Wichern, Nina Maria Annegret; Bialik, Or M; Nohl, Theresa; Percival, Lawrence; Becker, R Thomas; Kaskes, Pim; Claeys, Philippe; De Vleeschouwer, David (2024): Tuned K2O/Al2O3 ratios of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.965394, In: Wichern, NMA et al. (2024): Multiproxy dataset (pXRF, carbon isotopes, TOC, XRD) of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.965390
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Abstract:
A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
Keyword(s):
Funding:
Deutsche Forschungsgemeinschaft, Bonn (DFG), grant/award no. 451461400: Astronomical signatures in Late Devonian black shales of the Rhenish Massif
Coverage:
Latitude: 51.370194 * Longitude: 8.797500
Date/Time Start: 2021-09-08T00:00:00 * Date/Time End: 2021-09-08T00:00:00
Minimum Elevation: 350.0 m * Maximum Elevation: 350.0 m
Event(s):
Parameter(s):
# | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
---|---|---|---|---|---|---|
1 | Age, relative | Age rel | ka | Wichern, Nina Maria Annegret | ||
2 | Potassium oxide/Aluminium dioxide ratio | K2O/Al2O3 | Wichern, Nina Maria Annegret |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
982 data points
Data
1 Age rel [ka] | 2 K2O/Al2O3 |
---|---|
-80.965605560 | 0.166684123 |
-72.002424600 | 0.166945564 |
-55.455013600 | 0.137819663 |
-51.318160860 | 0.143247249 |
-45.802357190 | 0.165363468 |
-36.149700780 | 0.166141764 |
-27.875995280 | 0.153917646 |
-26.497044360 | 0.163888266 |
-16.154912490 | 0.103403969 |
-1.675927870 | 0.166628325 |
5.218826711 | 0.163684394 |
9.355679460 | 0.162563181 |
10.045154920 | 0.150166899 |
14.871483130 | 0.117145633 |
16.250434040 | 0.140048603 |
19.008335870 | 0.113473743 |
20.387286790 | 0.105880736 |
25.903090460 | 0.130737145 |
31.418894120 | 0.127253740 |
34.176795950 | 0.154531044 |
36.934697790 | 0.154237656 |
39.003124160 | 0.153025313 |
40.382075080 | 0.145332939 |
41.071550530 | 0.112171795 |
43.139976910 | 0.117812657 |
44.518927820 | 0.126204910 |
50.724206950 | 0.147492299 |
52.792633320 | 0.144179107 |
57.618961530 | 0.159668551 |
61.755814280 | 0.126734805 |
65.892667030 | 0.160800617 |
67.961093400 | 0.149620970 |
73.476897070 | 0.161275889 |
75.545323440 | 0.163735098 |
80.663295680 | 0.143935325 |
84.148996090 | 0.165666470 |
89.958496760 | 0.165208164 |
93.444197160 | 0.153932732 |
95.767997430 | 0.150536890 |
97.510847630 | 0.164344555 |
99.253697830 | 0.150442182 |
102.739398200 | 0.141781552 |
110.872699200 | 0.114768128 |
112.034599300 | 0.166884388 |
114.358399600 | 0.124205313 |
117.844100000 | 0.166549058 |
133.529751800 | 0.113736432 |
137.015452200 | 0.141542331 |
138.758302400 | 0.124582344 |
142.244002800 | 0.111723968 |
146.691570200 | 0.115598277 |
149.858264900 | 0.150941750 |
154.608306900 | 0.158640329 |
155.663871800 | 0.142707351 |
159.886131300 | 0.149165996 |
160.941696200 | 0.110019137 |
165.163955800 | 0.137196472 |
168.330650500 | 0.141287921 |
171.497345100 | 0.142446593 |
173.608474900 | 0.119000763 |
175.191822300 | 0.114559588 |
177.830734500 | 0.141473367 |
