/* DATA DESCRIPTION: Citation: Deußen, Katharina; Voigt, Claudia; Staubwasser, Michael; Münker, Carsten; El-Shenawy, Mohammed; Klipsch, Swea; Herwartz, Daniel (2024): Triple oxygen and hydrogen isotope data of gypsum from Cyprus [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.967561 Abstract: Gypsum samples collected in two outcrops located in the Polemi basin, Cyprus, have been analyzed for their triple oxygen and hydrogen isotopic composition. Respective methods are described in the original publication. The oxygen and hydrogen data provided here is derived from the crystal bound H2O within the Gypsum (CaSO4*2H2O), which allows calculating paleo-water isotopic compositions of the mother brine from which this gypsum precipitated during the Messinian Salinity Crisis. Because the isotopic composition of the mother brine is affected by the local hydroclimate at that time, such analyses allow reconstructing paleo-hydroclimate. One aim of the study was to reconstruct paleo-relative humidity of the Messinian Salinity Crisis. For this purpose, the triple oxygen and hydrogen isotope data was fitted to an appropriate isotope model that is based on the Craig and Gordon formula, which provides absolute paleo-relative humidity estimates. Model input and output data are summarized in Table S2. Keyword(s): Messinian Salinity Crisis; Paleoceanography; paleohumidity; Seawater δ18O; Sr isotopes; triple oxygen isotopes Related to: Deußen, Katharina; Voigt, Claudia; Staubwasser, Michael; Münker, Carsten; El-Shenawy, Mohammed; Klipsch, Swea; Herwartz, Daniel (2024): Hydroclimate of the Messinian Salinity Crisis constrained from paleo-water triple oxygen, hydrogen, and strontium isotopes. Geochimica et Cosmochimica Acta, 375, 134-145, https://doi.org/10.1016/j.gca.2024.05.007 Funding: German Research Foundation (DFG) (URI: http://www.dfg.de/en/), grant/award no. HE6357/4-1: Heisenberg grant Coverage: MEDIAN LATITUDE: 34.813182 * MEDIAN LONGITUDE: 32.575409 * SOUTH-BOUND LATITUDE: 34.812567 * WEST-BOUND LONGITUDE: 32.575000 * NORTH-BOUND LATITUDE: 34.813798 * EAST-BOUND LONGITUDE: 32.575818 MINIMUM ELEVATION: 370.0 m * MAXIMUM ELEVATION: 370.0 m Event(s): Polemi_basin_gypsum_outcrop_1 (Outcrop 1) * LATITUDE: 34.812567 * LONGITUDE: 32.575000 * ELEVATION: 370.0 m * LOCATION: Cyprus * METHOD/DEVICE: Outcrop sample (OUTCROP) Polemi_basin_gypsum_outcrop_2 (Outcrop 2) * LATITUDE: 34.813798 * LONGITUDE: 32.575818 * ELEVATION: 370.0 m * LOCATION: Cyprus * METHOD/DEVICE: Outcrop sample (OUTCROP) Comment: Isotope values are given in ‰ relative to standard mean ocean water (SMOW). For convenience, 17O-excess is given in ppm, which is ‰/1000. Parameter(s): Event label (Event) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) Outcrop ID (Outcrop ID) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) Sample code/label (Sample label) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) Sample ID (Sample ID) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) Date of determination (Date deter) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * COMMENT: Analyses date oxygen isotopes Time point, descriptive (Time point) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * COMMENT: Analyses time δ18O, water [‰ SMOW] (δ18O H2O) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O δ18O, water, standard deviation [±] (δ18O H2O std dev) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O δ17O, water [‰ SMOW] (δ17O H2O) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O