<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset964524">
<md:author id="dataset.author64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:author>
<md:author id="dataset.author52604">
<md:lastName>Lane</md:lastName>
<md:firstName>Christine S</md:firstName>
<md:eMail>csl44@cam.ac.uk</md:eMail>
<md:orcid>0000-0001-9206-3903</md:orcid>
</md:author>
<md:author id="dataset.author10987">
<md:lastName>Hoek</md:lastName>
<md:firstName>Wim Z</md:firstName>
<md:eMail>W.Z.Hoek@uu.nl</md:eMail>
<md:orcid>0000-0001-7313-100X</md:orcid>
</md:author>
<md:author id="dataset.author86101">
<md:lastName>Baneschi</md:lastName>
<md:firstName>Ilaria</md:firstName>
<md:eMail>ilaria.baneschi@igg.cnr.it</md:eMail>
</md:author>
<md:author id="dataset.author86102">
<md:lastName>Bouwman</md:lastName>
<md:firstName>Annerieke</md:firstName>
<md:eMail>anneriekebouwman@hotmail.com</md:eMail>
</md:author>
<md:author id="dataset.author103914">
<md:lastName>Brogan</md:lastName>
<md:firstName>Eilis</md:firstName>
<md:eMail>eilis.m.b@hotmail.co.uk</md:eMail>
</md:author>
<md:author id="dataset.author31951">
<md:lastName>Ramsey</md:lastName>
<md:firstName>Christopher Bronk</md:firstName>
<md:eMail>christopher.ramsey@arch.ox.ac.uk</md:eMail>
<md:orcid>0000-0002-8641-9309</md:orcid>
</md:author>
<md:author id="dataset.author35132">
<md:lastName>Collins</md:lastName>
<md:firstName>James A</md:firstName>
<md:eMail>jamescolly89@hotmail.com</md:eMail>
</md:author>
<md:author id="dataset.author86103">
<md:lastName>de Bruijn</md:lastName>
<md:firstName>Renee</md:firstName>
<md:eMail>renee.debruijn@tno.nl</md:eMail>
</md:author>
<md:author id="dataset.author86100">
<md:lastName>Haliuc</md:lastName>
<md:firstName>Aritina</md:firstName>
<md:eMail>aritinahaliuc@gmail.com</md:eMail>
<md:orcid>0000-0002-5681-8210</md:orcid>
</md:author>
<md:author id="dataset.author30088">
<md:lastName>Heiri</md:lastName>
<md:firstName>Oliver</md:firstName>
<md:eMail>oliver.heiri@unibas.ch</md:eMail>
<md:URI>http://www.bio.uu.nl/~palaeo/people/Olivier/index.html</md:URI>
<md:orcid>0000-0002-3957-5835</md:orcid>
</md:author>
<md:author id="dataset.author62601">
<md:lastName>Hubay</md:lastName>
<md:firstName>Katalin</md:firstName>
<md:eMail>hubay.katalin@atomki.mta.hu</md:eMail>
</md:author>
<md:author id="dataset.author76274">
<md:lastName>Jones</md:lastName>
<md:firstName>Gwydion</md:firstName>
<md:eMail>g.jones@swansea.ac.uk</md:eMail>
</md:author>
<md:author id="dataset.author64077">
<md:lastName>Jones</md:lastName>
<md:firstName>Vivienne</md:firstName>
</md:author>
<md:author id="dataset.author72349">
<md:lastName>Laug</md:lastName>
<md:firstName>Andreas</md:firstName>
<md:eMail>andreasjlaug@googlemail.com</md:eMail>
<md:orcid>0000-0002-5892-6725</md:orcid>
</md:author>
<md:author id="dataset.author969">
<md:lastName>Merkt</md:lastName>
<md:firstName>Josef</md:firstName>
<md:eMail>josefmerkt@gmx.de</md:eMail>
</md:author>
<md:author id="dataset.author64064">
<md:lastName>Muschitiello</md:lastName>
<md:firstName>Francesco</md:firstName>
<md:eMail>fm476@cam.ac.uk</md:eMail>
</md:author>
<md:author id="dataset.author86104">
<md:lastName>Müller</md:lastName>
<md:firstName>Meike</md:firstName>
<md:eMail>meikee.mueller@yahoo.de</md:eMail>
</md:author>
<md:author id="dataset.author86105">
<md:lastName>Peters</md:lastName>
<md:firstName>Tom</md:firstName>
<md:eMail>tompeters.home@gmail.com</md:eMail>
</md:author>
<md:author id="dataset.author49947">
<md:lastName>Peterse</md:lastName>
<md:firstName>Francien</md:firstName>
<md:eMail>f.peterse@uu.nl</md:eMail>
<md:orcid>0000-0001-8781-2826</md:orcid>
</md:author>
<md:author id="dataset.author103915">
<md:lastName>Pueschel</md:lastName>
<md:firstName>Ashley</md:firstName>
<md:eMail>AshleyPueschel@outlook.com</md:eMail>
</md:author>
<md:author id="dataset.author49496">
<md:lastName>Staff</md:lastName>
<md:firstName>Richard A</md:firstName>
<md:eMail>richard.staff@arch.ox.ac.uk</md:eMail>
<md:orcid>0000-0002-8634-014X</md:orcid>
