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Ruben, Manuel Jannis; Mollenhauer, Gesine (2024): Biogeochemical data of sediment cores of Herschel island (Yukon Coast 2022) [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.965379

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Abstract:
In July 2022 within the framework of an Alfred-Wegener-Institute-managed expedition and the Nunataryuk project, sediment cores were taken at three locations, off the coast of Herschel Island, Canada, using a hand corer:
YC22_MR_6: 69°34'23.12N, 138°54'37.76W; 3 m water depth; July 6th 2022
YC22_MR_7: 69°34'23.53N, 138°56'37.66W, 6 m water depth; July 7th 2022
YC22_MR_8: 69°30'22.75''N, 138°53'21.69''W; 45 m water depth; July 24th 2022
Data sets were obtained to investigate carbon feedback from the sediments to the water column and atmosphere, using DIC concentrations and isotopic values. The local sediments are supplied primarily by organic carbon previously stored in adjacent permafrost soils (biomarker and bulk data), which erode and redeposit quickly (age model) on the ocean floor.
The acquired data includes:
1) Sediment data: Bulk total organic carbon content (Lamping et al., 2021) and its isotopic values for 13C (Brodie et al., 2011; Werner & Brand, 2001) and 14C (Mollenhauer et al., 2021) and Biomarker data: Quantifying alkanes (CPI) , and fatty acids (TAR ratio) as described by Wei et al. (2020), Glycerol dialkyl glycerol tetraethers (GDGTs basis for BIT-Index) after Hopmans et al. (2016), Hopanes (fßß) following instructions by Meyer et al., (2019), and Sterols (Dinosterol) after Dauner et al. (2022).
2) Porewater was extracted from the cores using rhizomes and quantified as described in Oni et al., (2015). Dissolved inorganic carbon isotope signatures were determined as CO2 for 13C (Torres et al., 2005) and 14C (Mollenhauer et al., 2021).
3) Intact polar lipid fatty acids were extracted from the sediments, purified, and 14C analysis was performed as described in Ruben et al. (2023). The 13C isotopy was determined with GC-IRMS (Elvert et al., 2003). The respective precursor lipids of the polar fraction used for isotope analysis were quantified following the method described in Wörmer et al. (2013). Datasets are to be found at doi:10.1594/PANGAEA.966262 and doi:/10.1594/PANGAEA.966264.
4) Sedimentary age model of core YC22_MR_7 assuming constant rate of supply (CRS) model (Appleby, 2001), based on data obtained with a HPGe gamma detector.
References:
Appleby, Peter G (2001): Chronostratigraphic techniques in recent sediments. Tracking Environmental Change Using Lake Sediments: Basin Analysis, Coring, and Chronological Techniques, 171–203
Brodie, Chris R; Casford, James SL; Lloyd, Jeremy M; Leng, Melanie J; Heaton, Timothy H E; Kendrick, Christopher P; Zong, Yongqiang (2011): Evidence for bias in C/N, δ13C and δ15N values of bulk organic matter, and on environmental interpretation, from a lake sedimentary sequence by pre-analysis acid treatment methods. Quaternary Science Reviews, 30(21-22), 3076-3087, https://doi.org/10.1016/j.quascirev.2011.07.003
Dauner, Ana Lúcia Lindroth; Mollenhauer, Gesine; Hefter, Jens; Bícego, Márcia Caruso; de Mahiques, Michel Michaelovitch; Martins, César Castro (2022): Late Pleistocene to Holocene variations in marine productivity and terrestrial material delivery to the western South Atlantic. Frontiers in Marine Science, 9, 924556, https://doi.org/10.3389/fmars.2022.924556
Elvert, Marcus; Boetius, Antje; Knittel, Katrin; Jørgensen, Bo Barker (2003): Characterization of specific membrane fatty acids as chemotaxonomic markers for sulfate-reducing bacteria involved in anaerobic oxidation of methane. Geomicrobiology Journal, 20(4), 403-419, https://doi.org/10.1080/01490450303894
