Not logged in
PANGAEA.
Data Publisher for Earth & Environmental Science

Brown, Rachel Mary; Wilson, Paul A; Crocker, Anya J; Thomas, Chalk (2023): Late Pleistocene δ¹¹B based carbon dioxide levels from ODP Site 154-926 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.946154

Always quote citation above when using data! You can download the citation in several formats below.

RIS CitationBibTeX CitationShow MapGoogle Earth

Abstract:
Earth's climate cooled markedly during the Late Miocene from 12 to 5 million years ago, with far-reaching consequences for global ecosystems. However, the driving forces of these changes remain controversial. A major obstacle to progress is the uncertainty over the role played by greenhouse gas radiative forcing. Here we present boron isotope compositions for planktonic foraminifera, which record carbon dioxide change for the interval of most rapid cooling, the Late Miocene Cooling event between 7 and 5 Ma. Our record suggests that CO₂ declined by some 100 ppm over this two-million year-long interval to a minimum at approximately 5.9 Ma. Having accounted non-CO₂ greenhouse gasses and slow climate feedbacks, we estimate global mean surface temperature change for a doubling of CO₂ - Equilibrium Climate Sensitivity - to be 3.9˚C (1.8–6.7 ˚C at 95% confidence) based on comparison of our record of radiative forcing from CO₂ with a record of global mean surface temperature change. We conclude that changes in CO₂ and climate were closely coupled during the latest Miocene and that Equilibrium Climate Sensitivity was within range of estimates for the late Pleistocene, other intervals of the Cenozoic, and the 21st century as presented by the Intergovernmental Panel on Climate Change.
Keyword(s):
boron isotopes; CO2; Late Miocene; Trilobatus sacculifer
Related to:
Brown, Rachel Mary; Chalk, Thomas B; Crocker, Anya J; Wilson, Paul A; Foster, Gavin L (2022): Late Miocene cooling coupled to carbon dioxide with Pleistocene-like climate sensitivity. Nature Geoscience, 15(8), 664-670, https://doi.org/10.1038/s41561-022-00982-7
Coverage:
Median Latitude: 3.719020 * Median Longitude: -42.908300 * South-bound Latitude: 3.718830 * West-bound Longitude: -42.908400 * North-bound Latitude: 3.719130 * East-bound Longitude: -42.908100
Date/Time Start: 1994-02-19T11:30:00 * Date/Time End: 1994-02-27T16:00:00
Minimum DEPTH, sediment/rock: 135.235 m * Maximum DEPTH, sediment/rock: 172.525 m
Event(s):
154-926A  * Latitude: 3.719100 * Longitude: -42.908100 * Date/Time Start: 1994-02-19T11:30:00 * Date/Time End: 1994-02-21T10:30:00 * Elevation: -3610.0 m * Penetration: 327 m * Recovery: 334.92 m * Location: South Atlantic Ocean * Campaign: Leg154 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 35 cores; 327 m cored; 0 m drilled; 102.4 % recovery
154-926B  * Latitude: 3.719130 * Longitude: -42.908400 * Date/Time Start: 1994-02-21T10:30:00 * Date/Time End: 1994-02-25T19:00:00 * Elevation: -3610.0 m * Penetration: 605.8 m * Recovery: 593.25 m * Location: South Atlantic Ocean * Campaign: Leg154 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 64 cores; 605.8 m cored; 0 m drilled; 97.9 % recovery
154-926C  * Latitude: 3.718830 * Longitude: -42.908400 * Date/Time Start: 1994-02-25T19:00:00 * Date/Time End: 1994-02-27T16:00:00 * Elevation: -3610.0 m * Penetration: 398.3 m * Recovery: 394.21 m * Location: South Atlantic Ocean * Campaign: Leg154 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 42 cores; 397.8 m cored; 0 m drilled; 99.1 % recovery
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEventBrown, Rachel Mary
Date/Time of eventDate/TimeBrown, Rachel Mary
Latitude of eventLatitudeBrown, Rachel Mary
Longitude of eventLongitudeBrown, Rachel Mary
Sample code/labelSample labelBrown, Rachel Mary
DEPTH, sediment/rockDepth sedmBrown, Rachel MaryGeocode – mbsf
Depth, compositeDepth compmcdBrown, Rachel Mary
AGEAgeka BPBrown, Rachel MaryGeocode
Cibicides wuellerstorfi, δ18OC. wuellerstorfi δ18O‰ PDBBrown, Rachel Mary
10 Cibicides wuellerstorfi, δ13CC. wuellerstorfi δ13C‰ PDBBrown, Rachel Mary
11 Globigerinoides ruber, Magnesium/Calcium ratioG. ruber Mg/Cammol/molBrown, Rachel MaryInductively coupled plasma - mass spectrometry (ICP-MS)300-355 mm
12 Globigerinoides ruber, Magnesium/Calcium ratioG. ruber Mg/Cammol/molBrown, Rachel MaryCalculated according to Lear et al. (2015)
13 Globigerinoides ruber, Boron/Calcium ratioG. ruber B/Cammol/molBrown, Rachel MaryInductively coupled plasma - mass spectrometry (ICP-MS)300-355 mm
14 Globigerinoides ruber, Aluminium/Calcium ratioG. ruber Al/Cammol/molBrown, Rachel MaryInductively coupled plasma - mass spectrometry (ICP-MS)300-355 mm
15 Sea surface temperatureSST°CBrown, Rachel MarySea surface temperature used in subsequent calculations determined from measured Mg/Ca
16 Sea surface temperature, uncertaintySST unc±Brown, Rachel Mary1 sigma
17 Globigerinoides ruber, δ11BG. ruber δ11B‰ SRMBrown, Rachel MaryMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)1st δ¹¹B measurement of G. ruber (300-355 mm) as described in Methods
18 Globigerinoides ruber, δ11B, uncertaintyG. ruber δ11B unc±Brown, Rachel MaryCalculated, see reference(s)1st δ¹¹B measurement determined using equation [1] in Methods based on repeat measurements of in-house standard (see Methods for more details). 2 sigma.
19 Globigerinoides ruber, δ11BG. ruber δ11B‰ SRMBrown, Rachel MaryMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)2nd δ¹¹B measurement of G. ruber (300-355 mm) as described in Methods
20 Globigerinoides ruber, δ11B, uncertaintyG. ruber δ11B unc±Brown, Rachel MaryCalculated, see reference(s)2nd δ¹¹B measurement determined using equation [1] in Methods based on repeat measurements of in-house standard (see Methods for more details). 2 sigma.
21 Globigerinoides ruber, δ11BG. ruber δ11B‰ SRMBrown, Rachel MaryMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)Average (300-355 mm)
22 Globigerinoides ruber, δ11B, uncertaintyG. ruber δ11B unc±Brown, Rachel MaryCalculated, see reference(s)Permil Uncertainty in δ¹¹B determined using equation [1] in Methods based on repeat measurements of in-house standard (see Methods for more details). 2 sigma.
