Citation:

PANGAEA.959866

Name: X-ray fluorescence (XRF) data of sediment core GeoB24351-1, 10 kV run
Published: 2023-06-27
License: https://creativecommons.org/licenses/by/4.0/
Keywords: Gelendzhik MV; Mediterranean Ridge accretionary complex; mud volcano; Olimpi mud volcano field; R/V SONNE; SO278; XRF core scanner

Always quote citation above when using data! You can download the citation in several formats below.

Published: 2023-06-27 • DOI registered: 2023-07-26

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Abstract:

X-Ray fluorescence (XRF) scans were carried out for core GeoB24351-1 (Gelendzhik MV; 0-284 cm) in 10 mm steps downcore on the split core surface of the archive half with the XRF Core Scanner III (AVAATECH Serial No. 12) at MARUM – Center for Marine Environmental Sciences in Bremen. To avoid contamination of the XRF measurement unit and the desiccation of the sediment, the split core was covered with a 4 µm thin SPEXCerti Ultralene1 foil. Reported data was acquired with a SGX Sensortech Silicon drift detector (Modul S SiriusD®D65133Be-INF with 133 eV X-ray resolution), a Topaz-X High-Resolution Digital MCA, and an Oxford Instruments 100 W Neptune X-Ray tube with rhodium (Rh) target material. Data were obtained during three runs at 50 kV (1st run), 30 kV (2nd run) and 10 kV (3rd run). Processing of raw data took place by the analysis of X-ray spectra by an iterative least square software package from Canberra Eurisys (WIN AXIL).

Keyword(s):

Gelendzhik MV; Mediterranean Ridge accretionary complex; mud volcano; Olimpi mud volcano field; R/V SONNE; SO278; XRF core scanner

Related to:

Behrendt, Nele; Menapace, Walter; Bohrmann, Gerhard; Zabel, Matthias; Kopf, Achim J (2023): Pore water signatures and gas hydrates occurrence in and around the Olimpi mud volcano field, south of Crete. Marine and Petroleum Geology, 156, 106429, https://doi.org/10.1016/j.marpetgeo.2023.106429

Further details:

Bohrmann, Gerhard; Ahrlich, Frauke; Antoniou, Dimitra; Behrendt, Nele; Innocentini, Simone; Coulibaly, Ousmane; Eijsink, Agathe; Feddersen, Greta; Gaide, Stefanie; Kaul, Norbert; König, Tabea; Krahl, Julia; Kürzinger, Victoria; Lenius, Sven; Malnati, Janice; Marschall, Lara; Niederbockstruck, Bryan; Porrmann, Simon; Rau, Svenja; Römer, Miriam; Schillai, Sophia; Spiesecke, Ulli; Streuff, Katharina Teresa; Tseng, Yiting; Vejzovic, Ines; von Wahl, Till; Warnken, Niklas; Witzleb, Antonia (2021): Fluid-rock interaction at the backstop to the Mediterranean Ridge Accretionary Complex South of Crete, Cruise Report SO278, 12 October - 01 December 2020, Emden (Germany) - Emden (Germany). SONNE-Berichte, Gutachterpanel Forschungsschiffe, SO278, 208 pp, https://doi.org/10.48433/cr_so278

Project(s):

Center for Marine Environmental Sciences (MARUM)

The Ocean Floor - Earth's Uncharted Interface (ClusterOceanFloor)

Funding:

German Research Foundation (DFG), grant/award no. 390741603 : EXC 2077: The Ocean Floor – Earth's Uncharted Interface

Coverage:

Latitude: 33.903020 * Longitude: 24.269020

Date/Time Start: 2020-11-13T05:36:09 * Date/Time End: 2020-11-13T05:36:09

Minimum DEPTH, sediment/rock: 0.02 m * Maximum DEPTH, sediment/rock: 0.98 m

Event(s):

SO278_51-1 (GeoB24351-1) * Latitude: 33.903020 * Longitude: 24.269020 * Date/Time: 2020-11-13T05:36:09 * Elevation: -1695.6 m * Location: Mediterranean Sea * Campaign: (GPF 19-2-007H) * Basis: * Method/Device: Gravity corer (GC)

Comment:

Scanner: AVAATECH (Serial No. 12)

