Citation:

PANGAEA.974712

Name: Raw mass spectrometric data to dissolved organic matter molecular composition data of exemplary water masses resolved by online LC-FT-ICR-MS
Published: 2025-04-24
License: https://creativecommons.org/licenses/by/4.0/
Keywords: Dissolved Organic Matter; Fourier-transform ion cyclotron mass spectrometry; liquid chromatography high-resolution mass spectrometry; molecular composition; Orbitrap

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Published: 2025-04-24 • DOI registered: 2025-05-23

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Abstract:

The unique chromatographic behaviour of DOM was investigated on three exemplary water samples representing coastal DOM, oceanic surface DOM and oceanic refractory DOM. Weddell Sea surface (30 m depth, oceanic surface DOM) and deep water (1356 m depth, refractory DOM) was sampled with a rosette sampler on RV Polarstern during ANT XXII/2 (station PS67/006-130, latitude -67.5633, longitude -55.3448) and are described elsewhere (El Naggar et al., 2007; Koch et al., 2008). Coastal DOM is routinely extracted from southern North Sea (latitude 54.1447, longitude 7.8711) and used as an in-house laboratory standard. Mass spectra were obtained with liquid chromatography coupled to a Fourier-transform ion cyclotron resonance mass spectrometer (LC-FT-ICR-MS) with negative electrospray ionisation. A 7 Tesla scimaX MRMS system (Bruker Daltonics GmbH & Co. KG, Bremen, Germany) was coupled to an ultra-performance liquid chromatography system (UPLC, Elute LC, Bruker Daltonics GmbH & Co. KG, Bremen, Germany). Reversed phase chromatography was done with a C18 column (Waters AQUITY 2 x 100 mm, 1.7 µm) column at 0.3 mL min 1 and a linear gradient: A (ultrapure water, 4 mmol L 1 ammonium formate) 2 min: 99 %, 11 min: 0 %, 14.9 min: 99 %; B (MeOH, 4 mmol L 1 ammonium formate) 2 min: 1 %, 11 min: 100 %, 14.5 min 100 %, 14.9 min 1 %. The exact mass lists and intensities of the 1.1 min binned scans were exported with the DataAnalysis 5.3 software package (Bruker Daltonics GmbH & Co. KG, Bremen, Germany).

Keyword(s):

Dissolved Organic Matter; Fourier-transform ion cyclotron mass spectrometry; liquid chromatography high-resolution mass spectrometry; molecular composition; Orbitrap

Related to:

El Naggar, Saad El Dine; Dieckmann, Gerhard S; Haas, Christian; Schröder, Michael; Spindler, Michael (2007): The Expeditions ANTARKTIS-XXII/1 and XXII/2 of the Research Vessel Polarstern in 2004/2005. Berichte zur Polar- und Meeresforschung = Reports on Polar and Marine Research, 551, 259 pp, https://doi.org/10.2312/BzPM_0551_2007

Flerus, Ruth; Koch, Boris P; Schmitt-Kopplin, Philippe; Witt, Matthias; Kattner, Gerhard (2011): Molecular level investigation of reactions between dissolved organic matter and extraction solvents using FT-ICR MS. Marine Chemistry, 124(1-4), 100-107, https://doi.org/10.1016/j.marchem.2010.12.006

Koch, Boris P; Ludwichowski, Kai-Uwe; Kattner, Gerhard; Dittmar, Thorsten; Witt, Matthias (2008): Advanced characterization of marine dissolved organic matter by combining reversed-phase liquid chromatography and FT-ICR-MS. Marine Chemistry, 111(3-4), 233-241, https://doi.org/10.1016/j.marchem.2008.05.008

Leefmann, Tim; Frickenhaus, Stephan; Koch, Boris P (2019): UltraMassExplorer: a browser-based application for the evaluation of high-resolution mass spectrometric data. Rapid Communications in Mass Spectrometry, 33(2), 193-202, https://doi.org/10.1002/rcm.8315