23 SalinitySalBrown, Rachel MaryAssumed salinity, in practical salinity units
24 Salinity, uncertaintySal unc±Brown, Rachel Mary
25 δ11B, seawater, reconstructedδ11Bsw‰ SRMBrown, Rachel MaryReconstructed
26 δ11B, seawater, reconstructed, uncertaintyδ11Bsw unc±Brown, Rachel MaryReconstructed2 sigma
27 Carbon, inorganic, dissolvedDICµmol/kgBrown, Rachel MaryCalculated, see reference(s)calculated using equation [2]
28 Carbon, inorganic, dissolved, uncertaintyDIC unc±Brown, Rachel Mary1 sigma
29 δ11B, aqueousδ11Baq‰ SRMBrown, Rachel MaryFractionation from Klochko et al. (2006)
30 Boron, total, seawaterB tot swµmol/kgBrown, Rachel MaryCalculated with seacarb package in RTotal boron of seawater ([B]T) at S=35.
31 Boron, total, seawaterB tot swµmol/kgBrown, Rachel MaryCalculated with seacarb package in R[B]T: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
32 Boron, total, seawaterB tot swµmol/kgBrown, Rachel MaryCalculated with seacarb package in R[B]T: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
33 Boron, total, seawaterB tot swµmol/kgBrown, Rachel MaryCalculated with seacarb package in R[B]T: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
34 Boron, total, seawaterB tot swµmol/kgBrown, Rachel MaryCalculated with seacarb package in R[B]T: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
35 Boron, seawater, logarithmic base dissociation constantB sw pk(b)Brown, Rachel MaryCalculated with seacarb package in RDissacociation constant of boron in sea water (pKB)
36 Boron, seawater, logarithmic base dissociation constantB sw pk(b)Brown, Rachel MaryCalculated with seacarb package in RpKB: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
37 Boron, seawater, logarithmic base dissociation constantB sw pk(b)Brown, Rachel MaryCalculated with seacarb package in RpKB: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
38 Boron, seawater, logarithmic base dissociation constantB sw pk(b)Brown, Rachel MaryCalculated with seacarb package in RpKB: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
39 Boron, seawater, logarithmic base dissociation constantB sw pk(b)Brown, Rachel MaryCalculated with seacarb package in RpKB: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
40 Ion product of waterKwmol/kgBrown, Rachel MaryCalculated with seacarb package in RIon product of water (Kw)
41 Ion product of waterKwmol/kgBrown, Rachel MaryCalculated with seacarb package in RKw: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
42 Ion product of waterKwmol/kgBrown, Rachel MaryCalculated with seacarb package in RKw: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
43 Ion product of waterKwmol/kgBrown, Rachel MaryCalculated with seacarb package in RKw: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
44 Ion product of waterKwmol/kgBrown, Rachel MaryCalculated with seacarb package in RKw: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
45 Henry's law constantHBrown, Rachel MaryCalculated with seacarb package in RHenry's constant (K0)
46 Henry's law constantHBrown, Rachel MaryCalculated with seacarb package in RK0: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
47 Henry's law constantHBrown, Rachel MaryCalculated with seacarb package in RK0: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
48 Henry's law constantHBrown, Rachel MaryCalculated with seacarb package in RK0: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
49 Henry's law constantHBrown, Rachel MaryCalculated with seacarb package in RK0: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
50 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RFirst dissociation constant of carbonic acid (K1)
51 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK1: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
52 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK1: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
53 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK1: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
54 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK1: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
55 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RSecond dissociation constant of carbonic acid (K2)
56 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK2: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
57 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK2: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
58 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK2: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
59 Carbonic acid, dissociation constantH2CO3 Kmol/kgBrown, Rachel MaryCalculated with seacarb package in RK2: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
60 pHpHBrown, Rachel MaryCalculated from δ¹¹B, see referenceTotal scale
61 pHpHBrown, Rachel MaryCalculated from δ¹¹B, see referencepH (total scale): 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
62 pHpHBrown, Rachel MaryCalculated from δ¹¹B, see referencepH (total scale): 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
63 pHpHBrown, Rachel MaryCalculated from δ¹¹B, see referencepH (total scale): 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
64 pHpHBrown, Rachel MaryCalculated from δ¹¹B, see referencepH (total scale): 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
65 Carbon dioxide, partial pressurepCO2ppmvBrown, Rachel MaryCalculated from δ¹¹B, see referencepCO₂atm
66 Carbon dioxide, partial pressurepCO2ppmvBrown, Rachel MaryCalculated from δ¹¹B, see referencepCO₂atm: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
67 Carbon dioxide, partial pressurepCO2ppmvBrown, Rachel MaryCalculated from δ¹¹B, see referencepCO₂atm: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
68 Carbon dioxide, partial pressurepCO2ppmvBrown, Rachel MaryCalculated from δ¹¹B, see referencepCO₂atm: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
69 Carbon dioxide, partial pressurepCO2ppmvBrown, Rachel MaryCalculated from δ¹¹B, see referencepCO₂atm: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
70 Relative change in pHΔpHBrown, Rachel MaryCalculated from δ¹¹B, see referenceΔpH (total scale)
71 Relative change in pHΔpHBrown, Rachel MaryCalculated from δ¹¹B, see referenceΔpH (total scale): 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
72 Relative change in pHΔpHBrown, Rachel MaryCalculated from δ¹¹B, see referenceΔpH (total scale): 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
73 Relative change in pHΔpHBrown, Rachel MaryCalculated from δ¹¹B, see referenceΔpH (total scale): 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
74 Relative change in pHΔpHBrown, Rachel MaryCalculated from δ¹¹B, see referenceΔpH (total scale): 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
75 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MaryCalculated according to Hain et al. (2018)Climate forcing from CO₂ (ΔFCO₂)
76 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MaryCalculated according to Hain et al. (2018)ΔFCO₂: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
77 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MaryCalculated according to Hain et al. (2018)ΔFCO₂: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
78 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MaryCalculated according to Hain et al. (2018)ΔFCO₂: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
79 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MaryCalculated according to Hain et al. (2018)ΔFCO₂: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
80 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MarySmoothed ΔFCO₂Climate forcing from CO₂ (ΔFCO₂ sm)
81 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MarySmoothed ΔFCO₂ΔFCO₂ sm: 0.03; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
82 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MarySmoothed ΔFCO₂ΔFCO₂ sm: 0.14; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
83 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MarySmoothed ΔFCO₂ΔFCO₂ sm: 0.86; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
84 Climate forcing from carbon dioxideΔFCO2W/m2Brown, Rachel MarySmoothed ΔFCO₂ΔFCO₂ sm: 0.98; percentiles from the Monte Carlo output (see Methods), 2.5 and 97.5 percentiles form the 95% confidence interval, the 14 and 86 percentiles form the 68% confidence interval.
85 CommentCommentBrown, Rachel MaryMiscellaneous comments
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
3532 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Date/Time

Latitude

Longitude

Sample label

Depth sed [m]
(mbsf)

Depth comp [mcd]

Age [ka BP]

C. wuellerstorfi δ18O [‰ PDB]
10 
C. wuellerstorfi δ13C [‰ PDB]
11 
G. ruber Mg/Ca [mmol/mol]
(300-355 mm, Inductively coupl...)
12 
G. ruber Mg/Ca [mmol/mol]
(Calculated according to Lear ...)
13 
G. ruber B/Ca [mmol/mol]
(300-355 mm, Inductively coupl...)