X-ray tube: Oxford Instruments 100W Neptune Rh X-ray tube

X-ray detector: SiriusSD D65133BE-INF

Step size: 10 mm

Slit down-core: 10 mm

Slit cross-core: 12 mm

X-ray tube settings: 1st run: 50 kV; 0.5 mA; 8 sec. Cu filter

2nd run: 30 kV; 0.6 mA; 8 sec. Pd thick filter

3rd run: 10 kV; 0.05 mA; 8 sec. no filter

Processing model: 1st run: 50 kV; Averaged dead time: 29%

2nd run: 30 kV; Averaged dead time: 27%

3rd run: 10 kV; Averaged dead time: 27%

Data quality check of processed data at MARUM XRF Core Scanner Lab:

Data from listed elements are reliable for scientific publication:

1st run: Ba*, (Sr, Zr, Rb, Br)**

2nd run: Br, Sr, Zr, Rb

3rd run: Al, Si, S, K, ca, Ti, Mn, Fe

Data from listed elements are NOT reliable for scientific publication:

1st run: Mo, Ag, Sn, Te

2nd run: Ni, Cu, Zn, Ga, (Nb, Mo, Pb)***, Bi

3rd run: P, Cl, Rh, Cr, Mg

Notes (scatter & escape peaks, elements below detection limit, etc.):

Sediment surfaces are very poor and not really suitable for XRF scanning (all:

uneven/bumpy surfaces, x to y cm pebbles, holes, and cracks). Therefore highly

recommended to (only) work with elemental ratios from the acquired datasets.

Please also note: Ba*: small peaks only, general low total counts; (Sr,Rb,Zr,Br)**: better in

30 kV run; (Nb, Mo, Pb)***: please validate the higher peaks standing out from a different

chemical method

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	DEPTH, sediment/rock	Depth sed	m	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]	Geocode
2	Magnesium	Mg	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
3	Aluminium	Al	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
4	Silicon	Si	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
5	Phosphorus	P	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
6	Sulfur	S	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
7	Chlorine	Cl	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
8	Potassium	K	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
9	Calcium	Ca	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
10	Titanium	Ti	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
11	Chromium	Cr	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
12	Manganese	Mn	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
13	Iron	Fe	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
14	Rhodium	Rh	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

