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Dähnke, Kirstin; Jacob, Juliane; Schulz, Gesa; Ankele, Markus; Metzke, Marc; Schmidt, Leon; Sanders, Tina (2023): A decade of nitrate dual stable isotope measurements in the Elbe River (Germany) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.960361

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Published: 2023-07-11DOI registered: 2023-08-09

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Abstract:
We investigated nutrient input and retention in the Elbe River (Germany) at the river/estuarine transition with high agricultural loads of nitrogen. Surface water samples were taken at the weir Geesthacht (stream kilometre 585, 53°25'31''N, 10°20'10''E) from 2011 to 2021. In these samples, we analyzed nutrient concentrations, nitrate dual stable isotopes and suspended particulate matter composition. Usually, samples were taken once or twice per month. Aims of the study were to investigate 1) nitrate retention in the Elbe River and catchment, 2) seasonal dynamic of nitrate stable isotopes and 3) key nitrogen turnover processes and their respective controls over a ten year period.
Supplement to:
Schulz, Gesa; van Beusekom, Justus; Jacob, Juliane; Bold, Sina; Schöl, Andreas; Ankele, Markus; Sanders, Tina; Dähnke, Kirstin (2023): Low discharge intensifies nitrogen retention in rivers – A case study in the Elbe River. Science of the Total Environment, 904, 166740, https://doi.org/10.1016/j.scitotenv.2023.166740
Related to:
Jacob, Juliane; Sanders, Tina; Dähnke, Kirstin (2016): Nitrite consumption and associated isotope changes during a river flood event in the Elbe river [dataset]. Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research, PANGAEA, https://doi.org/10.1594/PANGAEA.865348
Project(s):
Coverage:
Latitude: 53.425270 * Longitude: 10.336110
Date/Time Start: 2011-07-06T06:00:00 * Date/Time End: 2021-06-14T06:00:00
Minimum DEPTH, water: m * Maximum DEPTH, water: m
Event(s):
GW2011-2016_Stat_1 * Latitude: 53.425270 * Longitude: 10.336110 * Date/Time Start: 2013-06-06T00:00:00 * Date/Time End: 2013-06-20T00:00:00 * Location: Geesthacht weir, Germany * Method/Device: Water sample (WS) * Comment: Elbe kilometer 585
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample IDSample IDDähnke, Kirstin
DEPTH, waterDepth watermDähnke, KirstinGeocode
DATE/TIMEDate/TimeDähnke, KirstinGeocode – UTC
δ15N, nitrateδ15N NO3‰ airDähnke, KirstinMeasurement as N2O using isotope-ratio mass spectrometry (IRMS). Bacterial conversion to N2O, so called Denitrifier-method (according to Sigman et al. 2001; Casciotti et al. 2002). Average of the measurement of 2 replicatesmeasured in water column
δ18O, nitrateδ18O NO3Dähnke, KirstinMeasurement as N2O using isotope-ratio mass spectrometry (IRMS). Bacterial conversion to N2O, so called Denitrifier-method (according to Sigman et al. 2001; Casciotti et al. 2002). Average of the measurement of 2 replicatesmeasured in water column
Nitrogen in ammoniumN-[NH4]+µmol/lDähnke, KirstinFluorescence measurement (OPA), with auto-analysermeasured in water column
Nitrogen in nitriteN-[NO2]-µmol/lDähnke, KirstinContinuous flow analyser, Seal, AA3measured in water column; Nutrient concentrations were analysed with a continuous flow analyser (AA3, Seal Analytics, Germany). For nitrite and nitrate analyses, standard photometric techniques were used (Grasshoff et al., 2009) with detection limits of 0.1 and 1.0 micromol per liter. Ammonium was measured fluorometrically with a detection limit of 0.5 micromol per liter based on (Holmes et al., 1999). Detection limits: nitrite (NO2) 0.1 micromol per liter, nitrate (NO3) 1.0 micromol per liter, amonnium (NH4) 0.5 micromol per liter. Average of the measurement of 2 replicates.