14 
G. ruber Al/Ca [mmol/mol]
(300-355 mm, Inductively coupl...)
15 
SST [°C]
(Sea surface temperature used ...)
16 
SST unc [±]
(1 sigma)
17 
G. ruber δ11B [‰ SRM]
(1st δ¹¹B measurement of G. ru...)
18 
G. ruber δ11B unc [±]
(1st δ¹¹B measurement determin...)
19 
G. ruber δ11B [‰ SRM]
(2nd δ¹¹B measurement of G. ru...)
20 
G. ruber δ11B unc [±]
(2nd δ¹¹B measurement determin...)
21 
G. ruber δ11B [‰ SRM]
(Average (300-355 mm), Multi-c...)
22 
G. ruber δ11B unc [±]
(Permil Uncertainty in δ¹¹B de...)
23 
Sal
(Assumed salinity, in practica...)
24 
Sal unc [±]
25 
δ11Bsw [‰ SRM]
(Reconstructed)
26 
δ11Bsw unc [±]
(2 sigma, Reconstructed)
27 
DIC [µmol/kg]
(calculated using equation [2]...)
28 
DIC unc [±]
(1 sigma)
29 
δ11Baq [‰ SRM]
(Fractionation from Klochko et...)
30 
B tot sw [µmol/kg]
(Total boron of seawater ([B]T...)
31 
B tot sw [µmol/kg]
([B]T: 0.03; percentiles from ...)
32 
B tot sw [µmol/kg]
([B]T: 0.14; percentiles from ...)
33 
B tot sw [µmol/kg]
([B]T: 0.86; percentiles from ...)
34 
B tot sw [µmol/kg]
([B]T: 0.98; percentiles from ...)
35 
B sw pk(b)
(Dissacociation constant of bo...)
36 
B sw pk(b)
(pKB: 0.03; percentiles from t...)
37 
B sw pk(b)
(pKB: 0.14; percentiles from t...)
38 
B sw pk(b)
(pKB: 0.86; percentiles from t...)
39 
B sw pk(b)
(pKB: 0.98; percentiles from t...)
40 
Kw [mol/kg]
(Ion product of water (Kw), Ca...)
41 
Kw [mol/kg]
(Kw: 0.03; percentiles from th...)
42 
Kw [mol/kg]
(Kw: 0.14; percentiles from th...)
43 
Kw [mol/kg]
(Kw: 0.86; percentiles from th...)
44 
Kw [mol/kg]
(Kw: 0.98; percentiles from th...)
45 
H
(Henry's constant (K0), Calcul...)
46 
H
(K0: 0.03; percentiles from th...)
47 
H
(K0: 0.14; percentiles from th...)
48 
H
(K0: 0.86; percentiles from th...)
49 
H
(K0: 0.98; percentiles from th...)
50 
H2CO3 K [mol/kg]
(First dissociation constant o...)
51 
H2CO3 K [mol/kg]
(K1: 0.03; percentiles from th...)
52 
H2CO3 K [mol/kg]
(K1: 0.14; percentiles from th...)
53 
H2CO3 K [mol/kg]
(K1: 0.86; percentiles from th...)
54 
H2CO3 K [mol/kg]
(K1: 0.98; percentiles from th...)
55 
H2CO3 K [mol/kg]
(Second dissociation constant ...)
56 
H2CO3 K [mol/kg]
(K2: 0.03; percentiles from th...)
57 
H2CO3 K [mol/kg]
(K2: 0.14; percentiles from th...)
58 
H2CO3 K [mol/kg]
(K2: 0.86; percentiles from th...)
59 
H2CO3 K [mol/kg]
(K2: 0.98; percentiles from th...)
60 
pH
(Total scale, Calculated from ...)
61 
pH
(pH (total scale): 0.03; perce...)
62 
pH
(pH (total scale): 0.14; perce...)
63 
pH
(pH (total scale): 0.86; perce...)
64 
pH
(pH (total scale): 0.98; perce...)
65 
pCO2 [ppmv]
(pCO₂atm, Calculated from δ¹¹B...)
66 
pCO2 [ppmv]
(pCO₂atm: 0.03; percentiles fr...)
67 
pCO2 [ppmv]
(pCO₂atm: 0.14; percentiles fr...)
68 
pCO2 [ppmv]
(pCO₂atm: 0.86; percentiles fr...)
69 
pCO2 [ppmv]
(pCO₂atm: 0.98; percentiles fr...)
70 
ΔpH
(ΔpH (total scale), Calculated...)
71 
ΔpH
(ΔpH (total scale): 0.03; perc...)
72 
ΔpH
(ΔpH (total scale): 0.14; perc...)
73 
ΔpH
(ΔpH (total scale): 0.86; perc...)
74 
ΔpH
(ΔpH (total scale): 0.98; perc...)
75 
ΔFCO2 [W/m2]
(Climate forcing from CO₂ (ΔFC...)
76 
ΔFCO2 [W/m2]
(ΔFCO₂: 0.03; percentiles from...)
77 
ΔFCO2 [W/m2]
(ΔFCO₂: 0.14; percentiles from...)
78 
ΔFCO2 [W/m2]
(ΔFCO₂: 0.86; percentiles from...)
79 
ΔFCO2 [W/m2]
(ΔFCO₂: 0.98; percentiles from...)
80 
ΔFCO2 [W/m2]
(Climate forcing from CO₂ (ΔFC...)
81 
ΔFCO2 [W/m2]
(ΔFCO₂ sm: 0.03; percentiles f...)
82 
ΔFCO2 [W/m2]
(ΔFCO₂ sm: 0.14; percentiles f...)
83 
ΔFCO2 [W/m2]
(ΔFCO₂ sm: 0.86; percentiles f...)
84 
ΔFCO2 [W/m2]
(ΔFCO₂ sm: 0.98; percentiles f...)