180.469646700 | 0.140897750 |
184.164123800 | 0.140912231 |
187.330818500 | 0.122311014 |
188.914165800 | 0.122649612 |
191.025295600 | 0.147140670 |
194.719772700 | 0.145043524 |
198.414249900 | 0.145488742 |
199.469814800 | 0.119343982 |
201.053162100 | 0.135090578 |
202.636509400 | 0.147403381 |
205.250209200 | 0.139990783 |
208.739189400 | 0.147056367 |
210.732892300 | 0.140915850 |
212.228169500 | 0.136948379 |
213.225021000 | 0.144895427 |
214.720298200 | 0.143425311 |
218.209278400 | 0.142659695 |
220.202981400 | 0.141113858 |
224.190387300 | 0.138090822 |
225.187238800 | 0.110200177 |
229.174644700 | 0.133927108 |
231.666773400 | 0.142537700 |
233.162050600 | 0.148452718 |
234.657327800 | 0.143081700 |
236.152605000 | 0.144953551 |
236.651030800 | 0.150842014 |
238.644733700 | 0.146945465 |
242.133713900 | 0.144507209 |
243.628991100 | 0.143620690 |
244.625842600 | 0.143454001 |
246.619545600 | 0.143427906 |
248.114822800 | 0.144492262 |
250.108525700 | 0.154419676 |
251.105377200 | 0.146082779 |
253.099080200 | 0.141496390 |
257.086486100 | 0.139790004 |
261.572317700 | 0.141894132 |
263.148890500 | 0.142307744 |
265.778558700 | 0.140486705 |
266.304492400 | 0.141770886 |
268.408227000 | 0.139902447 |
271.037895300 | 0.136753766 |
273.667563500 | 0.131694450 |
274.193497200 | 0.131826005 |
275.245364500 | 0.133929452 |
276.823165400 | 0.137015658 |
280.504701000 | 0.136856163 |
281.030634600 | 0.136534473 |
282.082501900 | 0.129807916 |
284.186236600 | 0.132176879 |
287.341838500 | 0.137615179 |
291.549307700 | 0.137070103 |
292.601175000 | 0.139699617 |
296.808644200 | 0.137650220 |
299.964246100 | 0.130133864 |
304.171715300 | 0.139304538 |
309.956985500 | 0.137128998 |
313.638521000 | 0.134250315 |
315.216322000 | 0.134223838 |
318.371923900 | 0.133823454 |
321.001592200 | 0.129062932 |
323.932006600 | 0.137078492 |
325.732479600 | 0.138522488 |
327.532952700 | 0.141256908 |
330.533741000 | 0.133906649 |
333.534529400 | 0.134297510 |
336.535317800 | 0.132817026 |
339.536106200 | 0.132163810 |
343.737209900 | 0.127200695 |
344.337367600 | 0.127699577 |
347.938313600 | 0.130827000 |
350.338944300 | 0.132763074 |
353.339732700 | 0.134272167 |
355.740363400 | 0.130717280 |
359.341309500 | 0.121588664 |
362.342097900 | 0.130835949 |
365.342886200 | 0.126708599 |
367.743516900 | 0.129401073 |
369.543990000 | 0.150010458 |
369.664021500 | 0.134532509 |
373.264967600 | 0.105635738 |
376.865913600 | 0.126493335 |
379.866702000 | 0.135532088 |
381.667175000 | 0.136043425 |
384.067805700 | 0.140778340 |
384.187837300 | 0.132666899 |
387.188625600 | 0.136754823 |
391.472929500 | 0.135524385 |
395.269764100 | 0.134980446 |
399.066598700 | 0.135550350 |
400.332210300 | 0.140080657 |
403.622800300 | 0.136847188 |
409.318052200 | 0.139285604 |
413.114886800 | 0.138066769 |
413.747692600 | 0.145302039 |
416.278915700 | 0.150800114 |
418.177333000 | 0.132651417 |
421.214800700 | 0.133388651 |
426.277246800 | 0.134181633 |
430.074081500 | 0.137061431 |
431.972498800 | 0.141468165 |
433.238110300 | 0.110273901 |
434.503721900 | 0.144542357 |