Moye, Fabian; Bareth, Marlo; Koch, Boris P; Tebben, Jan; Harder, Tilmann (2025): From Retention Time to Functional Group Assignment: A Chemical Database-Driven Approach for High-Resolution Mass Data of Marine Dissolved Organic Matter. Rapid Communications in Mass Spectrometry, 39(13), e10043, https://doi.org/10.1002/rcm.10043

Funding:

Helmholtz Association of German Research Centres (HGF), grant/award no. HIDSS-0005 : Helmholtz School for Marine Data Science (MarData)

Coverage:

Median Latitude: -6.709300 * Median Longitude: -23.736850 * South-bound Latitude: -67.563300 * West-bound Longitude: -55.344800 * North-bound Latitude: 54.144700 * East-bound Longitude: 7.871100

Date/Time Start: 2004-12-29T12:25:00 * Date/Time End: 2004-12-29T12:25:00

Minimum DEPTH, water: 30 m * Maximum DEPTH, water: 1356 m

Event(s):

PS67/006-130 * Latitude: -67.563300 * Longitude: -55.344800 * Date/Time: 2004-12-29T12:25:00 * Elevation: -1496.0 m * Location: Weddell Sea * Campaign: (PS67 ISPOL) * Basis: * Method/Device: (CTD-RO)

UT_NSSTD_01 * Latitude: 54.144700 * Longitude: 7.871100 * Campaign: * Basis:

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Event label	Event		Moye, Fabian
2	Latitude of event	Latitude		Moye, Fabian
3	Longitude of event	Longitude		Moye, Fabian
4	DEPTH, water	Depth water	m	Moye, Fabian		Geocode
5	Sample ID	Sample ID		Moye, Fabian
6	Mass-to-charge ratio	m/z		Moye, Fabian	Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS)
7	Intensity	Intensity		Moye, Fabian	Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS)
8	Retention time	RT	min	Moye, Fabian	Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS)	of bin
9	Signal/noise ratio	SNR		Moye, Fabian	Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS)
10	Peak resolution	Peak res		Moye, Fabian	Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS)