2535 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Depth sed [m]	2 Mg [cps]	3 Al [cps]	4 Si [cps]	5 P [cps]	6 S [cps]	7 Cl [cps]	8 K [cps]	9 Ca [cps]	10 Ti [cps]	11 Cr [cps]	12 Mn [cps]	13 Fe [cps]	14 Rh [cps]
0.02	128	2375	19210	154	4916	65117	10309	65338	11379	241	1796	104889	16822
0.03	107	2166	17125	118	5005	69023	10012	56353	11703	279	1948	109032	17530
0.04	124	2706	21763	247	5716	62453	10981	64308	12388	650	1752	113885	14937
0.05	118	2403	18939	180	5494	60776	10270	58740	11994	333	1833	105779	17208
0.06	66	1326	10832	65	5364	46850	6472	36000	7787	116	1162	75348	17209
0.11	128	3198	24704	177	6772	51115	10614	53984	12246	402	1693	109625	14981
0.12	129	2955	22123	155	6351	54287	9677	58970	11177	326	1897	101979	13856
0.13	109	2730	20345	162	6085	56784	10336	83316	9804	107	1686	89994	16011
0.14	115	2872	20628	158	5853	56712	10050	66040	10280	319	1601	95120	15806
0.15	93	2956	22279	165	6200	60297	10490	69046	11024	376	1962	98773	16260
0.16	150	3032	21754	160	6508	60414	10762	72655	10364	221	1697	94322	14473
0.17	119	2834	20511	152	6365	62999	10426	74455	9791	124	1531	88848	16531
0.18	127	3421	24117	120	6432	59581	11200	81974	10815	391	1762	91359	16223
0.19	134	3132	22389	178	7106	64913	10883	74911	10549	133	1737	93540	15884
0.20	149	3539	25404	165	6862	61250	11520	79356	11189	428	1756	97723	15671
0.21	155	4137	28741	200	7289	56622	12632	84120	11237	201	1948	98801	16088
0.22	146	4463	31001	178	6865	53340	12809	85756	11658	214	1718	100617	14371
0.23	156	3814	26945	267	7153	57149	11580	83044	10913	354	1847	95492	15515
0.24	139	3016	22258	192	7174	62334	10284	76624	9974	284	1676	91154	15730
0.25	117	2928	21625	142	7686	62872	10784	76291	10307	243	1658	94663	15648
0.26	138	3338	23933	211	8267	61506	11140	85604	10228	364	1712	94147	14390
0.27	122	3755	27273	278	6985	57994	11189	79240	11125	237	1780	96732	15592
0.28	152	3058	22506	118	7117	62544	9953	71946	10324	308	1748	93394	15127
0.29	149	3526	25798	156	7584	59540	10684	72748	11317	371	1735	100051	14986
0.30	130	3358	24512	171	7053	62286	10776	70317	11329	231	1556	98767	15183
0.31	127	3757	26621	248	7788	60154	11401	79741	11002	62	1676	97635	15109
0.32	121	3614	25935	191	7804	60883	10891	78647	10861	420	1638	93785	14864
0.33	149	3682	26251	249	6989	64506	10940	64982	11720	311	1824	105863	13913
0.34	170	4245	30229	205	6288	59499	11857	59790	13378	365	1697	113837	14633
0.35	138	3842	28165	174	6197	61169	11486	56263	13493	380	1836	115983	15386
0.36	125	2733	20339	158	6725	73294	9385	43765	12244	391	1367	109492	17514
0.37	135	2775	20285	129	6323	69035	9129	43615	11735	487	1580	103365	14456
0.38	126	3290	24453	203	5979	60764	9872	49621	12093	277	1368	104310	15705
0.39	154	3592	25201	228	6847	56135	9687	50481	11589	130	1653	98728	12676
0.40	127	3269	23614	171	6531	55231	9219	49903	10715	322	1589	93469	14758
0.41	120	2927	22349	152	5906	62010	9181	51317	11368	280	1688	100252	16370
0.42	111	2583	19086	121	6552	71800	8650	45269	10613	294	1743	102823	14205
0.43	119	2827	21135	170	7155	71173	9167	54482	11380	383	1637	106856	14481
0.44	181	3304	24293	301	7141	63490	10114	64207	11907	550	1907	104475	13841
0.45	142	2678	20934	145	6532	54966	8909	60525	10024	216	1540	90077	14650
0.46	147	2997	22446	126	6021	63689	9973	65263	10503	550	1877	98363	16019
0.47	116	3689	26518	192	5792	60196	10814	67824	12056	370	2013	107280	16847
0.48	144	4026	28172	178	5892	61215	11158	85345	11783	481	2058	102099	14756
0.49	119	3362	24118	163	6720	70472	9936	46092	12974	430	1563	111333	15105
0.50	168	3909	27567	159	7735	68295	9896	23998	14290	574	1375	122538	13868
