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Martín-Puertas, Celia; Valero-Garcés, Blas L (2024): Geochemical composition of the sedimentary record of Lake Zoñar (Spain) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.969557

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Abstract:
High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southernSpain, provides a detailed characterisation of major changes in lake and watershed processes during the last 4,000 years. This dataset presents major, trace and earth rare elements. Major elements (Fe, Mn, Al, Ca, Mg and K) were quantified using a Perkin Elmer model 5100 Atomic Absorption Spectrometer, model 5100 ZLZEEMAN with an analytic error of 2%. Trace and REE (Li, Rb, Cs, Be, Sr, Ba, Sc, V, Cr, Co, Ni, Cu, Zn, Ga, Y, Nb, Ta, Zr, Hf, Mo, Sn, Tl, Pb, U, Th, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) were determined by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) following HNO3+HF digestion. Measurements were made in triplicate by spectrometry (Perkin-Elmer Sciex Elan 5000) using Re and Rh as internal standards.
Keyword(s):
Atomic Absorption Spectrometer; Iberian Peninsula; ICP-MS; Lake Zoñar; Late Holocene; major and trace element data; REE
Related to:
Martín-Puertas, Celia; Valero-Garcés, Blas L; Mata, M Pilar; Moreno, Ana; Giralt, Santiago; Martinez-Ruiz, Francisca C; Jiménez-Espejo, Francisco Jose (2011): Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake, southern Spain. Journal of Paleolimnology, 46(3), 405-421, https://doi.org/10.1007/s10933-009-9373-0
Funding:
Ministerio de Educación, Formación Professional y Deportes, grant/award no. CSD2007-00067: Multidisciplinary research consortium on gradual and abrupt climate changes, and their impacts on the environment (GRACCIE)
Spanish Inter-Ministerial Science and Technology Commission (CICYT), grant/award no. CGL2004- 20236-E: High resolution lacustrine records of climate variability in Spain (IBERLIMNO)
Spanish Inter-Ministerial Science and Technology Commission (CICYT), grant/award no. CGL2006-13327-C04/CLI: CALIBRE
Coverage:
Latitude: 37.481750 * Longitude: -4.693250
Date/Time Start: 2004-04-24T13:34:11 * Date/Time End: 2004-04-24T13:34:11
Minimum DEPTH, sediment/rock: 0.05 m * Maximum DEPTH, sediment/rock: 5.96 m
Event(s):
ESP-ZON04-1B-1K * Latitude: 37.481750 * Longitude: -4.693250 * Date/Time: 2004-04-24T13:34:11 * Elevation: 300.0 m * Method/Device: KULLENBERG corer (KULC)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DEPTH, sediment/rockDepth sedmMartín-Puertas, CeliaGeocode
Calendar ageCal ageka BPMartín-Puertas, Celia
IronFemg/kgMartín-Puertas, CeliaAtomic absorption spectrometry (AAS), Perkin Elmer, ZLZEEMAN 5100
ManganeseMnmg/kgMartín-Puertas, CeliaAtomic absorption spectrometry (AAS), Perkin Elmer, ZLZEEMAN 5100
AluminiumAlmg/kgMartín-Puertas, CeliaAtomic absorption spectrometry (AAS), Perkin Elmer, ZLZEEMAN 5100
CalciumCamg/kgMartín-Puertas, CeliaAtomic absorption spectrometry (AAS), Perkin Elmer, ZLZEEMAN 5100
MagnesiumMgmg/kgMartín-Puertas, CeliaAtomic absorption spectrometry (AAS), Perkin Elmer, ZLZEEMAN 5100
PotassiumKmg/kgMartín-Puertas, CeliaAtomic absorption spectrometry (AAS), Perkin Elmer, ZLZEEMAN 5100
LithiumLimg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
10 RubidiumRbmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
11 CaesiumCsmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
12 BerylliumBemg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
13 Strontium-8888Srmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
14 BariumBamg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
15 ScandiumScmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
16 VanadiumVmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
17 ChromiumCrmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
18 CobaltComg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
19 NickelNimg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
20 CopperCumg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
21 ZincZnmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
22 GalliumGamg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
23 YttriumYmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
24 NiobiumNbmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
25 TantalumTamg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
26 ZirconiumZrmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
27 HafniumHfmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
28 MolybdenumMomg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
29 TinSnmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
30 ThalliumTlmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
31 LeadPbmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
32 UraniumUmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
33 ThoriumThmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
34 LanthanumLamg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
35 CeriumCemg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
36 PraseodymiumPrmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
37 NeodymiumNdmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
38 SamariumSmmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
39 EuropiumEumg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
40 GadoliniumGdmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
41 TerbiumTbmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
42 DysprosiumDymg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
43 HolmiumHomg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
44 ErbiumErmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
45 ThuliumTmmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
46 YtterbiumYbmg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
47 LutetiumLumg/kgMartín-Puertas, CeliaICP-MS, Perkin-Elmer, SCIEX Elan 5000
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2760 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Depth sed [m]

