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Wong, Wanyee; Risebrobakken, Bjørg; Fahl, Kirsten; Stein, Ruediger; Jansen, Eystein; Steinsland, Kristine; Kissel, Catherine (2024): Biomarker results from the eastern Fram Strait between 40 and 36.5 ka b2k [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.971113 (DOI registration in progress)

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Abstract:
Here we present a biomarker dataset from marine sediment core MD99-2304, which was retrieved from the eastern Fram Strait (77°37'15.6N, 9°56'54E) with piston corer at 1348 m water depth during cruise Marion Dufresne IMAGES 5 1999 leg MD114. This dataset contains sea ice history in the eastern Fram Strait between 40 and 36.5 ka b2k during MIS 3, with a temporal resolution of 20–40 yrs/sample, for the mechanical understanding of abrupt climate change during the Dansgaard-Oeschger events. Total Organic Carbon (TOC), Highly Branched Isoprenoids (HBIs) IP25, HBI diene, HBI-III (Z-isomer), and HBI III (E-isomer), and the sterols brassicasterol, dinosterol, campesterol, and sitosterol were measured in the organic geochemistry lab at the Alfred Wegener Institute (AWI), Germany in 2022 and 2023. Biomarker values are presented as biomarker μg/TOC. The age model of MD99-2304 is established by tuning is low field magnetic susceptibility to the magnetic susceptibility of Core MD95-2010 from the Norwegian Sea (Kissel et al., 1999 (doi:10.1016/S0012-821X(99)00162-4); updated in Sadatzki et al. (2020, doi:10.1073/pnas.2005849117)), and the age model of MD95-2010 was tied to the chronology of MD99-2284 (Berben et al., 2020, doi:10.1016/j.quascirev.2020.106277).
The biomarkers were measured on an Agilent 7890B GC (30m DB-1MS column, 0.25 mm i.d., 0.25 µm film thickness) coupled to an Agilent 5977A mass selective detector (MSD, 70 eV constant ionization potential, Scan 50–550 m/z, 1 scan/s, ion source temperature 230°C, Performance Turbo Pump), with selected ion monitoring mode (SIM) for HBIs and full scan mode (50-550 m/Z) for sterols. For biomarker concentration normalization, total organic carbon (TOC) was measured using a Carbon-Sulfur Analyzer (CS-125, Leco).
Keyword(s):
Arctic; HBI III; IP25; MIS 3; Sea ice
Supplement to:
Wong, Wanyee; Risebrobakken, Bjørg; Fahl, Kirsten; Stein, Ruediger; Jansen, Eystein; Steinsland, Kristine; Kissel, Catherine (2024): Sea ice in the Nordic Seas: Greenland stadial to interstadial changes. Quaternary Science Reviews, 343, 108916, https://doi.org/10.1016/j.quascirev.2024.108916
Project(s):
Funding:
The Research Council of Norway (RCN), grant/award no. 325333
Coverage:
Latitude: 77.621067 * Longitude: 9.948333
Date/Time Start: 1999-08-01T00:00:00 * Date/Time End: 1999-08-01T00:00:00
Minimum DEPTH, sediment/rock: 8.7425 m * Maximum DEPTH, sediment/rock: 9.7425 m
Event(s):
MD99-2304 (3280N) * Latitude: 77.621067 * Longitude: 9.948333 * Date/Time: 1999-08-01T00:00:00 * Elevation: -1348.0 m * Recovery: 22.885 m * Location: Spitsbergen slope * Campaign: MD114 (IMAGES V) * Basis: Marion Dufresne (1995) * Method/Device: Calypso Corer (CALYPSO)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Depth, top/minDepth topmWong, Wanyee
Depth, bottom/maxDepth botmWong, Wanyee
DEPTH, sediment/rockDepth sedmWong, WanyeeGeocode
Depth, correctedDepth corrmWong, WanyeeAfter removing the layer of the turbidte tail)
AgeAgeka b2kWong, Wanyee
Sample massSamp mgWong, Wanyee
Carbon, organic, totalTOC%Wong, WanyeeElement analyser CHN, LECO CS 125
2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyl)pentadecane, per unit mass total organic carbonIP25/TOCµg/gWong, Wanyeesee abstract
Diene highly branched isoprenoids, per unit mass total organic carbonHBI-diene/TOCµg/gWong, Wanyeesee abstract
10 (9Z)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbonC25 HBI (Z) triene/TOCµg/gWong, Wanyeesee abstract
11 (9E)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbonC25 HBI (E) triene/TOCµg/gWong, Wanyeesee abstract
12 24-Methylcholesta-5,22E-dien-3beta-ol, per unit mass total organic carbonBrassicasterol/TOCµg/gWong, Wanyeesee abstract
13 4alpha,23,24-Trimethyl-5alpha-cholest-22E-en-3beta-ol, per unit mass total organic carbonDinosterol/TOCµg/gWong, Wanyeesee abstract
14 24-Methylcholest-5-en-3beta-ol, per unit mass total organic carbonCampesterol/TOCµg/gWong, Wanyeesee abstract
15 24-ethylcholest-5-en-3beta-ol, per unit mass total organic carbonb-Sitosterol/TOCµg/gWong, Wanyeesee abstract
16 Sterols, terrestrial, per unit mass total organic carbonSterols terr/TOCµg/gWong, Wanyeesee abstract
17 Phytoplankton biomarker C25 HBI (Z) triene IP25 indexP(III)IP25Wong, Wanyeesee abstract
18 Phytoplankton biomarker Brassicasterol IP25 indexPBIP25Wong, Wanyeesee abstract
19 Phytoplankton biomarker Dinosterol IP25 indexPDIP25Wong, Wanyeesee abstract
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2751 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth top [m]

Depth bot [m]

Depth sed [m]

Depth corr [m]

Age [ka b2k]

Samp m [g]

TOC [%]

IP25/TOC [µg/g]

HBI-diene/TOC [µg/g]
10 
C25 HBI (Z) triene/TOC [µg/g]
11 
C25 HBI (E) triene/TOC [µg/g]
12 
Brassicasterol/TOC [µg/g]
13 
Dinosterol/TOC [µg/g]
14 
Campesterol/TOC [µg/g]
15 
b-Sitosterol/TOC [µg/g]
16 
Sterols terr/TOC [µg/g]
17 
P(III)IP25
18 
PBIP25
19 
PDIP25
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9.5209.5259.52259.407539.118306355.04100.6751179160.3958915500.5242303610.2034800550.17740301730.58209132014.1506076206.58004353817.57938942024.1594329600.4079519230.3381320480.387342069
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9.5659.5709.56759.452539.304603265.00300.5294063920.7139220980.9180647750.3337319860.26069696322.02166122011.4636824906.70353352838.13830811044.8418416400.4310483450.5612882470.584605492
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9.6309.6359.63259.517539.573698804.99350.5342014380.5491071990.7048821240.2295102490.28745456421.98945822016.7494816205.75635505114.43016488020.1865199300.4586782550.4963438700.425568503
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