438.300556500 | 0.132103029 |
440.831779600 | 0.133221096 |
444.628614200 | 0.131317821 |
447.159837300 | 0.131674550 |
450.956671900 | 0.135850143 |
455.386312300 | 0.134208640 |
458.803463400 | 0.137797252 |
463.182773700 | 0.126430037 |
464.399160400 | 0.138001726 |
464.520799100 | 0.130546862 |
466.345379200 | 0.132512566 |
469.994539400 | 0.129543793 |
473.035506300 | 0.120783752 |
476.684666500 | 0.110814030 |
477.901053300 | 0.130768645 |
483.982987000 | 0.129613041 |
485.807567100 | 0.129183104 |
487.632147200 | 0.130021765 |
489.456727300 | 0.129033489 |
490.673114100 | 0.123628223 |
493.714080900 | 0.129540607 |
496.146854400 | 0.128710129 |
498.579627900 | 0.123747618 |
502.228788100 | 0.123289489 |
505.269755000 | 0.123083719 |
507.094335100 | 0.123846139 |
508.918915200 | 0.124188115 |
511.959882100 | 0.128964266 |
515.609042300 | 0.130738403 |
517.433622400 | 0.128716342 |
527.286355100 | 0.124417269 |
531.507198300 | 0.128713310 |
534.751760000 | 0.133060324 |
536.374040800 | 0.139621874 |
536.482192900 | 0.128831760 |
537.131105200 | 0.107716839 |
540.375666900 | 0.121425440 |
543.620228600 | 0.131142176 |
546.864790300 | 0.129616250 |
551.190872600 | 0.132804196 |
552.272393100 | 0.133362198 |
553.462065700 | 0.134814887 |
557.788148000 | 0.120562680 |
561.032709700 | 0.124297554 |
564.277271400 | 0.127716419 |
567.521833100 | 0.127631531 |
569.144113900 | 0.127248444 |
569.684874200 | 0.125458717 |
572.929435900 | 0.125666481 |
576.173997600 | 0.126937626 |
578.337038700 | 0.126274759 |
581.581600400 | 0.125783920 |
584.826162100 | 0.126006022 |
588.070723800 | 0.123900944 |
591.315285500 | 0.123667230 |
594.305008600 | 0.125902492 |
597.077348300 | 0.124478935 |
599.849687900 | 0.121490287 |
602.622027600 | 0.122597523 |
603.546140900 | 0.123309971 |
606.780537200 | 0.126174263 |
608.628763600 | 0.130371460 |
612.325216600 | 0.135757367 |
616.021669500 | 0.116338174 |
616.945782700 | 0.112097031 |
619.718122400 | 0.110452895 |
621.566348900 | 0.104298153 |
623.414575300 | 0.104987950 |
625.262801800 | 0.133067063 |
627.111028300 | 0.130777033 |
632.655707700 | 0.120141597 |
633.579820900 | 0.124455459 |
635.428047400 | 0.103710009 |
637.276273800 | 0.127951346 |
639.124500300 | 0.132360610 |
641.896840000 | 0.136733980 |
643.745066400 | 0.129407232 |
645.581362100 | 0.127951456 |
646.434134100 | 0.132631168 |
647.286906100 | 0.138223493 |
648.139678100 | 0.134633704 |
648.992450100 | 0.130236694 |
652.403538000 | 0.123022669 |
654.109082000 | 0.123113083 |
654.961854000 | 0.130643581 |
657.520169900 | 0.131110709 |
659.225713900 | 0.128630507 |
660.078485900 | 0.130881172 |
660.931257900 | 0.130512979 |
661.784029900 | 0.126444205 |
663.148465100 | 0.128540382 |
664.854009100 | 0.134186406 |
666.133167000 | 0.131130100 |
669.544255000 | 0.130360498 |
670.397027000 | 0.131145557 |
671.249799000 | 0.127168182 |
672.102571000 | 0.129898842 |
672.955343000 | 0.133836209 |
673.381729000 | 0.125556158 |
675.940044900 | 0.134328462 |
677.645588900 | 0.140817192 |
679.351132900 | 0.142144239 |