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

48904926 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

5 Sample ID	6 m/z	7 Intensity	9 SNR	10 Peak res
Blank_1-1-54_1_2138.d	107.49829	20586	0.3	1091235
Blank_1-1-54_1_2138.d	107.50397	19855	0.3	956372
Blank_1-1-54_1_2138.d	107.50628	22719	0.3	1331872
Blank_1-1-54_1_2138.d	107.51809	21930	0.3	805528
Blank_1-1-54_1_2138.d	107.51969	21219	0.3	993123
Blank_1-1-54_1_2138.d	107.52671	23018	0.3	1109869
Blank_1-1-54_1_2138.d	107.53115	21018	0.3	1121376
Blank_1-1-54_1_2138.d	107.53176	24037	0.3	908014
Blank_1-1-54_1_2138.d	107.53339	20203	0.3	1012248
Blank_1-1-54_1_2138.d	107.53378	19548	0.3	994224
Blank_1-1-54_1_2138.d	107.53655	21723	0.3	1174747
Blank_1-1-54_1_2138.d	107.53821	39690	0.6	997124
Blank_1-1-54_1_2138.d	107.54286	20789	0.3	1236296
Blank_1-1-54_1_2138.d	107.54574	21094	0.3	1189430
Blank_1-1-54_1_2138.d	107.55177	23402	0.3	832884
Blank_1-1-54_1_2138.d	107.56375	21711	0.3	852490
Blank_1-1-54_1_2138.d	107.56463	20848	0.3	913701
Blank_1-1-54_1_2138.d	107.56714	20202	0.3	847857
Blank_1-1-54_1_2138.d	107.59576	22236	0.3	1160859
Blank_1-1-54_1_2138.d	107.59837	19183	0.3	1296630
Blank_1-1-54_1_2138.d	107.60430	20212	0.3	1280570
Blank_1-1-54_1_2138.d	107.60705	19787	0.3	947506
Blank_1-1-54_1_2138.d	107.60884	46771	0.7	1112911
Blank_1-1-54_1_2138.d	107.61155	22088	0.3	1200038
Blank_1-1-54_1_2138.d	107.61924	38204	0.5	1174945
Blank_1-1-54_1_2138.d	107.62215	19745	0.3	950362
Blank_1-1-54_1_2138.d	107.63006	20743	0.3	1027581
Blank_1-1-54_1_2138.d	107.63028	19289	0.3	997252
Blank_1-1-54_1_2138.d	107.63632	24773	0.3	1097129
Blank_1-1-54_1_2138.d	107.63859	20357	0.3	1197542
Blank_1-1-54_1_2138.d	107.65247	44889	0.6	1062984
Blank_1-1-54_1_2138.d	107.65452	20090	0.3	1008681
Blank_1-1-54_1_2138.d	107.66800	20727	0.3	836401
Blank_1-1-54_1_2138.d	107.67100	22208	0.3	1184223
Blank_1-1-54_1_2138.d	107.67820	39562	0.6	853492
Blank_1-1-54_1_2138.d	107.68108	20586	0.3	1271873
Blank_1-1-54_1_2138.d	107.68444	22768	0.3	1086509
Blank_1-1-54_1_2138.d	107.69517	19576	0.3	1096434
Blank_1-1-54_1_2138.d	107.71320	20192	0.3	1256559
Blank_1-1-54_1_2138.d	107.72510	23091	0.3	1156436
Blank_1-1-54_1_2138.d	107.73876	46205	0.7	1020249
Blank_1-1-54_1_2138.d	107.74513	20042	0.3	1068617
Blank_1-1-54_1_2138.d	107.75168	22214	0.3	813816
Blank_1-1-54_1_2138.d	107.75390	19443	0.3	1053293
Blank_1-1-54_1_2138.d	107.76042	41404	0.6	869838
Blank_1-1-54_1_2138.d	107.76502	22061	0.3	1276733
Blank_1-1-54_1_2138.d	107.77255	21026	0.3	1132319
Blank_1-1-54_1_2138.d	107.77827	22109	0.3	1142649
Blank_1-1-54_1_2138.d	107.79328	20783	0.3	1215426
Blank_1-1-54_1_2138.d	107.79832	19696	0.3	710869
Blank_1-1-54_1_2138.d	107.80393	21069	0.3	789312
Blank_1-1-54_1_2138.d	107.80925	23492	0.3	1137139
