Prow-Fleischer, Ashley; Blättler, Clara L; Todes, Jordan; Kemeny, Preston C; Todaro, Simona; He, Tianchen; van der Schootbrugge, Bas; Payne, Jonathan L (2025): Calcium and Trace Elemental Ratios of Late Triassic-Early Jurassic Carbonate Platforms (Mount Sparagio) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.975259
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Published: 2025-02-25 • DOI registered: 2025-03-26
Abstract:
Calcium isotope ratios (δ44Ca) and minor/trace elemental ratios (Mn, Sr, U, V, Cr, Fe /(Ca + Mg)) were measured from bulk carbonate powders in 2023 on samples collected in 2006 from an outcropping near Val Adrara, Lombardy Basin in the Italian Alps region using MC-ICP-MS at University of Chicago. Samples were collected with rock hammers and chemical measurements were performed on samples at an average resolution of 15 m. These deposits represent a shallow carbonate platform active during the Late Triassic (Rhaetian stage, ~199.7 Ma) to Early Jurassic (Hettangian stage, ~196.5 Ma)(van der Schootbrugge, 2008,doi:10.1029/2007GC001914). Carbon (δ13C), oxygen (δ18O), calcium (δ44Ca) isotope and minor/trace elemental ratios (Mn, Sr, U, V, Cr, Fe /(Ca + Mg)) were also measured in 2023 from samples collected from an outcrop near Mount Sparagio, Sicily in 2022. Carbon and oxygen isotope ratios were measured on a Finnigan MAT 253 mass spectrometer. Chemical analyses were performed at a resolution of approximately 5 m. These deposits represent a transitional to evaporitic setting during the Late Triassic (Rhaetian stage, exact dates uncertain) to Early Jurassic (Hettangian stage) (Todaro et al., 2022; doi:10.3389/feart.2022.875466). These analyses were performed to investigate potential differences in diagenetic alteration at the two sites, Val Adrara and Mount Sparagio, across the Triassic-Jurassic transition. The data is associated with the publication Prow-Fleischer et al., (2025), doi:10.1016/j.chemgeo.2024.122530.
Keyword(s):
Supplement to:
Prow-Fleischer, Ashley; Lu, Zunli; Blättler, Clara L; He, Tianchen; Singh, Pulkit; Kemeny, Preston C; Todes, Jordan; Pohl, Alexandre; Bhattacharya, Tripti; van de Schootbrugge, Bas; Wignall, Paul; Todaro, Simona; Payne, Jonathan L (2025): Calcium isotopes support spatial redox gradients on the Tethys European margin across the Triassic-Jurassic boundary. Chemical Geology, 673, 122530, https://doi.org/10.1016/j.chemgeo.2024.122530
Related to:
