Not logged in
PANGAEA.
Data Publisher for Earth & Environmental Science

Brünjes, Jonas; Schubotz, Florence (2022): Calculated intensity-weighted parameters and relative assignments to compound groups of FT-MS measurements of DOM for each sample from sediment core GeoB 19339-1 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.946418, In: Brünjes, J; Schubotz, F (2022): Chapopote asphalt volcano (GOM): asphalt dissolved organic matter released in mesocosm experiments (M114/2, GeoB 19339-1) [dataset publication series]. PANGAEA, https://doi.org/10.1594/PANGAEA.946420

Always quote citation above when using data! You can download the citation in several formats below.

Published: 2022-07-18 • DOI registered: 2022-10-06

RIS CitationBibTeX Citation ShareShow MapGoogle Earth

Keyword(s):
black carbon; Deep sea; Dissolved Organic Matter; dissolved organic sulfur; FT-ICR MS; mesocosm; Oil seeps; PARAFAC
Project(s):
Center for Marine Environmental Sciences (MARUM)
Funding:
German Research Foundation (DFG), grant/award no. 390741603: EXC 2077: The Ocean Floor – Earth's Uncharted Interface
Coverage:
Latitude: 21.899183 * Longitude: -93.436833
Date/Time Start: 2015-03-16T11:23:00 * Date/Time End: 2015-03-16T11:23:00
Minimum Elevation: -2905.0 m * Maximum Elevation: -2905.0 m
Event(s):
GeoB19339-1 (M114/2_96-1) * Latitude: 21.899183 * Longitude: -93.436833 * Date/Time: 2015-03-16T11:23:00 * Elevation: -2905.0 m * Location: Gulf of Mexico * Campaign: M114/2 * Basis: Meteor (1986) * Method/Device: Gravity corer (GC) * Comment: Recovery of piece of asphalt and sediment
Comment:
Based on molecular formulae assigned to ESI-FT-ICR-MS peaks (Electrospray ionization Fourier-transform ion cyclotron resonance mass spectrometry).
Compound group assignments after Seidel et al. 2014; https://doi.org/10.1016/j.gca.2014.05.038
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1 Sample IDSample IDBrünjes, Jonas
2 Unified atomic massUAMuBrünjes, JonasFTMS peak intensity-weighted mean
3 Polycondensed aromaticsPCA%Brünjes, JonasCalculated, see Comment% relative to all molecular formulae, polycondensed aromatics, Aimod >0.66)
4 AromaticsAromatics%Brünjes, JonasCalculated, see Comment% relative to all molecular formulae, polycondensed aromatics, 0.5 < Aimod >0. 66
5 AromaticsAromatics%Brünjes, JonasCalculated, see CommentHighly unsaturated (% relative to all molecular formulae, Aimod < 0.5, H/C < 1.5, O/C < 0.9)
6 Aliphatic hydrocarbonsAHC%Brünjes, JonasCalculated, see CommentUnsaturated aliphatics (% relative to all molecular formulae, 1.5 < H/C <2, P/C < 0.9, N = 0)
7 Hydrogen/Carbon ratioH/CBrünjes, JonasCalculated, see CommentFTMS peak intensity-weighted mean H/C ratio
8 Oxygen/Carbon ratioO/CBrünjes, JonasCalculated, see CommentFTMS peak intensity-weighted mean O/C ratio
9 Peak intensityPeak intBrünjes, JonasCalculated, see Comment
10 Peak intensityPeak intBrünjes, JonasCalculated, see Comment
11 CarbohydratesCHO%Brünjes, JonasCalculated, see Comment% relative to all molecular formulae, molecular formulae containing only CHO
12 NitrogenN%Brünjes, JonasCalculated, see Comment% relative to all molecular formulae, molecular formulae containing Nitrogen
13 SulfurS%Brünjes, JonasCalculated, see Comment% relative to all molecular formulae, molecular formulae containing Sulfur
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
156 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 
Sample ID		2 
UAM [u]
(FTMS peak intensity-weighted ...)		3 
PCA [%]
(% relative to all molecular f...)		4 
Aromatics [%]
(% relative to all molecular f...)		5 
Aromatics [%]
(Highly unsaturated (% relativ...)		6 
AHC [%]
(Unsaturated aliphatics (% rel...)		7 
H/C
(FTMS peak intensity-weighted ...)		8 
O/C
(FTMS peak intensity-weighted ...)		9 
Peak int		10 
Peak int		11 
CHO [%]
(% relative to all molecular f...)		12 
N [%]
(% relative to all molecular f...)		13 
S [%]
(% relative to all molecular f...)
ns1t0311.76106231.6457872769.89928764436.9196757626.308032421.5273695430.2820835220027.1923360434.58609678038.98305085
ns2t0290.15165591.68800931311.29220023043.1606519230.616996511.4845413470.2788943660030.2968568123.63213038046.65308498
ns3t0295.16220612.05375253512.37322515046.0699797228.600405681.4679745430.2828022310028.0172413825.12677485049.97464503
ns1t1257.87456203.41374601718.79836140042.9221665926.900318621.3773353770.2840957370035.0022758312.47155212052.25307237
ns2t1264.16898253.70370370420.38800705045.9964726622.116402121.3598670060.2931551540029.5238095222.18694885054.85008818
ns3t1268.96410884.02877697820.71942446046.9424460423.129496401.3513783110.2931110830030.8633093516.54676259057.05035971
ns1t2245.72420575.88235294123.44714109045.0843274422.418757711.3278021830.2910680290030.851501448.26820238661.99095023
ns2t2256.22331917.07517372124.51042325046.5571699318.919772581.3006955860.2862674340026.0897031021.69930512062.19204043
ns3t2249.94630656.26398210325.16778523045.4138702520.395227441.3441319880.2868196550030.0521998513.38553318062.08053691
nsdeadt0297.09944231.87330539812.07789007047.6706926328.099580971.4489290210.2856392950031.8215430125.33892038044.83608578
nsdeadt1284.45437691.26459144010.40856031042.2665369636.673151751.4900995380.2566507790037.9377431912.45136187049.36770428
nsdeadt3263.61674211.60618679411.83819155045.9250446237.239738251.5206409380.1755499670037.537180256.30577037553.36109459