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Martínez-Braceras, Naroa; Payros, Aitor; Dinarès-Turell, Jaume; Rosales, Idoia; Arostegi, Javier; Silva-Casal, Roi (2024): Elemental geochemistry of the lower Pliensbachian Santiurde section (Basque-Cantabrian basin, northern Spain) [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.968044 (DOI registration in progress)

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Abstract:
We present inorganic elemental geochemistry from the lowermost Pliensbachian organic-rich hemipelagic Santiurde section (Basque-Cantabrian basin, north Iberian palaeomargin, Spain). The Santiurde section studied herein is exposed at exit 144 of motorway A67 (UTM X411431.091 Y4769002.593), approximately 50 km south-west of Santander city. The expanded hemiplegic succession offered a potentially valuable orbitally paced stratigraphic record. An integrated multiproxy study was performed in the 19 beds found between 12.4 and 15.95 m of the lower Pliensbachian succession in order to disentangle what sedimentary processes and environmental factors influenced the formation of the hemipelagic rhytmites. Sampling was mainly carried out in 2019. One sample from the central part of each bed was studied for their mineralogical content, their organic geochemistry, and their elemental composition. Major and trace element concentrations were determined at the University of the Basque Country (UPV/EHU) using a Perkin-Elmer Optima 8300 spectrometer (ICP-OES; PerkinElmer) and a Thermo XSeries 2 quadrupole inductively coupled plasma mass spectrometer (ICP-MS; Thermo Fisher Scientific) equipped with a collision cell, an interphase specific for elevated total dissolved solids (Xt cones), a shielded torch, and a gas dilution system.
Keyword(s):
Basque-Cantabria basin; Calcium Carbonate content; colour; inorganic geochemistry; Organic Geochemistry; Pliensbachian; whole-rock mineralogy
Funding:
Agencia Estatal de Investigación (AEI), grant/award no. MARSA22/05: Margarita Salas post-doctoral grant of the Spanish Government with Next Generation funds from the European Union
Agencia Estatal de Investigación (AEI), grant/award no. PID2019-105670GB-I00: Spanish Government (MCIN/AEI)
Basque Government, grant/award no. IT602-22: Consolidated Research Group of the Basque Government
University of the Basque Country (UPV/EHU), grant/award no. DOCREC19/35: Post-doctoral grant from the University of the Basque Country
University of the Basque Country (UPV/EHU), grant/award no. ESPDOC21/49: Post-doctoral grant from the University of the Basque Country
Coverage:
Latitude: 43.068561 * Longitude: -4.087829
Date/Time Start: 2019-04-22T00:00:00 * Date/Time End: 2019-04-22T00:00:00
Minimum Elevation: 730.0 m * Maximum Elevation: 730.0 m
Event(s):
Santiurde_section * Latitude: 43.068561 * Longitude: -4.087829 * Elevation: 730.0 m * Location: Basque-Cantabrian basin, northern Spain * Method/Device: Hammer (HAM)
Comment:
Trace elements originally given in ppm
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample IDSample IDMartínez-Braceras, Naroa
2Sample code/labelSample labelMartínez-Braceras, NaroaBed label
3Stratigraphic heightStrat heightmMartínez-Braceras, Naroa
4Silicon dioxideSiO2%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
5Titanium dioxideTiO2%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
6Aluminium oxideAl2O3%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
7Calcium oxideCaO%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
8Iron oxide, Fe2O3Fe2O3%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell(t)
9Potassium oxideK2O%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
10Magnesium oxideMgO%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
11Manganese oxideMnO%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
12Sodium oxideNa2O%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
13Phosphorus pentoxideP2O5%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
14Loss on ignitionLOI%Martínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell1050
15CobaltComg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
16ChromiumCrmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
17CopperCumg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
18NickelNimg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
19StrontiumSrmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
20VanadiumVmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
21ZincZnmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
22LanthanumLamg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
23CeriumCemg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
24PraseodymiumPrmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
25NeodymiumNdmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
26SamariumSmmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
27EuropiumEumg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
28GadoliniumGdmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
29TerbiumTbmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
30DysprosiumDymg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
31HolmiumHomg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
32ErbiumErmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
33ThuliumTmmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
34YtterbiumYbmg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
35LutetiumLumg/kgMartínez-Braceras, NaroaSpectrometer (ICP-OES), Perkin-Elmer, Optima 8300 and a Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific, Thermo XSeries 2 quadrupole equipped with a collision cell
Size:
665 data points

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