85 
Comment
(Miscellaneous comments)
154-926B 1994-02-21T10:303.7191-42.9084154-926B-15H-4,23.5-25135.235151.77500004935.7153852.1868112920.6572839602.8937465314.02620622261.1903816048.0795325125.056726200.518.320.1918.160.1818.240.19351.539.80.3119290002500001.0272432.6817750396.6640390412.5077323453.0310387469.15419778.5968103228.5772993698.5857047258.6081301768.6172864050.0000000.0000000.0000000.0000000.0000000.0283504650.0275551190.0278973070.0288036170.0291968900.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0894424698.0526618608.0693183478.1096235278.125871936312.1333087221.2344268259.8180052364.4676919406.33448000.028812488-0.0000488000.0140105540.0436179580.057325142-0.383568296-0.793124468-0.603716204-0.1665628830.000562581-0.343075041-0.648395071-0.504511066-0.182170206-0.049033140
154-926B1994-02-21T10:303.7191-42.9084154-926B-15H-4,137.5-139136.375152.91500004976.9090912.1688815460.9529509092.8258296294.01641731465.0318519427.2493956524.800810690.518.080.2518.030.2418.050.25351.539.80.3119280002500001.0272432.6735810396.8327907412.5874844452.6710875469.13966768.5997793238.5803851328.5891480818.6112636408.6202462660.0000000.0000000.0000000.0000000.0000000.0285424540.0277242010.0280784280.0290040730.0293768080.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0724587318.0307954038.0501828648.0949430938.111870277327.1529917229.8402013272.2044125382.3447431428.15966110.013464245-0.018783814-0.0030172290.0298758930.045426694-0.179258979-0.616295953-0.4154922040.0579384370.254663995-0.188570267-0.402988184-0.303436504-0.0722886940.018531951
154-926B1994-02-21T10:303.7191-42.9084154-926B-15H-5,42-43.5136.920153.46000004998.5289261.9673271690.9100000003.0907481624.01127981870.8376922316.6954385525.800672780.518.170.2718.320.2518.250.26351.539.80.3119270002500001.0272432.5696608396.0318480411.9811299452.7483457469.63220188.5881974698.5684505168.5772051968.5997138398.6092087840.0000000.0000000.0000000.0000000.0000000.0278330280.0270451310.0273871230.0282790290.0286443530.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0817503728.0407523148.0598003358.1037554328.121647474319.9386417227.2011965266.3199310373.5220722418.38341150.020998119-0.0111070280.0045914430.0375346540.053328000-0.279384290-0.731159216-0.520017875-0.0427314920.146887454-0.111802385-0.304297738-0.216470200-0.0072238720.075406446
154-926B1994-02-21T10:303.7191-42.9084154-926B-15H-6,2-3.5138.020154.84452835052.3358492.1405509930.8500000003.3361596813.99849389472.34432071189.4270771026.660041600.518.270.1918.420.1918.350.19351.539.80.3119260002500001.0272432.5142089395.0367890412.3022966452.7031960469.15829588.5782802878.5586740108.5673042688.5898942788.5998102320.0000000.0000000.0000000.0000000.0000000.0272519040.0264911350.0268245470.0276845640.0280545040.0000010.0000010.0000010.0000010.0000020.0000000.0000000.0000000.0000000.0000008.0822438078.0450723568.0620875078.1026512288.118288453319.3641862225.6559568267.3309899372.6229553416.37251290.020791365-0.0079756840.0061969310.0352310400.049907920-0.276427017-0.685939634-0.491104436-0.0639677610.1084129920.034230032-0.148923211-0.0644147180.1347281580.216275266
154-926C 1994-02-25T19:003.7188-42.9084154-926C-15H-4,10-11.5138.100155.01207555057.6774052.0593108730.7695371743.5816743963.99722461372.6699231024.8525167027.450073980.517.760.1917.750.1817.750.18351.539.80.3119260002500001.0272432.8083971395.3798977412.5289932453.1488144469.18420318.5691917028.5495302698.5583521758.5806153148.5900766120.0000000.0000000.0000000.0000000.0000000.0267327290.0259911190.0263232950.0271394360.0274842990.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0088162647.9701301727.9877141358.0300872758.047268708391.8765493276.4949640329.2642268455.1155825510.1921170-0.047888401-0.077391771-0.062901249-0.032874090-0.0183227900.6381740560.2340732360.4087853960.8743459621.0884067160.041534477-0.140718195-0.0577294850.1424263270.224032901Single C. wuellerstorfii run for stable isotopes
154-926C1994-02-25T19:003.7188-42.9084154-926C-15H-4,109-110.5139.090156.21000005119.5789472.6221056920.9188740412.4365835493.98251548865.7329352918.5151659223.181650430.517.530.2117.480.2017.500.20351.539.80.3119250002500001.0272432.7122017395.7540142412.4905938452.9486608469.50556858.6186422328.5990483858.6078584488.6298552118.6395997810.0000000.0000000.0000000.0000000.0000000.0297546760.0288786480.0292631760.0302479390.0306685750.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0290221297.9884648948.0072188378.0510440408.069003834366.3572837258.1069031304.0483033427.3631086479.3082471-0.025488894-0.056428533-0.041121664-0.0097068090.0047861070.339084741-0.0654145670.1106905190.5709460870.780577815-0.008374976-0.182551215-0.1033309080.0871629110.168476489
154-926C1994-02-25T19:003.7188-42.9084154-926C-15H-5,55.5-57140.055157.42527785168.8935192.3511673010.7605168273.5349370183.97079749977.6544907182.9397394327.325587430.518.530.1718.510.1718.520.17351.539.80.3119240002500001.0272432.7801071396.4239052412.9754471452.6698101468.25474578.5706220658.5510544958.5595431728.5819660088.5911656920.0000000.0000000.0000000.0000000.0000000.0268063310.0260731720.0263887240.0272253730.0275764560.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0925865058.0567557548.0729425868.1121670628.127734758310.3825534219.3231465259.6054807362.3064515404.04259190.0298869230.0017399500.0160533250.0437618560.058229891-0.397180076-0.803015715-0.605514812-0.191567017-0.023151663-0.151699556-0.314089144-0.241446017-0.0623025630.015117994Single C. wuellerstorfii run for stable isotopes
154-926A 1994-02-19T11:303.7191-42.9081154-926A-16H-3,18.5-20140.185157.67805565179.4691362.2162119731.0800000003.6403617613.96828457583.28286782136.6974240027.654153790.518.660.2318.730.2218.690.22351.539.80.3119240002500001.0272432.8258735395.9268406412.2873799452.8531472469.02716558.5668481748.5466785148.5556577488.5783410678.5872523450.0000000.0000000.0000000.0000000.0000000.0265931770.0258486490.0261879740.0269974240.0273392620.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.1064411018.0694451648.0864748168.1268766148.143077770298.2780741209.0173197248.7493820347.3759776389.99971150.0420715740.0131990050.0269348400.0570957210.071830683-0.560417990-0.995692419-0.789310596-0.334556418-0.169477402-0.174669925-0.336097258-0.264584182-0.085263653-0.008950986
154-926C1994-02-25T19:003.7188-42.9084154-926C-15H-5,119.5-121140.695158.10305565199.1527782.1399947321.0712176893.5889061923.96360746983.41239658137.0330436027.499772010.518.290.1818.310.1718.300.18351.539.80.3119230002500001.0272432.8497145396.7838679413.3110831453.0054510468.95871988.5686208448.5489372458.5576129788.5799341748.5890617630.0000000.0000000.0000000.0000000.0000000.0266981410.0259591640.0262815070.0271117760.0274553100.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0676517598.0316418188.0477269158.0875819968.103287580332.1746232234.5423449277.5666093387.0436131432.86309810.006666718-0.022055033-0.0075406750.0208586590.035135651-0.088950051-0.477582023-0.2950857060.1161026780.292042817-0.200947447-0.362580284-0.289889881-0.112313419-0.037716945