0.51	186	3404	24633	163	7157	72379	8442	15783	14291	524	1559	123436	13846
0.52	130	2803	20036	150	5965	78235	8083	37306	11117	325	1560	105683	13195
0.53	117	3472	24116	122	5645	68499	10051	45132	12824	356	1833	114787	15276
0.54	128	3071	22230	143	6157	70802	9283	50099	11545	432	1832	109254	13874
0.55	94	2696	19104	133	6034	74027	8740	45166	11185	298	1710	103754	14583
0.56	113	2236	17003	95	5775	75966	8024	42705	10928	377	1766	104488	14908
0.57	91	2954	22620	180	5609	63916	9692	62917	11858	454	1946	108885	15594
0.58	133	3625	27608	163	4669	51911	11201	62246	13264	334	2031	114351	16798
0.59	133	2739	21454	152	4365	55798	9600	54177	12106	464	1820	103441	14794
0.60	94	1975	15780	55	3759	55610	7461	41419	10244	192	1482	94262	15153
0.61	121	2086	15802	45	3944	53037	7297	41765	9589	454	1580	88070	14567
0.62	89	2342	18079	92	4865	63172	8614	46480	10244	302	1550	90353	16405
0.63	125	3142	23482	230	5528	63276	9400	85468	9313	268	3239	78868	13773
0.64	124	3192	23716	175	5490	64550	9107	57727	11249	289	2174	91098	13681
0.65	119	2560	18341	79	4892	67652	7810	29138	12317	321	1582	101459	14233
0.66	113	2177	15511	57	5156	75304	6623	21305	10354	262	1250	96103	14400
0.67	150	2548	17574	126	5376	77032	7077	58002	9992	294	1654	92243	14266
0.68	143	3147	22424	133	5862	73195	9225	47616	12037	371	1626	101252	13575
0.69	103	3371	23150	178	5724	72647	9120	37939	12818	429	1365	104403	14921
0.70	107	2946	21066	140	5791	76954	8518	33187	12047	446	1183	100907	14657
0.71	130	3129	21163	182	6128	77699	8638	33237	12532	497	1411	104073	15476
0.72	164	3725	25249	128	5519	67956	9985	45021	12672	278	1264	101777	13918
0.73	119	3259	22960	128	5854	71436	9575	37806	12542	368	1587	106665	15300
0.77	150	2616	19472	197	4009	66191	9734	47598	13014	465	1860	114681	13762
0.78	164	2970	23451	164	3683	60151	11479	36459	13842	650	1907	130277	13905
0.79	123	2655	22074	149	3863	63492	10642	42735	12056	652	1875	123171	16319
0.80	161	2986	22728	119	4442	66113	10034	39973	13791	543	1877	113920	13357
0.81	115	2879	21463	145	4483	65904	9465	54954	12406	231	2055	110154	15866
0.82	156	2954	22310	83	4081	62429	9377	54326	12084	335	2033	109472	14900
0.83	137	2949	21835	127	4169	63527	9652	57357	12306	439	1897	109970	14808
0.84	117	3349	24418	162	4304	58493	10177	55966	12092	438	1941	112586	15044
0.85	132	2612	19920	136	4223	67656	8993	41453	12128	317	1911	113443	14672
0.86	136	2921	22377	268	4688	68329	9913	47955	12465	589	1952	119783	15475
0.87	84	3165	23448	178	4516	65654	10540	58095	12974	424	1985	117634	16611
0.88	168	3560	25672	141	4653	63931	11297	67159	13008	291	2205	114238	15881
0.89	125	3612	26181	208	4705	66034	10546	64885	12363	373	2220	113082	15112
0.91	172	5576	38707	327	5957	52880	14204	83626	15008	490	2248	122653	14275
0.92	199	5462	37140	275	5716	53332	13342	64706	15001	218	2027	128194	16155
0.93	197	5094	34823	250	5276	51131	13163	55629	14970	431	2303	130043	14700
0.94	126	4357	30871	179	4728	43713	12416	63571	13690	325	2063	117903	16672
0.95	122	3734	28349	198	4596	40515	11381	67104	12856	371	1941	109077	15972
0.96	159	4423	31247	207	5185	44468	11800	69684	13179	305	2315	115678	15547
0.97	161	4563	31866	180	5643	49550	11637	61165	14070	459	1970	119684	13637
0.98	164	4043	29042	179	5178	43157	11279	54937	14294	514	2064	117776	13858
	253	5780	39332	309	5180	56567	12713	71728	14741	438	2130	120551	12325
	209	5349	36238	317	5894	58662	13931	91136	13690	373	1925	116293	15497
	204	4041	29923	345	3952	54234	14579	221105	7746	591	2053	71880	13280
	193	3804	29525	400	3811	56187	15380	277423	5691	391	2182	56968	13641
	181	3997	29652	300	4605	57922	13184	196166	8703	406	2051	80009	14793
