<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_965916</Entry_ID>
<Entry_Title>Boron and carbon isotope, and B/Ca data for a Siderastrea siderea coral core CIM_C_2-2-1/CIM_C_2-2-2 from the Gulf of Mexico</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Harbott, Marie; Rixen, Tim; Kuhnert, Henning; Kasemann, Simone A; Meixner, Anette; Jimenez, Carlos; González-Díaz, Patricia; Wu, Henry C</Dataset_Creator>
<Dataset_Title>Boron and carbon isotope, and B/Ca data for a Siderastrea siderea coral core CIM_C_2-2-1/CIM_C_2-2-2 from the Gulf of Mexico</Dataset_Title>
<Dataset_Release_Date>2025-02-28</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.965916</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>Marie</First_Name>
<Last_Name>Harbott</Last_Name>
<Email>mharbott@ymail.com</Email>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>AGE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Age</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Siderastrea siderea, δ13C</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Siderastrea siderea, Boron/Calcium ratio</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Siderastrea siderea, δ11B</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>B/Ca</Keyword>
<Keyword>Boron isotope</Keyword>
<Keyword>Carbonate chemistry</Keyword>
<Keyword>Carbon isotopes</Keyword>
<Keyword>CIM_C_2-2-1/CIM_C_2-2-2</Keyword>
<Keyword>Diver-held corer</Keyword>
<Sensor_Name>
<Long_Name>Calculated</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Mass spectrometer, Finnigan, MAT 251; Mass spectrometer, Finnigan, MAT 253</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Inductively coupled plasma mass spectrometer (ICPMS), Analytik Jena, Plasma Quant MS Elite</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS), ThermoFisher Scientific, Neptune</Long_Name>
</Sensor_Name>
<Temporal_Coverage>
<Start_Date>2005-07-01</Start_Date>
<Stop_Date>2005-07-01</Stop_Date>
</Temporal_Coverage>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>23.1277</Southernmost_Latitude>
<Northernmost_Latitude>23.1277</Northernmost_Latitude>
<Westernmost_Longitude>-82.4239</Westernmost_Longitude>
<Easternmost_Longitude>-82.4239</Easternmost_Longitude>
</Spatial_Coverage>
<Project>
<Short_Name>MOPGA-OASIS</Short_Name>
<Long_Name>Make Our Planet Great Again-Ocean acidification crisis and global warming observations from tropical corals</Long_Name>
</Project>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>216 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Reference>Chen, Chung; Liu, Lon-Mu (1993): Joint Estimation of Model Parameters and Outlier Effects in Time Series. Journal of the American Statistical Association, 88(421), 284-297, https://doi.org/10.2307/2290724</Reference>
<Reference>Harbott, Marie; Wu, Henry C; Kuhnert, Henning; Jimenez, Carlos; González-Díaz, Patricia; Rixen, Tim (2023): A Warming Southern Gulf of Mexico: Reconstruction of Anthropogenic Environmental Changes From a Siderastrea siderea Coral on the Northern Coast of Cuba. Paleoceanography and Paleoclimatology, 38(12), e2023PA004717, https://doi.org/10.1029/2023PA004717</Reference>
<Reference>Howell, P; Pisias, Nicklas G; Ballance, J; Baughman, J; Ochs, L (2006): ARAND Time-Series Analysis Software. Brown University, Providence RI, https://github.com/jesstierney/arand</Reference>
<Summary>Massive scleractinian corals provide unique opportunities to reconstruct past climatic and chemical changes in the ocean, where there is no additional information. Regular pH measurements and carbonate chemistry observations of the ocean are still sparse but are essential to monitor the health of our oceans. Boron isotopes and B/Ca measured from coral skeletal material can be used to reconstruct the pH and the carbonate chemistry of their environment. The results from boron isotope measurements show an acidifying Gulf of Mexico over 160 years (1845-2005) and declining δ13C. A coral core was drilled in 2005 from a living Siderastrea siderea coral close to Havana, Cuba. The coral core was cut, slabbed and X-rayed at the Leibniz Center for Tropical Marine Research, Bremen. Yearly samples were drilled over two polyps with a Proxxon drill and 1 mm diamond-coated drill bit. Boron Isotopes were measured from the yearly samples for every 3rd year (if there was enough coral skeletal material) at the MARUM facilities in Bremen with a Thermo Fisher Neptune MC-ICP-MS. δ13C was measured on monthly samples on the Thermo Fisher Finnigan MAT 251 and Finnigan Mat 253plus isotope ratio mass spectrometer also at MARUM. Trace elements-Calcium ratios where measured at ZMT on a Plasma Quant MS Elite Inductively Coupled Plasma - Mass Spectrometer with monthly samples. The age model for the dataset was interpolated using the Arand software Ager and Timer (Howell et al., 2006). Outliers were identified with the detection method provided by Chen and Liu (1993). ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.965916"!</Summary>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/Kyr</URL>
<Description>AGE</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1029/2023PA004717</URL>
<Description>A Warming Southern Gulf of Mexico: Reconstruction of Anthropogenic Environmental Changes From a Siderastrea siderea Coral on the Northern Coast of Cuba</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.2307/2290724</URL>
<Description>Joint Estimation of Model Parameters and Outlier Effects in Time Series</Description>
</Related_URL>
<Related_URL>
<URL>https://github.com/jesstierney/arand</URL>
<Description>ARAND Time-Series Analysis Software</Description>
</Related_URL>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2025-02-28</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-08-13</Last_DIF_Revision_Date>
</DIF>