154-926A1994-02-19T11:303.7191-42.9081154-926A-16H-3,121-122.5141.210158.84000005234.1333332.1913234931.9000000003.0643527863.95529567769.7434152724.8502987925.750827120.518.250.1918.490.1918.370.19351.539.80.3119230002500001.0272432.3408149395.7176228412.2807463452.2804776468.64271108.5887737248.5693522248.5778995358.6002403768.6101944340.0000000.0000000.0000000.0000000.0000000.0278691110.0270956010.0274262730.0283111220.0286903270.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0952760898.0580815238.0748236938.1156398508.131622579307.0472097216.1623385254.6943078358.8146397402.31780410.0335675830.0046960390.0187446290.0484839840.062929355-0.446924859-0.870622594-0.672952271-0.228013866-0.060614722-0.207813709-0.376187451-0.299352915-0.116553190-0.041751002
154-926A1994-02-19T11:303.7191-42.9081154-926A-16H-4,61.5-63142.115159.74500005272.4000002.2401049151.1400000003.3766828333.94620317179.47377870235.8444485026.836603690.517.800.2317.750.2317.770.23351.539.80.3119220002500001.0272432.6387957396.2690978412.4029928452.5339698468.72572478.5762468038.5565114718.5651036938.5875437068.5969069110.0000000.0000000.0000000.0000000.0000000.0271268990.0263664220.0266993700.0275484240.0278964050.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0180488597.9777118177.9953814068.0403062438.058602173382.3964814269.8214136319.9213453445.2729830499.2802820-0.038668241-0.070377933-0.054765376-0.022736944-0.0070092220.5151137650.0907394440.2798119890.7549818990.980606396-0.185826716-0.358232912-0.281300541-0.091537796-0.010570688
154-926A1994-02-19T11:303.7191-42.9081154-926A-16H-4,140-141.5142.900160.53000005305.5000002.4212930521.0900000003.6809638803.93833839981.2397083335.3296167727.801641430.518.800.1918.800.1818.800.18351.539.80.3119210002500001.0272432.8049603395.9271083412.4339926452.9436156469.41035788.5651555618.5451946768.5539167838.5766459988.5860262740.0000000.0000000.0000000.0000000.0000000.0265037680.0257785610.0260955200.0269150780.0272641170.0000020.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.1156142238.0802229818.0962886838.1350841468.151115370290.5070860203.5418885242.1158461340.3883128380.34185230.0498300310.0213900370.0353561020.0643237850.078401021-0.662767994-1.096004407-0.892184132-0.437836456-0.279810309-0.177683148-0.350507887-0.273615206-0.083502998-0.003243096
154-926A1994-02-19T11:303.7191-42.9081154-926A-16H-5,90-91.5143.900161.67512205358.7560982.1554840811.1400000003.5368605703.92568458179.8691429323.7269279227.368143820.518.210.1718.360.1618.280.16351.539.80.3119200002500001.0272432.4894683395.5288952412.0437415452.7684613469.09089188.5701330168.5504761618.5591287818.5819134158.5914720160.0000000.0000000.0000000.0000000.0000000.0267852140.0260442060.0263662240.0272042190.0275581710.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0673354148.0307610908.0469613598.0870668858.104302656332.8381889234.1581979278.5309176386.4813410433.80284140.006729888-0.021207089-0.0073922990.0212334500.034625686-0.089630689-0.469064017-0.2983018840.1131285320.288775484-0.126618515-0.292802125-0.218146632-0.0349344260.041106201
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-1,115-116.5144.150162.13853665381.9268293.7660834823.92017920787.2749391652.2865532328.070323910.518.130.1718.230.1618.180.17351.539.80.3119200002500001.0272432.6189216395.4197033412.7822469452.5639090468.58966838.5620742978.5422057858.5509353168.5733740058.5829972210.0000000.0000000.0000000.0000000.0000000.0263327720.0256043410.0259317990.0267331560.0270725820.0000020.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0484147788.0119843188.0286100598.0686589328.085022147351.3977647250.0690460294.2933719409.3358364456.8871561-0.011555545-0.040062274-0.0259907940.0027393040.0172944100.153602030-0.230667705-0.0533850450.3641943200.536860558-0.097150506-0.261680354-0.189254163-0.0054159140.068867138
154-926A1994-02-19T11:303.7191-42.9081154-926A-16H-6,38-39.5144.880162.89888895416.8395062.4218901901.0201023863.6806150273.91188401984.07407524131.4718506027.821954310.518.620.1818.770.1718.700.18351.539.80.3119190002500001.0272432.5887138396.5612061412.9351063452.5722594468.49756898.5649225138.5452294058.5540367348.5761790328.5860309780.0000000.0000000.0000000.0000000.0000000.0264924440.0257682550.0260927610.0269025660.0272393820.0000020.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.1049313458.0700896788.0859202028.1241215728.139533807299.9728735210.2625668249.4181140350.3537302393.17574040.0406009560.0126597030.0265699980.0546431320.068411802-0.539546621-0.957053035-0.756394502-0.325848654-0.165230781-0.050671061-0.219981506-0.1425099370.0423354630.118632041
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-2,85.5-87145.355163.68500005452.0098041.4805785031.2275703812.8893065833.90352771260.8516278921.4329719025.139100030.517.670.2117.700.2017.680.21351.539.80.3119180002500001.0272432.5814535395.9035880412.8022403452.5463485468.46423248.5958553498.5759625718.5852140368.6072292238.6164319460.0000000.0000000.0000000.0000000.0000000.0283004200.0275029030.0278523540.0287475160.0291311500.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0274671927.9875946918.0056430278.0492369458.066381710370.8588933263.9796868309.8370210431.8718843484.0940127-0.028362514-0.059140582-0.044149867-0.0127852970.0021095430.376803012-0.0288243260.1495763550.6082199400.8141793110.009766994-0.160600944-0.0852228120.1057311830.181287901
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-3,14.5-16146.145164.47500005494.0263162.2087254271.0100797783.1934240343.89354489675.4693094143.4915047526.259111610.518.030.1918.080.1818.060.18351.539.80.3119170002500001.0272433.0733500397.1927632412.8808869453.0271074469.00040918.5829029148.5628690178.5718855478.5939652408.6034943220.0000000.0000000.0000000.0000000.0000000.0275143370.0267309020.0270858700.0279434470.0283110570.0000010.0000010.0000010.0000010.0000020.0000000.0000000.0000000.0000000.0000008.0557305398.0175540208.0351849188.0760740808.093010402344.0734560242.6063602287.4813039400.8439352450.4055706-0.002954845-0.032404621-0.0175953730.0118915440.0259639180.039068984-0.346710291-0.1739335720.2508679800.4393081720.055644332-0.118317418-0.0427412170.1536295270.233466626
