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Blumenberg, Martin; Naafs, Bernhard David A; Lückge, Andreas; Lauretano, Vittoria; Schefuß, Enno; Galloway, Jennifer M; Scheeder, Georg; Reinhardt, Lutz (2024): Bulk geochemistry and biomarker concentrations and isotopic compositions of lignites spanning the PETM from Stenkul Fiord (Ellesmere Island), Paleocene [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.962902

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Abstract:
This dataset contains bulk geochemical information (TOC, S, Tmax, Hydrogen and Oxygen Indices), relative and absolute abundances of selected plant wax and bacterial hopanoid biomarkers as well as stable carbon and hydrogen isotope signatures of selected compounds. Samples were analysed with a Leco C/S analyser, a Rock-Eval 6 pyrolysis unit, a gas chromatograph-triple quad mass spectrometer and gas chromatograph isotope ratio mass spectrometer (for d13C and d2H). The samples originate from two onshore outcrops at the Stenkul Fiord (Ellesmere Island) and are mostly coal samples of the lignite thermal maturity stage. The age of the samples are Paleogene and cover the Paleocene Eocene Thermal Maximum (PETM; Margaret Formation), and they were taken in 2017 (BGR CASE 19 expedition). The data were generated to reconstruct the terrestrial paleovenvironment in this high-latitude setting. More information on the studied sections can be found elswhere (Reinhardt et al., 2022).
Keyword(s):
Biomarkers; Ellesmere Island; Hopanoids; PETM; Stable carbon and hydrogen isotopes of plant-waxes; Stable carbon isotope (δ13C)
Supplement to:
Blumenberg, Martin; Naafs, Bernhard David A; Lückge, Andreas; Lauretano, Vittoria; Schefuß, Enno; Galloway, Jennifer M; Scheeder, Georg; Reinhardt, Lutz (submitted): Biomarker reconstruction of a high-latitude late Paleocene to early Eocene coal swamp environment across the PETM and ETM-2. Paleoceanography and Paleoclimatology
Related to:
Blumenberg, Martin; Naafs, Bernhard David A; Lückge, Andreas; Lauretano, Vittoria; Schefuß, Enno; Galloway, Jennifer M; Scheeder, Georg; Reinhardt, Lutz (2024): Bulk geochemistry and biomarker concentrations and isotopic compositions of lignites spanning the PETM from Stenkul Fiord (Ellesmere Island), early Eocene. PANGAEA, https://doi.org/10.1594/PANGAEA.962900
References:
Reinhardt, Lutz; von Gosen, Werner; Lückge, Andreas; Blumenberg, Martin; Galloway, Jennifer M; West, Christopher K; Sudermann, Markus; Dolezych, Martina (2022): Geochemical indications for the Paleocene-Eocene Thermal Maximum (PETM) and Eocene Thermal Maximum 2 (ETM-2) hyperthermals in terrestrial sediments of the Canadian Arctic. Geosphere, 18(1), 327-349, https://doi.org/10.1130/GES02398.1
Funding:
The Royal Society, grant/award no. NE/V003917/1: Royal Society Tata University Research
Coverage:
Latitude: 77.348150 * Longitude: -83.445730
Date/Time Start: 2017-07-17T00:00:00 * Date/Time End: 2017-07-17T00:00:00
Minimum SECTION, height: 6.00 m * Maximum SECTION, height: 133.00 m
Event(s):
LR17_Stenkul_Fiord_EAST * Latitude: 77.348150 * Longitude: -83.445730 * Date/Time: 2017-07-17T00:00:00 * Elevation: 73.0 m * Campaign: CASE19 * Method/Device: Outcrop sample (OUTCROP) * Comment: lat/lon hold for the base of the profile
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample IDSample IDBlumenberg, Martin
SECTION, heightSectionmBlumenberg, MartinGeocode
EpochEpochBlumenberg, Martin
SiteSiteBlumenberg, Martin
LocationLocationBlumenberg, Martin
Carbon, organic, totalTOC%Blumenberg, MartinElement analyser CS, LECO
Sulfur, totalTS%Blumenberg, MartinElement analyser CS, LECO
Pyrolysis temperature maximumTmax°CBlumenberg, MartinRock-Eval analysis
Hydrogen index, mass HC, per unit mass total organic carbonHI, HC/TOCmg/gBlumenberg, MartinRock-Eval analysis
10 Oxygen index, mass CO2, per unit mass total organic carbonOI, CO2/TOCmg/gBlumenberg, MartinRock-Eval analysis
11 n-Alkane, average chain lengthACL n-AlkaneBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)ACL = (25[n-C25]+27[n-C27]+29[n-C29]+31[n-C31]+33[n-C33])/(n-C27+n-C29+n-C31+n-C33)
12 Carbon Preference Index, n-AlkanesCPI n-AlkanesBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)CPI = 0.5x([n-C25+n-C27+n-C29+n-C31]+[n-C27+n-C29+n-C31+n-C33])/(n-C26+n-C28+n-C30+n-C32)
13 Hop-17(21)-ene, per unit mass total organic carbonHop-17(21)-ene/TOCµg/gBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)
14 Hopene, total, per unit mass total organic carbonHopane/TOCµg/gBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)
15 2-methyl hop-17(21)-ene/hop-17(21)-ene ratio2-methyl hop-17(21)-ene/hop-17(21)-eneµg/gBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)
16 Isopimarane, per unit mass total organic carbonIsopimarane/TOCµg/gBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)
17 Diterpenoids, total, per unit mass total organic carbonDiterpenoids/TOCµg/gBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)
18 n-Alkane, sum, per unit mass total organic carbonn-A sum/TOCµg/gBlumenberg, MartinGas chromatography triple quadrupole mass spectrometry (GC-QQQ-MS)Sum n-pentaosane, n-heptacosane, n-nonacosane
19 Hop-17(21)-ene, δ13CHop-17(21)-ene δ13C‰ PDBBlumenberg, MartinGas chromatography - Isotope ratio mass spectrometer (GC-IRMS)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
141 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample ID

Section [m]

Epoch

Site

Location

TOC [%]

TS [%]

Tmax [°C]

HI, HC/TOC [mg/g]
10 
OI, CO2/TOC [mg/g]
11 
ACL n-Alkane
12 
CPI n-Alkanes
13 
Hop-17(21)-ene/TOC [µg/g]
14 
Hopane/TOC [µg/g]
15 
2-methyl hop-17(21)-ene/hop-17(21)-ene [µg/g]
16 
Isopimarane/TOC [µg/g]
17 
Diterpenoids/TOC [µg/g]
18 
n-A sum/TOC [µg/g]
19 
Hop-17(21)-ene δ13C [‰ PDB]
East 32133.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island50.200.343899810228.945.549.117.400.0530.00204.2171.1
East 30128.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island47.300.49401908729.642.262.04.300.0612.50430.752.9
East 27112.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island56.600.714051836727.657.1313.417.500.031.2037.285.5-33.3
East 2194.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island29.400.534209310328.597.2924.938.700.023.6038.3561.1-43.6
East 1546.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island47.200.483961149328.306.1516.029.800.052.1049.2418.5-40.0
East 1139.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island32.200.384128010728.525.529.918.500.044.8082.0243.3-47.8
East 518.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island50.100.384051668027.2313.4217.427.000.0846.1053.3104.6-31.7
East 16.00PaleoceneStenkul Fiord, EAST sectionEllesmere Island50.100.654031357128.677.136.913.200.049.70507.159.0