Prow-Fleischer, Ashley; Blättler, Clara L; Todes, Jordan; Kemeny, Preston C; Todaro, Simona; He, Tianchen; van der Schootbrugge, Bas; Payne, Jonathan L (2025): Calcium and Trace Elemental Ratios of Late Triassic-Early Jurassic Carbonate Platforms (Val Adrara) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.976695
References:
Todaro, Simona; Rigo, Manuel; Di Stefano, Pietro; Aiuppa, Alessandro; Chiaradia, Massimo (2022): End-Triassic Extinction in a Carbonate Platform From Western Tethys: A Comparison Between Extinction Trends and Geochemical Variations. Frontiers in Earth Science, 10, 875466, https://doi.org/10.3389/feart.2022.875466
van de Schootbrugge, Bas; Payne, Jonathan L; Tomasovych, Adam; Pross, Jörg; Fiebig, J; Benbrahim, M; Föllmi, Karl B; Quan, Tracy M (2008): Carbon cycle perturbation and stabilization in the wake of the Triassic-Jurassic boundary mass-extinction event. Geochemistry, Geophysics, Geosystems, 9(4), 2007GC001914, https://doi.org/10.1029/2007GC001914
Funding:
National Science Foundation (NSF), grant/award no. 2120406: Collaborative Research: Testing the reduction of aerobic habitat as a common kill mechanism for major mass extinction events
National Science Foundation (NSF), grant/award no. 2121445: Collaborative Research: Testing the reduction of aerobic habitat as a common kill mechanism for major mass extinction events
Coverage:
Latitude: 38.064167 * Longitude: 12.721944
Date/Time Start: 2022-10-01T00:00:00 * Date/Time End: 2022-10-01T00:00:00
Minimum Elevation: 580.0 m * Maximum Elevation: 580.0 m
Event(s):
Sparagio_Sicily (SP) * Latitude: 38.064167 * Longitude: 12.721944 * Date/Time: 2022-10-01T00:00:00 * Elevation: 580.0 m * Location: Sicily * Campaign: MountSparagio_Sicily * Basis: Sampling on land * Method/Device: Hammer (HAM)
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Sample code/label | Sample label | ||||
| 2 | LATITUDE | Latitude | Geocode | |||
| 3 | LONGITUDE | Longitude | Geocode | |||
| 4 | Stratigraphic height | Strat height | m | |||
| 5 | Date | Date | of analysis | |||
| 6 | δ13C, bulk carbonate | δ13C bulk carb | ‰ PDB | He, Tianchen | Mass spectrometer, Finnigan, MAT 253 | Samples are reported relative to seawater by setting the δ44/40Ca value of 915b equal to -1.15 ‰ |
| 7 | δ18O, bulk carbonate | δ18O bulk carb | ‰ PDB | He, Tianchen | Mass spectrometer, Finnigan, MAT 253 | |
| 8 | δ44/40 Ca, bulk carbonate | δ44/40 Ca bulk carb | ‰ ASW | Blättler, Clara L | Multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS), ThermoFisher Scientific, Neptune XT | |
