Citation:

PANGAEA.959863

Name: X-ray fluorescence (XRF) data of sediment core GeoB24351-1, 30 kV run
Published: 2023-06-27
License: https://creativecommons.org/licenses/by/4.0/
Keywords: Gelendzhik MV; Mediterranean Ridge accretionary complex; mud volcano; Olimpi mud volcano field; R/V SONNE; SO278; XRF core scanner

Always quote citation above when using data! You can download the citation in several formats below.

Published: 2023-06-27 • DOI registered: 2023-07-26

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Abstract:

X-Ray fluorescence (XRF) scans were carried out for core GeoB24351-1 (Gelendzhik MV; 0-284 cm) in 10 mm steps downcore on the split core surface of the archive half with the XRF Core Scanner III (AVAATECH Serial No. 12) at MARUM – Center for Marine Environmental Sciences in Bremen. To avoid contamination of the XRF measurement unit and the desiccation of the sediment, the split core was covered with a 4 µm thin SPEXCerti Ultralene1 foil. Reported data was acquired with a SGX Sensortech Silicon drift detector (Modul S SiriusD®D65133Be-INF with 133 eV X-ray resolution), a Topaz-X High-Resolution Digital MCA, and an Oxford Instruments 100 W Neptune X-Ray tube with rhodium (Rh) target material. Data were obtained during three runs at 50 kV (1st run), 30 kV (2nd run) and 10 kV (3rd run). Processing of raw data took place by the analysis of X-ray spectra by an iterative least square software package from Canberra Eurisys (WIN AXIL).

Keyword(s):

Gelendzhik MV; Mediterranean Ridge accretionary complex; mud volcano; Olimpi mud volcano field; R/V SONNE; SO278; XRF core scanner

Related to:

Behrendt, Nele; Menapace, Walter; Bohrmann, Gerhard; Zabel, Matthias; Kopf, Achim J (2023): Pore water signatures and gas hydrates occurrence in and around the Olimpi mud volcano field, south of Crete. Marine and Petroleum Geology, 156, 106429, https://doi.org/10.1016/j.marpetgeo.2023.106429

Further details:

Bohrmann, Gerhard; Ahrlich, Frauke; Antoniou, Dimitra; Behrendt, Nele; Innocentini, Simone; Coulibaly, Ousmane; Eijsink, Agathe; Feddersen, Greta; Gaide, Stefanie; Kaul, Norbert; König, Tabea; Krahl, Julia; Kürzinger, Victoria; Lenius, Sven; Malnati, Janice; Marschall, Lara; Niederbockstruck, Bryan; Porrmann, Simon; Rau, Svenja; Römer, Miriam; Schillai, Sophia; Spiesecke, Ulli; Streuff, Katharina Teresa; Tseng, Yiting; Vejzovic, Ines; von Wahl, Till; Warnken, Niklas; Witzleb, Antonia (2021): Fluid-rock interaction at the backstop to the Mediterranean Ridge Accretionary Complex South of Crete, Cruise Report SO278, 12 October - 01 December 2020, Emden (Germany) - Emden (Germany). SONNE-Berichte, Gutachterpanel Forschungsschiffe, SO278, 208 pp, https://doi.org/10.48433/cr_so278

Project(s):

Center for Marine Environmental Sciences (MARUM)

The Ocean Floor - Earth's Uncharted Interface (ClusterOceanFloor)

Funding:

German Research Foundation (DFG), grant/award no. 390741603 : EXC 2077: The Ocean Floor – Earth's Uncharted Interface

Coverage:

Latitude: 33.903020 * Longitude: 24.269020

Date/Time Start: 2020-11-13T05:36:09 * Date/Time End: 2020-11-13T05:36:09

Minimum DEPTH, sediment/rock: 0.02 m * Maximum DEPTH, sediment/rock: 0.98 m

Event(s):

SO278_51-1 (GeoB24351-1) * Latitude: 33.903020 * Longitude: 24.269020 * Date/Time: 2020-11-13T05:36:09 * Elevation: -1695.6 m * Location: Mediterranean Sea * Campaign: (GPF 19-2-007H) * Basis: * Method/Device: Gravity corer (GC)

Comment:

Scanner: AVAATECH (Serial No. 12)