</md:author>
<md:author id="dataset.author86106">
<md:lastName>ter Schure</md:lastName>
<md:firstName>Anneke</md:firstName>
<md:eMail>a.t.m.t.schure@ibv.uio.no</md:eMail>
</md:author>
<md:author id="dataset.author86107">
<md:lastName>van den Bos</md:lastName>
<md:firstName>Valerie</md:firstName>
<md:eMail>valerie.vandenbos@vuw.ac.nz</md:eMail>
</md:author>
<md:author id="dataset.author79977">
<md:lastName>Wagner-Cremer</md:lastName>
<md:firstName>Frederike</md:firstName>
<md:eMail>F.Wagner@uu.nl</md:eMail>
</md:author>
<md:year>2024</md:year>
<md:title>Dry mass concentrations of individual n-alkanes in sediment core Haem13 from lake Hämelsee</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.964524</md:URI>
<md:dateTime>2024-04-17T06:26:57</md:dateTime>
<md:parentURI>https://doi.org/10.1594/PANGAEA.964375</md:parentURI>
</md:citation>
<md:abstract>This dataset provides concentrations of n-alkanes for the Lateglacial sediment sequence retrieved from Lake Hämelsee (Germany) in 2013. Concentrations of n-alkanes (ug/g), the Carbon Preference Index (CPI) and the Average Chain Length C21-C33 (ACL) are all presented against both depth (m) and age (cal yr. BP). The n-alkane concentration data provides information on the Lateglacial dynamics of local plant productivity, whereas the ACL and CPI of the sediment samples were determined to estimate origin and preservation condition. A total of 167 samples from the Lateglacial section of the core were processed using a Dionex 350 accelerated solvent extraction (ASE) system. Solid phase extraction (SPE) was used to separate the extracts into an aliphatic, aromatic and alcohol/fatty acid fraction. Separation was achieved by loading the extracts on activated silica columns and eluting each fraction with hexane, hexane/DCM (1:1 v/v) and DCM/MeOH (9:1 v/v) successively. The aliphatic fraction, containing the n-alkanes, was analyzed by gas chromatography-mass spectrometry (GC/MS). The peak areas for each n-alkane homologue were compared to the peak areas from an internal standard (5α-androstane) and an external n-alkane standard mixture for absolute quantification. We refer to Rach et al. (2020) for further details on the exact analytical setup. All measurements were performed in the laboratories of GeoForschungsZentrum Potsdam.</md:abstract>
<md:reference dataciteRelType="References" group="500" id="ref123991" relationType="References" relationTypeId="24">
<md:author id="ref123991.author50228">
<md:lastName>Rach</md:lastName>
<md:firstName>Oliver</md:firstName>
<md:eMail>rach@geo.uni-potsdam.de</md:eMail>
<md:orcid>0000-0003-3547-2182</md:orcid>
</md:author>
<md:author id="ref123991.author103987">
<md:lastName>Hadeen</md:lastName>
<md:firstName>Xennophone</md:firstName>
</md:author>
<md:author id="ref123991.author34250">
<md:lastName>Sachse</md:lastName>
<md:firstName>Dirk</md:firstName>
<md:eMail>dirk.sachse@gfz-potsdam.de</md:eMail>
<md:orcid>0000-0003-4207-0309</md:orcid>
</md:author>
<md:year>2020</md:year>
<md:title>An automated solid phase extraction procedure for lipid biomarker purification and stable isotope analysis</md:title>
<md:type id="ref123991.reftype1">journal article</md:type>
<md:source id="ref123991.journal12339" relatedTermIds="33971" type="journal">Organic Geochemistry</md:source>
<md:volume>142</md:volume>
<md:URI>https://doi.org/10.1016/j.orggeochem.2020.103995</md:URI>
<md:pages>103995</md:pages>
</md:reference>
<md:extent>
<md:geographic>
<md:westBoundLongitude>9.316667</md:westBoundLongitude>
<md:eastBoundLongitude>9.316667</md:eastBoundLongitude>
<md:southBoundLatitude>52.766667</md:southBoundLatitude>
<md:northBoundLatitude>52.766667</md:northBoundLatitude>
<md:meanLongitude>9.316667</md:meanLongitude>
<md:meanLatitude>52.766667</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>2013-07-08T09:00:00</md:minDateTime>
<md:maxDateTime>2013-07-12T17:00:00</md:maxDateTime>
</md:temporal>
<md:elevation name="Elevation" unit="m">
<md:min>22.0</md:min>