Nitrogen in nitrateN-[NO3]-µmol/lDähnke, Kirstinmeasured in water column; Nutrient concentrations were analysed with a continuous flow analyser (AA3, Seal Analytics, Germany). For nitrite and nitrate analyses, standard photometric techniques were used (Grasshoff et al., 2009) with detection limits of 0.1 and 1.0 micromol per liter. Ammonium was measured fluorometrically with a detection limit of 0.5 micromol per liter based on (Holmes et al., 1999). Detection limits: nitrite (NO2) 0.1 micromol per liter, nitrate (NO3) 1.0 micromol per liter, amonnium (NH4) 0.5 micromol per liter. Average of the measurement of 2 replicates.
Phosphorus in orthophosphateP-[PO4]3-µmol/lDähnke, Kirstinmeasured in water column; Nutrient concentrations were analysed with a continuous flow analyser (AA3, Seal Analytics, Germany). For nitrite and nitrate analyses, standard photometric techniques were used (Grasshoff et al., 2009) with detection limits of 0.1 and 1.0 micromol per liter. Ammonium was measured fluorometrically with a detection limit of 0.5 micromol per liter based on (Holmes et al., 1999). Detection limits: nitrite (NO2) 0.1 micromol per liter, nitrate (NO3) 1.0 micromol per liter, amonnium (NH4) 0.5 micromol per liter. Average of the measurement of 2 replicates.
10 Silicate, dissolvedDSi(OH)4µmol/lDähnke, Kirstinmeasured in water column; Nutrient concentrations were analysed with a continuous flow analyser (AA3, Seal Analytics, Germany). For nitrite and nitrate analyses, standard photometric techniques were used (Grasshoff et al., 2009) with detection limits of 0.1 and 1.0 micromol per liter. Ammonium was measured fluorometrically with a detection limit of 0.5 micromol per liter based on (Holmes et al., 1999). Detection limits: nitrite (NO2) 0.1 micromol per liter, nitrate (NO3) 1.0 micromol per liter, amonnium (NH4) 0.5 micromol per liter. Average of the measurement of 2 replicates.
11 Suspended particulate matterSPMmg/lDähnke, KirstinGF/F WHA1825047, Whatman, UKmasured in suspended particulate matter; SPM mass per volume (F_loaded-F_empty)/volume in water sample. Filter: Whatman GF/C, filtration method: vacuum filtration
12 Nitrogen, totalTN%Dähnke, KirstinElemental analyzer (EA), Thermo Scientific, FlashEA 1112wt. %; masured in suspended particulate matter; Total carbon (TC) in suspended matter was determined with an Elemental Analyser (Thermo Flash EA 1112) calibrated against a certified acetanilide standard (IVA Analysentechnik, Germany). The standard deviation of C/N analysis was 0.05% for carbon.
13 Carbon, totalTC%Dähnke, KirstinContinuous flow analyser, Seal, AA3wt. %; masured in suspended particulate matter; Nutrient concentrations were analysed with a continuous flow analyser (AA3, Seal Analytics, Germany). For nitrite and nitrate analyses, standard photometric techniques were used (Grasshoff et al., 2009) with detection limits of 0.1 and 1.0 micromol per liter. Ammonium was measured fluorometrically with a detection limit of 0.5 micromol per liter based on (Holmes et al., 1999). Detection limits: nitrite (NO2) 0.1 micromol per liter, nitrate (NO3) 1.0 micromol per liter, amonnium (NH4) 0.5 micromol per liter. Average of the measurement of 2 replicates.
14 Carbon/Nitrogen ratioC/NDähnke, KirstinElemental analyzer (EA), Thermo Scientific, FlashEA 1112molar; masured in suspended particulate matter; C/N ratios were determined with an Elemental Analyser (Thermo Flash EA 1112) calibrated against a certified acetanilide standard (IVA Analysentechnik, Germany). The standard deviation of C/N analysis was 0.05% for carbon and 0.005% for nitrogen.
