/* DATA DESCRIPTION: Citation: Brünjes, Jonas; Schubotz, Florence (2022): Relative abundances of PARAFAC components, 2D FDOM indices and other bulk, quantitative parameters determined on water sample from sediment core GeoB 19339-1 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.946417, In: Brünjes, J; Schubotz, F (2022): Chapopote asphalt volcano (GOM): asphalt dissolved organic matter released in mesocosm experiments (M114/2, GeoB 19339-1) [dataset publication series]. PANGAEA, https://doi.org/10.1594/PANGAEA.946420 Keyword(s): black carbon; Deep sea; Dissolved Organic Matter; dissolved organic sulfur; FT-ICR MS; mesocosm; Oil seeps; PARAFAC Project(s): Center for Marine Environmental Sciences (MARUM) (URI: https://www.marum.de/en/) Funding: German Research Foundation (DFG) (URI: http://www.dfg.de/en/), grant/award no. 390741603: EXC 2077: The Ocean Floor – Earth's Uncharted Interface (URI: https://gepris.dfg.de/gepris/projekt/390741603) Coverage: LATITUDE: 21.899183 * LONGITUDE: -93.436833 DATE/TIME START: 2015-03-16T11:23:00 * DATE/TIME END: 2015-03-16T11:23:00 MINIMUM ELEVATION: -2905.0 m * MAXIMUM ELEVATION: -2905.0 m Event(s): GeoB19339-1 (M114/2_96-1) * LATITUDE: 21.899183 * LONGITUDE: -93.436833 * DATE/TIME: 2015-03-16T11:23:00 * ELEVATION: -2905.0 m * LOCATION: Gulf of Mexico * CAMPAIGN: M114/2 * BASIS: Meteor (1986) (URI: https://en.wikipedia.org/wiki/RV_Meteor_(1986)) * METHOD/DEVICE: Gravity corer (GC) * COMMENT: Recovery of piece of asphalt and sediment Parameter(s): Sample ID (Sample ID) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Fluorescence peak [%] (Fl peak) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * COMMENT: c1 Fluorescence peak [%] (Fl peak) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * COMMENT: c2 Fluorescence peak [%] (Fl peak) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * COMMENT: c3 Fluorescence peak [%] (Fl peak) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * COMMENT: c4 Fluorescence index (FI) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Freshness index (FIX) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Biological index (BIX) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Humification index (HIX) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Peak-T/Peak-A ratio (P-T/P-A) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Carbon, organic, dissolved [µmol/l] (DOC) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: High temperature catalytic oxidation (Shimadzu TOC-VCPH) δ13C, dissolved inorganic carbon [‰ PDB] (δ13C DIC) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: High temperature catalytic oxidation (Shimadzu TOC-VCPH) * COMMENT: vs. VPDB δ13C, dissolved organic carbon [‰ PDB] (δ13C DOC) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: Delta Ray Isotope Ratio Infrared Spectrometer (IRIS) with URI Connect and autosampler (Thermo Fisher Scientific, Germany) * COMMENT: Solid-phase extracted (SPE) Extraction efficiency [%] (EE) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Sulfur, organic, dissolved, extracted [µmol/l] (DOS extr) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES iCAP 6000, Thermo Fisher Scientific GmbH, Bremen, Germany) * COMMENT: Solid-phase extracted (SPE) Carbon, organic, dissolved, extracted [µmol/l] (DOC extr) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: High temperature catalytic oxidation (Shimadzu TOC-VCPH) * COMMENT: Solid-phase extracted (SPE) Sulfur/Carbon ratio (S/C) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * COMMENT: Solid-phase extracted (SPE) Specific ultraviolet absorbance normalized to DOC, 254 nm, per mass carbon [l/mg/m] (SUVA254) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: UV-VIS absorption spectrophotometer (UV-1280, Shimadzu) Benzenepentacarboxylic acid [nmol/l] (B5CA) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: Liquid chromatography and diode-array detection (Waters Acquity UPLC) Benzenehexacarboxylic acid [nmol/l] (B6CA) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: Liquid chromatography and diode-array detection (Waters Acquity