<md:max>22.0</md:max>
</md:elevation>
</md:extent>
<md:award id="award958">
<md:funder id="award958.funder20957" semanticURI="http://doi.org/10.13039/501100000921">
<md:name>European Cooperation in Science and Technology</md:name>
<md:optionalName>COST</md:optionalName>
<md:crossrefFunderId>https://doi.org/10.13039/501100000921</md:crossrefFunderId>
</md:funder>
<md:number>ES0907</md:number>
<md:title>ES0907 - INTegrating Ice core, MArine and TErrestrial records - 60,000 to 8000 years ago (INTIMATE)</md:title>
<md:URI>https://www.cost.eu/actions/ES0907/</md:URI>
</md:award>
<md:event displayTypeName="Event" id="event2990124" typeName="Generic Event">
<md:label>Haemelsee_Haem13</md:label>
<md:latitude>52.766667</md:latitude>
<md:longitude>9.316667</md:longitude>
<md:location id="event2990124.term69859">
<md:name>Lake Haemelsee, Germany</md:name>
</md:location>
<md:elevation>22.0</md:elevation>
<md:dateTime>2013-07-08T09:00:00</md:dateTime>
<md:latitude2>52.766667</md:latitude2>
<md:longitude2>9.316667</md:longitude2>
<md:elevation2>22.0</md:elevation2>
<md:dateTime2>2013-07-12T17:00:00</md:dateTime2>
<md:method id="event2990124.method11372">
<md:name>Niederreiter Piston corer</md:name>
<md:optionalName>NPC</md:optionalName>
</md:method>
<md:attribute attid="37748" name="Lake water depth">3.4 m</md:attribute>
<md:comment>Lake sediment sequence retrieved using a 60 mm piston corer deployed from a floating platform.</md:comment>
</md:event>
<md:size unit="data points">3173</md:size>
<md:license id="license21">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
</md:license>
<md:comment>#0 = below detection limit</md:comment>
<md:matrixColumn behaviour="1" col="0" format="0" id="col0.ds15149299" source="geocode" type="numeric">
<md:parameter id="col0.ds15149299.geocode6262">
<md:name>ORDINAL NUMBER</md:name>
<md:shortName>Ord No</md:shortName>
</md:parameter>
<md:PI id="col0.ds15149299.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>Ord No</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="1" col="1" format="0.000" id="col1.ds15149300" source="geocode" type="numeric">
<md:parameter id="col1.ds15149300.geocode1">
<md:name>DEPTH, sediment/rock</md:name>
<md:shortName>Depth sed</md:shortName>
<md:unit>m</md:unit>
<md:term endOffset="5" fragment="1" id="col1.ds15149300.geocode1.term1073131" semanticURI="urn:obo:pato:term:0001595" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>depth</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0001595</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col1.ds15149300.geocode1.term38263" startOffset="7" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sediment</md:name>
<md:URI>http://purl.obolibrary.org/obo/ENVO_00002007</md:URI>
</md:term>
<md:term endOffset="20" fragment="3" id="col1.ds15149300.geocode1.term41056" startOffset="16" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>rock</md:name>
</md:term>
<md:term id="col1.ds15149300.geocode1.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
<md:URI>http://dbpedia.org/resource/Length</md:URI>
</md:term>
</md:parameter>
<md:PI id="col1.ds15149300.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>Depth sed [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="5" col="2" format="0.0000" id="col2.ds15149301" source="geocode" type="numeric">
<md:parameter id="col2.ds15149301.geocode2205">
<md:name>AGE</md:name>
<md:shortName>Age</md:shortName>
<md:unit>ka BP</md:unit>
<md:URI>http://en.wikipedia.org/wiki/Kyr</md:URI>
<md:term endOffset="3" fragment="1" id="col2.ds15149301.geocode2205.term1073135" semanticURI="urn:obo:pato:term:0000011" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>age</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0000011</md:URI>
</md:term>
<md:term id="col2.ds15149301.geocode2205.term43975" semanticURI="http://qudt.org/1.1/vocab/quantity#Time" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Time</md:name>
<md:optionalName>T</md:optionalName>
