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Wichern, Nina Maria Annegret; Bialik, Or M; Nohl, Theresa; Percival, Lawrence; Becker, R Thomas; Kaskes, Pim; Claeys, Philippe; De Vleeschouwer, David (2024): Calibrated pXRF data of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.965404, In: Wichern, NMA et al. (2024): Multiproxy dataset (pXRF, carbon isotopes, TOC, XRD) of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.965390

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Abstract:
A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
Keyword(s):
Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; TOC; Winsenberg; XRD
Funding:
Deutsche Forschungsgemeinschaft, Bonn (DFG), grant/award no. 451461400: Astronomical signatures in Late Devonian black shales of the Rhenish Massif
UNESCO, grant/award no. IGCP-652: Reading Time in Palaeozoic sedimentary rocks
Vrije Universiteit Brussel, grant/award no. W000522N: CycloNet
Coverage:
Latitude: 51.370194 * Longitude: 8.797500
Date/Time Start: 2021-09-08T00:00:00 * Date/Time End: 2021-09-08T00:00:00
Minimum Elevation: 350.0 m * Maximum Elevation: 350.0 m
Event(s):
Winsenberg_2021 * Latitude: 51.370194 * Longitude: 8.797500 * Elevation: 350.0 m * Location: Rhenish Massif * Method/Device: Sampling by hand (HAND)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Date of determinationDate deterWichern, Nina Maria Annegretdate of run
NumberNoWichern, Nina Maria AnnegretMeasurement
Sample IDSample IDWichern, Nina Maria Annegret
Stratigraphic heightStrat heightmWichern, Nina Maria Annegret
Aluminium oxideAl2O3%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
Calcium oxideCaO%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
ChromiumCrmg/kgWichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
Iron oxide, Fe2O3Fe2O3%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
Potassium oxideK2O%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
10 Manganese oxideMnO%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
11 Phosphorus pentoxideP2O5%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
12 Silicon dioxideSiO2%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
13 StrontiumSrmg/kgWichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
14 Titanium dioxideTiO2%Wichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
15 VanadiumVmg/kgWichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
16 ZincZnmg/kgWichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
17 ZirconiumZrmg/kgWichern, Nina Maria AnnegretX-ray fluorescence spectrometry (portable XRF), S1 TITAN Bruker
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
9452 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Date deter

No

Sample ID

Strat height [m]

Al2O3 [%]

CaO [%]

Cr [mg/kg]

Fe2O3 [%]

