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Saito, Ryosuke; Wörmer, Lars; Taubner, Heidi; Kaiho, Kunio; Takahashi, Satoshi; Tian, Li; Ikeda, Masayuki; Summons, Roger E; Hinrichs, Kai-Uwe (2022): MSI-based polycyclic and heterocyclic aromatic hydrocarbons (PAHs and C2-DBF) in the uppermost Permian Changxing Fm. in the Meishan C section [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.952280, In: Saito, R et al. (2022): An expanded record of proxy data in the uppermost Permian Changxing Fm. in the Meishan C section [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.952297

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Published: 2022-12-14DOI registered: 2023-03-31

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Abstract:
A 7T solariX XR Fourier transform-ion cyclotron resonance-mass spectrometer (FT-ICR-MS) equipped with a Smartbeam II laser (Bruker Daltonik, Bremen, Germany) was used for MSI analysis. Analyses were carried out in positive ion mode in a range of 150-750 Da. A defined area of the sample was scanned by the laser with a distance of 100 µm between spots. Laser power, frequency and number of shots per spot were adjusted for optimal signal intensities. PAHs and C2-DBF were identified based on their monoisotopic mass. Internal mass calibrated results were exported from DataAnalysis 4.4. SR1 (Bruker Daltonik) and further processed in MATLAB R2015b using a DataAnalysis Script File.
Keyword(s):
dibenzofuran; end-Permian mass extinction; FTICR-MS; Mass spectrometry imaging; Meishan; PAHs
Funding:
European Research Council (ERC), grant/award no. 670115: Zooming into paleoenvironmental and biogeochemical processes through molecular imaging of biomarker distributions in sediments
Japan Science and Technology Agency (JST), grant/award no. JPMJPR19G5: JST PRESTO
Japan Society for the Promotion of Science (JSPS), grant/award no. 25247084
Simons Foundation, grant/award no. 290361FY18: Simons Foundation Collaboration on the Origins of Life
Coverage:
Latitude: 31.076872 * Longitude: 119.698000
Date/Time Start: 2009-03-25T02:00:00 * Date/Time End: 2009-03-25T02:00:00
Minimum Elevation: 87.0 m * Maximum Elevation: 87.0 m
Event(s):
Changxing_formation * Latitude: 31.076872 * Longitude: 119.698000 * Date/Time: 2009-03-25T02:00:00 * Elevation: 87.0 m * Location: Meishan, Zhejiang Province, South China * Method/Device: Hammer (HAM) * Comment: Changxing formation in the Meishan C Section
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1DistanceDistmmSaito, RyosukeDepth, base of Bed 25 (0 mm)
27-ring polycyclic aromatic hydrocarbon, normalized to its maximum value7-ring PAHSaito, RyosukeUltra-high resolution mass spectrometry imaging (MSI)
36-ring polycyclic aromatic hydrocarbon, normalized to its maximum value6-ring PAHSaito, RyosukeUltra-high resolution mass spectrometry imaging (MSI)
45-ring polycyclic aromatic hydrocarbon, normalized to its maximum value5-ring PAHSaito, RyosukeUltra-high resolution mass spectrometry imaging (MSI)
54-ring polycyclic aromatic hydrocarbon, normalized to its maximum value4-ring PAHSaito, RyosukeUltra-high resolution mass spectrometry imaging (MSI)
6C2-dibenzofuran, normalized to its maximum valueC2-DBFSaito, RyosukeUltra-high resolution mass spectrometry imaging (MSI)
77-ring PAH/5-ring PAH ratioPAH 7/5Saito, RyosukeUltra-high resolution mass spectrometry imaging (MSI)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
13562 data points

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