| 9 | δ44/40 Ca, standard deviation | δ44/40 Ca std dev | ± | Blättler, Clara L | Multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS), ThermoFisher Scientific, Neptune XT | 1 sigma |
| 10 | Strontium/(Calcium+Magnesium) ratio | Sr/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | |
| 11 | Magnesium/(Calcium+Magnesium) ratio | Mg/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | |
| 12 | Uranium/(Calcium+Magnesium) ratio | U/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | |
| 13 | Vanadium/(Calcium+Magnesium) ratio | V/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | |
| 14 | Chromium/(Calcium+Magnesium) ratio | Cr/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | #0 = BD |
| 15 | Manganese/(Calcium+Magnesium) ratio | Mn/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | |
| 16 | Iron/(Calcium+Magnesium) ratio | Fe/(Ca+Mg) | mol/mol | Todes, Jordan | Inductively Coupled Plasma Mass Spectrometry; Thermo Fischer Scientific (USA), iCAP RQ | #0 = BDL |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
699 data points
Data
| 1 Sample label | 2 Latitude | 3 Longitude | 4 Strat height [m] | 5 Date | 6 δ13C bulk carb [‰ PDB] | 7 δ18O bulk carb [‰ PDB] | 8 δ44/40 Ca bulk carb [‰ ASW] | 9 δ44/40 Ca std dev [±] | 10 Sr/(Ca+Mg) [mol/mol] | 11 Mg/(Ca+Mg) [mol/mol] | 12 U/(Ca+Mg) [mol/mol] | 13 V/(Ca+Mg) [mol/mol] | 14 Cr/(Ca+Mg) [mol/mol] | 15 Mn/(Ca+Mg) [mol/mol] | 16 Fe/(Ca+Mg) [mol/mol] |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| SP0 | 38.064167 | 12.721944 | 0.00 | 2023-02-01 | 1.108 | -1.840 | |||||||||
| SP-2 | 38.064167 | 12.721944 | 2.00 | 2023-02-01 | 0.342 | -2.643 | -0.82 | 0.082 | 1.73E-04 | 1.48E-02 | 1.25E-07 | 1.20E-06 | 5.34E-06 | 4.63E-05 | 1.26E-04 |
| SP-4 | 38.064167 | 12.721944 | 9.20 | 2023-02-01 | 1.976 | 0.343 | -0.82 | 0.082 | 1.62E-04 | 3.19E-01 | 2.12E-07 | 2.47E-06 | 7.45E-06 | 4.40E-05 | 6.17E-04 |
| SP-8 | 38.064167 | 12.721944 | 14.90 | 2023-02-01 | -1.552 | -3.145 | -0.82 | 0.082 | 1.80E-04 | 3.10E-02 | 1.30E-07 | 2.26E-06 | 5.91E-06 | 3.02E-05 | 1.23E-04 |
| SP-12 | 38.064167 | 12.721944 | 19.90 | 2023-02-01 | -0.463 | -2.824 | -0.82 | 0.082 | 1.55E-04 | 1.33E-02 | 5.16E-08 | 3.83E-07 | 4.23E-06 | 7.07E-06 | 4.05E-05 |
| SP-17 | 38.064167 | 12.721944 | 28.25 | 2023-02-01 | -0.523 | -2.700 | -0.82 | 0.082 | 1.70E-04 | 1.50E-02 | 9.49E-08 | 9.46E-07 | 7.28E-06 | 1.77E-05 | 1.18E-04 |
