Citation:

PANGAEA.967014

Name: Dissolved copper-binding ligands measured in seawater samples from the POLARSTERN cruise PS94 (GEOTRACES GN04)
Published: 2024-03-26
License: https://creativecommons.org/licenses/by-sa/4.0/
Keywords: Arctic Ocean; copper; Eurasian Basin; GEOTRACES; GN04; Organic-binding ligands; PS94

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Abstract:

Copper (Cu) is an important micronutrient involved in different phytoplankton metabolic processes. In seawater, Cu speciation is controlled by the formation of organic complexes with natural binding ligands, which controls its bioavailability and toxicity. The information about Cu organic speciation in the ocean is scarce, particularly in the Arctic Ocean where the ongoing climate change is altering the seawater chemistry. This dataset contains measurements of Cu-binding ligands from station depth profiles sampled between from the Norwegian Coast to the Central Arctic Ocean. Samples were collected during GEOTRACES expedition GN04 (Polarstern cruise PS94) between 17 August and 14 October 2015, following GEOTRACES guidelines (https://www.geotraces.org). The Competitive-Ligand Exchange Adsorptive Cathodic Stripping Voltammetry (CLE-ACSV), using Salicylaldoxime (SA) as competitive ligand (Campos and van den Berg, 1994), was the technique applied to determine the Cu-binding ligand concentrations (LCu) and conditional stability constants (logKcu2+L). The concentration of dissolved copper used for the analysis has been reported by Gerringa et al. (2021) (doi:10.1594/PANGAEA.932797).

Keyword(s):

Arctic Ocean; copper; Eurasian Basin; GEOTRACES; GN04; Organic-binding ligands; PS94

Related to:

Arnone, Veronica; Santana-Casiano, Juana Magdalena; González-Dávila, Melchor; Planquette, Hélène; Sarthou, Géraldine; Gerringa, Loes J A; González, Aridane G (2023): Natural copper-binding ligands in the Arctic Ocean. The influence of the Transpolar Drift (GEOTRACES GN04). Frontiers in Marine Science, 10, 1306278, https://doi.org/10.3389/fmars.2023.1306278

Gerringa, Loes J A; Rijkenberg, Micha; Laan, Patrick; Middag, Rob; Rutgers van der Loeff, Michiel M (2021): Dissolved trace metals cadmium (Cd), cobalt (Co), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), zinc (Zn) measured in samples from the Polarstern cruise PS94 to the Arctic Ocean from August to October 2015. PANGAEA, https://doi.org/10.1594/PANGAEA.932797

References:

Lucia, Melcarne; Campos, A M; van den Berg, Constant M G (1994): Determination of copper complexation in sea water by cathodic stripping voltammetry and ligand competition with salicylaldoxime. Analytica Chimica Acta, 284(3), 481-496, https://doi.org/10.1016/0003-2670(94)85055-0

Project(s):

Global marine biogeochemical cycles of trace elements and their isotopes (GEOTRACES)

Funding:

Centre National de la Recherche Scientifique (CNRS), grant/award no. ANR-17-EURE-0015: ISblue

Ministerio de Ciencia e Innovación (MICINN), grant/award no. PRE2018-084476

Ministerio de Economía y Competitividad (MEC), grant/award no. CTM2017-83476-P

Coverage:

Median Latitude: 84.494613 * Median Longitude: 107.537676 * South-bound Latitude: 70.999300 * West-bound Longitude: 21.192800 * North-bound Latitude: 89.930200 * East-bound Longitude: -116.679800

Date/Time Start: 2015-08-20T01:23:00 * Date/Time End: 2015-10-09T04:27:00

Minimum Elevation: -4826.0 m * Maximum Elevation: -151.5 m

Event(s):

PS94/004-2 * Latitude: 79.253330 * Longitude: 30.046170 * Date/Time: 2015-08-20T01:23:00 * Elevation: -228.2 m * Location: Barents Sea * Campaign: (ARK-XXIX/3) * Basis: * Method/Device: (CTD-UC)