Blank_1-1-54_1_2138.d	107.81160	20252	0.3	1001561
Blank_1-1-54_1_2138.d	107.81993	20213	0.3	1093859
Blank_1-1-54_1_2138.d	107.82326	20963	0.3	960237
Blank_1-1-54_1_2138.d	107.83695	19784	0.3	960448
Blank_1-1-54_1_2138.d	107.84902	19687	0.3	1163570
Blank_1-1-54_1_2138.d	107.85386	20786	0.3	995916
Blank_1-1-54_1_2138.d	107.87510	19503	0.3	961564
Blank_1-1-54_1_2138.d	107.88564	21496	0.3	968219
Blank_1-1-54_1_2138.d	107.89181	19987	0.3	862288
Blank_1-1-54_1_2138.d	107.89247	20684	0.3	972997
Blank_1-1-54_1_2138.d	107.91456	20564	0.3	898377
Blank_1-1-54_1_2138.d	107.96122	23966	0.3	899444
Blank_1-1-54_1_2138.d	107.98117	42553	0.6	865336
Blank_1-1-54_1_2138.d	107.99054	20767	0.3	1074200
Blank_1-1-54_1_2138.d	107.99479	20452	0.3	723421
Blank_1-1-54_1_2138.d	108.00010	21637	0.3	914772
Blank_1-1-54_1_2138.d	108.01875	19458	0.3	1188215
Blank_1-1-54_1_2138.d	108.03094	40420	0.6	859493
Blank_1-1-54_1_2138.d	108.03372	20516	0.3	1074238
Blank_1-1-54_1_2138.d	108.04067	19682	0.3	1065314
Blank_1-1-54_1_2138.d	108.06444	21157	0.3	1120353
Blank_1-1-54_1_2138.d	108.06806	19642	0.3	1157593
Blank_1-1-54_1_2138.d	108.06993	20226	0.3	941475
Blank_1-1-54_1_2138.d	108.07845	23068	0.3	835143
Blank_1-1-54_1_2138.d	108.11193	23493	0.3	902025
Blank_1-1-54_1_2138.d	108.12922	21820	0.3	1149289
Blank_1-1-54_1_2138.d	108.13478	19620	0.3	1124829
Blank_1-1-54_1_2138.d	108.14112	21018	0.3	1259438
Blank_1-1-54_1_2138.d	108.14441	19725	0.3	1055972
Blank_1-1-54_1_2138.d	108.14460	22332	0.3	1067156
Blank_1-1-54_1_2138.d	108.14678	40532	0.6	1244570
Blank_1-1-54_1_2138.d	108.15360	20198	0.3	957394
Blank_1-1-54_1_2138.d	108.18014	23619	0.3	1044719
Blank_1-1-54_1_2138.d	108.18153	19759	0.3	1216936
Blank_1-1-54_1_2138.d	108.20061	46118	0.6	1163122
Blank_1-1-54_1_2138.d	108.22327	19432	0.3	1255796
Blank_1-1-54_1_2138.d	108.22379	39865	0.6	1123862
Blank_1-1-54_1_2138.d	108.22628	19928	0.3	1178028
Blank_1-1-54_1_2138.d	108.25411	20330	0.3	733274
Blank_1-1-54_1_2138.d	108.25501	20611	0.3	1218828
Blank_1-1-54_1_2138.d	108.26828	20386	0.3	1217872
Blank_1-1-54_1_2138.d	108.27895	23047	0.3	1022223
Blank_1-1-54_1_2138.d	108.29022	22181	0.3	1012854
Blank_1-1-54_1_2138.d	108.29866	19762	0.3	1173967
Blank_1-1-54_1_2138.d	108.30076	20373	0.3	874438
Blank_1-1-54_1_2138.d	108.30240	20662	0.3	833774
Blank_1-1-54_1_2138.d	108.30324	22968	0.3	885761
Blank_1-1-54_1_2138.d	108.30438	20030	0.3	1474624
Blank_1-1-54_1_2138.d	108.32478	20325	0.3	976132
Blank_1-1-54_1_2138.d	108.33545	21642	0.3	1173086
Blank_1-1-54_1_2138.d	108.34650	40205	0.6	1192932
Blank_1-1-54_1_2138.d	108.35373	19934	0.3	1238906
Blank_1-1-54_1_2138.d	108.36244	20165	0.3	1170308
Blank_1-1-54_1_2138.d	108.36992	19652	0.3	1113692
Blank_1-1-54_1_2138.d	108.38900	19238	0.3	1127356
Blank_1-1-54_1_2138.d	108.40345	41406	0.6	1239500
