Deußen Katharina k.deussen@uni-koeln.de University of Cologne https://ror.org/00rcxh774 Voigt Claudia cvoigt@ual.es University of Almería https://ror.org/003d3xx08 Staubwasser Michael m.staubwasser@uni-koeln.de 0000-0002-5892-1115 University of Cologne https://ror.org/00rcxh774 Münker Carsten c.muenker@uni-koeln.de 0000-0001-6406-559X University of Cologne https://ror.org/00rcxh774 El-Shenawy Mohammed mishenawy@gmail.com Beni-Suef University https://ror.org/05pn4yv70 Klipsch Swea sklipsc1@uni-koeln.de University of Cologne https://ror.org/00rcxh774 Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Ruhr University Bochum RUB https://www.ruhr-uni-bochum.de https://ror.org/04tsk2644 2024 Triple oxygen and hydrogen isotope data of gypsum from Cyprus dataset https://doi.org/10.1594/PANGAEA.967561 2024-05-02T11:36:14 Gypsum samples collected in two outcrops located in the Polemi basin, Cyprus, have been analyzed for their triple oxygen and hydrogen isotopic composition. Respective methods are described in the original publication. The oxygen and hydrogen data provided here is derived from the crystal bound H2O within the Gypsum (CaSO4*2H2O), which allows calculating paleo-water isotopic compositions of the mother brine from which this gypsum precipitated during the Messinian Salinity Crisis. Because the isotopic composition of the mother brine is affected by the local hydroclimate at that time, such analyses allow reconstructing paleo-hydroclimate. One aim of the study was to reconstruct paleo-relative humidity of the Messinian Salinity Crisis. For this purpose, the triple oxygen and hydrogen isotope data was fitted to an appropriate isotope model that is based on the Craig and Gordon formula, which provides absolute paleo-relative humidity estimates. Model input and output data are summarized in Table S2. Deußen Katharina k.deussen@uni-koeln.de Voigt Claudia cvoigt@ual.es Staubwasser Michael m.staubwasser@uni-koeln.de 0000-0002-5892-1115 Münker Carsten c.muenker@uni-koeln.de 0000-0001-6406-559X El-Shenawy Mohammed mishenawy@gmail.com Klipsch Swea sklipsc1@uni-koeln.de Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 2024 Hydroclimate of the Messinian Salinity Crisis constrained from paleo-water triple oxygen, hydrogen, and strontium isotopes journal article Geochimica et Cosmochimica Acta 375 https://doi.org/10.1016/j.gca.2024.05.007 134-145 32.575 32.575818 34.812567 34.813798 32.575409 34.813182499999996 370.0 370.0 German Research Foundation DFG http://www.dfg.de/en/ https://doi.org/10.13039/501100001659 HE6357/4-1 Heisenberg grant Polemi_basin_gypsum_outcrop_1 Outcrop 1 34.812567 32.575 Cyprus 370.0 Outcrop sample OUTCROP Polemi_basin_gypsum_outcrop_2 Outcrop 2 34.813798 32.575818 Cyprus 370.0 Outcrop sample OUTCROP 672 CC-BY-4.0 Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/ Isotope values are given in ‰ relative to standard mean ocean water (SMOW). For convenience, 17O-excess is given in ppm, which is ‰/1000. Event label Event Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Event Outcrop ID Outcrop ID Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Outcrop ID Sample code/label Sample label Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Sample label Sample ID Sample ID Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Sample ID Date of determination Date deter Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Analyses date oxygen isotopes Date deter (Analyses date oxygen isotopes) Time point, descriptive Time point Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Analyses time Time point (Analyses time) δ18O, water δ18O H2O ‰ SMOW δ18O http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes water http://purl.obolibrary.org/obo/CHEBI_15377 Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O δ18O H2O [‰ SMOW] (crystal bound H2O) δ18O, water, standard deviation δ18O H2O std dev ± δ18O http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes water http://purl.obolibrary.org/obo/CHEBI_15377 standard deviation std dev https://en.wikipedia.org/wiki/Standard_deviation Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O δ18O H2O std dev [±] (crystal bound H2O) δ17O, water δ17O H2O ‰ SMOW Δ17O water http://purl.obolibrary.org/obo/CHEBI_15377 Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O δ17O H2O [‰ SMOW] (crystal bound H2O) δ17O, water, standard deviation δ17O H2O std dev ± water http://purl.obolibrary.org/obo/CHEBI_15377 standard deviation std dev https://en.wikipedia.org/wiki/Standard_deviation Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O δ17O H2O std dev [±] (crystal bound H2O) Oxygen-17 excess 17O xs per meg https://doi.org/10.1002/rcm.3180 Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O 17O xs [per meg] (crystal bound H2O) Oxygen-17 excess, standard deviation 17O xs std dev ± oxygen-17 excess www.doi.org/10.1002/rcm.3180 standard deviation std dev https://en.wikipedia.org/wiki/Standard_deviation Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O 17O xs std dev [±] (crystal bound H2O) Date of determination Date deter Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 Analyses date deuterium Date deter (Analyses date deuterium) δ Deuterium δD ‰ SMOW https://en.wikipedia.org/wiki/Deuterium Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O δD [‰ SMOW] (crystal bound H2O) δ Deuterium, standard deviation δD std dev ± standard deviation std dev https://en.wikipedia.org/wiki/Standard_deviation Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O δD std dev [±] (crystal bound H2O) Deuterium excess d xs ‰ Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O d xs [‰] (crystal bound H2O) Deuterium excess, standard deviation d xs std dev ± standard deviation std dev https://en.wikipedia.org/wiki/Standard_deviation Isotope ratio mass spectrometer (IRMS), Thermo Fisher, MAT253 Thermo Fisher Scientific MAT 253 isotope ratio mass spectrometer http://vocab.nerc.ac.uk/collection/L22/current/TOOL2142/ Herwartz Daniel Daniel.Herwartz@rub.de 0000-0003-3604-8295 crystal bound H2O d xs std dev [±] (crystal bound H2O) CurationLevelC Enhanced curation https://wiki.pangaea.de/wiki/Curation_levels citable Messinian Salinity Crisis Paleoceanography paleohumidity Seawater δ18O Sr isotopes triple oxygen isotopes author105279 author105280 author105281 author105282 author30050 author39216 author91906 award3052 curlevel30 event3155723 event3155724 funder20472 geocode1600 geocode1601 geocode8128 inst12598 inst20654 inst21547 inst21548 journal6009 license21 method11405 method16724 param135373 param1537 param16065 param167254 param171964 param184866 param190246 param50137 param50140 param507230 param507232 param59577 param761 param790 param8146 pi91906 ref125449 term1073093 term22110 term2606205 term37764 term4047470 term44272 term44273 term47129 term47684 term50341 term68568 term74037 term74038