PS94/032-4 * Latitude: 81.854000 * Longitude: 30.893330 * Date/Time: 2015-08-22T14:35:00 * Elevation: -3169.0 m * Location: Arctic Ocean * Campaign: (ARK-XXIX/3) * Basis: * Method/Device: (CTD-UC)

PS94/050-3 * Latitude: 84.394000 * Longitude: 30.544170 * Date/Time: 2015-08-26T12:21:00 * Elevation: -4055.7 m * Location: Arctic Ocean * Campaign: (ARK-XXIX/3) * Basis: * Method/Device: (CTD-UC)

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Cruise/expedition	Expedition		Arnone, Veronica
2	Event label	Event		Arnone, Veronica
3	Station label	Station		Arnone, Veronica
4	LATITUDE	Latitude		Arnone, Veronica		Geocode
5	LONGITUDE	Longitude		Arnone, Veronica		Geocode
6	DATE/TIME	Date/Time		Arnone, Veronica		Geocode
7	ELEVATION	Elevation	m a.s.l.	Arnone, Veronica	CTD, Sea-Bird SBE 911plus	Geocode – neg. bottom depth
8	Bottle number	Bottle		Arnone, Veronica
9	DEPTH, water	Depth water	m	Arnone, Veronica	CTD, Sea-Bird SBE 911plus	Geocode
10	Pressure, water	Press	dbar	Arnone, Veronica	CTD, Sea-Bird SBE 911plus
11	Copper-binding ligand	Cu ligand	nmol/l	Arnone, Veronica	Competitive-ligand exchange adsorptive cathodic stripping voltammetry (CLE-ACSV)
12	Copper-binding ligand, standard deviation	Cu ligand std dev	±	Arnone, Veronica	Competitive-ligand exchange adsorptive cathodic stripping voltammetry (CLE-ACSV)
13	Copper-binding ligand, conditional stability constant	log KcondCu2+L		Arnone, Veronica	Competitive-ligand exchange adsorptive cathodic stripping voltammetry (CLE-ACSV)
14	Copper-binding ligand, conditional stability constant, standard deviation	log KcondCu2+L e	±	Arnone, Veronica	Competitive-ligand exchange adsorptive cathodic stripping voltammetry (CLE-ACSV)

License:

Creative Commons Attribution-ShareAlike 4.0 International (CC-BY-SA-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