X-ray tube: Oxford Instruments 100W Neptune Rh X-ray tube

X-ray detector: SiriusSD D65133BE-INF

Step size: 10 mm

Slit down-core: 10 mm

Slit cross-core: 12 mm

X-ray tube settings: 1st run: 50 kV; 0.5 mA; 8 sec. Cu filter

2nd run: 30 kV; 0.6 mA; 8 sec. Pd thick filter

3rd run: 10 kV; 0.05 mA; 8 sec. no filter

Processing model: 1st run: 50 kV; Averaged dead time: 29%

2nd run: 30 kV; Averaged dead time: 27%

3rd run: 10 kV; Averaged dead time: 27%

Data quality check of processed data at MARUM XRF Core Scanner Lab:

Data from listed elements are reliable for scientific publication:

1st run: Ba*, (Sr, Zr, Rb, Br)**

2nd run: Br, Sr, Zr, Rb

3rd run: Al, Si, S, K, ca, Ti, Mn, Fe

Data from listed elements are NOT reliable for scientific publication:

1st run: Mo, Ag, Sn, Te

2nd run: Ni, Cu, Zn, Ga, (Nb, Mo, Pb)***, Bi

3rd run: P, Cl, Rh, Cr, Mg

Notes (scatter & escape peaks, elements below detection limit, etc.):

Sediment surfaces are very poor and not really suitable for XRF scanning (all:

uneven/bumpy surfaces, x to y cm pebbles, holes, and cracks). Therefore highly

recommended to (only) work with elemental ratios from the acquired datasets.

Please also note: Ba*: small peaks only, general low total counts; (Sr,Rb,Zr,Br)**: better in

30 kV run; (Nb, Mo, Pb)***: please validate the higher peaks standing out from a different

chemical method

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	DEPTH, sediment/rock	Depth sed	m	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]	Geocode
2	Nickel	Ni	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
3	Copper	Cu	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
4	Zinc	Zn	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
5	Gallium	Ga	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
6	Bromine	Br	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
7	Rubidium	Rb	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
8	Strontium	Sr	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
9	Zirconium	Zr	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
10	Niobium	Nb	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
11	Molybdenum	Mo	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
12	Ruthenium	Ru	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
13	Rhodium	Rh	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
14	Lead	Pb	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]
15	Bismuth	Bi	cps	Behrendt, Nele	X-ray fluorescence (XRF), AVAATECH, Serial No. 12 [III Bremen]