Cal age [ka BP]

Fe [mg/kg]

Mn [mg/kg]

Al [mg/kg]

Ca [mg/kg]

Mg [mg/kg]

K [mg/kg]

Li [mg/kg]
10 
Rb [mg/kg]
11 
Cs [mg/kg]
12 
Be [mg/kg]
13 
88Sr [mg/kg]
14 
Ba [mg/kg]
15 
Sc [mg/kg]
16 
V [mg/kg]
17 
Cr [mg/kg]
18 
Co [mg/kg]
19 
Ni [mg/kg]
20 
Cu [mg/kg]
21 
Zn [mg/kg]
22 
Ga [mg/kg]
23 
Y [mg/kg]
24 
Nb [mg/kg]
25 
Ta [mg/kg]
26 
Zr [mg/kg]
27 
Hf [mg/kg]
28 
Mo [mg/kg]
29 
Sn [mg/kg]
30 
Tl [mg/kg]
31 
Pb [mg/kg]
32 
U [mg/kg]
33 
Th [mg/kg]
34 
La [mg/kg]
35 
Ce [mg/kg]
36 
Pr [mg/kg]
37 
Nd [mg/kg]
38 
Sm [mg/kg]
39 
Eu [mg/kg]
40 
Gd [mg/kg]
41 
Tb [mg/kg]
42 
Dy [mg/kg]
43 
Ho [mg/kg]
44 
Er [mg/kg]
45 
Tm [mg/kg]
46 
Yb [mg/kg]
47 
Lu [mg/kg]
0.05-0.0492142861.4346240800.1935561451.766526076-0.915641307-1.385200494-0.073449375-0.1248647061.5798497271.7105967321.834830222-0.9498130300.0349967372.3102594021.3852279391.9756703071.5367234581.4949702393.0559969221.6645317051.7266798491.5710193321.7439148811.9605887901.3621671561.123836435-0.3495584712.0268243341.8761719940.883697768-0.4847576991.4499355141.3564101651.2975636631.4013146261.3160461051.3784812481.1644096951.1634782241.2424762311.4308171661.7118637221.4923250111.5789978781.3787141741.094565276
0.15-0.0436428572.0082805510.0708218102.381247205-1.641945927-1.1189778221.3188744800.5537339032.5390027322.4826905191.951792351-1.0655835080.1024632242.7566804112.1577288312.7552732722.1144805762.4158630043.5562859822.4038199902.6840740552.3183832322.5036796392.6849096122.1377782482.255316637-0.3734188532.9386036612.6126133201.316843690-0.4864158602.1301275992.2238420872.1452115722.1902926332.1860471021.9721881141.9718433111.8594951702.3788873902.7002113691.9903298832.0959906532.1177823892.1869259322.148397256
0.25-0.0380714290.8630359440.0590659801.097755291-0.430095766-1.4571082230.212908845-1.0111292280.9319672130.8391482411.540844329-1.007358894-0.2030625591.2807297160.0531330401.1908687511.2429347811.1528159472.9529380361.0025018751.1709758031.2111554421.2498139691.3769127871.1637609721.054438982-0.3919251971.0460068850.9819218120.679080003-0.5272066091.0574049641.2694358821.2948069051.1104471591.2320213851.3588950420.8500653100.9384188520.9151898171.0226786101.0114791351.0157468721.2126244111.1206297481.049721362
0.33-0.0336142860.6856294080.0115037640.7298837320.969046129-0.5623712730.556197314-0.9650742880.5120218580.5985422700.551407938-0.456933155-0.1906777831.0828317430.6712721170.8458122830.6365353130.5423841221.8888756420.8419563960.7426369300.3966327970.5825521210.5189793860.3998459420.203565870-0.2638938810.9603043900.5610981970.706898822-0.2861100690.1689313630.2931810650.1740194250.1833071050.2439573250.0992571750.0611225400.092362324-0.0030303990.3296760010.4207933380.1896780990.2212609110.1426256040.354640695