1806 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Expedition	2 Event	3 Station	4 Latitude	5 Longitude	6 Date/Time	7 Elevation [m a.s.l.]	8 Bottle	9 Depth water [m]	10 Press [dbar]	11 Cu ligand [nmol/l]	12 Cu ligand std dev [±]	13 log KcondCu2+L	14 log KcondCu2+L e [±]
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	1	186.0	188.0	2.697	0.155	14.6800	0.103
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	2	149.0	151.0	2.555	0.070	14.8070	0.044
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	6	128.0	129.0	2.254	0.056	13.9580	0.028
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	15	64.0	65.0	2.114	0.127	15.0820	0.121
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	19	42.0	42.0	1.818	0.055	15.2160	0.061
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	21	17.0	17.0	2.438	0.194	15.4000	0.350
GN04 (PS94)	PS94/004-2	4	79.2497	30.0380	2015-08-20T01:23	228	23	10.0	10.0	2.656	0.146	14.7300	0.081
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	1	2564.9	2608.6	2.413	0.145	14.5530	0.095
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	3	1959.6	1990.1	1.908	0.172	14.4180	0.137
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	5	1467.5	1488.6	1.674	0.071	14.4460	0.058
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	7	977.5	990.4	2.542	0.191	14.4000	0.094
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	9	483.9	489.7	1.649	0.181	14.7090	0.257
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	12	198.0	200.2	1.710	0.077	15.0980	0.083
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	14	153.2	154.9	2.235	0.067	14.4140	0.050
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	19	76.6	77.4	2.230	0.234	14.1600	0.120
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	20	56.9	57.5	1.852	0.032	15.3530	0.031
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	21	40.4	40.8	2.012	0.146	14.8810	0.112
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	23	22.6	22.8	1.475	0.044	15.1370	0.061
GN04 (PS94)	PS94/032-4	32	81.8540	30.8933	2015-08-22T14:35	3169	24	7.6	7.7	1.396	0.073	15.1490	0.098
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	3	3184.4	3243.5	1.678	0.067	14.8170	0.074
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	5	2695.9	2742.8	1.662	0.116	14.8347	0.145
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	7	1962.3	1993.0	1.659	0.141	14.5320	0.138
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	11	979.9	992.9	1.601	0.104	14.3880	0.094
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	13	488.2	494.1	1.513	0.045	15.1830	0.076
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	16	242.5	245.3	1.640	0.030	14.7500	0.068
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	18	143.9	145.5	1.748	0.114	14.9460	0.120
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	21	55.3	55.9	1.600	0.040	14.5800	0.036
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	22	35.9	36.3	1.766	0.031	15.1030	0.038
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	23	20.0	20.0	1.620	0.201	14.6700	0.395
GN04 (PS94)	PS94/050-3	50	84.3940	30.5442	2015-08-26T12:21	4056	24	5.9	6.0	1.940	0.092	14.7630	0.074
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	1	3702.8	3776.2	1.778	0.178	14.3780	0.180
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	6	2450.6	2491.8	1.703	0.038	14.5980	0.029
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	8	1715.7	1741.5	1.610	0.142	14.6700	0.189
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	10	1225.5	1242.5	1.653	0.083	14.6130	0.110
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	12	732.5	741.7	1.717	0.047	14.8250	0.052
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	14	389.0	393.6	1.595	0.128	14.9590	0.142
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	15	292.7	296.1	1.970	0.266	14.6820	0.220
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	17	193.7	195.9	1.576	0.024	14.8710	0.030
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	19	96.4	97.5	1.695	0.152	14.9220	0.224
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	20	76.4	77.2	1.821	0.109	14.9390	0.112
GN04 (PS94)	PS94/054-3	54	85.0985	42.4398	2015-08-28T11:43	4017	21	56.8	57.4	2.033	0.076	14.4640	0.051
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	1	3653.0	3725.0	1.700	0.045	14.7700	0.059
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	5	1962.0	1992.7	1.760	0.097	14.9400	0.151