Blank_1-1-54_1_2138.d	108.41175	23849	0.3	995551
Blank_1-1-54_1_2138.d	108.42080	20247	0.3	1083573
Blank_1-1-54_1_2138.d	108.42109	40319	0.6	787696
Blank_1-1-54_1_2138.d	108.42713	20835	0.3	916952
Blank_1-1-54_1_2138.d	108.43331	19872	0.3	1338451
Blank_1-1-54_1_2138.d	108.43379	41288	0.6	1047447
Blank_1-1-54_1_2138.d	108.44645	20250	0.3	738223
Blank_1-1-54_1_2138.d	108.47367	21954	0.3	1086756
Blank_1-1-54_1_2138.d	108.47913	21928	0.3	1061386
Blank_1-1-54_1_2138.d	108.49773	20141	0.3	798293
Blank_1-1-54_1_2138.d	108.49998	39969	0.6	1106805
Blank_1-1-54_1_2138.d	108.50030	21331	0.3	1147730
Blank_1-1-54_1_2138.d	108.50174	19801	0.3	1396868
Blank_1-1-54_1_2138.d	108.50979	19617	0.3	1159220
Blank_1-1-54_1_2138.d	108.51031	21092	0.3	1159251
Blank_1-1-54_1_2138.d	108.51192	42446	0.6	941434
Blank_1-1-54_1_2138.d	108.52224	22451	0.3	800270
Blank_1-1-54_1_2138.d	108.52762	44006	0.6	673532
Blank_1-1-54_1_2138.d	108.54705	19853	0.3	1316921
Blank_1-1-54_1_2138.d	108.55184	40982	0.6	1419708
Blank_1-1-54_1_2138.d	108.56359	20382	0.3	794443
Blank_1-1-54_1_2138.d	108.56451	20041	0.3	915253
Blank_1-1-54_1_2138.d	108.57370	21828	0.3	894493
Blank_1-1-54_1_2138.d	108.57768	29064	0.4	883363
Blank_1-1-54_1_2138.d	108.57904	41240	0.6	1076088
Blank_1-1-54_1_2138.d	108.60198	24495	0.3	906306
Blank_1-1-54_1_2138.d	108.60242	22994	0.3	1009115
Blank_1-1-54_1_2138.d	108.61011	23720	0.3	966888
Blank_1-1-54_1_2138.d	108.61109	21572	0.3	822121
Blank_1-1-54_1_2138.d	108.61452	19757	0.3	885401
Blank_1-1-54_1_2138.d	108.61805	49610	0.7	1172418
Blank_1-1-54_1_2138.d	108.62996	19550	0.3	1468310
Blank_1-1-54_1_2138.d	108.63009	21051	0.3	1252824
Blank_1-1-54_1_2138.d	108.63175	20188	0.3	822050
Blank_1-1-54_1_2138.d	108.64561	23515	0.3	1089304
Blank_1-1-54_1_2138.d	108.64723	21829	0.3	930830
Blank_1-1-54_1_2138.d	108.65717	21924	0.3	698679
Blank_1-1-54_1_2138.d	108.66142	20293	0.3	865951
Blank_1-1-54_1_2138.d	108.68844	19678	0.3	1315718
Blank_1-1-54_1_2138.d	108.69342	22173	0.3	1124949
Blank_1-1-54_1_2138.d	108.69424	20759	0.3	863627
Blank_1-1-54_1_2138.d	108.69627	21155	0.3	951784
Blank_1-1-54_1_2138.d	108.69979	42062	0.6	826007
Blank_1-1-54_1_2138.d	108.70546	22038	0.3	1028559
Blank_1-1-54_1_2138.d	108.71281	20871	0.3	1300971
Blank_1-1-54_1_2138.d	108.71764	24356	0.3	1148428
Blank_1-1-54_1_2138.d	108.72117	40361	0.6	789251
Blank_1-1-54_1_2138.d	108.72714	20029	0.3	1238228
Blank_1-1-54_1_2138.d	108.73278	22279	0.3	1187478
Blank_1-1-54_1_2138.d	108.75077	20290	0.3	1209474
Blank_1-1-54_1_2138.d	108.75774	25708	0.4	951435
Blank_1-1-54_1_2138.d	108.76482	20112	0.3	1072541
Blank_1-1-54_1_2138.d	108.77686	39839	0.6	886126
Blank_1-1-54_1_2138.d	108.77881	19706	0.3	1002292
Blank_1-1-54_1_2138.d	108.78437	21912	0.3	941132
Blank_1-1-54_1_2138.d	108.78795	19628	0.3	1180713