15 δ15N, total nitrogenδ15N TN‰ airDähnke, KirstinElement analyser, Carlo Erba NA2500, coupled with an isotope ratio mass spectrometerFinnigan MAT 252masured in suspended particulate matter; d15N-SPM was analysed with an element analyser (Carlo Erba NA 2500) coupled with an isotope ratio mass spectrometer (Finnigan MAT 252). All samples were analysed in replicate. Standards for d15N-SPM are IAEA N1, IAEA N2, and a certified sediment standard (IVA Analysentechnik, Germany). Standard deviation of standards and samples was <0.1 permille.
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2723 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample ID

Depth water [m]

Date/Time

δ15N NO3 [‰ air]

δ18O NO3 []

N-[NH4]+ [µmol/l]

N-[NO2]- [µmol/l]

N-[NO3]- [µmol/l]

P-[PO4]3- [µmol/l]
10 
DSi(OH)4 [µmol/l]
11 
SPM [mg/l]
12 
TN [%]
13 
TC [%]
14 
C/N
15 
δ15N TN [‰ air]
t_GW2011-2016_Stat_1_Water_102011-07-06T06:00:0020.4676157411.435375130.527331.0793374.800000.070002.3400
t_GW2011-2016_Stat_1_Water_202011-07-21T06:00:0022.0937265512.674338181.612001.2106768.360000.040000.7100
t_GW2011-2016_Stat_1_Water_302011-08-04T06:00:0012.392068224.490932561.116001.12433146.400000.6800057.6600
t_GW2011-2016_Stat_1_Water_402011-08-18T06:00:0014.906389916.616270130.869330.58167119.550000.46000106.2100
t_GW2011-2016_Stat_1_Water_502011-09-01T06:00:0014.851670996.900856191.243670.58633119.360000.7300085.8300
t_GW2011-2016_Stat_1_Water_602011-09-15T06:00:0013.355183265.409859350.725670.59200161.300000.8900091.2800
t_GW2011-2016_Stat_1_Water_702011-09-30T06:00:0013.045031674.472769281.393330.48000174.930001.16000111.6000
t_GW2011-2016_Stat_1_Water_802011-10-13T06:00:0012.325817615.940427631.483330.54100168.68000
t_GW2011-2016_Stat_1_Water_902011-10-27T06:00:0011.683057412.699720901.549000.45933186.70000
t_GW2011-2016_Stat_1_Water_1002011-11-10T07:00:0011.506494732.329265242.939330.44000199.74000
t_GW2011-2016_Stat_1_Water_1102011-11-24T07:00:0011.620019332.943369646.490500.41800216.390001.69000186.9900
t_GW2011-2016_Stat_1_Water_1202011-12-08T07:00:0011.363501242.971274176.893330.45933203.350001.69000188.9900
t_GW2011-2016_Stat_1_Water_1302011-12-21T07:00:0010.366146572.5715958813.520001.47867274.15000174.1800
t_GW2011-2016_Stat_1_Water_1402012-01-05T07:00:008.967389771.941163789.090001.10400324.24000190.7400
t_GW2011-2016_Stat_1_Water_1502012-01-10T07:00:008.620821581.142767947.820001.15200269.31000180.6600
t_GW2011-2016_Stat_1_Water_1602012-01-18T07:00:008.847320101.788284244.500000.56667204.68000128.8300
t_GW2011-2016_Stat_1_Water_1702012-02-03T07:00:008.378790481.905898486.490001.10933248.57000159.4800
t_GW2011-2016_Stat_1_Water_1802012-02-16T07:00:009.092517211.791266817.750001.14933285.12000186.0600
t_GW2011-2016_Stat_1_Water_1902012-03-01T07:00:008.774389222.016987497.570001.16800247.11000179.9300
t_GW2011-2016_Stat_1_Water_2002012-03-15T07:00:008.390094261.749521338.550000.83067238.31000177.3800
t_GW2011-2016_Stat_1_Water_2102012-03-28T06:00:009.210083372.4148210012.850001.04533285.01000202.8800
