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PANGAEA.
Data Publisher for Earth & Environmental Science
Abstract:
During the continuous flow analysis (CFA) campaigns of the EGRIP ice core at the University of Bern, Switzerland in 2018, 2019 and 2020, subsamples for the analysis of ion concentrations were collected in a 2 – 5 cm resolution from the meltwater. The subsamples were collected into pre-cleaned 10 ml vials and were kept frozen during storage and transportation to the Alfred-Wegener-Institut in Bremerhaven, Germany. Prior to the analysis, the vials containing the discrete decontaminated aliquots of the ice core were melted at room temperature. The vials were then placed into an autosampler for the measurements. Simultaneous analysis of anions and cations was performed using a two-channel Dionex ICS 5000+ reagent-free HPIC system (Thermo Fisher). For the anion (cation) determination an AERS 500 2mm suppressor and ADRS 600 2mm suppressor (CERS 500 2mm and CDRS 600 2mm) together with the Dionex IonPac AG18-Fast-4µm guard column and the AS18 fast-4µm column (IonPac CG12A-5µm guard column and the CS12A-5µm column ) and the Dionex IonPac AS18-Fast-4µm analytical column (IonPac CS12A-5µm column) were used. For the anions an isocratic mode was used. For the cations the mode was changed from isocratic to gradient. Also, the eluent concentration was modified in-between measurements in order to improve the quality of the data. The measurements were calibrated with seven internal standards, prepared from available anion and cation standards. Premixed external standards were used for quality control. In this study, the IC provided a quantitative analysis of the concentration of Na+, NH4+, K+, NO3-, , F−, MSA−, C1−, Br−, and SO42− with an accuracy of 10 %. The accuracy for of Ca2+ and Mg2+ measurements is much lower. We recommend not to use these values. The concentrations of bromide and fluoride are close to the detection limit and are suggest to consider with great care. For details on the sampling protocol or potential contamination during the CFA campaign we ask the users to get in touch with the authors.
Keyword(s):
anions; cations; EGRIP; Ice core; Ion concentrations
Project(s):
Coverage:
Latitude: 75.630000 * Longitude: -35.980000
Event(s):
EGRIP (EastGRIP) * Latitude: 75.630000 * Longitude: -35.980000 * Location: Greenland * Method/Device: Ice drill (ICEDRILL)
Comment:
The depth information of samples was not available at the time of submission and will be added in due course.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labelHörhold, Maria
FluorideF-µg/kgHörhold, MariaIon chromatography (Thermo Fisher ICS 5000+)ppb
Methane sulfonic acidMSAµg/kgHörhold, MariaIon chromatography (Thermo Fisher ICS 5000+)ppb
ChlorideCl-µg/kgHörhold, MariaIon chromatography (Thermo Fisher ICS 5000+)ppb
BromideBr-µg/kgHörhold, MariaIon chromatography (Thermo Fisher ICS 5000+)ppb
Sulfate[SO4]2-µg/kgHörhold, MariaIon chromatography (Thermo Fisher ICS 5000+)ppb
Nitrate[NO3]-µg/kgHörhold, MariaIon chromatography (Thermo Fisher ICS 5000+)ppb
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
117722 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample label

F- [µg/kg]

MSA [µg/kg]

Cl- [µg/kg]

Br- [µg/kg]

[SO4]2- [µg/kg]