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-3,95-96.5146.950165.28000005536.6666672.3834625620.9700000003.4142080133.88341399471.1612331132.9455507427.010064630.518.300.2118.290.2018.290.20351.539.80.3119170002500001.0272432.4038039396.6036102412.5845022452.3767578469.85486218.5742503418.5544998058.5636320968.5857952278.5949811190.0000000.0000000.0000000.0000000.0000000.0270162020.0262720170.0266087680.0274348690.0277808420.0000010.0000010.0000010.0000020.0000020.0000000.0000000.0000000.0000000.0000008.0729523448.0357517898.0526854118.0930152458.109677615328.7293582232.3560395274.4364204382.5309800430.81324590.011648577-0.017284600-0.0032302460.0266667570.041105315-0.154795049-0.555735641-0.3733247350.0592213470.2280851170.074942061-0.108796984-0.0261437090.1759243110.257571474
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-4,40-41.5147.900166.23000005579.5555562.9080263103.87322417968.8263830324.0830122025.235248530.517.330.2017.570.2017.450.20351.539.80.3119160002500001.0272432.6316516396.3309374412.6082598452.8613840469.18327498.5947411028.5751749408.5839621658.6061495548.6156620130.0000000.0000000.0000000.0000000.0000000.0282333370.0274383490.0277829060.0286870870.0290595750.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000007.9984210837.9577502687.9754014618.0209376198.038065141400.7903527283.6446722335.1697655467.9780265522.1727428-0.055503826-0.086392926-0.070949831-0.040050896-0.0245928470.7363964450.3127365860.4957803630.9822288761.1997932710.068648097-0.120835123-0.0372510510.1726001610.258891616
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-4,100-101.5148.500166.83000005601.5641032.5065584371.2416020332.7872471863.86799530172.9181226618.2974321424.768115220.518.370.2518.340.2418.350.24351.539.80.3119150002500001.0272432.8466123396.1039440412.6051310452.9732264469.86694668.6001588738.5803569228.5892099228.6115021448.6205045660.0000000.0000000.0000000.0000000.0000000.0285586380.0277362770.0281018550.0290168860.0293933120.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.1047424828.0661770998.0835486148.1260600358.142776333299.2543852210.8219726249.8691873348.8073463392.18850650.0435467880.0121295970.0278864550.0593567330.074443786-0.579771873-1.038635316-0.819997534-0.341907030-0.1554030700.044002731-0.147290068-0.0625682670.1486698420.235007373
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-5,55-56.5149.550167.88000005654.1111112.1475197670.8400000002.7945226533.85551112164.1290653323.2502917524.807104310.517.640.2417.640.2317.640.23351.539.80.3119140002500001.0272432.6859665396.2430193412.5773727452.9327626469.80624718.5997062688.5801489908.5889291908.6109105698.6203820770.0000000.0000000.0000000.0000000.0000000.0285369260.0277174820.0280778310.0289962540.0293701280.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0258836847.9843883008.0030401298.0486731008.066500859372.2129585264.2013433310.2261935432.9446902489.0557333-0.029471003-0.061813182-0.045973137-0.0130052520.0028887580.391745845-0.0379905410.1517870710.6350030410.848940450-0.030488447-0.216451846-0.1353162660.0734301490.159520778
154-926B1994-02-21T10:303.7191-42.9084154-926B-17H-1,90-93150.400168.99270275708.1621623.1393494193.84266982380.5705083219.8031515226.111498990.518.430.2018.530.1918.480.20351.539.80.3119130002500001.0272432.4213720396.5090749412.8653131452.6113392468.15863998.5800319908.5601988578.5691569398.5910184048.6006810570.0000000.0000000.0000000.0000000.0000000.0273485060.0265743890.0269228390.0277657040.0281456270.0000010.0000010.0000010.0000010.0000020.0000000.0000000.0000000.0000000.0000008.1068145948.0717445488.0872376968.1264285298.142413161297.4619997208.7742392247.3405933347.2172022389.20775220.0437128790.0168389730.0297756600.0578367040.071116041-0.582391851-1.005865176-0.800583475-0.369416037-0.219295484-0.143249264-0.330549450-0.244799516-0.0413442750.039588348
154-926C1994-02-25T19:003.7188-42.9084154-926C-16H-5,127-128.5150.270169.14729735714.8378383.2534120453.84108385076.2238334274.6596954526.506769280.518.490.1718.650.1518.570.16351.539.80.3119130002500001.0272432.5417690396.6244187412.4854432452.0929098469.26244568.5846213358.5656343388.5738930168.5959825228.6054004640.0000000.0000000.0000000.0000000.0000000.0276267250.0268647560.0271911800.0280547000.0284220470.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.1021315088.0653097628.0820843688.1221959468.138894681302.0567872214.4421309252.3421827351.9490055396.26914550.0396778080.0104293870.0248697630.0542304650.068624493-0.526683724-0.948892815-0.749443965-0.305754383-0.135135642-0.153405832-0.341918152-0.255278498-0.0510723040.031711641
154-926B1994-02-21T10:303.7191-42.9084154-926B-17H-2,7.5-10.5151.075170.21500005765.9880952.4063599640.6500000002.6333520563.82893194064.9361078530.0953058124.168364630.517.250.2217.290.2217.270.22351.539.80.3119120002500001.0272432.7401547395.2354605412.3435978453.1766050470.12170098.6071307938.5873876108.5960859498.6183298848.6278538950.0000000.0000000.0000000.0000000.0000000.0289957680.0281522480.0285191780.0294649120.0298550030.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000007.9894373297.9454153947.9659164408.0125765968.030596796409.4409185291.0887239341.8868610476.8914202533.8710276-0.063299659-0.096374325-0.079841904-0.046854494-0.0304595280.8420308480.3908287870.5817898551.1083175071.350877395-0.234995688-0.427919077-0.340661896-0.128598940-0.042164501
154-926B1994-02-21T10:303.7191-42.9084154-926B-17H-2,117-120152.170171.31000005807.4042552.2336278520.8316773472.9324543313.81909273077.8007481227.9840723525.371593690.518.520.2318.420.2218.470.23351.539.80.3119110002500001.0272432.8333346396.0236205412.6630145452.7938404468.83823798.5931617928.5738507828.5824288588.6041613568.6138007850.0000000.0000000.0000000.0000000.0000000.0281300140.0273483150.0276869700.0285654640.0289530710.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.1099470888.0718511418.0890535458.1307089078.147700556294.6957288206.7110472245.4222953344.5613425388.00588610.0475778840.0171951840.0320568740.0630826140.078273658-0.632185618-1.088650226-0.866837116-0.396465564-0.221975656-0.402770565-0.602118126-0.511169855-0.296108982-0.210308809
154-926B1994-02-21T10:303.7191-42.9084154-926B-17H-3,80-83153.300172.44000005852.1948052.3764937871.0200000002.9402656363.80845201177.1915663522.4714303425.409656200.518.550.1618.690.1518.620.15351.539.80.3119100002500001.0272432.6217970396.1553105412.2884082452.8177746469.08318898.5927210668.5732337148.5818688828.6042755288.6138530080.0000000.0000000.0000000.0000000.0000000.0281090170.0273190130.0276585760.0285588190.0289306390.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.1247686328.0904970048.1058843738.1435639088.158699122283.0472918198.3945726236.3523655330.4161684369.73883680.0609576120.0342137760.0471867060.0748641030.088438453-0.811545813-1.248012957-1.040460546-0.588035815-0.434680931-0.571597742-0.773987841-0.680829535-0.462983041-0.378112153