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

2744 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Depth sed [m]	2 Ni [cps]	3 Cu [cps]	4 Zn [cps]	5 Ga [cps]	6 Br [cps]	7 Rb [cps]	8 Sr [cps]	9 Zr [cps]	10 Nb [cps]	11 Mo [cps]	12 Ru [cps]	13 Rh [cps]	14 Pb [cps]	15 Bi [cps]
0.02	2722	242	720	162	905	1872	15732	9052	1408	328	19429	16547	202	24
0.03	2833	228	773	208	853	1814	15769	10381	1586	316	18712	16403	249	35
0.04	2893	235	767	182	863	1941	19058	10234	1258	188	18822	16496	254	24
0.05	2915	328	744	186	840	1856	18924	9670	1552	88	17653	16550	248	34
0.06	2683	231	578	160	831	1393	17491	6966	1389	446	14285	13672	175	28
0.11	2977	259	707	156	815	1727	13609	9217	1269	172	18109	17609	186	46
0.12	2882	214	630	161	758	1631	15633	8893	1261	261	18106	17498	213	62
0.13	2730	231	596	159	629	1693	19712	8529	1223	333	17264	17398	221	38
0.14	2860	213	630	210	776	1718	24194	9544	1447	352	18126	17780	184	27
0.15	3064	287	689	183	747	1708	17898	9290	1013	430	17656	17588	189	34
0.16	2884	210	641	156	742	1892	17283	8733	1392	418	17407	17254	211	20
0.17	2807	292	686	164	788	1790	19046	8428	1192	129	18159	17970	190	40
0.18	2827	298	742	162	608	1750	18226	8797	1013	159	17949	17440	182	31
0.19	2855	266	660	177	838	1839	19600	8961	1125	102	17492	17281	202	37
0.20	2754	285	694	174	686	1950	17703	9036	1195	210	17773	17614	181	19
0.21	2881	277	682	167	663	1769	17300	9344	1335	388	17456	18216	195	51
0.22	2845	264	721	173	692	1750	18252	9123	1124	219	17158	17716	170	34
0.23	2842	244	623	171	713	1671	20514	8464	1107	194	17688	17644	157	15
0.24	2788	232	558	158	693	1743	34804	8569	1319	279	17708	17008	168	35
0.25	2882	286	717	162	648	1692	32226	8435	1238	84	17499	16951	169	42
0.26	2889	288	648	141	655	1735	30036	8199	1076	278	16621	17142	217	34
0.27	2878	219	587	159	758	1707	28016	8835	1152	331	17450	16721	207	26
0.28	2903	250	596	149	654	1692	25381	8794	1313	401	17895	16893	169	20
0.29	2849	271	678	142	730	1702	28277	8567	1475	209	18078	17704	227	37
0.30	2879	246	722	195	646	1864	26139	9251	1021	371	17565	16835	196	45
0.31	3048	256	658	161	710	1808	31973	8293	1054	335	17828	16495	194	40
0.32	2927	275	581	143	717	1815	25573	8838	1383	181	17043	17255	208	31
0.33	2860	254	608	122	737	1790	23238	9125	1281	305	18033	17930	208	46
0.34	3078	309	758	213	698	1759	15502	10024	1300	314	17244	17676	195	49
0.35	2954	263	778	196	686	1754	12491	9519	1476	285	18291	17783	193	41
0.36	2867	239	656	165	665	1746	13549	9325	1207	346	17324	17645	187	33
0.37	2793	192	646	175	828	1541	15162	8922	1423	577	18452	16491	207	62
0.38	2858	265	690	150	801	1518	14309	8279	1527	346	18213	16300	160	28
0.39	2899	245	632	183	757	1598	17111	8056	887	155	18384	16556	172	26
0.40	2815	183	631	148	596	1437	18551	7930	1148	496	17028	15825	197	30
0.41	2866	221	638	138	620	1565	23685	8825	1269	193	17152	16673	169	42
0.42	2906	241	656	214	635	1730	20135	9180	1374	271	17466	16953	245	28
0.43	2828	267	648	220	654	1801	21849	9831	1174	207	16829	16937	169	32
0.44	2844	264	695	149	563	1616	27095	8443	1118	181	16262	16281	199	70
0.45	2775	252	639	152	637	1644	33086	6681	1077	448	16440	15762	191	11
0.46	2876	231	718	141	693	1776	32244	8199	1476	172	17614	16660	215	61
0.47	2884	297	726	202	651	1721	22821	8701	1493	315	17025	15939	206	31
0.48	2856	282	666	174	626	1729	21244	7842	1336	385	16959	16060	183	43
0.49	2813	270	797	168	807	1757	17824	9294	1228	268	18259	17131	214	44