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	7	1470.8	1492.0	1.583	0.091	14.3270	0.079
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	9	980.3	993.3	1.888	0.099	14.8920	0.089
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	11	487.4	493.3	1.808	0.095	14.6970	0.081
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	14	242.0	244.8	1.714	0.081	14.8900	0.074
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	18	93.9	94.9	1.675	0.046	15.4360	0.093
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	21	36.3	36.7	1.723	0.065	15.4360	0.178
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	23	16.5	16.7	1.770	0.167	14.4300	0.093
GN04 (PS94)	PS94/058-7	58	85.3097	59.8220	2015-08-30T05:15	3930	24	6.5	6.6	1.743	0.074	14.7210	0.081
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	1	1083.8	1098.4	2.070	0.197	14.2330	0.100
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	4	684.2	692.8	2.057	0.046	15.1170	0.053
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	10	388.7	393.3	1.970	0.158	14.7930	0.118
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	12	290.3	293.7	1.812	0.127	15.0650	0.173
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	14	191.8	194.0	1.916	0.057	14.6120	0.044
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	16	142.2	143.8	1.919	0.077	14.7120	0.059
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	18	94.9	96.0	2.003	0.080	14.9200	0.090
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	19	75.7	76.5	2.400	0.090	14.2720	0.043
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	20	55.9	56.5	2.636	0.191	14.3580	0.086
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	22	26.2	26.5	2.710	0.221	14.4500	0.079
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	23	16.2	16.4	2.536	0.152	14.9680	0.172
GN04 (PS94)	PS94/064-2	64	86.4153	60.1520	2015-09-01T08:56	2104	24	6.7	6.8	2.411	0.157	14.6610	0.110
GN04 (PS94)	PS94/069-2	69	86.9982	58.7307	2015-09-02T10:17	4826	1	4230.3	4319.6	1.729	0.060	14.6100	0.058
GN04 (PS94)	PS94/069-2	69	86.9982	58.7307	2015-09-02T10:17	4826	4	3426.6	3492.3	1.871	0.075	14.8550	0.082
GN04 (PS94)	PS94/069-2	69	86.9982	58.7307	2015-09-02T10:17	4826	8	1961.9	1992.6	1.720	0.028	14.7500	0.052
GN04 (PS94)	PS94/069-2	69	86.9982	58.7307	2015-09-02T10:17	4826	11	979.6	992.6	2.201	0.121	14.7340	0.088
GN04 (PS94)	PS94/069-2	69	86.9982	58.7307	2015-09-02T10:17	4826	18	95.4	96.5	2.362	0.106	15.0680	0.151
GN04 (PS94)	PS94/069-2	69	86.9982	58.7307	2015-09-02T10:17	4826	21	37.2	37.6	3.198	0.104	14.8770	0.082
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	2	2842.1	2892.6	1.695	0.119	14.7820	0.118
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	4	2646.7	2692.5	1.796	0.189	14.3900	0.122
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	5	2549.0	2592.5	1.720	0.075	14.9300	0.129
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	9	1962.2	1992.9	1.635	0.098	14.8260	0.089
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	11	1226.0	1243.0	1.839	0.069	15.0420	0.068
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	13	733.5	742.8	1.838	0.046	15.0060	0.045
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	15	239.9	242.6	1.670	0.036	15.2700	0.077
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	17	116.5	117.8	2.236	0.553	14.9910	0.412
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	20	56.9	57.5	2.654	0.119	14.8990	0.104
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	23	17.3	17.5	2.999	0.128	14.5030	0.073
GN04 (PS94)	PS94/070-4	70	86.9535	55.4368	2015-09-03T12:07	3254	24	7.6	7.7	2.835	0.213	14.7210	0.184
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4401	1	4147.0	4233.0	1.940	0.136	14.8580	0.163
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4401	3	3427.0	3492.0	1.691	0.068	15.0000	0.075
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4401	5	2451.0	2492.0	1.760	0.083	15.3000	0.203
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4401	8	1472.0	1493.0	1.630	0.066	14.7100	0.067
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4401	10	980.0	993.0	1.529	0.046	15.0130	0.075
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4400	14	191.0	193.0	2.089	0.078	14.9340	0.075
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4400	17	94.0	95.0	2.488	0.044	15.1820	0.061
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4400	18	76.0	77.0	3.029	0.068	14.9210	0.060