UPLC) Benzenepentacarboxylic acid/Benzenehexacarboxylic acid ratio (B6CA/B5CA) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) Black carbon, dissolved [µmol/l] (DBC) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: Liquid chromatography and diode-array detection (Waters Acquity UPLC) * COMMENT: Converted from the sum of B5CA and B6CA to DBC after Stubbins et al., 2015 (doi:10.1016/j.marchem.2015.06.020) Black carbon, dissolved/carbon, organic, dissolved ratio [%] (DBC/DOC) * PI: Brünjes, Jonas (https://orcid.org/0000-0001-7759-2583, jbruenjes@marum.de) * METHOD/DEVICE: Liquid chromatography and diode-array detection (Waters Acquity UPLC) License: Creative Commons Attribution 4.0 International (CC-BY-4.0) (URI: https://creativecommons.org/licenses/by/4.0/) Status: Curation Level: Enhanced curation (URI: https://wiki.pangaea.de/wiki/Curation_levels) Size: 276 data points */ Sample ID Fl peak [%] (c1) Fl peak [%] (c2) Fl peak [%] (c3) Fl peak [%] (c4) FI FIX BIX HIX P-T/P-A DOC [µmol/l] (High temperature catalytic ox...) δ13C DIC [‰ PDB] (vs. VPDB, High temperature ca...) δ13C DOC [‰ PDB] (Solid-phase extracted (SPE), ...) EE [%] DOS extr [µmol/l] (Solid-phase extracted (SPE), ...) DOC extr [µmol/l] (Solid-phase extracted (SPE), ...) S/C (Solid-phase extracted (SPE)) SUVA254 [l/mg/m] (UV-VIS absorption spectrophot...) B5CA [nmol/l] (Liquid chromatography and dio...) B6CA [nmol/l] (Liquid chromatography and dio...) B6CA/B5CA DBC [µmol/l] (Converted from the sum of B5C...) DBC/DOC [%] (Liquid chromatography and dio...) t0_1 28.62 38.88 27.90 4.60 1.365842626 2.105622774 2.287430328 0.181756744 1.839372284 825.2826768 -3.3260 -28.01900000 6.477740269 2.7 53.45966828 5.1 0.000000000 8.2 5.0 0.608405244 0.832650238 0.100892732 t0_2 28.69 39.85 27.18 4.27 0.504251196 2.036652522 2.206295914 0.175873548 1.786063973 813.3550432 -3.1870 -28.01900000 6.786780012 2.7 55.20061750 5.1 0.276631960 8.2 5.0 0.608405244 0.832650238 0.102372297 t0_3 29.46 38.70 27.49 4.35 1.324951415 2.279947992 2.288275677 0.177664617 1.911961084 919.8584796 -3.2565 -28.01900000 5.279351679 2.7 48.56256409 5.1 0.108712375 8.2 5.0 0.608405244 0.832650238 0.090519385 t1_1 35.47 36.37 17.69 10.47 1.895051409 1.848165406 1.876168365 0.269614780 1.155315940 917.1443140 -4.4300 -28.33250000 28.450722080 13.0 260.93417980 5.0 0.190809666 31.1 20.1 0.644662445 3.078550895 0.335667010 t1_2 34.09 35.83 19.08 10.99 2.007285181 1.504437834 1.776831236 0.275989194 1.288294388 970.3960322 -3.4170 -28.49500000 31.150949260 12.6 302.28757560 4.2 1.700336713 33.0 21.0 0.634768992 3.240186272 0.333903496 t1_3 34.82 36.01 18.10 11.08 1.664177061 1.672821063 1.905512212 0.273839860 1.167829855 1014.5376680 -2.9070 -29.14300000 26.771240130 12.0 271.60431530 4.4 1.108879478 34.8 20.1 0.578385082 3.292179154 0.324500436 t2_1 38.20 33.51 15.18 13.11 1.819761568 1.324060235 1.708834481 0.283126003 1.036040215 1952.7822260 -8.9400 -28.04750000 48.891608480 36.4 954.74664060 3.8 1.753907811 112.6 82.6 0.733322295 11.193910580 0.573228823 t2_2 35.77 35.92 14.75 13.56 1.755035978 1.275850613 1.453053706 0.300785709 1.152761845 2326.5773560 -7.5660 -28.65050000 47.711954900 38.8 1110.05553900 3.5 1.450628749 132.8 76.7 0.577817803 11.986681610 0.515206666 t2_3 35.14 37.41 15.72 11.73 1.646582116 1.401028423 1.581804876 0.259143550 1.178421860 2922.0198480 -8.2970 -28.01866667 56.196088040 45.2 1642.06084600 2.8 2.523939050 162.6 130.6 0.802823630 16.577143640 0.567317969 t0_dead 35.91 31.36 27.33 5.41 1.722547646 2.407802047 3.181779882 0.226299598 1.381934404 375.6954195 -3.2810 -28.01900000 19.385577690 4.9 72.83072742 6.7 0.665432654 27.7 9.9 0.356898111 2.288975467 0.609263608 t1_dead 31.74 34.61 28.13 5.53 1.023510475 1.870364702 2.820834472 0.218037063 1.655664343 856.0034524 -1.2180 -28.59500000 17.505008000 9.1 149.84347280 6.1 0.730137242 36.6 14.2 0.386988472 3.052565717 0.356606706 t2_dead 36.53 32.89 25.76 4.82 2.728559203 2.229925583 2.964255478 0.221974234 1.225848583 784.8133248 0.1800 -27.78000000 27.584377680 17.2 216.48587160 8.0 1.337897774 63.0 23.7 0.376492551 5.119983299 0.652382310