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Paine, Alice R; Frieling, Joost; Shanahan, Timothy M; Mather, Tamsin A; McKay, Nicholas; Robinson, Stuart A; Pyle, David A; Fendley, Isabel M; Kiely, R; Gosling, William D (2025): Evidence for millennial-scale interactions between Hg cycling and hydroclimate from Lake Bosumtwi, Ghana [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.981521 (DOI registration in progress)

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Published: 2025-04-28

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Abstract:
The datasets include measurements of mercury, total organic, and inorganic carbon in sediment samples from core BOS04-5B, extracted from Lake Bosumtwi in 2004 as part of the ICDP Lake Bosumtwi Drilling Project. Lake Bosumtwi is the only natural lake in Ghana, western Africa (6°300 N, 1°250 W), and occupies a meteorite impact crater dated to 1.08 ± 0.04 Ma: one of the youngest and best-preserved impact craters on Earth. Focusing on the uppermost ∼ 47 m of the BOS04-5B sediment record, this data was generated to assesses whether major shifts in local hydroclimate produced measurable changes in how Hg has been transported to, and buried within, this system since ∼ 96 ka. Total Hg (HgT) in the bulk sediments of the core was measured using an RA-915 portable mercury analyser with a PYRO-915+ pyrolyser, Lumex, at the University of Oxford (UK). For this study, we analysed 165 samples spanning the composite depth interval 47.7 to 0 m, with an average temporal resolution of ∼ 0.6 ka between each sample (range: 0.01 to 5.85 kyr). Quantitative values for total organic carbon (TOC) and total inorganic carbon (TIC) content were measured on the same powdered sample material also analysed for Hg, using a Stroehlein Coulomat 702 at the University of Oxford (UK). Analytical reproducibility for this instrument was ≤ 0.2% based on repeat measurements, with a detection limit of ca. 0.1 %-0.2 %.
Keyword(s):
biogeochemical cycles; lake sediment proxies; mercury; organic carbon content; XRF
Related to:
Paine, Alice R; Frieling, Joost; Shanahan, Timothy M; Mather, Tamsin A; McKay, Nicholas; Robinson, Stuart A; Pyle, David M; Fendley, Isabel M; Kiely, R; Gosling, William D (2025): Evidence for millennial-scale interactions between Hg cycling and hydroclimate from Lake Bosumtwi, Ghana. Climate of the Past, 21(4), 817-839, https://doi.org/10.5194/cp-21-817-2025
Funding:
European Commission (EC), grant/award no. 818717: Revealing hidden volcanic triggers for global environmental change events in Earth's geological past using mercury (Hg)
Coverage:
Latitude: 6.506002 * Longitude: -1.410212
Date/Time Start: 2004-07-15T00:00:00 * Date/Time End: 2004-10-15T00:00:00
Minimum DEPTH, sediment/rock: 0.200 m * Maximum DEPTH, sediment/rock: 47.724 m
Event(s):
GLAD6_BOS04_5B * Latitude: 6.506002 * Longitude: -1.410212 * Date/Time Start: 2004-07-15T00:00:00 * Date/Time End: 2004-10-15T00:00:00 * Location: Lake Bosumtwi, Ghana * Method/Device: Core (CORE)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Core section labelSec labelPaine, Alice R
2DEPTH, sediment/rockDepth sedmPaine, Alice RGeocode
3MercuryHgµg/kgPaine, Alice RMercury analyzer, Lumex Instruments, RA-915M; coupled with PYRO-915+ thermal decomposition attachment
4Carbon, organic, totalTOC%Paine, Alice RCoulomat, STRÖHLEIN, 702[wt %]
5Carbon, inorganic, totalTIC%Paine, Alice RCoulomat, STRÖHLEIN, 702[wt %]
6Accumulation rate, mercuryAcc rate Hgmg/m2/kaPaine, Alice RCalculated
7Density, dry bulkDBDg/cm3Paine, Alice RCalculated
8AGEAgeka BPPaine, Alice RGeocode
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
976 data points

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