t_GW2011-2016_Stat_1_Water_2202012-04-19T06:00:0012.831920056.167655370.177500.09100156.508500.0675046.5750
t_GW2011-2016_Stat_1_Water_2302012-05-10T06:00:0014.965512668.104662800.156500.06800107.336000.049500.7305
t_GW2011-2016_Stat_1_Water_2402012-05-29T06:00:0018.0534218711.004778870.192500.0565090.443000.039003.6535
t_GW2011-2016_Stat_1_Water_2502012-06-07T06:00:0020.9315036213.525439500.161000.0760053.664500.166002.0250
t_GW2011-2016_Stat_1_Water_2602012-06-22T06:00:0020.5272607912.259477940.196500.0900064.759000.033000.9870
t_GW2011-2016_Stat_1_Water_2702012-07-05T06:00:0019.0941819511.100643480.247000.3270068.870500.0790019.8295
t_GW2011-2016_Stat_1_Water_2802012-07-19T06:00:0016.542278747.214220090.765500.9955086.366000.2920068.1065
t_GW2011-2016_Stat_1_Water_2902012-08-02T06:00:0020.5075175311.092786320.574501.0730060.170000.059505.6315
t_GW2011-2016_Stat_1_Water_3002012-08-16T06:00:0024.4067038814.514436120.755000.8705037.220000.044500.0505
t_GW2011-2016_Stat_1_Water_3102012-08-30T06:00:0022.5796650113.470503960.396500.9450040.610500.057004.1425
t_GW2011-2016_Stat_1_Water_3202012-09-13T06:00:0017.318332958.179921690.256500.9745080.811500.0450032.6585
t_GW2011-2016_Stat_1_Water_3302012-09-27T06:00:0013.546022484.217723960.951000.73800128.614500.2810090.1050
t_GW2011-2016_Stat_1_Water_3402012-10-12T06:00:0012.702956883.653861360.680000.60950136.700500.8420071.8860
t_GW2011-2016_Stat_1_Water_3502012-10-25T06:00:0011.923071903.108206803.853000.72000156.782501.3720060.6815
t_GW2011-2016_Stat_1_Water_3602012-11-08T07:00:0011.628952002.316117154.766500.68500177.103501.7910088.2055
t_GW2011-2016_Stat_1_Water_3702012-11-22T07:00:0011.538102001.792895584.254000.67400181.827001.8110084.3905
t_GW2011-2016_Stat_1_Water_3802012-12-14T07:00:0010.797817591.953103748.893000.79550202.273001.97100149.9650
t_GW2011-2016_Stat_1_Water_3902013-01-02T07:00:007.938669951.361010409.306501.51800318.695502.01900166.9235
t_GW2011-2016_Stat_1_Water_4002013-01-17T07:00:007.684780621.587916385.090501.42150285.742002.37700175.0825
t_GW2011-2016_Stat_1_Water_4102013-01-30T07:00:008.673659871.8256137211.332001.32300277.056502.16400196.2285
t_GW2011-2016_Stat_1_Water_4202013-02-13T07:00:007.835025661.515885556.016501.62900342.457001.88950177.5965
t_GW2011-2016_Stat_1_Water_4302013-02-28T07:00:008.808505541.245536197.129001.14200308.553000.85700166.9010
t_GW2011-2016_Stat_1_Water_4402013-03-13T07:00:008.889960941.553313502.497001.23400346.771000.68300158.3680
t_GW2011-2016_Stat_1_Water_4502013-04-04T06:00:009.305002842.220999041.268000.83600300.765000.00000101.6450
t_GW2011-2016_Stat_1_Water_4602013-04-17T06:00:009.836894452.823560051.266000.82700299.060000.0000061.3860
t_GW2011-2016_Stat_1_Water_4702013-05-02T06:00:0010.439198223.790317181.268000.76600205.952000.0000032.2700
t_GW2011-2016_Stat_1_Water_4802013-05-22T06:00:0011.566775923.801799831.267000.75400209.821000.2170063.2440
t_GW2011-2016_Stat_1_Water_4902013-06-06T08:08:009.000000003.240584471.267004.19900225.827000.28500131.3610
