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Kammann, Ulrike; Töpker, Verena; Schmidt, Nicole; Rödiger, Marcellus; Aust, Marc-Oliver; Gabel, Michael; Scharsack, Jörn Peter (2024): Contamination of dab (Limanda limanda) with explosive chemicals leaking from marine dumped munition [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.968913

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Published: 2024-07-15 • DOI registered: 2024-08-13

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Abstract:
Conventional munition dumped into the North Sea and the Baltic Sea close to the German coastline is corroding. A major concern is that biota, including fish, take up toxic explosives leaking into marine environments. With the present study, we investigated bile fluids of fish living in close proximity to munition dumping sites for the explosives 2,4,6-trinitrotoluene (TNT), its metabolites 2-amino-4,6-dinitrolouene and 4-amino-2,6-dinitrolouene as well as octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) using HPLC-MS/MS (high performance liquid chromatography with mass selective detection) as device. The flat fish species common dab (Limanda limanda) was used as a model, since it lives in the vicinity of dumping sites and exhibits minor migratory activity.
Keyword(s):
Baltic Sea; bile; HMX; metabolites; North Sea; TNT
Supplement to:
Kammann, Ulrike; Töpker, Verena; Schmidt, Nicole; Rödiger, Marcellus; Aust, Marc-Oliver; Gabel, Michael; Scharsack, Jörn Peter (2024): Explosives leaking from dumped munition contaminate fish from German coastal waters: a reason for chronic effects? Environmental Sciences Europe, 36, 116, https://doi.org/10.1186/s12302-024-00942-5
Project(s):
DAM sustainMare - CONMAR: CONcepts for conventional MArine Munition Remediation in the German North and Baltic Sea (CONMAR)
Research Mission of the German Marine Research Alliance (DAM): Protection and sustainable use of marine areas (sustainMare)
Funding:
Federal Ministry of Education and Research (BMBF), grant/award no. 03F0912F: DAM sustainMare - CONMAR, Thünen
Coverage:
Median Latitude: 54.125556 * Median Longitude: 8.950847 * South-bound Latitude: 53.699183 * West-bound Longitude: 6.674067 * North-bound Latitude: 54.716450 * East-bound Longitude: 10.913950
Date/Time Start: 2021-07-15T10:42:00 * Date/Time End: 2023-07-12T12:25:00
Minimum DEPTH, water: 9 m * Maximum DEPTH, water: 39 m
Event(s):
CLU355_1  * Latitude: 54.443717 * Longitude: 10.415233 * Date/Time: 2021-07-15T10:42:00 * Location: Kolberger Heide East * Campaign: CLU355 * Basis: Clupea (2012) * Method/Device: Gillnet (GN)
CLU355_2  * Latitude: 54.443717 * Longitude: 10.415233 * Date/Time: 2021-07-16T09:03:00 * Location: Kolberger Heide East * Campaign: CLU355 * Basis: Clupea (2012) * Method/Device: Gillnet (GN)
CLU355_3  * Latitude: 54.453133 * Longitude: 10.321483 * Date/Time: 2021-07-16T09:03:00 * Location: Kolberger Heide * Campaign: CLU355 * Basis: Clupea (2012) * Method/Device: Gillnet (GN)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1 Event labelEventScharsack, Jörn Peter
2 LATITUDELatitudeScharsack, Jörn PeterGeocode
3 LONGITUDELongitudeScharsack, Jörn PeterGeocode
4 DEPTH, waterDepth watermScharsack, Jörn PeterGeocode
5 DATE/TIMEDate/TimeScharsack, Jörn PeterGeocode
6 Cruise/expeditionExpeditionScharsack, Jörn Peter
7 Location IDLoc IDScharsack, Jörn Peter
8 LocationLocationScharsack, Jörn Peter
9 Limanda limanda, sexL. limanda sexScharsack, Jörn Peter
10 Limanda limanda, ageL. limanda ageaScharsack, Jörn Peter
11 Limanda limanda, bile, 2,4,6-trinitrotolueneL. limanda bile TNTng/mlScharsack, Jörn PeterUltra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500
12 Limanda limanda, bile, 2-amino-4,6-dinitroloueneL. limanda bile 2-ADNTng/mlScharsack, Jörn PeterUltra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500
13 Limanda limanda, bile, 4-amino-2,6-dinitroloueneL. limanda bile 4-ADNTng/mlScharsack, Jörn PeterUltra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500
14 Limanda limanda, bile, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocineL. limanda bile HMXng/mlScharsack, Jörn PeterUltra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1741 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 
Event		2 
Latitude		3 
Longitude		4 
Depth water [m]		5 
Date/Time		6 
Expedition		7 
Loc ID		8 
Location		9 
L. limanda sex		10 
L. limanda age [a]		11 
L. limanda bile TNT [ng/ml]		12 
L. limanda bile 2-ADNT [ng/ml]		13 
L. limanda bile 4-ADNT [ng/ml]		14 
L. limanda bile HMX [ng/ml]
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