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4400	20	37.0	37.0	3.957	0.089	14.8450	0.059
GN04 (PS94)	PS94/081-10	81	89.0056	60.0000	2015-09-06T18:08	4400	23	17.0	17.0	6.272	0.094	14.8020	0.037
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	1	3943.6	4024.2	2.259	0.147	14.0360	0.070
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	4	2939.8	2992.8	1.853	0.130	14.8220	0.126
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	7	1962.2	1993.0	2.040	0.066	14.9990	0.060
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	9	1225.8	1242.8	1.661	0.141	14.2920	0.100
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	11	733.6	742.9	1.850	0.042	15.0170	0.060
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	13	293.3	296.7	1.449	0.065	14.6080	0.080
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	15	143.9	145.5	2.276	0.051	15.1650	0.068
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	17	94.5	95.5	3.633	0.136	14.4700	0.058
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	19	54.6	55.2	4.286	0.193	14.2580	0.078
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	23	15.6	15.8	5.928	0.296	14.5600	0.102
GN04 (PS94)	PS94/087-1	87	89.9302	-120.1948	2015-09-08T04:28	4264	24	6.5	6.6	7.141	0.232	14.2090	0.057
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	1	1085.7	1100.4	1.837	0.078	15.3790	0.115
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	7	486.4	492.3	2.783	0.195	14.7560	0.081
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	12	190.7	192.9	2.409	0.127	14.7460	0.081
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	15	116.5	117.8	2.498	0.075	15.2350	0.091
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	17	76.7	77.5	4.932	0.296	14.7870	0.111
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	23	17.1	17.3	7.911	0.158	14.3020	0.043
GN04 (PS94)	PS94/091-2	91	89.1633	-116.6798	2015-09-09T11:01	1331	24	7.1	7.2	7.350	0.165	14.6300	0.066
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	3	2939.5	2992.5	1.866	0.117	14.6160	0.095
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	6	1961.7	1992.4	2.161	0.162	14.5090	0.080
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	8	1470.3	1491.6	2.274	0.262	14.6960	0.176
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	10	978.8	991.8	2.380	0.305	14.8600	0.163
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	12	485.5	491.4	2.137	0.123	15.3390	0.153
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	14	189.2	191.3	2.087	0.110	14.6630	0.103
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	17	96.6	97.7	3.355	0.117	14.8820	0.074
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	18	76.9	77.7	3.976	0.089	14.2690	0.043
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	19	56.9	57.5	4.952	0.124	14.3480	0.050
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	20	37.1	37.5	6.423	0.161	14.5150	0.058
GN04 (PS94)	PS94/096-4	96	88.3530	-124.9295	2015-09-11T10:43	3587	24	7.6	7.7	7.586	0.209	14.4450	0.058
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	1	3452.5	3519.0	1.978	0.336	14.2930	0.214
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	2	3183.4	3242.7	1.979	0.218	14.3110	0.114
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	4	2451.1	2492.4	1.816	0.064	14.6180	0.051
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	7	1716.3	1742.2	1.656	0.108	14.4050	0.079
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	9	1225.3	1242.3	1.887	0.170	14.4350	0.115
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	11	732.8	742.1	2.063	0.155	14.9240	0.179
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	13	288.4	291.7	2.132	0.064	14.9400	0.052
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	14	193.7	195.9	2.140	0.059	15.2380	0.061
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	16	118.8	120.1	2.667	0.060	14.9120	0.052
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	17	96.6	97.7	3.123	0.109	14.9770	0.090
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	19	56.9	57.5	4.760	0.095	14.5770	0.051
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	21	31.1	31.4	6.890	0.131	14.2400	0.043
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	23	17.2	17.4	7.445	0.168	14.1510	0.035
GN04 (PS94)	PS94/099-3	99	88.1827	-155.6600	2015-09-12T20:59	3763	24	7.5	7.6	7.793	0.253	14.0400	0.049
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	1	4119.2	4204.9	2.146	0.172	14.2510	0.086