K2O [%]
10 
MnO [%]
11 
P2O5 [%]
12 
SiO2 [%]
13 
Sr [mg/kg]
14 
TiO2 [%]
15 
V [mg/kg]
16 
Zn [mg/kg]
17 
Zr [mg/kg]
2022-09-26266W2a-20.75023.09201722015.699325110204.439152709.3928499603.9519920000.4968332740.00011054427.177643990226.494847700.665162654122.081050600121.569722800116.698974600
2022-09-26267W2a-30.76025.20922050015.761589600209.062326208.6133070754.2303168280.3893238940.00011054427.279363220218.198531800.768777056140.053080800112.787023300146.747731200
2022-09-26268W2a-40.77022.36431098016.828077380204.191843207.9160956273.7277755600.6821190180.00011054428.627143030243.835774800.604482796113.068211600106.124285700120.130184900
2022-09-26269W2a-6.50.79523.84556230016.185999440198.271556707.7487131594.1095592070.7969886090.00011054427.105564790348.879064000.673243070128.797761600138.832270100146.558609400
2022-09-26270W2b-00.8153.2857518509.75983014692.8470511321.3938930800.5971521750.0070985260.4561043753.091995176101.399417100.30007684021.8239459401.36283268215.221605380
2022-09-26271W2c-00.83522.22298832017.520053790201.713701107.3537256213.7100293190.7919632390.00011054429.112077680284.601593900.583469202109.012434000129.368154300122.567154700
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2022-09-26278W2c-150.9858.69978077738.760837770124.331064202.4476794901.2462196650.6281255090.00011054411.074765510443.424531200.13967833420.43983138045.73060778023.694263250
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2022-09-26281W2c-261.09526.04133676013.002357320199.674659509.3687014284.3265536330.7968209270.07119031027.934728100168.648378100.771241808154.591648500175.855891300141.020041600
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2022-09-26285W2c-331.16523.92202418014.724865110196.409164808.0349776703.9205390570.9659253870.00011054427.789896080262.987793100.618512926139.935055500169.496005500144.213498700
2022-09-26286W2c-351.18517.32520896025.457710530166.262641805.7372855712.9250921730.9054862950.00011054420.207603120296.194746600.38508822970.933189100148.876851700109.155715400
2022-09-26287W2d-01.19515.0883032700.504652537163.7542169025.9534703102.9757218950.0538105840.34080702613.401087700114.684367500.629459857123.54027220091.66311671087.255407750
2022-09-26288W3a-01.2055.6792725770.295112269107.0496822026.2137985301.1848892630.0024771160.2821081835.554981530123.002373100.70224679671.90957999022.71387804087.671475770
2022-09-26289W3b-01.21031.6979344307.016691871206.2359319010.7685726205.3887820900.9743247160.15454045528.730967380141.991718500.886299703202.917633100193.497003200269.152781500
2022-09-26290W3c-0.51.2404.37309261644.97038968090.086269611.0803341520.4521951340.4562593820.0001105444.363232954299.903687800.0643047609.81755680367.68735655017.426225540
2022-09-26291W4-01.25525.4022208509.216847010197.8930217010.7462482804.5070472681.1577456370.12126672323.864948390139.844436800.845829912166.254691400249.196479700203.311368100
2022-09-26292W4-51.30523.76277253013.735326460191.397362108.8029804954.1399471231.1063283290.04963423823.878252730198.742857500.676448151150.503682300195.490777000170.101575200
2022-09-26293W4-81.33525.76765594011.228875090204.9287246010.1309827904.4145853210.8125042480.04609683125.897901540166.880666400.767905815203.271708900191.755605900197.270276600
2022-09-26294W4-91.34524.53319196013.639631300198.907495409.3836075924.0879246740.9870609040.05339273225.607142840224.640377100.689367788197.874735000187.238068000168.858774600
2022-09-26295W4-111.36522.83151948014.421190590191.866745408.7079920223.8458926720.8501487910.01801866525.615815920258.357038900.637490617186.898384600173.836879900134.930318700
2022-09-26296W4-141.39521.24796743017.727305740196.666568507.6760247443.4779606710.7344636580.07638587627.192548210382.715019300.544186645169.376996400175.628752500108.231720200
2022-09-26297W4-171.42521.12140982018.546877390196.530295907.2733640683.4335635600.7258509150.04454921526.824068610389.818400900.533840102173.293289500159.072859200107.977756600
2022-09-26298W4-17.51.43014.57838158027.509983710174.196734204.5682853932.1891903610.6079681350.00011054423.433736320643.154270800.29374341984.95673745069.80731851060.464950010
2022-09-26299W5-01.4352.90291509147.57014687071.275606440.6323054400.2271090270.3659856490.0001105441.655042625582.466448500.03991905910.54716758014.03212910013.751858600
2022-09-26300W5-31.4655.97035507141.157338730125.607988801.7573945060.6994010220.5759866610.00011054411.685333510964.910346400.09829216114.40981288032.22846917035.246905170
2022-09-26301W5-41.4757.00338153139.892802780114.186327702.0990707310.9808137970.6345685510.0001105449.764456771752.036639600.12667744224.35612453060.44415322035.771042810
2022-09-26302W5-61.4955.46728858642.468317940114.433637201.5172082830.6203937000.5581869940.0001105449.548724428934.197710100.08484436311.255319220128.15674740028.422308940
2022-09-26303W5-71.5055.60122872042.558365540111.526488901.4496069640.5930622210.5557200400.0001105449.502496069959.075813000.08352621711.31969664029.78041787032.869373630
2022-09-26304W5-111.5456.46287508842.201519190110.491826701.7049664540.8449378410.5893453030.0001105448.336261505850.009081700.09632848517.87546408043.58540819032.220955930
2022-09-26305W5-121.5553.72237559146.78305621074.965060370.6278284310.3607036840.3702158010.0001105442.347457558448.781890800.05229247713.66947253034.22224291013.065616540
2022-09-26306W5-151.5855.03857469545.47612324092.978276581.1561488860.6411774720.4358962170.0001105444.979611077550.647636800.08419431917.457010840224.16073860022.851320250
