Henkel, Susann; Staubwasser, Michael; Kasemann, Simone A; Meixner, Anette; Kasten, Sabine (2024): Solid phase geochemistry of a multicorer core and a gravity core at Station HE443/10, North Sea [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.971563, In: Henkel, S et al. (2024): Pore-water and solid-phase data of a multicorer core and a gravity core at Station HE443/10, North Sea [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.971490
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Published: 2024-08-12 • DOI registered: 2024-09-10
Abstract:
Solid-phase samples were collected onboard (RV Heincke expedition HE443) using cut-off syringes. The MUC was sliced and sampled. For sampling the GC, small windows were drilled into the liner through which the syringes were introduced. All samples were stored anoxically and frozen at -20°C until processing. The processing involved freeze-drying and grinding before splitting the samples for the different kinds of analyses.
Keyword(s):
Related to:
Aromokeye, David Adeyemi; Kulkarni, Ajinkya; Elvert, Marcus; Wegener, Gunter; Henkel, Susann; Coffinet, Sarah; Eickhorst, Thilo; Oni, Oluwatobi Emmanuel; Richter-Heitmann, Tim; Taubner, Heidi; Wunder, Lea C; Yin, Xiuran; Zhu, Qing-Zeng; Hinrichs, Kai-Uwe; Kasten, Sabine; Friedrich, Michael (2018): Pore water geochemistry of sediment core HE443/10-3 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.893766
Henkel, Susann; et al. (in review): Stable iron isotope signals indicate a "pseudo-abiotic process driving deep iron release in methanic sediments.
References:
Henkel, Susann; Kasten, Sabine; Poulton, Simon W; Staubwasser, Michael (2016): Determination of the stable iron isotopic composition of sequentially leached iron phases in marine sediments. Chemical Geology, 421, 93-102, https://doi.org/10.1016/j.chemgeo.2015.12.003
Poulton, Simon W; Canfield, Donald E (2005): Development of a sequential extraction procedure for iron: implications for iron partitioning in continentally derived particulates. Chemical Geology, 214(3-4), 209-221, https://doi.org/10.1016/j.chemgeo.2004.09.003
Project(s):
Funding:
Federal Ministry of Education and Research (BMBF), grant/award no. 03F0874A: Ozeane unter Stress: APOC - Anthropogene Einflüsse auf den Kreislauf partikulären organischen Kohlenstoffs in der Nordsee
Coverage:
Median Latitude: 54.086085 * Median Longitude: 7.969670 * South-bound Latitude: 54.085670 * West-bound Longitude: 7.969170 * North-bound Latitude: 54.086500 * East-bound Longitude: 7.970170
Date/Time Start: 2015-04-30T09:52:59 * Date/Time End: 2015-04-30T10:15:59
Minimum DEPTH, sediment/rock: 0.005 m * Maximum DEPTH, sediment/rock: 4.750 m
Event(s):
Comment:
The data have been partially published in PANGAEA before (Aromokeye, D A et al., 2018), but with core depth, not sediment depths.
Methods:
Bulk elemental composition: Dissolution of dry sediment in a mixture of 65% HNO3 (3 ml), 30% HCl (2 ml), and 40% suprapur® HF (0.5 ml) in a CEM Mars Xpress microwave system. Elemental contents determined by ICP-OES (Inductively coupled plasma – optical emission spectroscopy; Iris Intrepid II).
Sequential Fe extraction after Poulton and Canfield (2005) and Henkel et al. (2016). Fe aca (1 M Na-acetate, 24 h, pH 4.5); Fe hyam (1 M hydroxylamine-HCl in 25% v/v acetic acid, 48 h); Fe di-ct (Na-dithionite (50 g L-1)/0.02 M Na-citrate, 2 h, pH 4.8); Fe oxa (0.2 M ammonium oxalate/0.17 M oxalic acid, 6 h). Iron contents determined by ICP-OES (Inductively coupled plasma – optical emission spectroscopy; Iris Intrepid II ICP-OES)
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Event label | Event | Henkel, Susann | |||
| 2 | DEPTH, sediment/rock | Depth sed | m | Henkel, Susann | Geocode – core depth | |
| 3 | Depth, corrected | Depth corr | m | Henkel, Susann | actual depth | |
| 4 | Carbon, organic, total | TOC | % | Henkel, Susann | Carbon-Sulfur analyzer, ELTRA, CS-2000 | wt%; after removal of inorganic carbon with HCl |
| 5 | Nitrogen, total | TN | % | Henkel, Susann | wt% | |
| 6 | Carbon, total | TC | % | Henkel, Susann | CHSN Elemental Analyser, Elementar Analysen systeme GmbH, Germany, vario EL III | wt% |
| 7 | Carbon, inorganic, total | TIC | % | Henkel, Susann | wt% | |
| 8 | Aluminium | Al | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 9 | Barium | Ba | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 10 | Calcium | Ca | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 11 | Iron | Fe | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 12 | Potassium | K | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 13 | Magnesium | Mg | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 14 | Manganese | Mn | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 15 | Phosphorus | P | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 16 | Sulfur | S | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 17 | Strontium | Sr | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 18 | Titanium | Ti | mg/g | Henkel, Susann | Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II | |
| 19 | Acid volatile sulfides | AVS | % | Henkel, Susann | Hot extraction using 6 M HCl and trapping of extracted S as Ag2S | wt% |
| 20 | Chromium reducible iron (pyrite) | CRFe | % | Henkel, Susann | Hot extraction using and a chromous chloride solution and trapping of extracted S as Ag2S | wt% |
| 21 | Iron, acetate-leached | Fe-aca | mg/g | Henkel, Susann | Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016) | |
| 22 | Iron, hydroxylamine-HCl-leached | Fe-hyam | mg/g | Henkel, Susann | Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016) | |
| 23 | Iron, dithionite-citrate-leached | Fe-di-ct | mg/g | Henkel, Susann | Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016) | |
| 24 | Iron, oxalate-leached | Fe-oxa | mg/g | Henkel, Susann | Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016) | |
| 25 | Iron, reactive | Fe react | mg/g | Henkel, Susann | sum of sequentially extracted Fe-aca, Fe-hyam, Fe-di-ct and Fe-oxa | |
| 26 | Iron in acid volatile sulfides | Fe AVS | mg/g | Henkel, Susann | ||
| 27 | Iron in pyrite | Fe Py | mg/g | Henkel, Susann |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
Size:
815 data points