0.50	2896	238	784	151	786	1789	12877	9197	1397	406	18717	16666	238	42
0.51	2832	254	837	207	739	1805	12219	10146	1501	382	17722	16955	208	43
0.52	2858	276	762	172	751	1587	24730	9143	1280	419	17426	17565	201	28
0.53	2873	269	710	151	696	1731	26774	9873	1614	378	16577	17285	234	40
0.54	2902	202	740	214	614	1779	32415	9428	1641	180	16086	17359	229	16
0.55	2835	231	655	130	651	1703	15269	9660	1403	198	16681	17117	249	44
0.56	2768	259	690	159	509	1801	13729	10032	1340	201	16283	17012	151	32
0.57	2850	272	717	134	611	1787	14078	8588	1212	246	16796	16840	207	17
0.58	2749	286	744	182	588	1628	12954	9226	1305	162	16116	16068	214	68
0.59	2767	221	705	127	631	1573	12212	8608	1400	137	16930	15478	193	42
0.60	2709	223	565	145	612	1375	11836	7068	1152	106	16026	15355	174	37
0.61	2592	226	594	116	687	1355	12828	7495	1224	172	15994	14832	166	41
0.62	2773	258	675	178	819	1561	13808	7613	1298	277	18632	16131	198	34
0.63	2814	219	596	151	856	1572	21942	7721	1153	53	17361	16491	175	34
0.64	2810	249	683	172	825	1509	16342	8945	1299	40	18752	16861	184	32
0.65	2756	275	691	183	705	1564	16323	9830	1434	273	17392	16441	180	33
0.66	2763	221	715	182	869	1644	18268	9475	1430	193	19488	16555	195	36
0.67	2574	194	577	157	830	1356	17680	8108	1159	410	17906	17376	151	23
0.68	2860	286	739	196	905	1738	16395	9200	1255	67	19393	17439	229	18
0.69	2843	191	685	201	869	1554	18957	9052	1495	126	18313	16677	210	35
0.70	2860	252	705	176	878	1750	19742	10207	1374	378	18311	17361	186	36
0.71	2942	291	784	129	912	1659	16795	9889	1476	398	18700	17931	196	42
0.72	2962	306	695	175	943	1869	15813	9725	1283	229	18238	17954	212	67
0.73	2857	268	739	183	842	1772	13705	9874	1620	292	18006	17380	212	40
0.77	2655	295	653	172	503	1684	16302	10878	1347	284	15701	16382	205	52
0.78	2874	275	710	157	444	2025	10636	10120	1564	228	16149	16284	167	23
0.79	3116	272	566	131	530	1842	12527	8976	1356	193	16195	16269	186	34
0.80	3001	261	733	194	555	1582	20280	14556	1629	386	16181	15985	223	30
0.81	2738	221	673	157	563	1689	19266	9913	1382	141	16230	16693	214	25
0.82	2911	263	676	185	640	1682	19093	8720	1269	168	16004	16293	186	50
0.83	2824	262	731	168	574	1866	15238	9164	1531	166	16703	16536	229	42
0.84	2929	262	727	157	579	1779	13344	9738	1359	303	16602	16446	200	31
0.85	2919	235	778	171	580	1926	11456	11373	1606	378	16079	16113	218	46
0.86	2890	254	2745	210	611	1774	11409	11369	1724	-74	17034	17212	231	54
0.87	2763	268	725	158	558	1767	13318	10457	1409	155	16656	16472	255	36
0.88	2857	269	734	159	618	1807	14036	9727	1178	273	16148	17185	231	35
0.89	2824	324	712	172	571	1687	15195	9729	1355	170	15897	17607	215	22
0.91	2889	249	701	167	647	1995	14958	10047	1296	220	16202	17587	230	60
0.92	3002	263	721	159	563	2036	11580	11773	1721	270	16450	17399	224	62
0.93	2786	253	789	214	597	2001	11063	11043	1623	446	15891	16993	252	75
0.94	2814	270	797	196	547	1755	12042	9799	1460	156	15431	15997	195	41
0.95	2676	279	671	123	530	1622	12976	8567	1368	160	15709	15411	178	32
0.96	2849	292	678	175	532	1794	12548	9063	1286	303	16672	16755	228	46
0.97	2865	314	735	149	564	1811	12203	9743	1400	220	16154	16183	248	47
0.98	2784	282	777	166	535	1777	10509	9216	1341	261	15663	15570	217	41
	2884	313	712	166	632	1727	12315	9802	1510	233	16621	17236	223	32
	3091	324	671	156	687	1837	12010	10150	1302	425	15309	17396	280	39
	2762	243	488	134	473	1807	26725	4057	854	242	13878	16651	160	49
	2715	229	462	97	474	1806	29508	3441	562	139	14079	17531	179	20