δ17O, water, standard deviation [±] (δ17O H2O std dev) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O Oxygen-17 excess [per meg] (17O xs) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O Oxygen-17 excess, standard deviation [±] (17O xs std dev) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O Date of determination (Date deter) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * COMMENT: Analyses date deuterium δ Deuterium [‰ SMOW] (δD) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O δ Deuterium, standard deviation [±] (δD std dev) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O Deuterium excess [‰] (d xs) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O Deuterium excess, standard deviation [±] (d xs std dev) * PI: Herwartz, Daniel (https://orcid.org/0000-0003-3604-8295, Daniel.Herwartz@rub.de) * METHOD/DEVICE: Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 * COMMENT: crystal bound H2O License: Creative Commons Attribution 4.0 International (CC-BY-4.0) (URI: https://creativecommons.org/licenses/by/4.0/) Status: Curation Level: Enhanced curation (URI: https://wiki.pangaea.de/wiki/Curation_levels) Size: 672 data points */ Event Outcrop ID Sample label Sample ID Date deter (Analyses date oxygen isotopes) Time point (Analyses time) δ18O H2O [‰ SMOW] (crystal bound H2O) δ18O H2O std dev [±] (crystal bound H2O) δ17O H2O [‰ SMOW] (crystal bound H2O) δ17O H2O std dev [±] (crystal bound H2O) 17O xs [per meg] (crystal bound H2O) 17O xs std dev [±] (crystal bound H2O) Date deter (Analyses date deuterium) δD [‰ SMOW] (crystal bound H2O) δD std dev [±] (crystal bound H2O) d xs [‰] (crystal bound H2O) d xs std dev [±] (crystal bound H2O) Polemi_basin_gypsum_outcrop_1 1 1 1_1 2020-09-10 00:01-23:59 4.17 2.19 -10 13 2020-10-06 -24.1 0.4 -57.5 Polemi_basin_gypsum_outcrop_1 1 1 1_1 2020-09-10 00:01-23:59 4.07 2.13 -16 15 2020-10-06 -24.1 0.4 -56.6 Polemi_basin_gypsum_outcrop_1 1 1 1_2 2021-05-26 00:01-23:59 2.13 1.10 -26 7 2021-06-02 -25.7 0.1 -42.8 Polemi_basin_gypsum_outcrop_1 1 1 1_2 2021-05-26 00:01-23:59 2.52 1.30 -25 1 2021-06-02 -25.7 0.1 -45.8 Polemi_basin_gypsum_outcrop_1 1 1 1_3 2021-10-05 00:01-23:59 3.33 1.74 -17 9 2021-10-27 -24.5 0.3 -51.1 Polemi_basin_gypsum_outcrop_1 1 1 1_3 2021-10-05 00:01-23:59 3.17 1.66 -14 6 2021-10-27 -24.5 0.3 -49.8 Polemi_basin_gypsum_outcrop_1 Mean 3.23 0.81 1.69 0.43 -18 6 -24.8 0.7 -50.6 5.8 Polemi_basin_gypsum_outcrop_1 1 2 2_1 2021-05-26 00:01-23:59 3.17 1.66 -9 7 2021-06-02 -28.8 0.4 -54.1 Polemi_basin_gypsum_outcrop_1 1 2 2_1 2021-05-26 00:01-23:59 2.45 1.28 -18 2 2021-06-02 -28.8 0.4 -48.4 Polemi_basin_gypsum_outcrop_1 1 2 2_2 2020-04-01 00:01-23:59 2.82 1.47 -22 17 2020-04-11 -24.2 0.4 -46.8 Polemi_basin_gypsum_outcrop_1 Mean 2.82 0.36 1.47 0.19 -16 7 -27.2 2.6 -49.8 3.9 Polemi_basin_gypsum_outcrop_1 1 3 3_1 2020-03-31 00:01-23:59 4.16 2.18 -18 7 2020-04-11 -17.4 0.4 -50.7 Polemi_basin_gypsum_outcrop_1 1 3 3_1 2020-03-31 00:01-23:59 4.60 2.43 0 13 2020-04-11 -17.4 0.4 -54.3 Polemi_basin_gypsum_outcrop_1 Mean 4.38 0.31 2.30 0.18 -9 13 -17.4 0.0 -52.5 2.5 Polemi_basin_gypsum_outcrop_1 1 4 4_1 2020-03-31 00:01-23:59 4.05 2.12 -22 8 2020-04-11 -16.6 0.4 -49.1 Polemi_basin_gypsum_outcrop_1 1 4 4_1 2020-03-31 00:01-23:59 4.18 2.19 -12 7 2020-04-11 -16.6 0.4 -50.0 Polemi_basin_gypsum_outcrop_1 Mean 4.12 0.09 2.15 0.05 -17 7 -16.6 0.0 -49.6 0.7 Polemi_basin_gypsum_outcrop_1 1 6 6_1 2020-09-10 00:01-23:59 5.90 3.09 -19 8 2020-10-06 -13.3 0.4 -60.5 