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Wichern, Nina Maria Annegret; Bialik, Or M; Nohl, Theresa; Percival, Lawrence; Becker, R Thomas; Kaskes, Pim; Claeys, Philippe; De Vleeschouwer, David (2024): Total organic carbon data of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.965405, In: Wichern, NMA et al. (2024): Multiproxy dataset (pXRF, carbon isotopes, TOC, XRD) of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.965390

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Abstract:
A total of 34 samples (35 cm average sample spacing) were analysed for organic carbon d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements were carried out at the Analytical, Environmental and Geo-Chemistry Research Group (AMGC) of the Vrije Universiteit Brussel (Belgium). The samples were decarbonated with 10% HCl in two steps, rinsed with milliQ water, and dried in an oven at 50°C. Total organic carbon (TOC) contents and δ13Corg compositions were determined on a Euro EA 150 Elemental Analyzer (CHNS) - Euro Vector HT-PyrOH combustion system coupled to a Nu-Instruments Horizon 2 isotope ratio mass spectrometer.
Keyword(s):
Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; TOC; Winsenberg; XRD
Funding:
Deutsche Forschungsgemeinschaft, Bonn (DFG), grant/award no. 451461400: Astronomical signatures in Late Devonian black shales of the Rhenish Massif
UNESCO, grant/award no. IGCP-652: Reading Time in Palaeozoic sedimentary rocks
Vrije Universiteit Brussel, grant/award no. W000522N: CycloNet
Coverage:
Latitude: 51.370194 * Longitude: 8.797500
Date/Time Start: 2021-09-08T00:00:00 * Date/Time End: 2021-09-08T00:00:00
Minimum Elevation: 350.0 m * Maximum Elevation: 350.0 m
Event(s):
Winsenberg_2021 * Latitude: 51.370194 * Longitude: 8.797500 * Elevation: 350.0 m * Location: Rhenish Massif * Method/Device: Sampling by hand (HAND)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample IDSample ID
Date of determinationDate deter
Stratigraphic heightStrat heightm
Carbon, organic, totalTOC%Element analyser CHNSwt%
Carbon, organic, total, standard deviationTOC std dev±based on duplicates and applied to all wt%
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
240 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample ID

Date deter

Strat height [m]

TOC [%]

TOC std dev [±]
W2c-102022-11-08T00:00:000.9352.1997754390.016
W2c-322022-12-06T00:00:001.1550.8400000000.016
W6-5.52022-11-08T00:00:001.6951.0226068700.016
W9-02022-12-06T00:00:001.8500.8800000000.016
W14b-02022-11-08T00:00:002.2150.9216141910.016
W19g-02022-11-08T00:00:002.7500.9208855880.016
W20c-02022-11-08T00:00:003.2201.1428459900.016
W20g-02022-11-08T00:00:003.3651.1466988850.016
W20i-02022-11-08T00:00:003.3850.0881853910.016
W20m-10.52022-11-08T00:00:003.6350.0730998990.016
W20m-10.52022-11-08T00:00:003.6350.0755309730.016
W20o-0.52022-11-08T00:00:003.7550.0808047660.016
W20q-72022-11-08T00:00:003.9200.0822805220.016
W21b-02022-11-08T00:00:004.2401.6197646390.016
W21g-02022-11-08T00:00:004.4450.8911678800.016
W21h-02022-11-08T00:00:004.4750.5306516130.016
W22c-32022-11-08T00:00:004.6360.0744572570.016
W22e-92022-11-08T00:00:004.8170.1088863480.016
W22h-02022-11-08T00:00:004.9631.2799026560.016
W24b-02022-11-08T00:00:005.1171.1702960720.016
W25e-02022-11-08T00:00:005.3190.8368318790.016
W27c-82022-11-08T00:00:005.5550.1765036230.016
W28a-02022-11-08T00:00:005.6450.1476025090.016
W28a-112022-11-08T00:00:005.7550.1906934590.016
W29a-42022-11-08T00:00:005.8810.1695812750.016
W33-02022-11-08T00:00:006.5990.2054833090.016
W35e-52022-11-08T00:00:007.2140.1307161180.016
W35e-52022-11-08T00:00:007.2140.1450689380.016
W35j-02022-11-08T00:00:007.8070.0812265260.016
W35r-02022-11-08T00:00:008.3120.0860202180.016
W35u-02022-11-08T00:00:008.4430.0783137300.016
W35w-32022-11-08T00:00:008.6030.1060419710.016
W35y-22022-11-08T00:00:008.7650.0959174400.016
W35ac-42022-11-08T00:00:008.8800.0929049610.016
W35ac-162022-11-08T00:00:009.0000.0924292300.016
W35ac-262022-11-08T00:00:009.1000.3726328490.016
W35ac-262022-11-08T00:00:009.1000.4254684410.016
W37-32022-11-08T00:00:009.1500.1467676300.016
W39-12022-11-08T00:00:009.2130.8002334110.016
W41-42022-11-08T00:00:009.3180.6141325830.016
W41-152022-11-08T00:00:009.4280.5782437400.016
W41-152022-11-08T00:00:009.4280.5723591780.016
W41-252022-12-06T00:00:009.5281.1600000000.016
W43-62022-11-08T00:00:009.6781.1440014490.016
W45-62022-11-08T00:00:009.8480.6787724950.016
W45-62022-11-08T00:00:009.8480.6422429700.016
W50-22022-11-08T00:00:0010.2080.7879163320.016
W55b-02022-11-08T00:00:0010.7330.8394391100.016