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Kuss, Joachim; Schneider, Bernd (2023): Elemental mercury in Atlantic surface water during Polarstern cruise ANT-XXV/5 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.961639

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Abstract:
During the Polarstern cruise ANT-XXV/5 in April/May 2009, surface seawater from below the ship's hull was continuously pumped through a shower head into a 20 L equilibrator bottle and drained at the bottom. Equilibrium between the supplied water and the headspace air (Hg0 equ) was achieved in about 1 h. The equilibrated air was transferred to the TEKRAN 2537A after closing the drain and elemetal mercury (Hg0) was preconcentrated by amalgamation on gold traps and finally analyzed by cold vapor atomic fluorescence spectrometry. The detection limit was 0.1 ng L-1. Wind speed was taken from the Polarstern Meteorological station and surface water salinity and temperature from the thermosalinograph. Hg0 equil. was a duplicate measurement of the headspace and provided at standard reference condition of 0°C by the Tekran instrument. The value was corrected to the in situ temperature and divided by Henry's Law constant at respective sea surface water temperature.
Keyword(s):
Atlantic Ocean; Elemental mercury; Mercury sea-air gas exchange; surface water
Related to:
Kuss, Joachim; Zülicke, Christoph; Pohl, Christa; Schneider, Bernd (2011): Atlantic mercury emission determined from continuous analysis of the elemental mercury sea-air concentration difference within transects between 50°N and 50°S. Global Biogeochemical Cycles, 25(3), https://doi.org/10.1029/2010GB003998
Zenk, Walter; El Naggar, Saad El Dine (2010): The Expedition of the Research Vessel Polarstern to the Antarctic in 2009 (ANT-XXV/5). Berichte zur Polar- und Meeresforschung = Reports on Polar and Marine Research, 603, 62 pp, https://doi.org/10.2312/BzPM_0603_2010
References:
Sanemasa, Isao (1975): The Solubility of Elemental Mercury Vapor in Water. Bulletin of the Chemical Society of Japan, 48(6), 1795-1798, https://doi.org/10.1246/bcsj.48.1795
Funding:
Deutsche Forschungsgemeinschaft, Bonn (DFG), grant/award no. 58202066: Marine Quecksilberemissionen: Messungen im Atlantik und Prozesstudien im Labor (QueMar)
Coverage:
Median Latitude: -6.366081 * Median Longitude: -29.843516 * South-bound Latitude: -49.662853 * West-bound Longitude: -63.401196 * North-bound Latitude: 48.662278 * East-bound Longitude: -5.716961
Date/Time Start: 2009-04-13T16:52:25 * Date/Time End: 2009-05-20T23:52:31
Minimum DEPTH, water: 11 m * Maximum DEPTH, water: 11 m
Event(s):
PS73/5_0_Underway-1 * Latitude Start: -49.662900 * Longitude Start: -63.401200 * Latitude End: 48.662300 * Longitude End: -5.717000 * Date/Time Start: 2009-04-13T16:52:25 * Date/Time End: 2009-05-20T23:52:31 * Campaign: ANT-XXV/5 (PS73) * Basis: Polarstern * Method/Device: Thermosalinograph (TSG) * Comment: event was not logged in DSHIP
PS73/5_0_Underway-2 * Latitude Start: -51.309010 * Longitude Start: -65.952060 * Latitude End: 49.181810 * Longitude End: -4.563030 * Date/Time Start: 2009-04-13T00:02:25 * Date/Time End: 2009-05-21T05:57:30 * Campaign: ANT-XXV/5 (PS73) * Basis: Polarstern * Method/Device: Ship Weather Station (SWEAS) * Comment: event was not logged in DSHIP
PS73/5_0_Underway-3 * Latitude Start: -49.662900 * Longitude Start: -63.401200 * Latitude End: 48.662300 * Longitude End: -5.717000 * Date/Time Start: 2009-04-13T16:52:25 * Date/Time End: 2009-05-20T23:52:31 * Campaign: ANT-XXV/5 (PS73) * Basis: Polarstern * Method/Device: Sea water pump, trace metals (TMPUMP) * Comment: event was not logged in DSHIP
Comment:
Further notes on calculated parameters:
* H surf ocean and H equil: Solubility of elemental mercury according to Sanemasa (1975) at surface ocean temperature or equilibrator temperature in °C by using the fit H-Sanemasa = 0.000000442*T^3 + 0.000068931*T^2 + 0.005360591*T + 0.16096243
* Hg0-equi sea surface (ng m-3), recalculated from the measurement result Hg0 equil. (ng m-3) at 0°C to in situ temperature by accounting for the solubility difference between equilibrator and the surface ocean (H equil./H surf ocean). This was used for the flux calculation.
* Hg0 surf. water (ng m-3): final concentration of elemental mercury in surface water (same as in equilibrator water) in nanogram per cubic metre (Hg0 equil/H-equi)
H-equi refers to the Henry's Law constant at a certain temperature (sea surface, equilibrator).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DATE/TIMEDate/TimeKuss, JoachimGeocode
LONGITUDELongitudeKuss, JoachimGeocode
LATITUDELatitudeKuss, JoachimGeocode
DEPTH, waterDepth watermKuss, JoachimGeocode
Temperature, waterTemp°CKuss, JoachimThermosalinograph (TSG)
SalinitySalKuss, JoachimThermosalinograph (TSG)
Wind speedffm/sKuss, JoachimAnemometeraltitude 25 m
MercuryHgng/m3Kuss, JoachimMercury vapour analyzer, Tekran, 2537AHg0 equil. : duplicate measurement of the headspace and provided at standard reference condition of 0°C
Temperature, technicalT tech°CKuss, JoachimTemp equil.
10 Henry's law constantHKuss, JoachimCalculated according to Sanemasa (1975)H surf (Sanemasa)
11 MercuryHgng/m3Kuss, JoachimCalculatedHg0-equi sea surface: recalculated from the measurement result Hg0 equil. (ng m-3) at 0°C to in situ temperature
12 MercuryHgng/m3Kuss, JoachimCalculatedHg0 surf. water: final concentration of elemental mercury in surface water
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
5256 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Date/Time