Hopmans, Ellen C; Schouten, Stefan; Sinninghe Damsté, Jaap S (2016): The effect of improved chromatography on GDGT-based palaeoproxies. Organic Geochemistry, 93, 1-6, https://doi.org/10.1016/j.orggeochem.2015.12.006
Lamping, Nele; Müller, Juliane; Hefter, Jens; Mollenhauer, Gesine; Haas, Christian; Shi, Xiaoxu; Vorrath, Maria-Elena; Lohmann, Gerrit; Hillenbrand, Claus-Dieter (2021): Evaluation of lipid biomarkers as proxies for sea ice and ocean temperatures along the Antarctic continental margin. Climate of the Past, 17(5), 2305-2326, https://doi.org/10.5194/cp-17-2305-2021
Meyer, Vera D; Hefter, Jens; Köhler, Peter; Tiedemann, Ralf; Gersonde, Rainer; Wacker, Lukas; Mollenhauer, Gesine (2019): Permafrost-carbon mobilization in Beringia caused by deglacial meltwater runoff, sea-level rise and warming. Environmental Research Letters, 14(8), 085003, https://doi.org/10.1088/1748-9326/ab2653
Mollenhauer, Gesine; Grotheer, Hendrik; Gentz, Torben; Bonk, Elizabeth; Hefter, Jens (2021): Standard operation procedures and performance of the MICADAS radiocarbon laboratory at Alfred Wegener Institute (AWI), Germany. Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms, 496, 45-51, https://doi.org/10.1016/j.nimb.2021.03.016
Oni, Oluwatobi Emmanuel; Miyatake, Tetsuro; Kasten, Sabine; Richter-Heitmann, Tim; Fischer, David; Wagenknecht, Laura; Kulkarni, Ajinkya; Blumers, Mathias; Shylin, Sergii I; Ksenofontov, Vadim; Costa, Benilde F O; Klingelhöfer, Göstar; Friedrich, Michael W (2015): Distinct microbial populations are tightly linked to the profile of dissolved iron in the methanic sediments of the Helgoland mud area, North Sea. Frontiers in Microbiology, 6, https://doi.org/10.3389/fmicb.2015.00365
Ruben, Manuel Jannis; Hefter, Jens; Schubotz, Florence; Geibert, Walter; Butzin, Martin; Gentz, Torben; Grotheer, Hendrik; Forwick, Matthias; Szczuciński, Witold; Mollenhauer, Gesine (2023): Fossil organic carbon utilization in marine Arctic fjord sediments by subsurface micro-organisms. Nature Geoscience, 16(7), 625-630, https://doi.org/10.1038/s41561-023-01198-z
Torres, Marta E; Mix, Alan C; Rugh, William D (2005): Precise δ 13 C analysis of dissolved inorganic carbon in natural waters using automated headspace sampling and continuous‐flow mass spectrometry. Limnology and Oceanography-Methods, 3(8), 349-360, https://doi.org/10.4319/lom.2005.3.349
Wei, Bingbing; Jia, Guodong; Hefter, Jens; Kang, Manyu; Park, Eunmi; Wang, Shizhu; Mollenhauer, Gesine (2020): Comparison of the U₃₇ᴷ', LDI, TEX₈₆ᴴ, and RI-OH temperature proxies in sediments from the northern shelf of the South China Sea. Biogeosciences, 17(17), 4489-4508, https://doi.org/10.5194/bg-17-4489-2020
Werner, Roland A; Brand, Willi A (2001): Referencing strategies and techniques in stable isotope ratio analysis. Rapid Communications in Mass Spectrometry, 15(7), 501-519, https://doi.org/10.1002/rcm.258
Wörmer, Lars; Lipp, Julius S; Schröder, Jan Martin; Hinrichs, Kai-Uwe (2013): Application of two new LC–ESI–MS methods for improved detection of intact polar lipids (IPLs) in environmental samples. Organic Geochemistry, 59, 10-21, https://doi.org/10.1016/j.orggeochem.2013.03.004
Funding:
Horizon 2020 (H2020), grant/award no. 773421: NUNATARYUK, Permafrost thaw and the changing Arctic coast, science for socioeconomic adaptation
Coverage:
Median Latitude: 69.563632 * Median Longitude: -138.931260 * South-bound Latitude: 69.506319 * West-bound Longitude: -138.943794 * North-bound Latitude: 69.573203 * East-bound Longitude: -138.889358
Date/Time Start: 2022-07-06T00:00:00 * Date/Time End: 2022-07-24T00:00:00
Size:
7 datasets

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