| SP-19 | 38.064167 | 12.721944 | 33.35 | 2023-02-01 | 1.062 | -0.847 | -0.82 | 0.082 | 1.47E-04 | 6.80E-02 | 9.24E-08 | 2.35E-06 | 6.31E-06 | 2.41E-05 | 1.59E-04 |
| SP-21 | 38.064167 | 12.721944 | 37.95 | 2023-02-01 | 2.464 | 0.024 | |||||||||
| SP-26 | 38.064167 | 12.721944 | 47.25 | 2023-02-01 | -0.082 | -2.539 | -0.82 | 0.082 | 1.72E-04 | 1.28E-02 | 8.79E-08 | 1.04E-06 | 3.58E-06 | 2.53E-05 | 1.74E-04 |
| SP-29 | 38.064167 | 12.721944 | 52.95 | 2023-02-01 | -2.314 | -3.275 | -0.91 | 0.082 | 1.47E-04 | 1.21E-02 | 7.03E-08 | 6.50E-07 | 5.75E-06 | 1.66E-05 | 1.72E-04 |
| SP-32 | 38.064167 | 12.721944 | 57.95 | 2023-02-01 | -0.108 | -2.407 | -0.76 | 0.195 | 1.87E-04 | 5.25E-02 | 2.70E-07 | 3.48E-06 | 7.96E-06 | 3.77E-05 | 3.30E-04 |
| SP-36 | 38.064167 | 12.721944 | 62.75 | 2023-02-01 | 0.049 | -2.187 | -0.75 | 0.082 | 1.49E-04 | 5.76E-02 | 5.32E-08 | 6.53E-07 | 5.31E-06 | 2.70E-05 | 1.29E-04 |
| SP-38 | 38.064167 | 12.721944 | 69.75 | 2023-02-01 | -0.270 | -1.829 | -0.77 | 0.082 | 1.88E-04 | 6.34E-02 | 6.58E-08 | 1.01E-06 | 5.71E-06 | 3.57E-05 | 1.93E-04 |
| SP-41 | 38.064167 | 12.721944 | 75.55 | 2023-02-01 | 0.792 | -2.854 | -0.68 | 0.082 | 1.63E-04 | 1.24E-02 | 1.16E-07 | 9.63E-07 | 4.73E-06 | 9.02E-06 | 7.61E-05 |
| SP-43 | 38.064167 | 12.721944 | 79.85 | 2023-02-01 | -0.699 | -2.963 | -0.78 | 0.082 | 1.41E-04 | 1.18E-02 | 6.12E-08 | 9.10E-07 | 1.97E-06 | 9.34E-06 | 4.81E-05 |
| SP-46.5 | 38.064167 | 12.721944 | 87.45 | 2023-02-01 | 1.269 | -1.896 | -0.57 | 0.082 | 1.59E-04 | 1.32E-02 | 7.03E-08 | 5.21E-07 | 3.26E-06 | 7.05E-06 | 5.37E-05 |
| SP-48 | 38.064167 | 12.721944 | 91.45 | 2023-02-01 | 0.179 | -1.928 | -0.85 | 0.082 | 1.52E-04 | 2.80E-02 | 1.55E-07 | 1.33E-06 | 8.23E-06 | 1.59E-05 | 1.31E-04 |
| SP-49.5 | 38.064167 | 12.721944 | 94.45 | 2023-02-01 | -1.893 | -3.177 | -0.87 | 0.082 | 2.26E-04 | 1.66E-02 | 1.05E-07 | 5.38E-07 | 5.05E-06 | 4.62E-05 | 2.45E-04 |
| SP-51 | 38.064167 | 12.721944 | 101.95 | 2023-02-01 | 0.615 | -1.711 | -0.91 | 0.082 | 1.58E-04 | 1.53E-02 | 2.32E-07 | 1.49E-06 | 4.97E-06 | 1.54E-05 | 1.09E-04 |
| SP-53.5 | 38.064167 | 12.721944 | 108.40 | 2023-02-01 | -1.335 | -3.562 | -0.87 | 0.082 | 1.56E-04 | 1.29E-02 | 6.33E-08 | 3.56E-07 | 3.93E-06 | 1.42E-05 | 7.33E-05 |
| SP-55 | 38.064167 | 12.721944 | 111.03 | 2023-02-01 | -0.112 | -2.444 | -0.84 | 0.082 | 1.69E-04 | 1.35E-02 | 5.76E-08 | 7.12E-07 | 3.80E-06 | 6.90E-06 | 1.78E-04 |
| SP-60 | 38.064167 | 12.721944 | 129.11 | 2023-02-01 | -0.364 | -3.014 | -0.71 | 0.082 | 1.57E-04 | 1.33E-02 | 5.87E-08 | 6.02E-07 | 6.05E-06 | 7.70E-06 | 6.81E-05 |