0.43-0.0280428572.3536841190.2663162552.183863526-2.036190664-0.7184129081.5900867220.5642846712.6002732242.4012914842.625114880-1.052545172-0.1927830652.2591741121.8614579192.6972532852.6828266372.1415592702.7935677732.2150793482.5904116672.2723230322.4416350042.1223303331.9648131331.950571302-0.3735352452.5219943082.4548044641.718952085-0.3899109182.3770067392.0200617611.9209217522.0348603302.1296339052.2378260321.9286980032.4235328552.0243271081.9688937121.9312613031.8132209571.7729603022.1495716072.215663127
0.53-0.0224714291.166634070-0.1885713261.344491902-1.030897521-1.1376531541.202663973-0.4738774171.5739754101.4592173601.351176012-1.056923512-0.2043881071.6222187760.6121217071.6430533242.3178412621.5025587882.1661452711.5824503941.5275982872.0652007101.7269936171.7918150061.9290419661.718240701-0.3976284111.7959037211.5342528071.072796770-0.4976913511.8016836692.0307759852.0897456041.9485090501.8768456531.8669122571.8485710032.0164810281.8879577692.2504260222.3700564662.3215709722.1824365302.2344678002.013865514
0.63-0.0169000000.538653902-0.0218515010.477290987-0.144294860-1.421752032-0.069431090-1.3169340310.4755464480.3938476380.639919820-1.032559503-0.4991860490.768956353-0.3396464350.6098333910.9413717530.4301182321.7377500910.6147256470.4992714770.7817555070.7681219840.5822695550.8837384760.764780051-0.3345438890.5746431600.6663041010.408018940-0.4505995930.6532223010.6312043060.6801601700.7568613930.7138292720.7419295560.4925756170.6188901140.6424511390.5295806000.6486292880.7043824890.7169426610.5161688540.780657878
0.730.0066763270.481063264-0.1310220870.049377457-3.570865879-1.266060099-0.508383857-1.003090548-0.107581967-0.094546571-0.757303455-0.997643281-0.904985627-0.5178406982.887855891-0.017246632-0.076659204-1.908047692-0.0474771680.447409618-0.117959745-0.581329269-0.400009281-0.563985728-0.509202700-0.7861021460.2228579050.7222419020.3506863905.7180798610.298888962-0.251272955-0.492318561-0.396519183-0.482052227-0.453471655-0.472415210-0.764801922-0.414715890-0.230312631-0.343336149-0.313344723-0.251950976-0.360626361-0.363355706-0.452549758
0.880.098306122-0.7200321950.768761706-0.8280105900.419798448-0.894003593-1.308806337-1.365836004-1.053483607-1.222162613-0.7857537030.298090669-0.160768486-0.175431182-0.615595203-0.964411320-0.441235403-0.866854103-0.583713167-1.144504083-1.041259274-0.886515243-1.060502623-1.049210357-0.942127725-1.2326596660.078066126-0.994188633-1.161648477-0.2892908150.033583279-1.053083967-1.067105128-1.077548648-0.989252374-1.023078327-1.074691041-0.962037615-1.181584861-1.121258980-0.963040405-1.022167678-0.944577870-0.942513632-1.018754316-0.990676726
0.980.1601428570.452296765-0.2094102180.365617392-0.312602848-0.7960177190.198184663-0.5279710380.3941256830.4106062630.086720559-0.576738651-0.4124926200.7367404040.5973341050.5100390130.280142643-0.084787150-0.2159990590.2456843620.4142307310.3128329480.4071350170.2798831920.2768238630.019511758-0.2037191620.2842069250.1797267960.483773495-0.2138142710.3306044280.2167109220.2356605310.2851107190.2446714160.2192226860.1474131550.2354556280.3151647250.3646593060.2604643360.3803093540.0919526280.0509377160.242530910
