Citation:

PANGAEA.971623

Name: Carbon monoxide stable isotope data from laboratory heating experiments and collection of air from Stony Brook, NY, on Long Island, 2019-2022
Published: 2024-08-08
License: https://creativecommons.org/licenses/by/4.0/
Keywords: Atmosphere; carbon monoxide; clumped isotope

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Published: 2024-08-08 • DOI registered: 2024-08-08

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Abstract:

Clumped isotope data of carbon monoxide (analyzed as CO oxidized to CO2) from laboratory heating experiments and collections of natural air samples from the campus of Stony Brook University from 2019-2022. Air sampling was done from the School of Marine and Atmospheric Sciences building roof (Dana Hall), see doi:10.1594/PANGAEA.971624. Laboratory heating experiments equilibrated CO in tube furnaces at elevated temperatures 300-1000 °C for periods of hours to days. These heating experiments were done (1) in the presence of platinum wire, (2) by the reaction of graphite with CO2, and (3) by the decomposition of calcium carbonate in the presence of Zn metal.

Keyword(s):

Atmosphere; carbon monoxide; clumped isotope

Related to:

Henkes, Gregory A; Place, Philip F; Mak, John E (2024): Large, Negative Atmospheric Carbon Monoxide Clumped Isotope Values Result From Kinetic Isotope Fractionation, Tracing OH• Reactivity. AGU Advances, 5(5), e2023AV000922, https://doi.org/10.1029/2023AV000922

Funding:

National Science Foundation (NSF), grant/award no. 1927950 : EAGER: The Presence of a Clumped Isotope Signal in Atmospheric Carbon Monoxide (CO)

Coverage:

Latitude: 40.906200 * Longitude: -73.119200

Event(s):

Stony-Brook_Dana-Hall * Latitude: 40.906200 * Longitude: -73.119200 * Method/Device: Air sample (AIR)

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Sample code/label	Sample label		Henkes, Gregory A
2	Experiment	Exp		Henkes, Gregory A		Experiment type
3	LATITUDE	Latitude		Henkes, Gregory A		Geocode
4	LONGITUDE	Longitude		Henkes, Gregory A		Geocode
5	Julian day	Julian day		Henkes, Gregory A		Date 1
6	Julian day	Julian day		Henkes, Gregory A		Date 2
7	Julian day	Julian day		Henkes, Gregory A		Date 3
8	Julian day	Julian day		Henkes, Gregory A		Date 4
9	Julian day	Julian day		Henkes, Gregory A		Date 5
10	Julian day	Julian day		Henkes, Gregory A		Date 6
11	Year of sampling	Year sampl		Henkes, Gregory A		Alternative date
12	Day of the year	DOY	day	Henkes, Gregory A		Average
13	Day of the year	DOY	day	Henkes, Gregory A		Maximum
14	Day of the year	DOY	day	Henkes, Gregory A		Minimum
15	Treatment: temperature	T:temp	°C	Henkes, Gregory A
16	Time in minutes	Time min	min	Henkes, Gregory A
17	δ13C	δ13C	‰	Henkes, Gregory A		VPDB
18	δ13C, standard deviation	δ13C std dev	±	Henkes, Gregory A		‰, VPDB
19	δ18O	δ18O	‰	Henkes, Gregory A		VSMOW
20	δ18O, standard deviation	δ18O std dev	±	Henkes, Gregory A		‰, VSMOW
21	Δ47, carbon dioxide clumped isotope	Δ47	‰	Henkes, Gregory A	Measured	CDES
22	Δ47, carbon dioxide clumped isotope, standard deviation	Δ47 std dev	±	Henkes, Gregory A	Measured	‰, CDES
23	Δ31, carbon monoxide clumped isotope	Δ31	‰	Henkes, Gregory A	Derived from Δ47	CDES
24	Δ31, carbon monoxide clumped isotope, standard deviation	Δ31 std dev	±	Henkes, Gregory A	Derived from Δ47	‰, CDES
25	Carbon monoxide	CO	ppbv	Henkes, Gregory A
26	Carbon monoxide, standard deviation	CO std dev	±	Henkes, Gregory A