[NO3]- [µg/kg]
149.67310354.9300137.7120
217.378601.266200143.4160128.1020
311.364700.47389672.3597110.4080
416.33370164.210088.5953
56.2119689.036087.4447
614.0024079.0206107.6860
710.64210107.1780154.5860
827.11590213.4330156.7660
927.20840295.8530123.3230
1015.11130184.3980145.9310
110.0049705411.2506065.3626142.5000
1230.41090215.8910103.9560
1320.27450185.9640106.6040
140.0039842916.40320150.8760107.7230
1529.08090178.816082.8061
1625.768801.01793097.883286.0716
178.769480.53284170.3630106.5440
186.549370.52711963.2767121.4100
1916.682700.47184975.4330115.9410
2022.219501.305960143.427088.0609
2110.30950119.873094.7573
2211.4300058.6430112.0720
2319.77880151.195086.5031
2419.59900125.5880108.4910
2517.492200.742237110.5610121.9850
2621.125602.557070207.814087.3903
2718.932300.955564117.119077.6716
283.9631727.546474.7019
2913.9083087.929795.5399
3019.126801.173030170.336095.8891
310.0051633024.405702.024390164.922080.4554
32256.98800204.6650446.1700
3320.1213099.095977.3279
3410.4683074.875870.8952
3517.13850109.9490100.1150
3616.72480113.687080.3813
3715.207200.32994747.842680.3515
3829.14250116.4240101.1960
3928.46870193.315079.0267
400.039225207.10934103.685065.2192
413.085400.25631329.838862.4097
425.157560.26894135.526573.4402
430.0060297811.62840163.724061.2549
448.8825994.086568.1947
455.341200.39080239.616286.5252
467.105750.60049439.3604120.2320
4711.2559081.2946117.0210
4821.145701.311530161.273085.0926
4921.79130115.575074.5957
509.1043268.513083.2359
5111.3054089.0916108.7320
5218.63510192.5950118.8830
5324.34480275.879095.8402
5410.51540108.3200106.3910
5513.0379056.2844112.7360
5619.7454090.341895.0873
5730.142900.87890090.399979.7305
5824.512800.72457194.261591.6918
5925.56790117.381074.6279
6049.10740137.850053.2569
6149.05820129.153069.2742
6216.2965090.939689.2284
6318.8936077.162369.4410
640.0061214828.10180130.948064.8237
6545.484101.151210145.867042.0956
6629.219101.296930102.224044.1392
671.634470009.427441.19589070.946170.6567
686.9824243.196871.8149
6914.42960144.497069.6798
7013.96970151.508068.0217
7113.01760154.168079.9323
7215.13820208.835060.0116
738.2240674.556563.9851
745.8859032.227680.1798
758.9055840.016592.5578
7610.8840091.625072.8291
774.9740765.408854.0402
784.2068627.515060.5053
799.8197352.417771.6234
8024.14290122.940063.7437
819.144060.64410462.843565.5056
829.3383852.660156.3422
837.289550.56862160.806838.7211
840.0373522011.9014099.085645.3929
853.043977.7916882.841965.5908
863.194417.27251102.604065.1564
8710.202900.44764751.694298.4488
8811.973700.51158051.0165122.7190
892.7279512.928100.92044364.5250123.3890
9026.35020120.446086.0814
9110.5460072.533590.2803
927.5657153.452590.1176
933.7823313.6523093.084963.3260
944.544897.000850.36270050.092063.9056
953.461574.646820.70505249.087688.2020
965.768080.37401737.516191.8743
973.8172811.580200.676244104.9130103.3450
983.5592318.06330101.484066.7730
993.300578.2890345.158676.1896
1003.207639.4093066.776483.0738
10111.96600101.630069.2041
10210.7917043.887775.1286
1035.176770.28665224.518574.4796
1049.6690743.703991.9823
1053.3870122.29770125.350064.7471
1062.875247.6384062.540255.4977
1073.7035110.911700.59631746.845941.2638
1083.2457516.764200.47391747.626846.0120
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1103.773409.2571194.956963.6526
1113.399483.4865541.375264.6958
11225.2071055.180375.0055
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12312.9290051.362075.9874
1243.1612518.4941070.447374.2148
1253.479146.3182039.029992.3337
1262.9295215.2125076.9125104.1500
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1303.5816112.231901.56464094.151756.5319
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1323.0882427.00840162.128070.1117
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1343.893726.766020.72913669.050788.4863
1354.3549323.6827099.189282.7177
1364.9523916.9256063.163984.8947
1373.206946.9062673.444495.7461
1383.4282910.49570131.046058.6081
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1403.683438.63942129.630083.1795
1414.2769913.13230184.117070.4354
1424.3241511.6896088.001784.7787
1434.5939118.14640177.934076.2094
1443.9568336.76830207.888065.0791
1453.8494712.0439064.975570.3042
1465.2987410.8261083.457374.2712
1474.5465722.89620129.677064.8655
1483.9777526.904501.146680118.871066.9121