Polemi_basin_gypsum_outcrop_1 1 6 6_1 2020-09-10 00:01-23:59 5.88 3.08 -17 10 2020-10-06 -13.3 0.4 -60.4 Polemi_basin_gypsum_outcrop_1 1 6 6_2 2021-05-26 00:01-23:59 6.07 3.18 -25 2 2021-06-02 -11.2 0.2 -59.8 Polemi_basin_gypsum_outcrop_1 1 6 6_2 2021-05-26 00:01-23:59 5.93 3.11 -20 0 2021-06-02 -11.2 0.2 -58.7 Polemi_basin_gypsum_outcrop_1 Mean 5.95 0.09 3.12 0.04 -20 3 -12.3 1.2 -59.9 0.8 Polemi_basin_gypsum_outcrop_1 1 7 7_1 2020-03-31 00:01-23:59 6.63 3.46 -38 18 2020-04-11 -5.7 0.4 -58.7 Polemi_basin_gypsum_outcrop_1 1 7 7_1 2020-03-31 00:01-23:59 7.02 3.69 -9 4 2020-04-11 -5.7 0.4 -61.9 Polemi_basin_gypsum_outcrop_1 Mean 6.82 0.28 3.57 0.16 -24 20 -5.7 0.0 -60.3 2.2 Polemi_basin_gypsum_outcrop_1 1 8 8_1 2020-04-01 00:01-23:59 5.94 3.11 -24 9 2020-04-11 -4.7 0.4 -52.2 Polemi_basin_gypsum_outcrop_1 1 8 8_1 2020-04-01 00:01-23:59 6.34 3.31 -35 17 2020-04-11 -4.7 0.4 -55.4 Polemi_basin_gypsum_outcrop_1 Mean 6.14 0.29 3.21 0.14 -30 8 -4.7 0.0 -53.8 2.3 Polemi_basin_gypsum_outcrop_1 1 9 9_1 2020-09-10 00:01-23:59 5.95 3.12 -16 11 2020-10-06 -15.9 0.3 -63.5 Polemi_basin_gypsum_outcrop_1 1 9 9_1 2020-09-10 00:01-23:59 5.94 3.11 -24 11 2020-10-06 -15.9 0.3 -63.5 Polemi_basin_gypsum_outcrop_1 1 9 9_2 2021-06-01 00:01-23:59 5.31 2.77 -28 2 2021-06-02 -15.7 0.1 -58.2 Polemi_basin_gypsum_outcrop_1 1 9 9_2 2021-06-01 00:01-23:59 5.18 2.71 -24 1 2021-06-02 -15.7 0.1 -57.1 Polemi_basin_gypsum_outcrop_1 Mean 5.59 0.41 2.93 0.22 -23 5 -15.8 0.1 -60.6 3.4 Polemi_basin_gypsum_outcrop_2 2 B B_1 2021-06-01 00:01-23:59 5.24 2.75 -15 4 2021-06-02 -16.6 0.4 -58.5 Polemi_basin_gypsum_outcrop_2 2 B B_1 2021-06-01 00:01-23:59 4.86 2.54 -25 3 2021-06-02 -16.6 0.4 -55.5 Polemi_basin_gypsum_outcrop_2 Mean 5.05 0.27 2.65 0.15 -20 7 -16.6 0.0 -57.0 2.1 Polemi_basin_gypsum_outcrop_2 2 C C_1 2021-06-01 00:01-23:59 4.91 2.57 -23 11 2021-06-03 -18.8 0.6 -58.1 Polemi_basin_gypsum_outcrop_2 2 C C_1 2021-06-01 00:01-23:59 4.39 2.29 -27 4 2021-06-03 -18.8 0.6 -53.9 Polemi_basin_gypsum_outcrop_2 Mean 4.65 0.37 2.43 0.20 -25 3 -18.8 0.0 -56.0 2.9 Polemi_basin_gypsum_outcrop_2 2 E E_1 2021-06-01 00:01-23:59 4.21 2.21 -15 5 2021-06-03 -22.1 0.5 -55.7 Polemi_basin_gypsum_outcrop_2 2 E E_1 2021-06-01 00:01-23:59 3.75 1.96 -20 4 2021-06-03 -22.1 0.5 -52.1 Polemi_basin_gypsum_outcrop_2 Mean 3.98 0.33 2.08 0.17 -18 3 -22.1 0.0 -53.9 2.6 Polemi_basin_gypsum_outcrop_2 2 F F_1 2020-04-01 00:01-23:59 5.67 2.97 -19 17 2020-04-11 -11.0 0.4 -56.3 Polemi_basin_gypsum_outcrop_2 2 F F_1 2020-04-01 00:01-23:59 5.65 2.95 -25 12 2020-04-11 -11.0 0.4 -56.2 Polemi_basin_gypsum_outcrop_2 2 F F_2 2021-10-05 00:01-23:59 5.49 2.88 -17 5 2021-10-27 -12.2 0.3 -56.1 Polemi_basin_gypsum_outcrop_2 2 F F_2 2021-10-05 00:01-23:59 5.09 2.66 -22 7 2021-10-27 -12.2 0.3 -52.9 Polemi_basin_gypsum_outcrop_2 Mean 5.47 0.27 2.87 0.14 -21 3 -11.6 0.7 -55.4 1.6 Polemi_basin_gypsum_outcrop_2 2 G1 G1_1 2021-04-20 00:01-23:59 5.83 3.06 -15 3 2020-04-11 -14.8 0.4 -61.5 Polemi_basin_gypsum_outcrop_2 2 G1 G1_2 2021-10-05 00:01-23:59 5.53 2.90 -10 4 2021-10-27 -10.4 0.3 -54.6 Polemi_basin_gypsum_outcrop_2 2 G1 G1_2 2021-10-05 00:01-23:59 5.58 2.93 -14 5 2021-10-27 -10.4 0.3 -55.0 Polemi_basin_gypsum_outcrop_2 Mean 5.64 0.16 2.96 0.08 -13 3 -11.9 2.6 -57.0 3.8 Polemi_basin_gypsum_outcrop_2 2 G G_1 2020-07-10 00:01-23:59 5.74 3.00 -32 2020-10-06 -19.9 0.4 -65.9 Polemi_basin_gypsum_outcrop_2 2 G G_1 2020-07-10 00:01-23:59 5.73 2.98 -41 2020-10-06 -19.9 0.4 -65.7 Polemi_basin_gypsum_outcrop_2 Mean 5.74 0.01 2.99 0.01 -37 7 -19.9 0.0 -65.8 0.1