2022-09-26307W5-171.60515.82971991029.590656300162.073521704.6010662052.4461831500.7610488300.00011054419.668103850597.757697500.33508896573.980387050128.45959910066.203446600
2022-09-26308W5-191.62519.00156992023.751428080182.781906806.2189115812.9307576100.8459313420.00011054423.846591770506.606670700.447907817116.684076800152.56154750082.413888970
2022-09-26309W6-01.64016.90598689026.657744180175.095123805.3862698512.5870439350.7262853630.00011054421.957375990527.786677300.37182099989.506075240135.67756480071.990574530
2022-09-26310W6-11.65015.25493745028.900695420174.211875604.7919324832.2170449010.6070509670.00011054422.351538010637.796911200.31817426264.409610370239.90902740060.708106640
2022-09-26311W6-1.51.6555.64552388243.469853840107.488782801.4239711550.6332685470.5263503350.0001105447.510297979702.649158700.08568400420.643693210106.95712790024.569627140
2022-09-26312W6-31.6706.68382357641.692583000121.898346301.8256028770.7874390130.5587637170.00011054410.029954070769.811360900.11264731319.291767360210.73431290028.227783630
2022-09-26313W6-41.6807.10462761639.551055290123.644654202.1906263250.8966388910.5937685440.00011054411.983165400790.731090900.12176148021.53424754070.08493257031.048400600
2022-09-26314W6-5.51.6953.92592240845.67782361086.659266580.9421933820.3688205730.4646002760.0001105444.338139964676.079258000.0536286805.300407716304.13882690021.403187400
2022-09-26315W6-8.51.72514.76083547031.232522330161.538525704.0719353352.1771095570.7879744470.00011054420.485310090719.491222400.27376809055.976168130118.16264110070.542441680
2022-09-26316W7-01.74012.43850339030.905878750149.147815203.8431465151.7933723110.5907629760.00011054419.929222500697.454472000.24812292849.248727570520.57684700068.786310420
2022-09-26317W7-0.51.7453.04581972247.38034271071.472444610.5916086690.2026386250.4594859840.0001105442.208604071587.455083000.03803663812.23171011081.29044574017.091209730
2022-09-26318W8-01.77529.12354180012.313952300207.280688409.2173967344.6501137300.8358958460.06301005727.542502780302.560677900.795645566192.359735900260.048665900190.705047400
2022-09-26319W8-31.8055.36287856145.89194557090.156929460.8761218350.6796633710.3567783990.0001105444.128722971361.654306100.07126114014.624404290676.72213970015.032483550
2022-09-26320W8-61.83523.02504715017.606545160188.000641907.3091497883.7024417930.7628755440.00011054425.444796250343.868739900.599562320139.119608200161.924712800142.046702900
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2022-09-26322W9-41.89024.65553097016.270823820185.714290808.2634629653.9763426650.7642017540.00011054426.063363700364.539038200.533293884143.658216400152.940112100221.877728100
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2022-09-27330W12-92.02526.05662914015.472028900199.689800907.6109700084.3047678540.7546769252.93648972827.628980970402.745471000.672597540169.570128600147.236405000155.695895400
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2022-09-27333W12-15.52.09021.59389155017.052746820187.869416408.0303428273.5488385010.7214429190.00011054426.159104400406.541171100.587744148205.117195000201.068295900139.123419800
2022-09-27334W12-172.10515.52123575023.957826330184.533261806.0558452532.3350485780.6722791510.00011054427.198189920548.804011000.327952017109.581101200131.41240330076.848303760
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2022-09-27336W14a-02.1355.57433522845.58454306090.752491110.9071300550.7903379010.4026291830.0001105444.419565872323.881667600.08143614313.680202100132.16953250020.479192180
2022-09-27337W14a-72.2054.88354162844.38731803087.572797581.5583269550.5604749300.5957172080.0001105444.990810297402.018865500.06834948211.48064020049.92005640019.041866290
2022-09-27338W14b-02.21525.2841004208.714846497204.9590074013.1115538304.2195216190.7799867000.21412364925.941266940140.050489100.806339703297.756304700196.676946200155.863403300
2022-09-27339W14c-02.2354.34672644845.65471816086.290825900.9530778260.5398865180.5060684710.0001105444.165604613410.109129200.05992598720.611504500395.44861670017.539698640
2022-09-27340W14c-32.2656.88051518942.19953901090.702019781.9559521341.1459433230.7422379910.0001105445.516752614248.650891500.11533326115.6329838901318.46490700035.333360870
2022-09-27341W15-02.2753.8241490000.515179813104.6422000023.1180423800.6834886440.3062071210.0378060343.127782158136.157185200.20548632231.5234774708.83317479312.925126040
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2022-10-18731W35n-58.13728.33413873014.783083370218.338955908.2348586713.9328341260.2026535040.00011054434.627988240235.593683100.817394975137.799871100139.236072400160.164574000
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2022-10-18733W35o-08.17224.78103393018.760352750206.604372607.0098093753.3519598420.2387279370.00011054432.576004840287.085066300.659005288106.458796300117.329798900134.833056100
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2022-10-18736W35p-68.26224.49364270019.056505630208.825110906.7593912893.4110404550.3253914320.00011054432.625348780283.126693300.688613916108.357930200117.935502300141.727897600
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2022-10-18747W35u-58.49326.41362705017.234261500209.713406307.2439159723.6182353770.2442182430.00011054433.940878210245.288985700.721296714114.323571300126.465825400141.517161800
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2022-10-26980W68-011.97322.87317802017.496433090186.4764078011.0130931902.5886824370.2631561130.00011054426.592674200182.703313400.56112391973.948198340145.873572300107.821055600
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