<md:URI>http://dbpedia.org/resource/Time</md:URI>
</md:term>
</md:parameter>
<md:PI id="col2.ds15149301.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>Age [ka BP]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="3" format="0.00000" id="col3.ds15149302" source="data" type="numeric">
<md:parameter id="col3.ds15149302.param174905">
<md:name>n-Alkane C17, per unit sediment mass</md:name>
<md:shortName>C17/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col3.ds15149302.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col3.ds15149302.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C17/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="4" format="0.00000" id="col4.ds15149303" source="data" type="numeric">
<md:parameter id="col4.ds15149303.param155089">
<md:name>n-Alkane C21, per unit sediment mass</md:name>
<md:shortName>C21/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col4.ds15149303.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col4.ds15149303.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C21/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" format="0.00000" id="col5.ds15149304" source="data" type="numeric">
<md:parameter id="col5.ds15149304.param164360">
<md:name>n-Alkane C22, per unit sediment mass</md:name>
<md:shortName>C22/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col5.ds15149304.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col5.ds15149304.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C22/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="0.00000" id="col6.ds15149305" source="data" type="numeric">
<md:parameter id="col6.ds15149305.param132225">
<md:name>n-Alkane C23, per unit sediment mass</md:name>
<md:shortName>C23/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col6.ds15149305.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col6.ds15149305.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C23/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="0.00000" id="col7.ds15149306" source="data" type="numeric">
<md:parameter id="col7.ds15149306.param164361">
<md:name>n-Alkane C24, per unit sediment mass</md:name>
<md:shortName>C24/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col7.ds15149306.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col7.ds15149306.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C24/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="0.00000" id="col8.ds15149307" source="data" type="numeric">
<md:parameter id="col8.ds15149307.param132226">
<md:name>n-Alkane C25, per unit sediment mass</md:name>
<md:shortName>C25/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col8.ds15149307.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col8.ds15149307.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C25/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="0.00000" id="col9.ds15149308" source="data" type="numeric">
<md:parameter id="col9.ds15149308.param160871">
<md:name>n-Alkane C26, per unit sediment mass</md:name>
<md:shortName>C26/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col9.ds15149308.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col9.ds15149308.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C26/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="0.00000" id="col10.ds15149309" source="data" type="numeric">
<md:parameter id="col10.ds15149309.param132227">
<md:name>n-Alkane C27, per unit sediment mass</md:name>
<md:shortName>C27/sed</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col10.ds15149309.method16296">
<md:name>Gas chromatography-mass spectrometry, following the analytical setup and protocol of Rach et al. (2020)</md:name>
</md:method>
<md:PI id="col10.ds15149309.pi64590">
<md:lastName>Engels</md:lastName>
<md:firstName>Stefan</md:firstName>
<md:eMail>s.engels@bbk.ac.uk</md:eMail>
<md:orcid>0000-0002-2078-0361</md:orcid>
</md:PI>
<md:caption>C27/sed [µg/g]</md:caption>
</md:matrixColumn>
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