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

1301 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Sample label	2 Exp (Experiment type)	3 Latitude	4 Longitude	5 Julian day (Date 1)	6 Julian day (Date 2)	7 Julian day (Date 3)	8 Julian day (Date 4)	9 Julian day (Date 5)	10 Julian day (Date 6)	11 Year sampl (Alternative date)	12 DOY [day] (Average)	13 DOY [day] (Maximum)	14 DOY [day] (Minimum)	15 T:temp [°C]	16 Time min [min]	17 δ13C [‰] (VPDB)	18 δ13C std dev [±] (‰, VPDB)	19 δ18O [‰] (VSMOW)	20 δ18O std dev [±] (‰, VSMOW)	21 Δ47 [‰] (CDES, Measured)	22 Δ47 std dev [±] (‰, CDES, Measured)	23 Δ31 [‰] (CDES, Derived from Δ47)	24 Δ31 std dev [±] (‰, CDES, Derived from Δ47)	25 CO [ppbv]	26 CO std dev [±]
AL03 630-375-1	CO + Pt wire													375	50055	-33.280	0.015	41.686	0.010	0.245	0.027
AL03 630-375-2	CO + Pt wire													375	60620	-33.889	0.015	42.860	0.010	0.223	0.040
SBU-CO-5	CO + Pt wire													450		-42.127	0.015	-5.346	0.010	0.097	0.039
AL03 Batch T-1	CO + Pt wire													650	38170	-33.672	0.015	42.033	0.010	0.109	0.023
AL03 Batch T-2	CO + Pt wire													650	38170	-33.925	0.015	42.074	0.010	0.094	0.026
AL03 Batch T-3	CO + Pt wire													650	38170	-33.898	0.015	42.002	0.010	0.098	0.036
SBU-CO-1	CO + Pt wire													1000		-43.000	0.015	-5.394	0.010	0.017	0.040
SBU-CO-2	CO + Pt wire													1000		-42.802	0.015	-4.936	0.010	0.027	0.026
SBU-CO-8	CO + Pt wire													1000		-42.255	0.015	-4.116	0.010	-0.026	0.019
AL01 Batch 4 600T-1	CO + Pt wire													1000	1080	-38.973	0.015	-0.777	0.010	0.057	0.033
AL01 Batch 4 600T-2	CO + Pt wire													1000	1335	-43.060	0.015	-3.725	0.010	0.018	0.016
AL02 Batch 3 623T-1	CO + Pt wire													1000	1300	-33.939	0.015	33.690	0.010	0.110	0.041
AL02 Batch 3 623T-2	CO + Pt wire													1000	1415	-33.535	0.015	33.509	0.010	0.132	0.025
AL03 Batch 2 556T	CO + Pt wire													1000	2595	-33.908	0.015	34.665	0.010	0.150	0.031
AL03 Batch 2 632T-1	CO + Pt wire													1000	1465	-33.385	0.015	36.018	0.010	0.125	0.024
AL03 Batch 2 632T-2	CO + Pt wire													1000	1455	-33.146	0.015	35.499	0.010	0.115	0.019
AL03 450T-1	CO + Pt wire													1000	2674	-33.224	0.018	31.853	0.010	0.088	0.022
AL03 450T-2	CO + Pt wire													1000	1795	-33.246	0.015	27.468	0.010	0.111	0.015
Pt-21-01	CO + Pt wire													1000	4206	-32.074	0.015	23.260	0.010	0.038	0.029
Pt-21-02	CO + Pt wire													1000	142	-33.719	0.015	40.157	0.010	-0.014	0.039
Pt-21-03	CO + Pt wire													1000	182	-33.567	0.015	39.764	0.010	0.045	0.032
Pt-21-07	CO + Pt wire													1000	182	-33.523	0.015	40.701	0.010	-0.087	0.037
Pt-21-04	CO + Pt wire													350	26799	-33.129	0.027	44.428	0.010	0.028	0.026
Pt-21-05	CO + Pt wire													350	47309	-33.040	0.015	44.245	0.010	0.104	0.029
Pt-21-06	CO + Pt wire													350	26799	-33.093	0.015	44.643	0.010	-0.018	0.022
Pt-21-08	CO + Pt wire													350	47309	-33.791	0.015	44.419	0.010	0.042	0.037
Pt-21-09	CO + Pt wire													1000	152	-33.399	0.015	41.947	0.010	0.134	0.022
Pt-21-10	CO + Pt wire													1000	120	-32.403	0.015	41.739	0.010	0.134	0.033