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	4	2940.1	2993.0	1.623	0.179	14.2200	0.142
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	7	1962.2	1992.9	1.751	0.088	14.6820	0.081
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	10	980.4	993.4	1.656	0.133	14.8720	0.171
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	12	487.7	493.6	1.630	0.046	14.8000	0.067
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	13	289.7	293.0	1.630	0.143	14.4900	0.175
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	15	141.2	142.8	3.655	0.548	13.8340	0.104
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	17	96.4	97.5	2.106	0.074	14.4790	0.065
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	19	56.7	57.3	2.890	0.034	14.8600	0.037
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	23	17.2	17.4	3.932	0.138	14.3690	0.057
GN04 (PS94)	PS94/117-3	117	84.5425	115.9608	2015-09-18T23:37	4320	24	7.1	7.2	3.819	0.162	14.7790	0.111
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	1	4114.8	4200.4	2.101	0.263	14.2090	0.171
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	3	3428.0	3493.7	1.696	0.051	14.7340	0.059
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	5	2451.5	2492.7	1.600	0.035	14.9800	0.060
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	8	1472.2	1493.4	1.660	0.042	15.0700	0.084
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	11	733.5	742.8	1.655	0.074	14.6830	0.073
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	12	487.6	493.5	1.750	0.110	14.7300	0.127
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	14	191.0	193.2	1.750	0.105	15.0630	0.128
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	16	116.9	118.2	2.088	0.136	14.7540	0.125
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	17	95.6	96.7	2.779	0.111	14.4850	0.065
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	19	56.6	57.2	3.261	0.179	14.6370	0.110
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	21	31.0	31.3	4.756	0.071	14.9360	0.052
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	23	16.8	17.0	5.218	0.091	14.8070	0.059
GN04 (PS94)	PS94/119-1	119	84.8128	123.8932	2015-09-20T10:20	4386	24	7.2	7.3	5.699	0.142	14.6870	0.059
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	1	4090.5	4175.4	1.721	0.120	14.7560	0.177
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	2	3670.4	3742.9	1.681	0.088	14.6570	0.103
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	4	2939.5	2992.4	1.838	0.124	14.8800	0.156
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	7	1962.4	1993.1	1.620	0.081	14.7750	0.089
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	10	980.5	993.5	1.754	0.066	15.1180	0.106
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	12	487.4	493.3	1.809	0.253	14.4830	0.217
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	13	289.6	292.9	2.250	0.113	14.5770	0.066
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	15	141.1	142.7	2.246	0.140	15.1200	0.129
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	17	96.1	97.2	2.485	0.248	14.6410	0.176
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	18	76.4	77.2	2.637	0.112	14.6870	0.088
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	20	36.8	37.2	4.131	0.124	14.6080	0.051
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	23	17.0	17.2	6.507	0.211	14.9640	0.097
GN04 (PS94)	PS94/121-2	121	85.0123	132.7320	2015-09-21T04:14	4322	24	6.9	7.0	6.732	0.047	15.3350	0.046
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	1	3633.1	3704.5	1.742	0.148	14.7880	0.185
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	2	3427.5	3493.2	1.714	0.077	14.8110	0.104
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	4	2451.0	2492.2	2.093	0.063	14.2870	0.036
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	7	1471.5	1492.7	2.286	0.172	14.6830	0.117
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	9	980.0	993.0	2.431	0.152	14.0150	0.056
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	11	486.7	492.6	1.659	0.046	15.1200	0.076
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	13	288.9	292.2	1.810	0.055	15.0600	0.610
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	14	189.9	192.0	2.180	0.098	15.0080	0.090
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	16	115.7	117.0	2.517	0.069	14.9770	0.052
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	17	96.0	97.1	2.796	0.070	14.9170	0.045
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	19	56.4	57.0	3.250	0.081	14.4610	0.043