	2651	232	578	163	489	1775	24668	5821	837	139	14080	16784	169	56
	2724	277	674	148	499	1677	19386	8437	1094	310	14895	16132	176	38
	2787	278	715	206	622	1824	10053	10393	1671	292	16072	15894	209	41
	2687	263	710	190	724	1790	9034	10161	1493	77	15671	15345	266	54
	2744	260	735	157	701	1827	8327	11372	1522	146	16035	16205	249	72
	2706	289	775	187	641	1798	7693	12123	1706	217	16671	15868	246	56
	2688	244	711	178	673	1707	8880	11456	1767	274	15378	15570	233	45
	2528	169	691	184	576	1581	10327	8436	1189	103	13319	14065	169	50
	2586	269	651	209	552	1637	9147	9064	1246	29	14340	14941	174	25
	2789	283	692	208	587	1600	9977	9122	1090	214	14778	15891	174	47
	2598	190	577	128	558	1478	10180	7759	1132	91	12618	14282	156	26
	2459	223	618	155	545	1462	11191	6758	994	153	11672	13575	179	58
	2771	225	720	168	625	1682	11022	8658	1292	109	13977	15673	231	35
	2896	277	723	182	666	1859	12329	9642	1371	235	15802	17014	227	25
	2678	234	662	151	703	1667	12811	8266	1116	279	15449	15761	186	29
	2768	272	680	182	718	1722	12466	8322	1371	328	15326	15886	199	57
	2806	223	653	161	595	1634	14742	9340	1344	197	15190	16107	171	29
	2667	219	545	114	536	1680	16618	7732	864	186	15392	16700	207	29
	2620	249	447	161	470	1498	21438	5558	749	371	13847	17467	171	24
	2655	244	561	105	547	1549	18708	6787	1015	194	14102	16944	181	36
	2528	231	436	100	488	1440	16792	5459	930	203	13812	15105	169	19
	2058	138	232	60	293	839	8518	2926	502	156	7508	9821	96	17
	2718	248	692	203	804	1749	10592	9166	1342	12	16189	15501	183	39
	2755	238	695	172	703	1657	12784	8898	1262	39	16040	15779	207	42
	2845	285	709	158	853	1698	11692	8819	1296	354	17373	16812	204	28
	2897	327	767	156	867	1656	12218	9603	1386	201	17078	16923	220	32
	2721	234	799	135	928	1722	8991	11204	1608	306	17631	17333	227	46
	2848	234	779	158	828	1757	13104	9563	1274	168	16840	17523	204	40
	2902	282	747	197	720	1705	13467	8969	1183	280	15153	16525	246	29
	2420	221	468	110	357	1211	15668	4747	682	397	9945	13045	173	8
	2681	274	524	121	485	1439	13183	6646	995	418	12025	14276	196	36
	2919	322	787	146	643	1820	15783	8922	1399	574	15014	16378	239	35
	2853	316	740	162	606	1942	16097	9120	1445	252	15020	16989	247	30
	2829	286	897	195	576	1914	16535	9160	1272	132	15028	16875	204	44
	2786	280	695	177	620	2004	16111	9469	1232	245	15302	16928	254	42
	2822	330	739	157	610	1762	16033	9127	1305	228	15577	17341	216	24
	2801	295	657	138	573	1727	18281	7371	1031	354	13913	16116	203	60
	2667	209	648	133	544	1580	15707	7755	1187	295	13966	14643	200	57
	2734	301	710	193	591	1642	13589	8922	1320	381	15556	15230	204	51
	2464	235	587	158	555	1407	10659	7253	950	169	13000	13529	167	42
	2512	229	613	127	407	1593	14823	7538	1388	142	13533	14450	212	34
	2922	283	713	183	445	1878	14792	8828	1326	84	15871	16070	208	44
	2614	231	658	183	472	1794	14619	8026	1224	322	14967	15936	218	35
	2362	213	506	108	310	1254	9918	5660	883	295	10189	11981	147	15
	2573	253	592	158	359	1235	12539	6128	1023	169	13695	13923	179	17
	2399	185	458	114	354	1154	10305	5336	987	252	11560	12894	155	35
	2827	270	687	174	583	1713	15026	8852	1236	134	15696	16755	215	36
	2843	268	756	160	522	1728	14660	9009	1483	370	15616	16369	206	33
	2706	228	683	146	428	1648	13266	7478	1390	203	15800	15642	196	40
	2644	242	567	164	420	1378	12764	6863	1052	169	13742	14732	187	30
	2764	287	648	153	465	1695	14882	7894	1034	117	15595	15874	190	26