1493.7459317.102200.92018597.519386.8940
1501.844060003.8470211.207700.20859555.7919112.4090
1514.8171113.61360103.026089.1490
1525.312399.504871.00695094.858165.5239
1535.030544.9674040.091856.2451
1545.1980623.767900.59993479.997049.7446
1554.6531126.5154059.205352.6168
1564.8192064.0601032.901377.9257
1574.27354101.68100114.636068.6194
1584.1650262.90640122.504045.8663
1595.143359.0710237.937471.2459
1604.7890610.1399044.750389.2642
1614.9674118.65060120.671070.2252
1624.982009.2105955.479297.3776
1635.6415710.1412049.6056135.3660
1644.9716831.90030217.653051.3979
1655.0091311.43890152.505060.2206
1665.727996.0178356.965173.8177
1675.1945022.90140126.712064.0683
1685.0773730.11500150.943073.9235
1694.8470017.49420146.651084.2550
1706.3844512.16720140.160061.0665
1716.221547.6508968.026551.5399
1725.595493.1318435.421272.1549
1734.8060211.8749093.612798.0247
1744.7003412.68470109.614094.9102
1754.849893.5303957.517267.3952
1763.7804040.735278.0598
17711.8865051.1563109.8370
1785.0354221.5547091.173256.8669
1795.3948339.3378062.031639.1187
1805.1112317.853100.30289733.936248.2100
1817.617503.942700.12959128.010362.9976
1820.017057507.7004611.6650053.666078.1086
1837.8365120.3065083.033461.6217
1847.975118.9248860.826242.1268
1859.047182.911680.35740138.804653.7622
1860.933558007.762788.645830.54457668.206185.5688
1878.6660612.9001099.577689.0807
1881.567450009.7893034.23410168.628092.0923
1892.915980005.6297726.82490317.392067.7351
1901.518830007.6181546.36560372.252057.7256
1917.1455313.5566073.420284.1542
1921.178500006.974647.8254229.732983.6581
1936.3050312.2335062.536480.8684
1946.2383931.246200.886318103.964075.8642
1951.123560007.268388.6729138.440987.9902
1966.4150017.2400065.980385.7002
1971.136000006.0465112.6532063.9326115.1750
1986.2857412.3491053.831696.8807
1997.5287413.0260075.111779.4034
2007.3832518.9517068.119264.1299
2017.265636.4895219.791741.0196
2023.2925200012.008100.75431773.2265184.9900
2038.0222613.17890108.166062.5265
2047.5345811.1571089.666746.2673
2051.532870006.785428.6370370.369252.7228
2067.4515911.76940104.775062.5192
2071.433750006.8879558.00770146.786049.6620
2081.121060007.1258769.2725098.266350.2496
2091.400350007.2996415.9990034.677482.7543
2107.354479.2839647.484692.7491
2111.408500007.8089014.8033071.4800102.6910
2128.5412012.6679045.810269.6071
2138.557659.5462430.534756.7094
2141.780470009.023108.1065925.052464.4467
2158.4675814.9111071.638774.5773
2161.617680008.4190720.13580109.414065.1046
2171.304870007.630029.008200.76682960.214565.9175
2187.417099.6390674.848669.0443
2197.3659416.8635099.307962.2203
2208.187016.644300.46086474.355983.5647
2216.7333813.8705091.912294.0455
2226.5492513.4228069.075180.2581
2237.944094.3188631.312888.2226
2247.1455325.0149071.265283.2822
2256.7700340.9270094.703073.6493
2266.4359113.223200.62431554.8162105.1970
2271.856440006.399868.2594731.301482.1252
2281.348840005.7562416.5478059.987859.3800
2296.1881513.2820035.414361.0548
2306.9210613.2373052.632876.2145
2311.830340007.3585125.94850104.148077.1817
2321.521920007.5795724.2058067.389369.4582
2336.3973014.4229035.892061.3282
2345.7307811.165600.32064731.836252.5375
2355.5244612.737100.31656038.647655.3199
2361.287500008.786787.2280419.179856.1382
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2386.8952027.552600.61802657.946747.7373
2391.734910007.791899.6499030.256767.1728
2408.617285.8006720.161375.9946
2416.9688326.6972052.088861.9183
2427.4822032.3664041.264352.0976
2431.558630008.039305.4234225.018384.9206
2448.712715.7435118.1498100.1760
2457.7018413.4960038.4714113.9380
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2471.278650008.2330511.465500.78953449.3215150.1350
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2507.3524524.424400.35779861.448465.0122
2517.6940110.8073032.543560.9163
2521.798520006.8486528.885488.7344
2533.3906000016.3414050.7544144.3040
25451.6595091.041175.9951
2557.0422437.2458055.6144106.2400
2568.6931718.26890270.0410121.2380
2575.565300009.1420163.27050824.289073.6876
2589.6769039.31550262.7550117.3020
2597.7109618.7557040.9293126.3670
2606.510720007.787137.5704826.1057114.3560
2619.1102914.4575076.468196.9288
2626.2702212.0510037.885976.9905
2633.036920006.6186424.3988070.230672.7532
2645.5329714.455800.70339250.321659.5330
2657.4167632.9799066.835353.5117
2666.5988113.020400.29553123.579446.9301