1.080.2219795920.147889109-0.3517665750.1121946391.299846552-0.770918096-0.622375863-0.6465415740.1833333330.1628180250.494507443-0.440203124-0.3923105050.9963089080.1694448840.4050460440.1483878320.179249723-0.1975309070.1182496480.2351357030.2584521950.2492032190.1322061310.3901134520.088909210-0.3611976810.0532863120.1665760580.308468949-0.3945537670.0888230870.1152409250.0424669400.1396769850.020208778-0.047639369-0.0190044600.1854424350.2060692540.1231079150.0157516490.173792161-0.0373556540.027166782-0.295596059
1.180.3456530610.231687964-0.2661641460.2091091360.487415929-0.682659694-0.207487063-0.5214396100.3288251370.1879559620.472379472-0.397029421-0.3209778370.9696156930.2213312080.4623233750.0403652550.344189072-0.2479060910.2420672190.3311494490.2902485920.2582278930.3783345660.195634413-0.013678328-0.3528174500.146130682-0.0175342730.126726990-0.3932272390.0400298650.1131400970.0507372130.0687780400.0118777150.078446831-0.1237859220.0090070010.0878824930.0231556160.1338888090.0816537210.1135040090.0203750860.018311340
1.280.407489796-0.073607998-0.268206748-0.1428486510.526323523-0.772204345-0.298918440-0.862413640-0.057923497-0.015541625-0.020758154-0.341160705-0.3483854880.676910785-0.1930675690.185127084-0.2571060100.083946473-0.332167037-0.1640729640.083865068-0.076152875-0.058199746-0.120954545-0.157893989-0.282216296-0.375863087-0.094312430-0.569865268-0.078005730-0.456568971-0.306620491-0.164379294-0.166605577-0.201183329-0.172119760-0.276553151-0.524420922-0.404991103-0.275769078-0.306686972-0.136138984-0.112154722-0.058907035-0.315813838-0.026532574
1.380.469326531-0.108901653-0.269427964-0.1917537420.226097890-1.039979819-0.564888350-0.790232988-0.294330601-0.1807337850.020336648-0.418636990-0.4520836161.128854527-0.3068715730.030561838-0.311117298-0.157994331-0.411151367-0.123913407-0.171649064-0.145688920-0.151266698-0.268631606-0.173175704-0.550754264-0.374582774-0.075267431-0.543563792-0.135367676-0.457232235-0.469750070-0.386016659-0.415816489-0.415698086-0.404437399-0.463846245-0.524420922-0.309132481-0.248495210-0.270037796-0.397728408-0.309140352-0.360626361-0.434668508-0.497393672
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1.580.5884634630.310351682-0.2759556000.1109503230.260676034-0.771097492-0.264927954-0.6436945420.2405054640.333995407-0.033402709-0.510659070-0.4691662890.6538993920.0334162370.346190569-0.0631563820.055377817-0.2822040880.2152632660.2739330950.2465656920.3078636010.1814318180.139032305-0.031782012-0.3799368100.4627537910.3506863900.123163422-0.4559057060.0946491440.0898209050.0488626180.1133171210.0294919630.012343386-0.0806406140.0909730690.1697040970.0881246110.2098341250.1293115350.1997095300.1086671270.444328523
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