681.056676900 | 0.140296874 |
683.614992800 | 0.140956354 |
684.467764800 | 0.134727151 |
687.026080800 | 0.129220652 |
687.878852800 | 0.136106000 |
689.584396800 | 0.140175009 |
691.289940700 | 0.143225297 |
692.142712700 | 0.144163610 |
694.684667100 | 0.141008597 |
696.350084300 | 0.137025478 |
698.015501500 | 0.139454010 |
699.347835300 | 0.133185391 |
702.678669700 | 0.118201167 |
705.176795600 | 0.139870893 |
706.842212800 | 0.128336304 |
708.507630000 | 0.139106618 |
709.423609500 | 0.123792311 |
711.921735300 | 0.132213944 |
714.419861100 | 0.137863059 |
716.085278300 | 0.137020614 |
716.917986900 | 0.134900021 |
720.248821400 | 0.132712811 |
721.914238600 | 0.135271375 |
722.746947200 | 0.138325962 |
723.579655800 | 0.125784462 |
725.245073000 | 0.136626490 |
726.910490200 | 0.138496761 |
727.326844500 | 0.135290506 |
728.992261700 | 0.130788197 |
729.824970400 | 0.124414555 |
732.739450500 | 0.135109510 |
734.404867700 | 0.135367941 |
736.070284900 | 0.136440592 |
736.902993500 | 0.138801965 |
738.568410700 | 0.138027599 |
739.817473700 | 0.135263115 |
742.320932400 | 0.137786097 |
745.671820000 | 0.139284447 |
747.347263800 | 0.139262277 |
749.022707600 | 0.131264922 |
749.860429500 | 0.127757327 |
751.535873300 | 0.134267186 |
754.049039000 | 0.136624608 |
756.562204800 | 0.139950972 |
757.483698800 | 0.132587641 |
759.996864600 | 0.138583969 |
760.834586500 | 0.138590507 |
762.510030300 | 0.137568415 |
764.185474100 | 0.137453253 |
766.698639800 | 0.136983663 |
768.374083600 | 0.136551972 |
769.211805500 | 0.138584291 |
770.049527400 | 0.138493855 |
770.887249300 | 0.137392276 |
772.562693100 | 0.141304486 |
773.400415000 | 0.137531544 |
775.913580700 | 0.136882753 |
778.007885500 | 0.136920277 |
779.264468300 | 0.137095273 |
780.939912100 | 0.135868863 |
782.615355900 | 0.135617823 |
784.290799700 | 0.137089905 |
785.714927000 | 0.134849835 |
787.809231700 | 0.134936233 |
789.505485600 | 0.134585055 |
790.393715300 | 0.103212466 |
792.170174800 | 0.135120158 |
793.946634300 | 0.133829422 |
796.167208600 | 0.135898486 |
797.943668100 | 0.129453944 |
799.720127600 | 0.141881858 |
800.608357400 | 0.131191690 |
802.384816900 | 0.135842981 |
804.161276300 | 0.133202577 |
806.825965600 | 0.138466472 |
809.490654800 | 0.134443040 |
810.378884500 | 0.132415218 |
811.267114300 | 0.132115407 |
814.820033300 | 0.131557825 |
817.484722500 | 0.139763031 |
819.261182000 | 0.139321422 |
821.037641500 | 0.138123728 |
823.702330700 | 0.143080505 |
826.367019900 | 0.146152020 |
828.143479400 | 0.162252803 |
828.409948300 | 0.153627180 |
829.298178100 | 0.148532355 |
830.186407800 | 0.147843371 |
831.074637600 | 0.146791595 |
831.962867300 | 0.138834280 |
832.851097100 | 0.131368798 |
833.739326800 | 0.142934935 |
834.627556600 | 0.151587712 |
835.071671400 | 0.146177226 |
836.848130900 | 0.148086546 |
838.624590400 | 0.139530184 |
840.466468700 | 0.149140550 |
842.415020400 | 0.145124736 |
844.363572200 | 0.152234640 |
846.312123900 | 0.159266586 |
849.234951500 | 0.151194507 |
851.183503200 | 0.151630778 |