Blank_1-1-54_1_2138.d	108.79432	20829	0.3	1369031
Blank_1-1-54_1_2138.d	108.79783	20585	0.3	1103715
Blank_1-1-54_1_2138.d	108.80278	24495	0.3	1177148
Blank_1-1-54_1_2138.d	108.80602	21017	0.3	1050561
Blank_1-1-54_1_2138.d	108.80704	19638	0.3	880711
Blank_1-1-54_1_2138.d	108.81000	21093	0.3	1002606
Blank_1-1-54_1_2138.d	108.81229	44317	0.6	1050061
Blank_1-1-54_1_2138.d	108.81261	20238	0.3	1042975
Blank_1-1-54_1_2138.d	108.82632	19677	0.3	935722
Blank_1-1-54_1_2138.d	108.83688	20855	0.3	1225172
Blank_1-1-54_1_2138.d	108.84131	44948	0.6	1171220
Blank_1-1-54_1_2138.d	108.84973	19514	0.3	950662
Blank_1-1-54_1_2138.d	108.85688	42882	0.6	1197098
Blank_1-1-54_1_2138.d	108.85710	19395	0.3	1122659
Blank_1-1-54_1_2138.d	108.87269	20921	0.3	971470
Blank_1-1-54_1_2138.d	108.87304	19676	0.3	1274364
Blank_1-1-54_1_2138.d	108.88118	43941	0.6	889547
Blank_1-1-54_1_2138.d	108.90923	20317	0.3	919905
Blank_1-1-54_1_2138.d	108.92007	20206	0.3	1129370
Blank_1-1-54_1_2138.d	108.93137	20883	0.3	789796
Blank_1-1-54_1_2138.d	108.93478	20132	0.3	983144
Blank_1-1-54_1_2138.d	108.93638	20609	0.3	955280
Blank_1-1-54_1_2138.d	108.93890	22762	0.3	864331
Blank_1-1-54_1_2138.d	108.93994	20295	0.3	825212
Blank_1-1-54_1_2138.d	108.94020	22091	0.3	1010536
Blank_1-1-54_1_2138.d	108.94188	23489	0.3	1009745
Blank_1-1-54_1_2138.d	108.94392	40114	0.6	1145364
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Blank_1-1-54_1_2138.d	113.46640	56426	0.8	1077509
Blank_1-1-54_1_2138.d	113.46731	21341	0.3	801181
Blank_1-1-54_1_2138.d	113.46766	19826	0.3	925885
Blank_1-1-54_1_2138.d	113.46792	25033	0.4	840116
Blank_1-1-54_1_2138.d	113.47083	45259	0.6	986750
Blank_1-1-54_1_2138.d	113.47130	58184	0.8	829531
Blank_1-1-54_1_2138.d	113.47168	23713	0.3	678034
Blank_1-1-54_1_2138.d	113.47238	25601	0.4	864477
Blank_1-1-54_1_2138.d	113.47386	20962	0.3	1243733
Blank_1-1-54_1_2138.d	113.47444	23121	0.3	751781
Blank_1-1-54_1_2138.d	113.47513	45058	0.6	892297
Blank_1-1-54_1_2138.d	113.47639	20044	0.3	1101468
Blank_1-1-54_1_2138.d	113.47805	19909	0.3	726728
Blank_1-1-54_1_2138.d	113.48111	20197	0.3	1171299
Blank_1-1-54_1_2138.d	113.48492	21375	0.3	856578
Blank_1-1-54_1_2138.d	113.48589	42861	0.6	1015065
Blank_1-1-54_1_2138.d	113.48649	40957	0.6	864466
Blank_1-1-54_1_2138.d	113.48794	41481	0.6	1069482
Blank_1-1-54_1_2138.d	113.49097	28164	0.4	1080234
Blank_1-1-54_1_2138.d	113.49279	42202	0.6	843284
Blank_1-1-54_1_2138.d	113.49522	19880	0.3	629329
Blank_1-1-54_1_2138.d	113.49663	27099	0.4	917358
Blank_1-1-54_1_2138.d	113.49902	20267	0.3	1147077
Blank_1-1-54_1_2138.d	113.49961	22475	0.3	803951
Blank_1-1-54_1_2138.d	113.50324	25057	0.4	1250796
Blank_1-1-54_1_2138.d	113.50566	21053	0.3	1328806
Blank_1-1-54_1_2138.d	113.50667	27005	0.4	826701
Blank_1-1-54_1_2138.d	113.50726	21782	0.3	1175059