	128	4541	31671	254	4888	49465	11952	104416	12731	356	1877	107268	14677
	131	4344	30274	221	4356	48099	11069	49518	15314	553	1814	126638	14928
	134	4538	32230	279	4091	47101	11426	37097	15854	567	1996	133136	13596
	133	5115	34671	204	4483	50486	11736	26425	17231	605	2170	141180	13779
	184	5538	36826	240	4070	47006	11966	23539	17517	572	1991	141522	14741
	140	4326	30803	535	3913	48780	12161	47859	14688	319	2205	135602	14391
	103	3499	24680	455	3214	37942	9780	34346	12912	374	2174	120348	14853
	146	3730	27416	261	3822	43465	10219	37638	14059	591	2075	126578	14453
	146	3891	28878	182	4665	47907	11319	54386	13505	447	1822	112559	14499
	105	2621	20184	158	3502	34253	8645	65015	9535	314	1542	80513	15286
	86	2423	19285	125	3260	31687	8965	58427	10018	389	1611	83331	15675
	123	4055	29956	277	4930	48296	12039	68391	13373	379	1914	109660	15791
	151	5336	36600	267	6196	58468	13426	88419	14200	283	2108	116367	15292
	176	4655	32365	206	5826	52010	12268	79254	12241	325	1935	104027	16076
	189	4741	33297	273	5760	53772	12809	78364	12588	328	1939	104821	14714
	187	4861	34378	266	6141	56123	12827	91409	12690	345	1912	106821	15079
	184	4692	33995	250	6263	58535	14052	145779	11169	418	2146	90196	14935
	186	4448	32713	268	5892	58795	14948	221322	7819	368	1842	68378	15171
	191	4802	33734	317	5980	62289	14319	176414	9814	390	2148	81511	13987
	141	3335	25515	190	5098	51510	11898	152549	8470	401	1770	69263	15427
	57	787	6384	70	1337	15225	3662	63163	2968	237	786	26135	13413
	185	4425	32485	240	6234	52159	12828	50480	14299	388	1706	113755	13764
	119	4569	32382	230	6021	50757	12743	59643	13847	426	1901	111877	16227
	182	4721	34302	208	7070	56439	12827	52774	13693	120	1590	109631	14214
	186	4713	33463	170	7777	63570	12357	53436	13366	293	1656	108306	14192
	178	4314	30649	201	8377	73686	11674	34406	13805	370	1687	112731	12616
	155	4624	31636	276	8319	69036	11762	44737	13486	426	2050	111653	14032
	178	4580	32883	171	6473	54931	12769	64456	13278	335	2174	111548	15070
	47	1828	14355	150	3146	20894	7626	86371	6900	262	1501	60435	14821
	110	3249	22891	144	3692	33133	9841	70685	10205	239	1660	84721	15234
	190	5421	36738	247	5521	52024	13949	101341	13597	564	2467	113803	15096
	220	5984	39842	254	5820	54304	14747	93932	14423	419	2384	120097	14556
	179	5649	38742	299	5972	54416	13559	84894	14882	486	2280	123303	14433
	154	5666	37891	220	5486	52598	13998	93648	14082	482	2271	118156	14885
	191	5579	37481	222	5082	48517	14113	94642	14100	546	2234	116368	13488
	116	4513	32157	226	4544	39859	13029	89856	13071	484	2035	106011	16379
	128	3681	27972	208	3892	35157	11698	82792	12165	488	2039	99425	14332
	114	4368	31952	277	4498	38997	12353	74941	13531	473	2024	111337	15236
	119	3723	27414	192	3643	27947	12001	91697	12151	417	2039	98741	15567
	156	5160	36743	273	4624	33068	14139	101875	13971	543	2124	115351	14335
	150	4612	32929	158	4161	29980	13150	89373	13202	393	2070	108731	14377
	83	2132	16715	160	2389	17335	7303	52723	8078	288	1237	66491	13653
	106	2866	22926	176	2873	22288	9885	67698	10555	475	1733	86314	13942
	63	1752	14826	72	1950	15574	6724	50702	7662	303	1312	68087	13343
	195	5418	37524	269	4314	34372	13581	92590	13826	342	2335	114156	14556
	170	5287	36417	264	4161	33133	12882	88147	13848	574	2195	115094	13485
	133	4240	30035	166	3236	27451	11013	73626	11992	467	1829	102170	13656
	92	3180	23146	222	2801	21991	9135	64794	10139	401	1643	84050	14099
	133	4671	33016	288	4097	32906	12107	84751	12659	493	2001	104805	14546
	166	4777	32759	235	4554	32381	12213	89205	11768	408	1993	100325	13882