Pt-21-11	CO + Pt wire													350	34428	-32.392	0.032	43.957	0.010	0.039	0.026
Pt-21-12	CO + Pt wire													1000	204	-33.237	0.015	40.846	0.010	0.098	0.027
Pt-21-13	CO + Pt wire													1000	204	-33.349	0.022	39.984	0.010	0.233	0.040
Pt-21-14	CO + Pt wire													1000	301	-33.971	0.015	40.397	0.010	0.128	0.018
Pt-21-15	CO + Pt wire													1000	216	-33.807	0.015	40.521	0.016	0.143	0.027
Pt-21-16	CO + Pt wire													1000	192	-33.927	0.015	41.502	0.017	0.069	0.032
Pt-21-17	CO + Pt wire													1000	364	-33.855	0.015	40.590	0.010	0.122	0.021
Pt-21-18	CO + Pt wire													1000	216	-33.542	0.020	40.836	0.010	0.141	0.025
Pt-21-19	CO + Pt wire													1000	364	-33.762	0.015	39.991	0.010	0.166	0.012
RXN073	CaCO3 + Zn decomposition													1000	187	-7.333	0.015	17.731	0.010	0.080	0.039
RXN074	CaCO3 + Zn decomposition													1000	900	-7.401	0.015	17.557	0.010	0.110	0.033
RXN075	CaCO3 + Zn decomposition													1000	275	2.273	0.015	25.359	0.010	0.039	0.040
RXN076	CaCO3 + Zn decomposition													1000	1215	2.347	0.015	23.413	0.010	0.044	0.033
RXN077	CaCO3 + Zn decomposition													775	3758	3.927	0.015	28.508	0.010	0.062	0.020
RXN078	CaCO3 + Zn decomposition													1000	3755	2.930	0.015	20.379	0.010	0.009	0.038
RXN079	CaCO3 + Zn decomposition													775	3758	-5.851	0.015	19.009	0.010	0.091	0.016
RXN080	CaCO3 + Zn decomposition													1000	3755	-5.872	0.015	15.654	0.010	0.070	0.031
RXN087	CaCO3 + Zn decomposition													1000	302	-6.495	0.015	17.563	0.010	-0.002	0.024
RXN088	CaCO3 + Zn decomposition													1000	231	-5.694	0.015	16.408	0.010	0.005	0.041
RXN107	CaCO3 + Zn decomposition													1000	144	-6.568	0.015	17.328	0.010	0.061	0.037
RXN108	CaCO3 + Zn decomposition													1000	133	3.075	0.015	25.060	0.010	0.082	0.019
RXN106	CaCO3 + Zn decomposition													1000	133	-7.284	0.015	17.499	0.010	0.070	0.024
RXN115	CaCO3 + Zn decomposition													1000	140	-7.114	0.015	18.683	0.010	0.030	0.011
RXN118	CaCO3 + Zn decomposition													1000	140	2.295	0.015	27.168	0.010	0.033	0.014
RXN116	CaCO3 + Zn decomposition													1000	140	-7.428	0.015	19.049	0.010	0.009	0.022
RXN119	CaCO3 + Zn decomposition													1000	303	2.513	0.015	26.642	0.010	-0.027	0.024
RXN117	CaCO3 + Zn decomposition													1000	303	-7.350	0.015	18.890	0.010	0.028	0.031
RXN120-B	CaCO3 + Zn decomposition													1000	130	-6.927	0.015	17.982	0.010	0.153	0.009
RXN121	CaCO3 + Zn decomposition													1000	130	-7.426	0.015	18.221	0.010	0.065	0.012
RXN122	CaCO3 + Zn decomposition													1000	130	-6.917	0.015	19.026	0.010	0.170	0.012
RXN123	CaCO3 + Zn decomposition													1000	126	-7.537	0.015	18.398	0.010	0.129	0.022
RXN124	CaCO3 + Zn decomposition													1000	136	-7.193	0.015	17.851	0.010	0.389	0.026
RXN126	CaCO3 + Zn decomposition													1000	129	2.395	0.015	25.570	0.010	0.096	0.021
RXN127	CaCO3 + Zn decomposition													1000	129	2.226	0.015	25.917	0.010	0.131	0.030
RXN128	CaCO3 + Zn decomposition													1000	126	2.354	0.015	26.211	0.010	0.140	0.020
RXN129	CaCO3 + Zn decomposition													1000	136	2.412	0.015	25.379	0.010	0.132	0.032