| SP-63 | 38.064167 | 12.721944 | 133.71 | 2023-02-01 | -0.037 | -2.650 | -0.89 | 0.140 | 1.57E-04 | 1.37E-02 | 1.31E-07 | 1.07E-06 | 4.75E-06 | 7.39E-06 | 8.62E-05 |
| SP-65 | 38.064167 | 12.721944 | 137.81 | 2023-02-01 | 0.288 | -2.078 | -0.94 | 0.090 | 1.56E-04 | 1.52E-02 | 4.17E-08 | 4.45E-07 | 5.92E-06 | 1.48E-05 | 1.56E-04 |
| SP-67 | 38.064167 | 12.721944 | 141.81 | 2023-02-01 | -3.153 | -4.033 | -0.81 | 0.082 | 1.73E-04 | 1.45E-02 | 5.54E-08 | 3.65E-07 | 3.02E-06 | 9.99E-06 | 5.17E-05 |
| SP-73 | 38.064167 | 12.721944 | 147.61 | 2023-02-01 | 0.910 | -2.044 | -0.74 | 0.082 | 1.35E-04 | 1.68E-02 | 4.34E-08 | 9.12E-07 | 5.28E-06 | 9.00E-06 | 8.14E-05 |
| SP-76 | 38.064167 | 12.721944 | 153.41 | 2023-02-01 | 1.460 | -1.446 | -0.67 | 0.104 | 1.14E-04 | 6.00E-02 | 4.38E-08 | 3.38E-06 | 3.65E-06 | 1.40E-05 | 1.52E-04 |
| SP-78 | 38.064167 | 12.721944 | 159.41 | 2023-02-01 | 1.136 | -1.238 | -0.77 | 0.082 | 1.60E-04 | 5.00E-02 | 6.33E-08 | 1.24E-06 | 5.45E-06 | 2.02E-05 | 3.12E-04 |
| SP-80 | 38.064167 | 12.721944 | 164.11 | 2023-02-01 | 0.941 | -1.683 | -0.77 | 0.118 | 1.65E-04 | 7.43E-02 | 4.90E-08 | 4.90E-07 | 5.80E-06 | 1.81E-05 | 9.23E-05 |
| SP-82 | 38.064167 | 12.721944 | 168.11 | 2023-02-01 | 2.119 | -0.643 | -0.79 | 0.083 | 1.51E-04 | 1.32E-02 | 7.41E-08 | 1.64E-06 | 5.68E-06 | 6.42E-06 | 3.83E-05 |
| SP-84 | 38.064167 | 12.721944 | 173.21 | 2023-02-01 | -0.253 | -2.332 | |||||||||
| SP-86 | 38.064167 | 12.721944 | 178.51 | 2023-02-01 | 1.541 | -3.192 | -0.88 | 0.157 | 1.76E-04 | 1.43E-02 | 3.79E-08 | 4.55E-07 | 6.23E-06 | 8.63E-06 | 9.42E-05 |
| SP-88 | 38.064167 | 12.721944 | 183.01 | 2023-02-01 | 1.948 | -1.659 | -0.78 | 0.082 | 1.54E-04 | 1.29E-02 | 4.06E-08 | 2.42E-07 | 6.45E-06 | 5.32E-06 | 6.15E-05 |
| SP-92 | 38.064167 | 12.721944 | 187.01 | 2023-02-01 | 2.252 | -1.451 | -0.76 | 0.082 | 1.38E-04 | 1.36E-01 | 7.42E-08 | 2.33E-06 | 6.88E-06 | 2.45E-05 | 3.04E-04 |
| SP-94 | 38.064167 | 12.721944 | 191.01 | 2023-02-01 | 2.999 | 0.187 | -0.50 | 0.105 | 1.50E-04 | 1.69E-01 | 1.24E-07 | 4.32E-06 | 6.23E-06 | 2.72E-05 | 3.48E-04 |
| SP-95 | 38.064167 | 12.721944 | 195.01 | 2023-02-01 | 2.708 | -0.737 | -0.82 | 0.093 | 1.67E-04 | 9.13E-03 | 6.09E-08 | 2.82E-07 | 3.05E-07 | 5.43E-06 | #0.00E00 |
| SP-96 | 38.064167 | 12.721944 | 199.01 | 2023-02-01 | 2.828 | -0.550 | -1.05 | 0.082 | 1.01E-03 | 6.56E-03 | 1.93E-07 | 3.84E-07 | #0.00E00 | 4.39E-06 | 2.84E-05 |