2670.4713617.0368045.587455.2377
26839.7060031.837641.5156
2691.9800900010.5972020.865857.3638
2702.665400007.3611643.2001058.069561.1205
2717.4929817.4045041.682585.3388
2722.518630007.8101815.0208040.586095.1110
2738.429346.107680.31356125.729196.2009
2747.7493935.5480080.885083.8879
2750.333553008.6167011.940200.43125743.003378.8925
2760.715699008.1662428.5764047.025886.3853
2778.8089524.3585064.721377.8157
2782.0127800010.1594015.3918095.846882.6408
27911.0521029.56120115.297066.4946
28011.409508.3794078.406188.0839
2812.2039300010.0355017.0400051.133173.0822
2829.1779015.292500.59227040.219887.8867
2838.7505425.8966044.088377.2298
2841.125670009.6716346.9097072.289776.0703
2857.3064313.4171026.510070.5974
2865.9062720.8449063.048263.0952
2876.3286713.529500.44162039.183349.8886
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2897.6366717.8775032.738940.5202
29011.562703.9268023.364946.1220
29110.8493010.187900.32839942.461076.0945
29210.006209.5356027.132680.9811
2931.537830009.727139.064470.53426543.290190.5216
2949.7410018.1210062.720981.3157
29510.5479010.3005035.858070.6794
2960.3707590012.2924010.6241040.623563.3328
2970.2722920012.0784027.0312030.314463.8947
2981.9907600013.334508.5939718.1700104.7940
29911.7402017.9438031.7435153.8100
3002.0077500011.5714018.8692037.1278156.2840
30112.959408.7490077.2121121.3350
30211.7081022.1951072.342468.2857
3031.6815700010.9394029.086800.31022738.508771.7122
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3067.3331634.81760115.197053.6843
3079.7203419.6373044.671888.0963
3089.4100916.0987026.710964.1031
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3107.9438958.11460103.393051.7090
3119.690599.5586631.853139.0972
31212.964904.6174018.584341.7973
3131.8932400011.6464031.5941042.047950.4610
31411.7828020.597300.18972529.396565.3960
3151.8747200011.2116023.9621055.166679.1123
31611.063007.4546322.895066.3366
31711.9020015.8209033.7272157.3420
3183.3940700011.1067019.5143022.176857.9565
31910.763105.7196025.321656.8830
32012.7159013.2138029.257971.0689
3211.7813300012.7780014.1276040.217371.0697
32213.757307.254550.34338526.595877.1577
32312.6877024.1608037.504770.7654
32410.5248028.423400.19214326.648560.0125
3259.338348.7630344.274062.7278
32611.512909.7564621.425660.4106
32711.5703010.338300.29008528.756261.1950
32812.3325016.7637054.2163103.7630
3299.7111614.7160037.522081.1508
3309.0731319.4562043.566278.2728
3318.0015215.9409024.997554.7025
3329.091955.355630.36390039.644767.7852
3330.570304009.3873735.9601076.144992.1556
3341.682740008.8608718.901300.60041159.048680.4203
3359.9178922.3312048.271373.8207
3368.0445014.0295053.440758.8861
3376.6735539.2258092.419451.6836
3388.395417.2780942.579555.1617
3398.8336018.5819092.250258.5601
3401.983120009.9318634.7151050.187956.9958
3416.9600713.225300.33602343.457071.5211
3420.104439006.4286931.2574044.944953.9295
3438.1045515.543300.15032825.136651.4333
34411.166007.3689630.474959.6112
3459.6430219.048400.61046388.127552.8793
34610.1167012.4984073.469452.6989
3470.2806040011.6138027.8711048.730064.6428
3489.3764417.112500.29368522.944465.8116
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3501.342780007.8148820.1645044.809668.1491
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3531.590930007.934616.5933325.018166.2659
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3566.5502711.0449036.884853.0357
3576.0972422.8697028.498251.9437
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3601.556780009.493626.7493615.077243.4311
3619.505746.403760.46415433.423253.5720
36212.5178033.2003065.322663.3855
3631.289790008.4787215.503100.22219525.301382.1918
3648.3864624.044501.03353081.9798156.8670
3658.2188918.9606023.139077.7637
3661.4988300012.1736010.7187032.112766.6432
3670.7785160041.4466042.473249.9801
3680.7419140014.9101026.342057.4380
36914.259506.398090.31827928.566267.5902
37010.9579011.0884058.698262.1267
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11890.523755002.768514.802020.13215624.7029103.2570
11900.605306002.5837029.1923048.815577.2008
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12380.586508003.0144620.910600.06369032.681892.2017
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20002.1140411.307400.14010516.932684.3170

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