RXN130	CaCO3 + Zn decomposition													1000	120	-7.278	0.015	18.600	0.010	0.122	0.024
RXN132	CaCO3 + Zn decomposition													1000	153	-7.082	0.015	17.874	0.010	0.122	0.023
RXN134	CaCO3 + Zn decomposition													1000	120	2.290	0.015	25.994	0.010	0.139	0.013
RXN136	CaCO3 + Zn decomposition													1000	153	2.386	0.015	27.225	0.010	0.103	0.024
Boudouard-21-02	Bouduard reaction (CO2 + C)													1000	143	-33.749	0.015	38.421	0.010	0.001	0.026
Boudouard-21-03	Bouduard reaction (CO2 + C)													1000	149	-33.779	0.015	38.585	0.010	-0.014	0.023
Boudouard-21-04	Bouduard reaction (CO2 + C)													1000	141	-33.919	0.015	38.249	0.010	0.002	0.031
Boudouard-21-06	Bouduard reaction (CO2 + C)													1000	128	-33.867	0.015	39.576	0.010	0.027	0.028
Boudouard-21-07	Bouduard reaction (CO2 + C)													1000	128	-33.477	0.024	39.934	0.010	0.042	0.011
Boudouard-21-08	Bouduard reaction (CO2 + C)													1000	154	-33.760	0.017	41.360	0.010	0.140	0.032
Boudouard-21-09	Bouduard reaction (CO2 + C)													1000	154	-33.534	0.025	41.067	0.010	0.069	0.028
Boudouard-21-10	Bouduard reaction (CO2 + C)													1000	200	-31.628	0.094	44.789	0.010	-0.018	0.027
Boudouard-21-11	Bouduard reaction (CO2 + C)													1000	193	-32.793	0.075	41.015	0.010	0.075	0.025
Boudouard-21-12	Bouduard reaction (CO2 + C)													1000		-34.107	0.015	41.007	0.010	0.132	0.025
Boudouard-21-13	Bouduard reaction (CO2 + C)													1000	142	-33.488	0.015	44.119	0.010	0.149	0.021
Boudouard-21-14	Bouduard reaction (CO2 + C)													1000	142	-33.888	0.015	40.228	0.010	0.138	0.018
SBU-CO-3	CO bottle gases															-29.268	0.015	-7.428	0.010	-0.126	0.022
SBU-CO-4	CO bottle gases															-6.147	0.015	40.243	0.010	0.134	0.016
SBU-CO-6	CO bottle gases															-5.792	0.015	40.975	0.010	0.096	0.033
CO-CG-21_01	CO bottle gases															-25.035	0.017	1.299	0.010	0.038	0.025
CO-CG-21-02	CO bottle gases															-24.564	0.015	2.269	0.010	-0.080	0.035
CO-CG-21-03	CO bottle gases															-24.150	0.029	3.123	0.010	-0.119	0.032
CO-CG-21-04	CO bottle gases															-24.637	0.015	2.119	0.010	0.057	0.031
CO-CG-21-05	CO bottle gases															-24.395	0.050	2.619	0.010	0.111	0.015
CO-CG-21-06	CO bottle gases															-36.599	0.019	1.655	0.010	0.219	0.027
CO-CG-21-07	CO bottle gases															-38.780	0.038	2.703	0.010	0.095	0.051
CO-CG-21-08	CO bottle gases															-38.830	0.015	2.798	0.010	0.150	0.029
CO-CG-21-09	CO bottle gases															-39.327	0.015	2.619	0.010	0.144	0.020
CO-CG-21-10	CO bottle gases															-39.146	0.015	3.103	0.010	0.239	0.027
CO-CG-22-01	CO bottle gases															-39.001	0.015	2.653	0.010	0.246	0.033
CO-CG-22-02	CO bottle gases															-39.027	0.015	2.585	0.010	0.222	0.029
Dec-19-Mak-Lab	Stony Brook, NY troposhere	40.9062	-73.1192	19337	19338	19339	19340	19343		2019	339.0	2.0	4.0			-28.272	0.015	13.028	0.010			-4.715	0.078	172	53
CO-W20-1	Stony Brook, NY troposhere	40.9062	-73.1192	20036	20049	20050	20051	20065		2020	50.0	14.0	15.0			-27.629	0.015	10.606	0.010			-5.187	0.056	141	7