Longitude

Latitude

Depth water [m]

Temp [°C]
(Thermosalinograph)

Sal
(Thermosalinograph)

ff [m/s]
(altitude 25 m, Anemometer)

Hg [ng/m3]
(Hg0 equil. : duplicate measur...)

T tech [°C]
(Temp equil.)
10 
H
(H surf (Sanemasa), Calculated...)
11 
Hg [ng/m3]
(Hg0-equi sea surface: recalcu...)
12 
Hg [ng/m3]
(Hg0 surf. water: final concen...)
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2009-04-13T18:12:24-63.17095-49.51122118.8433.4215.281.2010.730.2141.135.3
2009-04-13T19:27:25-62.96813-49.37761119.1933.3715.691.1010.790.2161.044.8
2009-04-13T20:42:25-62.78149-49.25414118.9733.4117.591.3310.800.2151.255.8
2009-04-13T21:57:25-62.60461-49.13713119.0133.4213.481.2310.770.2151.165.4
2009-04-13T23:12:26-62.43613-49.02448119.0833.5013.321.1710.900.2151.105.1
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2009-04-14T01:37:24-62.13027-48.82123119.0933.5113.021.1510.840.2161.095.0
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2009-04-16T13:22:29-55.58241-44.256271116.5434.629.001.9917.540.2711.947.2
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2009-04-16T23:07:30-54.59942-43.538151117.8934.667.722.2918.950.2812.217.9
2009-04-17T00:22:30-54.45671-43.432861117.6434.686.222.2018.840.2792.127.6
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2009-04-17T05:17:29-53.86251-42.993671117.0334.895.202.0818.270.2731.997.3
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