154-926B1994-02-21T10:303.7191-42.9084154-926B-17H-4,22-25154.220173.36000005892.7037042.3147703560.8100000003.1516881143.79882859784.7035276033.4741440226.188876830.518.780.1718.700.1618.740.16351.539.80.3119090002500001.0272432.4498408395.6590151412.2185210452.4560326468.99783698.5837134428.5646077418.5730053458.5951717438.6043935350.0000000.0000000.0000000.0000000.0000000.0275689610.0268051250.0271413980.0280050590.0283575040.0000010.0000010.0000010.0000010.0000020.0000000.0000000.0000000.0000000.0000008.1275982408.0936067058.1086000828.1464679558.162215786280.7798067197.4778502232.9368070328.5364657367.69611670.0628920240.0350338790.0490736550.0769699290.090269779-0.836425702-1.277769724-1.066992586-0.612742835-0.447667030-0.607822443-0.818136633-0.718843506-0.497452653-0.414383565
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-3,4-7155.540174.94000005971.3750002.4840120231.0700000002.8998412643.78013955981.83911866124.9734326025.278421060.518.340.1818.380.1718.360.17351.539.80.3119080002500001.0272432.5000248395.8843299412.7329134452.3986274469.45121778.5942409308.5746185188.5835385478.6056404758.6149482830.0000000.0000000.0000000.0000000.0000000.0282018960.0273899780.0277560240.0286540560.0290140540.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0999380228.0635355778.0798774368.1196632548.135380757302.7752105211.4016075253.1788805354.3958777394.57601550.0381345810.0103304030.0239107480.0524919490.066071873-0.507383732-0.918631942-0.727338725-0.290569445-0.133432431-0.320497283-0.521331851-0.429637771-0.210904274-0.126437171
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-3,109-112156.590175.99000006018.5000002.1963011890.7700000003.0522481573.76894483378.5318471049.9083051425.856472410.517.510.2017.970.1917.740.20351.539.80.3119070002500001.0272432.4412868395.7152075412.2222930452.5151544468.75274688.5875525188.5676007208.5766884688.5989184948.6083942500.0000000.0000000.0000000.0000000.0000000.0277866620.0269903830.0273428970.0282326330.0286074170.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0251568287.9856047058.0030904838.0471634398.063489641373.5831703263.0748993313.0526902434.1086060485.6472921-0.031057441-0.061368237-0.046520454-0.015810850-0.0012791700.4134333130.0177954250.1893182670.6429359520.846615494-0.040650656-0.238342665-0.1490939790.0660271960.156810059
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-4,39-43157.390176.79000006061.4615382.7702811463.75873929871.7601067430.8982756624.787593920.517.500.1918.250.1817.870.19351.539.80.3119060002500001.0272432.7913557396.3630027412.5535886452.8947265468.97471588.5999327458.5807031268.5889992188.6110037388.6204700960.0000000.0000000.0000000.0000000.0000000.0285458120.0277519210.0280871370.0289976420.0293894140.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0525657268.0144195918.0312340728.0733980718.089589459345.3436056243.0843876288.0735644403.4737834450.8279940-0.004815746-0.034144077-0.0199216700.0103451980.0247515080.063955437-0.323895021-0.1518668140.2790303970.4628186600.168075159-0.0364657640.0543350240.2803412590.377214644
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-4,122-126158.220177.62000006102.9375002.3894357970.9700000002.8832300893.74888679370.97841668208.7044532025.239449300.517.640.2217.950.2217.800.22351.539.80.3119050002500001.0272432.7865859396.1885366412.7677423452.9534371468.92225498.5946924318.5751498148.5838099878.6058763438.6155731450.0000000.0000000.0000000.0000000.0000000.0282219000.0274198160.0277743870.0286786950.0290504690.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0388992287.9984635978.0169927308.0609531568.078611532359.4090013253.6386595299.2631686419.3629566468.8937498-0.017870400-0.049090643-0.033453896-0.0018774270.0125648520.237787006-0.1691187190.0067251560.4670511560.6776759060.3314266560.1069962800.2069105390.4567808090.558739723
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-5,73-76159.230178.63000006157.1250002.2072521200.920000000
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-6,34-37160.340179.74000006229.3333332.0479658450.6500000002.5953247843.71886258568.7139881445.3690534724.094374260.517.410.1417.060.2517.230.19351.539.80.3119030002500001.0272432.7432471396.5012416412.6264485452.2478782468.86521198.6079921938.5885369428.5971597968.6190166308.6288045160.0000000.0000000.0000000.0000000.0000000.0290574790.0282175930.0285842210.0295314780.0299475380.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000007.9856945027.9395463027.9611606638.0102145188.028841507413.7375099292.4688454345.4093312482.1731108544.8764793-0.066484196-0.101579617-0.083862205-0.048874831-0.0326504730.8859778510.4124247940.6107575521.1636640341.4072289370.5166042440.2726673180.3775537890.6571703580.782181723
154-926C1994-02-25T19:003.7188-42.9084154-926C-17H-6,109-112161.090180.80000006291.7567572.3302492640.9850232562.9975915773.70403489469.1318792975.4279665925.707189120.518.050.1118.220.2118.140.16351.539.80.3119010002500001.0272432.9353976397.0896454412.8389012452.8247903468.89276528.5892783098.5698390758.5783893898.6004503378.6101812980.0000000.0000000.0000000.0000000.0000000.0278946980.0271172000.0274531390.0283306970.0287214250.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0708658518.0335322498.0499913068.0918061828.108708894328.7916023231.9425479274.1610196382.7951605430.60088230.011215896-0.019200489-0.0039291580.0265307970.041652376-0.149371156-0.562954909-0.3694641190.0681601200.2519540940.3325657300.1069291030.2088560400.4576592600.567415334
154-926B1994-02-21T10:303.7191-42.9084154-926B-18H-2,71-74161.210180.92000006298.8918922.2928684930.8900000002.7873529513.70234007573.2029195978.2627647424.900564750.517.400.1517.730.2617.570.20351.539.80.3119010002500001.0272432.7197188396.6180708413.0110300452.8812311468.80530658.5986216418.5792843268.5880008688.6099233798.6195539620.0000000.0000000.0000000.0000000.0000000.0284759160.0276768880.0280233280.0289349970.0293354700.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0160982397.9722145827.9922585998.0399249068.059211509381.4723586267.1388236317.5929516445.9887689500.4801843-0.039163671-0.073955372-0.056786986-0.021527578-0.0041788090.5208507160.0539938250.2591224190.7855897091.0197587870.3090738490.0837460420.1852622630.4341445030.542526922
154-926B1994-02-21T10:303.7191-42.9084154-926B-18H-3,15.5-18.5162.155181.86500006346.4285712.1286045221.0600000002.7524004763.69104871374.9343968049.7262002024.769274410.517.730.2417.470.4217.600.33351.539.80.3119000002500001.0272432.4032023395.2033314412.5623491452.5824541468.46802218.6001454168.5806896778.5894335928.6114461978.6209826710.0000000.0000000.0000000.0000000.0000000.0285610050.0277531960.0281128010.0290166280.0293906540.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0220736007.9662723177.9915310088.0528258408.076780059376.3707593262.4441713310.1560723444.5811003501.3323692-0.033384979-0.080026815-0.056730420-0.0095670340.0129342220.444384224-0.1685119040.0996557170.7894663001.1092528600.164598299-0.0709953250.0355661440.2959349330.403626853Single C. wuellerstorfii run for stable isotopes