	163	5184	35354	203	4668	37062	13132	87488	13108	391	2061	110284	14415
	165	5418	36995	278	5123	40842	14015	97972	13500	456	2140	112068	13398
	149	4984	35296	214	5186	36482	13851	91317	13628	208	2034	115030	16560
	139	5166	36759	191	5063	35783	13946	88017	14002	354	2270	116919	16377
	170	5243	35508	297	4996	36508	13984	92716	13574	600	2095	115015	17263
	83	3600	26771	247	3904	30305	11793	80570	12259	578	1885	100832	14772
	95	2726	22672	159	3153	25370	10193	70695	11286	327	1718	93095	14176
	101	3610	26569	103	3141	28773	10811	69141	12590	402	1878	104118	13735
	88	3392	25821	273	3112	27649	10570	69341	11717	327	1715	98304	15261
	74	2805	21888	140	2821	25050	9483	59004	11111	450	1701	92255	13395
	77	2335	18593	145	2586	23363	9166	62876	10310	371	1671	84466	13429
	64	1754	14229	122	2038	19018	7428	52920	8467	229	1603	72358	14013
	80	1245	11209	157	1642	15710	6355	45745	7166	194	981	61618	12885
	82	1815	15231	125	1922	19571	7740	60277	8705	233	1375	71956	13899
	102	3946	29057	192	3268	29879	11976	76363	12523	414	1994	103942	16455
	164	5291	36848	262	4079	40349	13300	82972	14317	444	2310	119165	15937
	181	5270	36944	206	4190	39124	13900	105609	13551	617	2193	112322	15588
	137	4781	33405	178	4483	38684	12656	87291	12856	218	2110	110403	15507
	166	4949	34672	232	4862	41274	13028	91676	12986	366	2049	110468	14833
	153	5149	35598	192	4880	41559	13552	90836	13686	435	2275	112541	15244
	182	5362	36568	259	4968	43703	13590	83422	14180	269	1995	117239	14255
	191	5928	40132	298	5316	47286	14406	95973	14681	500	2166	120066	15790
	222	6169	41956	318	4978	47675	14533	96796	14774	410	2333	122418	16301
	213	5608	37132	226	4320	44404	12897	74214	14009	453	2156	113846	13866
	123	2269	18916	113	3598	29362	9610	54177	8972	477	1767	87663	13610
	184	5539	37758	235	5718	48022	13403	73314	13508	530	1967	112287	12826
	174	5152	35135	192	5805	47945	12443	67788	13706	475	1994	114464	14876
	107	3607	26376	226	4640	39330	10930	68189	11933	414	1815	100513	15489
	74	2066	17030	98	3271	27320	8090	55051	8880	341	1565	75244	13768
	106	3414	25895	167	4817	38266	11279	76823	11439	274	1829	93917	13829
	249	5545	37032	202	6361	49864	14029	89715	13868	493	2197	112545	13643
	274	6772	43899	277	7004	53669	14929	95132	14257	484	2177	117499	13282
	99	4809	32992	304	5613	44084	12603	80903	12793	399	1991	105632	15711
	123	4110	29709	172	5642	44505	12625	97163	11799	340	2025	97563	15147
	182	5320	36824	250	6559	53598	14314	90951	13419	414	2213	112106	14458
	129	4069	29503	194	5454	43950	12764	97223	11713	396	1904	98040	14825
	153	4167	30376	190	5561	43978	12871	100338	11976	420	1733	97012	14721
	138	4923	34140	272	6526	49786	13719	93506	13385	364	2172	108935	15588
	136	3974	29401	219	5737	44497	12539	107405	11047	436	2040	94196	14164
	93	3215	22727	173	4732	36931	10296	67015	10589	320	1832	89710	13560
	80	1812	14716	123	3974	25012	7735	49293	8516	301	1337	73492	13661
	85	3649	27276	219	4842	40550	12054	84012	11281	314	1760	93932	15697
	212	5919	40148	269	7025	57985	15017	94291	13926	332	2167	114802	13168
	207	6495	42729	327	7220	57749	15522	96960	13836	398	2141	115798	15328
	182	6218	41380	264	7209	58239	15271	99180	13372	429	2194	112635	14974
	183	5552	38317	189	7238	53368	14738	87149	13888	460	2202	113336	15343
	153	4140	29144	262	5453	43316	13135	74405	13754	425	2079	109150	14256
	111	3121	23257	227	4416	35627	11434	50177	13611	194	1785	104253	13509
	115	2870	20804	132	3910	32592	10870	42667	13049	279	1853	102374	13293
	120	3081	22054	184	4102	34407	11413	40741	14186	417	2197	111455	13598
	103	2556	18804	173	3869	32074	9442	62087	10687	374	1655	86538	13626