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	21	30.6	30.9	4.907	0.123	14.7750	0.066
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	23	16.7	16.9	5.782	0.318	14.6140	0.146
GN04 (PS94)	PS94/125-3	125	85.0808	139.9020	2015-09-22T09:40	3920	24	7.0	7.1	6.172	0.262	14.4110	0.079
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	1	787.7	797.8	1.990	0.105	14.3200	0.057
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	4	586.1	593.3	1.887	0.075	14.9170	0.075
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	6	487.1	493.0	1.617	0.044	14.7850	0.044
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	8	388.8	393.4	1.864	0.149	14.6390	0.117
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	10	289.6	292.9	1.804	0.180	14.7850	0.170
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	15	141.6	143.2	2.312	0.133	14.7000	0.088
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	17	96.0	97.1	2.546	0.095	14.7000	0.074
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	18	76.0	76.8	3.153	0.189	14.6230	0.088
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	20	36.3	36.7	4.443	0.155	14.6990	0.073
GN04 (PS94)	PS94/130-2	130	85.0170	151.6872	2015-09-23T22:45	868	24	6.7	6.8	6.956	0.122	14.4790	0.036
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	4	2452.0	2494.0	1.588	0.091	14.7980	0.104
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	6	1962.0	1993.0	1.884	0.132	14.5800	0.095
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	9	980.0	993.0	1.963	0.069	15.4620	0.093
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	10	733.0	742.0	2.200	0.093	14.6550	0.059
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	11	486.0	492.0	1.640	0.033	14.9700	0.084
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	14	190.0	192.0	2.165	0.195	14.4250	0.151
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	16	116.0	117.0	2.252	0.158	14.9120	0.157
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	17	96.0	97.0	2.642	0.066	15.0980	0.068
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	21	31.0	31.0	5.204	0.182	14.7370	0.103
GN04 (PS94)	PS94/134-2	134	84.4668	167.0097	2015-09-24T18:26	3181	24	7.0	7.0	6.224	0.233	14.7290	0.103
GN04 (PS94)	PS94/147-2	147	75.0065	24.2572	2015-10-06T18:43	152	1	129.9	131.3	2.221	0.200	15.5290	0.272
GN04 (PS94)	PS94/147-2	147	75.0065	24.2572	2015-10-06T18:43	152	8	66.4	67.1	2.360	0.142	15.2130	0.106
GN04 (PS94)	PS94/147-2	147	75.0065	24.2572	2015-10-06T18:43	152	10	43.8	44.3	2.116	0.085	15.2670	0.076
GN04 (PS94)	PS94/147-2	147	75.0065	24.2572	2015-10-06T18:43	152	12	30.7	31.0	2.095	0.100	15.5930	0.133
GN04 (PS94)	PS94/147-2	147	75.0065	24.2572	2015-10-06T18:43	152	14	17.7	17.9	2.275	0.114	15.3140	0.092
GN04 (PS94)	PS94/147-2	147	75.0065	24.2572	2015-10-06T18:43	152	16	8.8	8.9	1.701	0.085	16.0060	0.320
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	1	343.9	347.7	1.767	0.238	15.2370	0.381
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	2	343.6	347.4	2.199	0.187	14.7910	0.155
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	4	343.6	347.4	2.251	0.079	15.0730	0.068
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	6	300.7	304.0	1.843	0.166	15.0770	0.219
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	10	125.0		1.958	0.069	15.4580	0.093
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	12	99.4	100.5	1.744	0.096	15.2490	0.183
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	14	61.0	61.6	1.922	0.250	15.0260	0.338
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	16	40.4	40.8	1.790	0.081	15.4900	0.108
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	19	15.0		1.908	0.172	15.6200	0.390
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	22	2.5	2.5	2.236	0.168	15.3920	0.177
GN04 (PS94)	PS94/169-2	169	71.5673	21.9125	2015-10-08T23:11	358	24	2.9	2.9	2.172	0.282	15.3260	0.307
GN04 (PS94)	PS94/173-2	173	70.9993	21.1928	2015-10-09T04:27	176	1	158.8	160.5	1.826	0.119	15.0760	0.181
GN04 (PS94)	PS94/173-2	173	70.9993	21.1928	2015-10-09T04:27	176	2	140.7	142.2	1.700	0.061	14.8290	0.074
GN04 (PS94)	PS94/173-2	173	70.9993	21.1928	2015-10-09T04:27	176	9	70.2	70.9	2.231	0.201	14.2410	0.121
GN04 (PS94)	PS94/173-2	173	70.9993	21.1928	2015-10-09T04:27	176	11	49.8	50.3	2.236	0.084	15.9010	0.278
GN04 (PS94)	PS94/173-2	173	70.9993	21.1928	2015-10-09T04:27	176	16	9.1	9.2	2.780	0.104	14.7830	0.074