric Pieter (in prep.): Distribution of WWII legacy munition compounds in the Baltic Sea; Insights from assessment of the water column over the 2020-2023 study period.
References:
Gledhill, Martha; Beck, Aaron; Stamer, Beate; Schlosser, Christian; Achterberg, Eric Pieter (2019): Quantification of munition compounds in the marine environment by solid phase extraction – ultra high performance liquid chromatography with detection by electrospray ionisation – mass spectrometry. Talanta, 200, 366-372, https://doi.org/10.1016/j.talanta.2019.03.050
Funding:
Federal Ministry of Education and Research (BMBF), grant/award no. 03F0912A: DAM sustainMare - CONMAR, GEOMAR
Federal Ministry of Education and Research (BMBF), grant/award no. 03F0942A: VAMOS - Verbesserte Autonome Meeresboden Observations-Systeme
Coverage:
Median Latitude: 54.854343 * Median Longitude: 10.916465 * South-bound Latitude: 54.010000 * West-bound Longitude: 9.720000 * North-bound Latitude: 56.220000 * East-bound Longitude: 12.640000
Date/Time Start: 2023-10-03T06:37:57 * Date/Time End: 2023-10-15T18:32:34
Minimum DEPTH, water: 1.273 m * Maximum DEPTH, water: 34.754 m
Event(s):
AL603_1-1 * Latitude: 54.340000 * Longitude: 10.170000 * Date/Time: 2023-10-03T06:17:53 * Elevation: -12.0 m * Campaign: AL603 (MecoMM-BS - II) * Basis: Alkor (1990) * Method/Device: CTD/Rosette (CTD-RO)
AL603_2-1 * Latitude: 54.370000 * Longitude: 10.190000 * Date/Time: 2023-10-03T07:03:10 * Elevation: -11.0 m * Campaign: AL603 (MecoMM-BS - II) * Basis: Alkor (1990) * Method/Device: CTD/Rosette (CTD-RO)
AL603_3-1 * Latitude: 54.420000 * Longitude: 10.220000 * Date/Time: 2023-10-03T07:38:12 * Elevation: -8.0 m * Campaign: AL603 (MecoMM-BS - II) * Basis: Alkor (1990) * Method/Device: CTD/Rosette (CTD-RO)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventArinaitwe, Kenneth
2Device typeDeviceArinaitwe, Kenneth
3LATITUDELatitudeArinaitwe, KennethGeocode – Geocode rounded to 2 decimal places
4LONGITUDELongitudeArinaitwe, KennethGeocode – Geocode rounded to 2 decimal places
5PositionPositionArinaitwe, Kennethunified bottle position
6Bottle numberBottleArinaitwe, Kennethoriginal bottle position
7DATE/TIMEDate/TimeArinaitwe, KennethGeocode
8DEPTH, waterDepth watermArinaitwe, KennethGeocode – sampled depth
91,3,5,7-tetranitro-1,3,5,7-tetrazocaneHMXng/lArinaitwe, KennethSolid phase extraction (SPE) followed by high performance liquid chromatography (HPLC) coupled with electrospray ionization mass spectrometry (ESI-MS) after Gledhill et al. (2019)
101,3,5-trinitro-1,3,5-triazinaneRDXng/lArinaitwe, KennethSolid phase extraction (SPE) followed by high performance liquid chromatography (HPLC) coupled with electrospray ionization mass spectrometry (ESI-MS) after Gledhill et al. (2019)
111,3-dinitrobenzeneDNBng/lArinaitwe, KennethSolid phase extraction (SPE) followed by high performance liquid chromatography (HPLC) coupled with electrospray ionization mass spectrometry (ESI-MS) after Gledhill et al. (2019)
122,4,6-trinitrotolueneTNTng/lArinaitwe, KennethSolid phase extraction (SPE) followed by high performance liquid chromatography (HPLC) coupled with electrospray ionization mass spectrometry (ESI-MS) after Gledhill et al. (2019)
134-amino-2,6-dinitrotoluene4-ADNTng/lArinaitwe, KennethSolid phase extraction (SPE) followed by high performance liquid chromatography (HPLC) coupled with electrospray ionization mass spectrometry (ESI-MS) after Gledhill et al. (2019)
142-amino-4,6-dinitrotoluene2-ADNTng/lArinaitwe, KennethSolid phase extraction (SPE) followed by high performance liquid chromatography (HPLC) coupled with electrospray ionization mass spectrometry (ESI-MS) after Gledhill et al. (2019)
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1782 data points

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