	2635	228	640	153	430	1606	14491	8057	986	81	15454	16000	212	17
	2677	263	709	220	383	1819	15451	8528	1355	454	15784	16741	190	53
	2805	269	614	177	492	1784	17652	8295	912	67	15438	16348	211	29
	2904	282	732	164	489	1735	16096	8632	1226	369	14952	16553	234	32
	2871	259	725	118	486	1843	16354	8948	1223	324	14575	16512	201	26
	2886	301	771	169	538	1819	16306	8745	1442	266	14938	16504	202	44
	2733	232	619	123	423	1628	14148	7390	1269	166	14815	15351	209	35
	2554	275	601	160	391	1583	12924	7212	1092	286	13651	14946	206	32
	2601	244	639	150	441	1674	12595	8318	1397	119	13710	14574	224	33
	2623	268	678	140	432	1613	12864	7387	1163	112	13333	14398	188	31
	2521	238	583	129	449	1440	11810	7231	1288	530	12545	13515	178	34
	2510	237	547	119	427	1265	11758	5933	1056	251	11987	13016	162	20
	2425	189	456	114	329	1073	9800	5361	1010	168	10329	12075	142	17
	2267	168	439	67	352	961	8252	4165	1054	159	9616	11331	117	22
	2381	224	467	108	334	1141	10340	5249	1091	327	10117	11867	146	41
	2713	266	711	177	539	1490	13145	7345	1330	334	14316	15005	231	57
	2964	253	783	123	549	1886	14387	9317	1280	164	15135	16228	190	48
	2842	272	736	187	509	1839	17425	8358	948	270	15589	16117	238	30
	2819	267	655	160	490	1837	14816	8657	1324	330	15892	16410	177	43
	2686	250	656	182	578	1675	15577	8854	1489	457	15676	16483	290	38
	2792	323	691	153	574	1863	15169	9015	1395	292	15887	16444	237	28
	2791	324	718	175	476	1998	14574	9458	1473	244	15681	16962	226	25
	2846	353	797	175	599	1980	15993	9469	1179	291	15611	17342	209	34
	2908	332	774	226	592	1985	15992	9612	1423	350	15245	17530	253	50
	2766	235	671	183	554	1912	13672	9566	1451	46	15376	16813	220	37
	2574	216	501	118	461	1224	8778	6171	1127	146	11507	13411	153	44
	2855	255	674	159	568	1791	12551	9217	1335	328	15646	16265	233	39
	2766	311	714	161	552	1751	12495	9271	1314	220	15074	15759	205	36
	2599	238	658	163	563	1561	11357	7405	1252	101	14457	14928	138	27
	2522	228	460	128	432	1317	10399	5865	1057	600	11801	13183	175	23
	2642	229	623	154	587	1476	11919	7494	1224	120	13154	14761	197	51
	2886	359	703	230	582	1797	13503	8635	1293	434	15387	16071	232	39
	2810	320	744	174	569	1783	15090	9320	1274	398	15417	17330	253	29
	2719	281	605	142	672	1672	13125	8721	1315	196	14344	15723	246	43
	2758	314	608	184	547	1604	15562	7559	1102	437	13629	15259	206	34
	2797	275	668	175	611	1726	14376	8259	1383	199	15214	16677	193	30
	2680	273	622	159	603	1649	14402	7119	1251	235	13895	15207	196	17
	2696	265	789	132	563	1711	15442	7309	1432	191	13276	15481	214	32
	2688	262	666	144	684	1771	13943	8182	1470	249	14450	15573	207	33
	2694	234	548	161	471	1535	17333	6141	1089	295	13872	15135	179	37
	2658	229	554	127	474	1561	10218	6956	1321	257	13101	14147	191	44
	2392	230	460	111	420	1088	8278	5287	974	110	10435	12327	173	19
	2625	262	635	120	620	1619	14390	6717	1208	133	13145	14586	191	52
	2868	294	684	165	640	1906	15162	9204	1457	256	15191	16722	243	23
	2828	260	668	157	649	1860	15009	9007	1170	193	14691	17146	211	58
	2727	292	642	145	672	1919	13900	8456	1183	389	14841	16467	210	43
	2803	299	718	113	673	1888	12344	8812	1218	320	14978	16375	224	57
	2739	283	607	115	546	1715	14215	7872	1461	454	14224	14718	232	27
	2675	250	647	157	433	1616	10341	8112	1370	149	12615	14011	201	49
	2497	221	504	124	402	1425	10085	7902	1127	77	11436	13632	168	28
	2335	216	519	130	441	1481	10376	8793	1557	733	12413	14055	170	38
	2408	227	444	89	489	1346	10732	6933	1275	220	11109	13249	172	52