Blank_1-1-54_1_2138.d	113.50787	22069	0.3	948412
Blank_1-1-54_1_2138.d	113.50990	23629	0.3	849921
Blank_1-1-54_1_2138.d	113.51042	20755	0.3	1020114
Blank_1-1-54_1_2138.d	113.51149	20656	0.3	837200
Blank_1-1-54_1_2138.d	113.51209	23129	0.3	1029126
Blank_1-1-54_1_2138.d	113.51379	42399	0.6	739649
Blank_1-1-54_1_2138.d	113.51428	23457	0.3	1097361
Blank_1-1-54_1_2138.d	113.51644	19655	0.3	826495
Blank_1-1-54_1_2138.d	113.51868	24450	0.3	965705
Blank_1-1-54_1_2138.d	113.51895	62002	0.9	1075817
Blank_1-1-54_1_2138.d	113.52150	22337	0.3	846462
Blank_1-1-54_1_2138.d	113.52223	21627	0.3	661945
Blank_1-1-54_1_2138.d	113.52322	19751	0.3	1229037
Blank_1-1-54_1_2138.d	113.52346	20188	0.3	1100042
Blank_1-1-54_1_2138.d	113.52522	19680	0.3	743191
Blank_1-1-54_1_2138.d	113.52561	23689	0.3	1054296
Blank_1-1-54_1_2138.d	113.52634	41243	0.6	1086283
Blank_1-1-54_1_2138.d	113.52671	42929	0.6	858197
Blank_1-1-54_1_2138.d	113.52839	20945	0.3	722211
Blank_1-1-54_1_2138.d	113.52869	19228	0.3	715110
Blank_1-1-54_1_2138.d	113.53014	20453	0.3	1153041
Blank_1-1-54_1_2138.d	113.53069	40531	0.6	1008862
Blank_1-1-54_1_2138.d	113.53130	19868	0.3	886425
Blank_1-1-54_1_2138.d	113.53159	20203	0.3	916133
Blank_1-1-54_1_2138.d	113.53312	19986	0.3	1541639
Blank_1-1-54_1_2138.d	113.53378	44338	0.6	1170686
Blank_1-1-54_1_2138.d	113.53514	20485	0.3	997925
Blank_1-1-54_1_2138.d	113.53677	34425	0.5	847566
Blank_1-1-54_1_2138.d	113.53744	22612	0.3	1086988
Blank_1-1-54_1_2138.d	113.53896	20960	0.3	1459445
Blank_1-1-54_1_2138.d	113.54056	39921	0.6	1224235
Blank_1-1-54_1_2138.d	113.54120	42913	0.6	465402
Blank_1-1-54_1_2138.d	113.54156	20640	0.3	795217
Blank_1-1-54_1_2138.d	113.54258	42989	0.6	756861
Blank_1-1-54_1_2138.d	113.54291	41089	0.6	699762
Blank_1-1-54_1_2138.d	113.54312	21059	0.3	1007464
Blank_1-1-54_1_2138.d	113.54377	19586	0.3	955735
Blank_1-1-54_1_2138.d	113.54391	21889	0.3	1502629
Blank_1-1-54_1_2138.d	113.54663	22396	0.3	1245278
Blank_1-1-54_1_2138.d	113.54813	20100	0.3	721043
Blank_1-1-54_1_2138.d	113.54989	19584	0.3	797675
Blank_1-1-54_1_2138.d	113.55082	20474	0.3	1062005
Blank_1-1-54_1_2138.d	113.55303	35646	0.5	741826
Blank_1-1-54_1_2138.d	113.55533	21764	0.3	756268
Blank_1-1-54_1_2138.d	113.55555	40526	0.6	1327250
Blank_1-1-54_1_2138.d	113.55568	40253	0.6	908510
Blank_1-1-54_1_2138.d	113.55621	24289	0.3	688162
Blank_1-1-54_1_2138.d	113.55647	20754	0.3	1015574
Blank_1-1-54_1_2138.d	113.56036	21488	0.3	1122920
Blank_1-1-54_1_2138.d	113.56252	24653	0.3	872354
Blank_1-1-54_1_2138.d	113.56335	28120	0.4	1167525
Blank_1-1-54_1_2138.d	113.56538	37483	0.5	766721
Blank_1-1-54_1_2138.d	113.56585	45062	0.6	1097093
Blank_1-1-54_1_2138.d	113.56674	23068	0.3	929915
Blank_1-1-54_1_2138.d	113.56992	39681	0.6	932179

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