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O'Sullivan, Edel Mary; Steiner, Zvi (2025): Dissolved major element (Ca, Sr, Mg, K, Li) concentration data of the western Atlantic Ocean meridional section GA02 (GEOTRACES) and Arctic Ocean cruise JR271 (BODC) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.977811

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Published: 2025-03-24DOI registered: 2025-04-22

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Abstract:
This dataset presents salinity-normalized dissolved major element (Ca, Mg, K, Sr, Li) concentrations in the western Atlantic Ocean and the Arctic Ocean. Atlantic samples were collected along the western meridional GEOTRACES section GA02 comprised of cruises JR057 (Punta Arenas (Chile) 02-03-2011 to Las Palmas (Spain) 06-04-2011 ), PE321 (Bermuda 11-06-2010 to Fortaleza (Brazil) 08-07-2010), PE319 (Scrabster 28-04-2010 to Bermuda 25-05-2010), and PE358 (Reykjavik (Iceland) 29-07-2012 to Texel (Netherlands) 19-08-2012). Samples for dissolved major ions were sub-sampled from trace metal sample collection stored at the Royal Netherlands Institute for Sea Research (NIOZ). Samples for the Arctic Ocean were collected on BODC cruise JR271 (Immingham 01-06-2012 to Reykjavik 02-07-2012). Samples were analysed for Na, Ca, Mg, K, Li and Sr using a Varian-720 ES ICP-OES. Samples were diluted by a factor of 78-82 in 0.12 M HCl to the same final salinity. Multiple spectral lines were selected for each element, and samples were corrected for instrumental drift by sample-standard bracketing with IAPSO P157 diluted to the same final salinity. Calibration was performed on 7 dilutions of IAPSO P157. Element-to-sodium ratios were calculated for all combinations of spectral lines. Assuming a constant Na-to-salinity (PSU)=35 ratio, the element/Na ratios were multiplied by 0.46847 µmol kg-1 to obtain the salinity (PSU)-normalized element concentration, and by the ratio of practical to absolute salinity (TEOS-10). The TEOS-10 absolute salinities were calculated from EOS-80 values using the Gibb's Oceanographic Toolbox using the R package 'gsw' (v 1.1-1).
Keyword(s):
Arctic Ocean; Atlantic; calcium; GEOTRACES; magnesium; major elements; Potassium; Strontium
Funding:
Deutsche Forschungsgemeinschaft, Bonn (DFG), grant/award no. 458035111: Biogeochemistry of major elements in the Atlantic and Pacific Oceans
Coverage:
Median Latitude: 8.844647 * Median Longitude: -42.398741 * South-bound Latitude: -49.547200 * West-bound Longitude: -67.072690 * North-bound Latitude: 78.992760 * East-bound Longitude: 8.442730
Minimum DEPTH, water: 8.0 m * Maximum DEPTH, water: 5804.0 m
Event(s):
GA02/64PE321_21_01_ROS * Latitude: 31.666700 * Longitude: -64.166690 * Campaign: 64PE321 * Basis: Pelagia * Method/Device: CTD/Rosette (CTD-RO)
GA02/64PE321_25_02_ROS * Latitude: 24.714400 * Longitude: -67.072690 * Campaign: 64PE321 * Basis: Pelagia * Method/Device: CTD/Rosette (CTD-RO)
GA02/64PE321_26_02_ROS * Latitude: 23.274700 * Longitude: -65.552800 * Campaign: 64PE321 * Basis: Pelagia * Method/Device: CTD/Rosette (CTD-RO)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventO'Sullivan, Edel Mary
2CampaignCampaignO'Sullivan, Edel Mary
3Station labelStationO'Sullivan, Edel Mary
4LONGITUDELongitudeO'Sullivan, Edel MaryGeocode
5LATITUDELatitudeO'Sullivan, Edel MaryGeocode
6DEPTH, waterDepth watermO'Sullivan, Edel MaryCalculatedGeocode – Calculated average/mean values
7Bottle numberBottleO'Sullivan, Edel Mary
8SalinitySalO'Sullivan, Edel MaryCTDPSU
9Salinity, absoluteASALg/kgO'Sullivan, Edel MaryCalculatedcalculated from EOS-80 values using the Gibb's Oceanographic Toolbox using the R package 'gsw' (v 1.1-1)
10Temperature, waterTemp°CO'Sullivan, Edel MaryCTD
11CalciumCa2+mmol/kgO'Sullivan, Edel MaryICP-OES, VARIAN 720-ES
12Standard deviationStd dev±O'Sullivan, Edel MaryICP-OES, VARIAN 720-ESCalcium Average Deviation
13MagnesiumMg2+mmol/kgO'Sullivan, Edel MaryICP-OES, VARIAN 720-ES
14Standard deviationStd dev±O'Sullivan, Edel MaryICP-OES, VARIAN 720-ESMagnesium Average Deviation
15PotassiumK+mmol/kgO'Sullivan, Edel MaryICP-OES, VARIAN 720-ES
16Standard deviationStd dev±O'Sullivan, Edel MaryICP-OES, VARIAN 720-ESPotassium Average Deviation
17StrontiumSr2+µmol/kgO'Sullivan, Edel MaryICP-OES, VARIAN 720-ES
18Standard deviationStd dev±O'Sullivan, Edel MaryICP-OES, VARIAN 720-ESStrontium Average Deviation
19LithiumLiµmol/kgO'Sullivan, Edel MaryICP-OES, VARIAN 720-ES
20Standard deviationStd dev±O'Sullivan, Edel MaryICP-OES, VARIAN 720-ESLithium Average Deviation
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
13040 data points

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