853.132055000 | 0.155416396 |
855.080606700 | 0.152329962 |
857.029158500 | 0.156272844 |
858.977710200 | 0.154424376 |
860.926261900 | 0.159984424 |
862.874813700 | 0.155523359 |
864.823365400 | 0.153346736 |
865.797641300 | 0.150050173 |
867.746193000 | 0.148976601 |
869.694744800 | 0.149441959 |
871.643296500 | 0.149212659 |
873.591848300 | 0.133292566 |
875.540400000 | 0.106080471 |
880.411779300 | 0.107419699 |
884.308882800 | 0.103899778 |
900.495536900 | 0.155713811 |
902.143568900 | 0.123258207 |
904.890288900 | 0.117619183 |
908.186352900 | 0.146868449 |
911.482417000 | 0.151267407 |
912.581105000 | 0.153542057 |
913.679793000 | 0.150632995 |
914.229137000 | 0.144845471 |
914.778481000 | 0.138529352 |
916.975857000 | 0.127133040 |
919.173233000 | 0.141527334 |
923.567985000 | 0.119735665 |
925.765361000 | 0.144380801 |
926.864049000 | 0.147268148 |
929.061425000 | 0.166407756 |
931.258801000 | 0.119169776 |
933.456177000 | 0.117404874 |
935.653553000 | 0.152238225 |
937.850929000 | 0.135902529 |
940.048305000 | 0.137508615 |
941.146993000 | 0.149985126 |
942.245681000 | 0.155857323 |
944.443057000 | 0.150189646 |
945.541745000 | 0.154907278 |
946.640433000 | 0.105953283 |
949.936497000 | 0.110499071 |
952.133873000 | 0.146901381 |
954.331249000 | 0.150896537 |
956.528625000 | 0.154527777 |
958.858234700 | 0.125971146 |
962.617303800 | 0.149510195 |
965.123349900 | 0.127309122 |
967.629396000 | 0.111241697 |
968.882419100 | 0.144866405 |
971.388465200 | 0.134961001 |
973.894511300 | 0.143700164 |
975.147534300 | 0.141283595 |
977.653580400 | 0.138420035 |
981.412649600 | 0.143713140 |
983.918695700 | 0.147425162 |
985.171718700 | 0.142792508 |
986.424741800 | 0.147071680 |
987.677764900 | 0.152146135 |
990.183811000 | 0.151906825 |
990.810322500 | 0.147019200 |
992.689857100 | 0.118933269 |
996.448926200 | 0.122176303 |
997.701949300 | 0.121018765 |
998.954972300 | 0.139826333 |
1001.461018000 | 0.123980511 |
1002.714041000 | 0.139457583 |
1003.967065000 | 0.141232604 |
1006.473111000 | 0.140625164 |
1008.979157000 | 0.154498961 |
1010.232180000 | 0.155211462 |
1012.111714000 | 0.142856309 |
1013.364737000 | 0.146501043 |
1013.991249000 | 0.143187672 |
1016.497295000 | 0.143414701 |
1017.750318000 | 0.105947859 |
1019.003341000 | 0.141186171 |
1020.256364000 | 0.106514879 |
1022.762410000 | 0.127263042 |
1026.521479000 | 0.142044133 |
1029.027526000 | 0.139955785 |
1031.533572000 | 0.138386804 |
1034.039618000 | 0.137137409 |
1036.545664000 | 0.140497159 |
1039.051710000 | 0.136141347 |
1040.304733000 | 0.131126078 |
1042.810779000 | 0.138475161 |
1045.316825000 | 0.140132781 |
1046.569848000 | 0.106155499 |
1047.822871000 | 0.137386874 |
1049.075894000 | 0.135609575 |
1050.328917000 | 0.118842293 |
1051.581940000 | 0.142312028 |
1052.834964000 | 0.135435068 |
1055.341010000 | 0.133090050 |
1057.847056000 | 0.131685838 |
1060.353102000 | 0.127689746 |
1060.979613000 | 0.132564099 |
1061.606125000 | 0.133350657 |
1064.112171000 | 0.132339459 |
1066.618217000 | 0.128232233 |
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