t_GW2011-2016_Stat_1_Water_5002013-06-06T15:00:009.129544273.508531700.002001.62350269.636501.00850122.3050
t_GW2011-2016_Stat_1_Water_5102013-06-07T07:10:008.758196633.195558960.002501.66500261.839501.43050115.4105
t_GW2011-2016_Stat_1_Water_5202013-06-07T14:50:008.965150903.484203510.002501.75950256.698501.04650118.4625
t_GW2011-2016_Stat_1_Water_5302013-06-08T07:10:008.490708373.120024110.002501.80150251.749001.23900112.0000
t_GW2011-2016_Stat_1_Water_5402013-06-08T14:45:008.482988813.356769250.001501.67250255.407251.29550122.4940
t_GW2011-2016_Stat_1_Water_5502013-06-09T06:55:008.428621043.325355010.067502.20250229.611500.95700121.0010
t_GW2011-2016_Stat_1_Water_5602013-06-09T14:55:008.275359003.352402660.000002.36200228.130000.69350122.2480
t_GW2011-2016_Stat_1_Water_5702013-06-10T07:25:007.909676343.357346300.770502.69900238.712501.02300128.6540
t_GW2011-2016_Stat_1_Water_5802013-06-10T14:55:007.841337913.425337220.244002.82600244.051001.06000139.6455
t_GW2011-2016_Stat_1_Water_5902013-06-11T07:12:007.647751612.923678931.437503.13700267.432501.61950151.9140
t_GW2011-2016_Stat_1_Water_6002013-06-11T14:48:007.621365702.784415640.994503.29400263.881501.31200145.2995
t_GW2011-2016_Stat_1_Water_6102013-06-12T07:00:007.617952272.945172052.873503.69100268.966002.19950126.1415
t_GW2011-2016_Stat_1_Water_6202013-06-12T15:00:007.562653942.328904312.794503.89575275.573501.59850170.9410
t_GW2011-2016_Stat_1_Water_6302013-06-13T07:15:007.587032282.244753183.211004.24050274.195751.77300172.5360
t_GW2011-2016_Stat_1_Water_6402013-06-13T15:00:007.670053402.134464372.861504.43950280.593501.83550170.6505
t_GW2011-2016_Stat_1_Water_6502013-06-14T06:55:007.906521692.345246532.358004.44850263.290001.76900168.8725
t_GW2011-2016_Stat_1_Water_6602013-06-14T15:05:008.080666842.656575793.401504.38400254.942008.72900161.4275
t_GW2011-2016_Stat_1_Water_6702013-06-15T12:20:008.282693162.953448850.000004.10750242.384501.47400155.1480
t_GW2011-2016_Stat_1_Water_6802013-06-16T07:20:008.509785573.324231610.000003.98200229.618501.31850152.6860
t_GW2011-2016_Stat_1_Water_6902013-06-18T06:55:008.790322003.496421820.000003.68000225.705501.35350142.9125
t_GW2011-2016_Stat_1_Water_7002013-06-20T07:25:008.971876693.909755361.296503.26450180.005001.64770143.4790
t_GW2011-2016_Stat_1_Water_7102013-06-24T06:00:009.882187543.1832916812.515005.18900137.955007.75550138.2310
t_GW2011-2016_Stat_1_Water_7202013-06-27T06:00:0010.045935053.1140471010.319005.70550139.389503.59400136.2460
t_GW2011-2016_Stat_1_Water_7302013-07-02T06:00:003.99000136.12000
t_GW2011-2016_Stat_1_Water_7402013-07-19T06:00:000.00000104.44000
t_GW2011-2016_Stat_1_Water_7502013-08-01T06:00:001.964250.73925110.237000.2542569.3635
t_GW2011-2016_Stat_1_Water_7602013-08-21T06:00:005.889000.82900106.334750.09650-0.1270
t_GW2011-2016_Stat_1_Water_7702013-09-03T06:00:002.051000.81000107.471000.2450064.1315
t_GW2011-2016_Stat_1_Water_7802013-09-19T06:00:000.000000.55900154.009000.12300101.5005
t_GW2011-2016_Stat_1_Water_7902013-10-10T06:00:001.084500.36100190.063501.09000129.7535