CO-W20-2	Stony Brook, NY troposhere	40.9062	-73.1192	20034	20043	20048	20058	20062		2020	49.0	15.0	13.0			-27.961	0.015	11.179	0.010			-5.109	0.047	157	7
CO-W20-3	Stony Brook, NY troposhere	40.9062	-73.1192	20037	20041	20055	20056			2020	47.0	10.0	9.0			-26.948	0.015	13.998	0.010			-4.151	0.086	207	27
CO-Su20-1	Stony Brook, NY troposhere	40.9062	-73.1192	20191	20192	20196	20198	20199		2020	195.0	4.0	4.0			-28.851	0.015	9.025	0.010			-6.026	0.051	125	9
CO-Su20-2	Stony Brook, NY troposhere	40.9062	-73.1192	20190	20195	20202	20204			2020	198.0	8.0	6.0			-28.220	0.017	9.870	0.010			-4.460	0.069	168	10
CO-LIA-21-01	Stony Brook, NY troposhere	40.9062	-73.1192	21105	21109	21118	21119			2021	113.0	8.0	6.0			-23.872	0.020	13.949	0.010			-3.670	0.055	210	40
CO-LIA-21-02	Stony Brook, NY troposhere	40.9062	-73.1192	21095	21098	21106	21131	21134		2021	113.0	18.0	21.0			-25.510	0.015	11.911	0.010			-6.144	0.037	151	3
CO-LIA-21-03	Stony Brook, NY troposhere	40.9062	-73.1192	21125	21135	21136	21137			2021	133.0	8.0	4.0			-24.611	0.015	12.758	0.010			-5.286	0.068	171	4
CO-LIA-21-04	Stony Brook, NY troposhere	40.9062	-73.1192	21126	21132	21145	21146	21147		2021	138.0	12.0	9.0			-25.557	0.015	9.775	0.010			-6.132	0.067	145	17
CO-LIA-21-05	Stony Brook, NY troposhere	40.9062	-73.1192	21148	21169	21180	21181			2021	170.0	22.0	11.0			-28.713	0.015	11.609	0.010			-5.716	0.032	153	11
CO-LIA-21-06	Stony Brook, NY troposhere	40.9062	-73.1192	21167	21168	21174	21175	21182	21190	2021	176.0	9.0	14.0			-27.362	0.015	9.557	0.010			-7.745	0.071	120	7
CO-LIA-21-07	Stony Brook, NY troposhere	40.9062	-73.1192	21209	21210	21211				2021	210.0	1.0	1.0			-28.060	0.015	9.766	0.010			-5.100	0.035	207	26
CO-LIA-21-08	Stony Brook, NY troposhere	40.9062	-73.1192	21207						2021	207.0					-28.518	0.015	11.693	0.010			-3.688	0.035	315
CO-LIA-21-09	Stony Brook, NY troposhere	40.9062	-73.1192	21208						2021	208.0					-27.877	0.037	11.644	0.010			-2.888	0.046	301
CO-LIA-21-10	Stony Brook, NY troposhere	40.9062	-73.1192	21242	21243					2021	242.5	0.5	0.5			-27.164	0.023	16.027	0.031			-3.555	0.066	231	6
CO-LIA-21-11	Stony Brook, NY troposhere	40.9062	-73.1192	21265	21266	21267				2021	266.0	1.0	1.0			-26.043	0.022	10.397	0.010			-6.024	0.038	171	55
CO-LIA-21-12	Stony Brook, NY troposhere	40.9062	-73.1192	21288						2021	288.0					-27.733	0.015	16.918	0.010			-4.245	0.066	223
CO-LIA-21-13	Stony Brook, NY troposhere	40.9062	-73.1192	21316						2021	316.0					-26.678	0.015	17.371	0.010			-3.840	0.049	200
CO-LIA-21-14	Stony Brook, NY troposhere	40.9062	-73.1192	21339						2021	339.0					-26.030	0.015	19.043	0.010			-3.346	0.044	231
CO-LIA-21-15	Stony Brook, NY troposhere	40.9062	-73.1192	21364						2021	364.0					-25.598	0.015	24.439	0.010			-1.761	0.058	494
CO-LIA-22-1	Stony Brook, NY troposhere	40.9062	-73.1192	22033						2022	33.0					-25.983	0.015	22.694	0.010			-2.812	0.052	305
CO-LIA-22-2	Stony Brook, NY troposhere	40.9062	-73.1192	22049	22050					2022	49.5	0.5	0.5			-26.575	0.015	15.118	0.010			-5.394	0.047	143	2
CO-LIA-22-3	Stony Brook, NY troposhere	40.9062	-73.1192	22063						2022	63.0					-27.127	0.015	20.442	0.010			-3.553	0.047	272