| SP-97 | 38.064167 | 12.721944 | 201.10 | 2023-02-01 | 3.107 | -1.266 | -0.64 | 0.082 | 1.77E-04 | 8.45E-03 | 6.39E-08 | 3.06E-07 | #0.00E00 | 3.23E-06 | 3.50E-05 |
| SP-98 | 38.064167 | 12.721944 | 203.01 | 2023-02-01 | -0.93 | 0.085 | 2.40E-04 | 9.80E-03 | 6.83E-08 | 6.87E-07 | 5.22E-07 | 4.37E-06 | 2.67E-05 | ||
| SP-99 | 38.064167 | 12.721944 | 205.01 | 2023-02-01 | 3.047 | -1.156 | -1.18 | 0.082 | 1.07E-03 | 8.29E-03 | 2.08E-07 | 4.00E-07 | 1.10E-06 | 5.19E-06 | 4.07E-05 |
| SP-100 | 38.064167 | 12.721944 | 207.21 | 2023-02-01 | 2.770 | -2.295 | -0.41 | 0.082 | 1.36E-04 | 2.68E-01 | 1.40E-07 | 1.41E-06 | 1.15E-06 | 1.24E-04 | 2.42E-04 |
| SP-102 | 38.064167 | 12.721944 | 209.21 | 2023-02-01 | 3.468 | -1.847 | -0.87 | 0.145 | 2.05E-04 | 4.23E-01 | 9.30E-07 | 5.18E-05 | 1.53E-05 | 1.45E-04 | 8.01E-03 |
| SP-103 | 38.064167 | 12.721944 | 212.21 | 2023-02-01 | 2.015 | -0.455 | -0.42 | 0.082 | 1.47E-04 | 2.48E-01 | 5.14E-07 | 4.12E-06 | 7.85E-07 | 1.26E-04 | 2.87E-04 |
| SP-104 | 38.064167 | 12.721944 | 218.21 | 2023-02-01 | 1.333 | -0.028 | -0.59 | 0.082 | 1.02E-04 | 8.92E-03 | 1.22E-07 | 2.17E-06 | 1.86E-06 | 6.58E-06 | 5.18E-05 |
| SP-105 | 38.064167 | 12.721944 | 221.21 | 2023-02-01 | 2.156 | -1.041 | -0.99 | 0.089 | 1.03E-04 | 1.13E-02 | 1.72E-07 | 3.37E-06 | 1.53E-06 | 9.09E-06 | 6.70E-05 |
| SP-108 | 38.064167 | 12.721944 | 223.71 | 2023-02-01 | 2.210 | -1.093 | -0.83 | 0.158 | 1.55E-04 | 1.27E-02 | 1.40E-07 | 2.07E-06 | 3.04E-06 | 1.13E-05 | 8.58E-05 |
| SP-110 | 38.064167 | 12.721944 | 230.21 | 2023-02-01 | 2.306 | -1.267 | -0.60 | 0.082 | 1.39E-04 | 1.25E-02 | 9.89E-08 | 5.33E-07 | 1.43E-06 | 1.27E-05 | 5.01E-05 |
| SP-113 | 38.064167 | 12.721944 | 234.61 | 2023-02-01 | 2.404 | -1.280 | -0.52 | 0.082 | 1.34E-04 | 1.94E-02 | 1.34E-07 | 1.06E-06 | 1.41E-06 | 1.69E-05 | 1.07E-04 |
| SP-115 | 38.064167 | 12.721944 | 241.11 | 2023-02-01 | 2.275 | -1.157 | -0.72 | 0.082 | 1.52E-04 | 3.16E-02 | 1.33E-07 | 1.17E-06 | 3.90E-06 | 1.44E-05 | 8.01E-05 |
| SP-118 | 38.064167 | 12.721944 | 251.81 | 2023-02-01 | 1.862 | -1.362 | -0.64 | 0.082 | 1.07E-04 | 1.18E-02 | 2.78E-07 | 2.93E-06 | 1.41E-06 | 1.41E-05 | 7.16E-05 |
| SP-123 | 38.064167 | 12.721944 | 263.81 | 2023-02-01 | 1.487 | -1.907 | -0.66 | 0.082 | 1.34E-04 | 1.32E-02 | 1.25E-07 | 1.89E-06 | 1.84E-06 | 1.07E-05 | 8.63E-05 |
| SP-126 | 38.064167 | 12.721944 | 271.21 | 2023-02-01 | 1.612 | -2.007 | -0.58 | 0.082 | 1.50E-04 | 1.23E-02 | 2.24E-07 | 2.52E-06 | 1.78E-06 | 1.60E-05 | 8.19E-05 |