t_GW2011-2016_Stat_1_Water_8002013-10-29T07:00:002.861000.42100190.882501.90450159.0100
t_GW2011-2016_Stat_1_Water_8102013-11-19T07:00:003.676000.46200223.571001.94800157.3830
t_GW2011-2016_Stat_1_Water_8202013-12-04T07:00:005.655500.60900233.536501.74550101.6335
t_GW2011-2016_Stat_1_Water_8302013-12-20T07:00:006.484000.87050266.137501.73200137.7275
t_GW2011-2016_Stat_1_Water_8402014-01-08T07:00:005.652500.69300250.717501.61750146.7415
t_GW2011-2016_Stat_1_Water_8502014-01-21T07:00:004.804500.67300252.099501.49850164.0755
t_GW2011-2016_Stat_1_Water_8602014-02-05T07:00:0011.494000.74100263.389001.29300167.3680
t_GW2011-2016_Stat_1_Water_8702014-02-18T07:00:001.396000.51750256.999000.55750163.3640
t_GW2011-2016_Stat_1_Water_8802014-03-12T07:00:0012.480000004.620000001.490000.37000198.240000.0800081.6800
t_GW2011-2016_Stat_1_Water_8902014-03-27T07:00:0013.670000005.440000001.860000.46000204.050000.6800014.1300
t_GW2011-2016_Stat_1_Water_9002014-04-08T06:00:0014.100000005.940000001.170000.42000149.470000.030000.4700
t_GW2011-2016_Stat_1_Water_9102014-04-22T06:00:0015.890000007.000000000.970000.44000110.300000.210000.6800
t_GW2011-2016_Stat_1_Water_9202014-05-05T06:00:0017.370000008.640000001.030000.5300094.97000-0.030000.9600
t_GW2011-2016_Stat_1_Water_9302014-05-20T06:00:0018.370000009.190000000.360000.5600079.100000.070000.5000
t_GW2011-2016_Stat_1_Water_9402014-06-06T06:00:0012.120000002.950000000.980000.93000182.930000.45000107.9900
t_GW2011-2016_Stat_1_Water_9502014-06-18T06:00:0020.7000000010.630000000.200000.7700067.950000.0100041.7800
t_GW2011-2016_Stat_1_Water_9602014-07-01T06:00:0023.5400000014.190000002.260000.5800039.47000-0.0100015.1100
t_GW2011-2016_Stat_1_Water_9702014-07-16T06:00:0018.840000008.710000001.920000.8900074.760000.0100015.7100
t_GW2011-2016_Stat_1_Water_9802014-07-31T06:00:0020.8400000010.790000007.930000.7600064.040000.3300035.4700
t_GW2011-2016_Stat_1_Water_9902014-08-12T06:00:0016.080000006.240000001.100000.90000102.070000.5500095.9800
t_GW2011-2016_Stat_1_Water_10002014-08-27T06:00:0017.690000006.170000000.570000.58000100.580000.1200098.4600
t_GW2011-2016_Stat_1_Water_10102014-09-11T06:00:0013.190000002.530000001.920000.50000146.990001.04000100.9900
t_GW2011-2016_Stat_1_Water_10202014-09-24T06:00:0011.440000001.160000002.600000.37000198.720002.32000148.0400
t_GW2011-2016_Stat_1_Water_10302014-10-07T06:00:0010.830000001.260000002.510000.29000199.560002.37000158.2100
t_GW2011-2016_Stat_1_Water_10402014-10-22T06:00:0012.370000001.170000003.160000.29000192.330002.63000172.4300
t_GW2011-2016_Stat_1_Water_10502014-11-05T07:00:0010.790000001.000000002.760000.36000199.850002.43000179.3000
t_GW2011-2016_Stat_1_Water_10602014-11-20T07:00:0011.410000000.820000003.830000.27000217.280002.26000193.5600
t_GW2011-2016_Stat_1_Water_10702014-12-04T07:00:0010.770000000.280000005.990000.30000222.610002.10000198.5500
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t_GW2011-2016_Stat_1_Water_10902015-01-07T07:00:0010.100000001.0500000010.300000.61000242.060002.29000180.8100
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