154-926B1994-02-21T10:303.7191-42.9084154-926B-18H-3,91-94162.910182.62000006385.0833332.3197480521.0200000002.7942664463.68186719282.1064461715.0664094424.944255660.518.260.1818.250.2518.250.22351.539.80.3118990002500001.0272432.4306218396.4351115412.5408098452.3823190469.24536108.5981147488.5784449258.5872371428.6095119888.6187231380.0000000.0000000.0000000.0000000.0000000.0284336600.0276229080.0279794950.0288937130.0292796600.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0922172738.0521260308.0700714448.1143204998.132069152309.7496780217.0491021256.7325293362.5009835407.61576000.031413692-0.0016053180.0147172230.0479975910.063631274-0.417332799-0.874400356-0.661860993-0.1750631270.0203188040.077600082-0.158679025-0.0526338720.2068571900.313668745
154-926B1994-02-21T10:303.7191-42.9084154-926B-18H-4,81-84164.310184.02000006456.9655172.4282618271.0700000002.7979431103.66479358179.7135644053.3823769624.972321720.517.430.1317.690.2217.560.18351.539.80.3118980002500001.0272432.9600563396.9082398412.7882308452.9328729468.67979628.5977891818.5780709618.5868066048.6089362518.6177996670.0000000.0000000.0000000.0000000.0000000.0284072750.0275865810.0279593540.0288641860.0292375760.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0146486977.9727825937.9914828748.0379397648.055760796384.1728418271.7245281320.9280633448.4778005502.7965436-0.040182485-0.071559539-0.056396186-0.024087854-0.0079210240.5335639930.1077103890.2968966190.7751169981.0051169230.085473875-0.135176777-0.0347143580.2057200200.306546587
154-926B1994-02-21T10:303.7191-42.9084154-926B-18H-5,16-19165.160184.87000006504.6470592.4392127581.0300000002.7952290593.65346837180.5173214520.2078514624.970450800.518.180.1918.120.2418.150.22351.539.80.3118970002500001.0272432.5743361395.7923495412.4562079452.8205910468.31328258.5978108838.5780729148.5867909878.6093124158.6184003350.0000000.0000000.0000000.0000000.0000000.0284165470.0275949320.0279467260.0288748950.0292732730.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0811138968.0416010048.0591247648.1029490288.119638504320.6756480225.7550986267.6527945375.5387872422.00077830.021326006-0.0101628960.0051681910.0375847750.052847498-0.284005474-0.725512912-0.521744542-0.0491086160.1316815730.138957551-0.0642901150.0280806890.2506722210.342696161
154-926B1994-02-21T10:303.7191-42.9084154-926B-18H-5,125.5-128.5166.255185.96500006563.4767442.2719621700.7200000003.1631086243.63949551383.1336539792.3972399226.355223490.517.810.0917.690.1917.750.14351.539.80.3118960002500001.0272432.5881529396.6089460412.9413585452.2397008468.77742618.5817941178.5624492988.5711070068.5931082808.6023430160.0000000.0000000.0000000.0000000.0000000.0274567970.0266981940.0270305100.0278876270.0282366060.0000010.0000010.0000010.0000010.0000020.0000000.0000000.0000000.0000000.0000008.0206223947.9814583797.9993713498.0420724548.058864017378.1294294266.5964479316.3028118439.9149627495.5839091-0.035699820-0.065606876-0.050750356-0.020425904-0.0050121670.4749414240.0632750440.2479915540.7045835070.9099560660.3102688480.1224066330.2060823420.4135712200.499867586
154-926C1994-02-25T19:003.7188-42.9084154-926C-18H-4,56-59167.060186.38436786588.4252872.3954090330.8600000003.0414606153.63356996974.6628868553.9288046025.924126380.518.030.1218.350.2218.190.17351.539.80.3118950002500001.0272432.5975691396.6515214412.7384034452.5841880468.99470568.5867707438.5670585238.5758704898.5980543588.6075794010.0000000.0000000.0000000.0000000.0000000.0277462640.0269613500.0273060800.0281922850.0285520550.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0737838038.0346981118.0525428158.0946241988.112456259327.7560826232.6199911273.6055651382.4194026428.29233860.013731163-0.017317487-0.0017999860.0291234820.044372919-0.182968500-0.613001796-0.4080622950.0395418750.2296855380.3971557470.2033214660.2893640020.5034746820.594314001
154-926C1994-02-25T19:003.7188-42.9084154-926C-18H-4,106-109167.560186.72000006604.6000002.3526008460.8900000002.9184858053.62972832872.7874644542.5674468925.468552540.517.310.0817.150.1817.230.13351.539.80.3118950002500001.0272432.4260268396.1649456412.4165996452.7682524469.39205008.5920392438.5724495228.5811844058.6036616738.6128329640.0000000.0000000.0000000.0000000.0000000.0280668230.0272690490.0276181420.0285224500.0289118320.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000007.9693907417.9281932637.9465561627.9918882108.009671786434.2323672310.1813173363.5651515505.8078182567.8685522-0.083055779-0.113350786-0.098738077-0.067322619-0.0526252401.1023568670.6584544050.8411748101.3733579121.6083139540.4520526290.2497251070.3389885220.5623564080.659847294
154-926C1994-02-25T19:003.7188-42.9084154-926C-18H-5,21-24168.210187.37000006632.5217392.3595696210.8400000002.8010777873.62309670773.6106149212.1436217125.017523800.517.500.1117.710.1917.600.15351.539.80.3118940002500001.0272432.5606766395.4057004412.3543857452.8067564469.25562618.5972649188.5776139168.5863948108.6086110588.6182801610.0000000.0000000.0000000.0000000.0000000.0283829650.0275934230.0279303830.0288390160.0292207400.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0188120307.9792608597.9970634728.0401493598.058397280378.8017451269.4586098316.6591533440.6956852493.1558612-0.036167168-0.066590770-0.051687082-0.020764740-0.0050793280.4810275790.0657002630.2529659630.7127257290.9177261760.5246635010.3045914340.4029476760.6461200050.748409438
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-2,7.5-9169.575189.07000006720.5000002.2684912480.994043604
154-926C1994-02-25T19:003.7188-42.9084154-926C-18H-5,116-119169.160189.68029416772.3702422.3665383950.6200000003.0739054303.58988251976.7189051033.0067996026.076234140.517.430.1117.520.2017.480.15351.539.80.3118920002500001.0272432.6829820396.8281395412.9900366451.9060926468.48363238.5850138338.5657277458.5740994048.5962526628.6057824350.0000000.0000000.0000000.0000000.0000000.0276365990.0268644490.0271988670.0280692270.0284589900.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000007.9926612907.9519150977.9703496508.0148506848.033809873408.2739090291.1876041342.3948523474.5234277530.1446929-0.061908209-0.092759815-0.077792782-0.046214949-0.0306637460.8235790920.3937383300.5756166901.0809783351.3037475750.4976956130.2427320690.3536345320.6414919960.769348223
154-926C1994-02-25T19:003.7188-42.9084154-926C-18H-6,131-134170.810189.90235296787.5250542.5616640821.2500000003.0856867873.58628332084.4928110737.9797505626.128776490.517.990.1118.280.1518.130.13351.539.80.3118910002500001.0272432.2742499396.2114699412.5679591451.8212120467.63514648.5844906278.5653097148.5738729298.5958405798.6049606960.0000000.0000000.0000000.0000000.0000000.0276195090.0268296910.0271895080.0280494030.0284139630.0000010.0000010.0000010.0000010.0000010.0000000.0000000.0000000.0000000.0000008.0657768378.0295540548.0458641328.0858093378.100230388333.7485939234.0736688278.6450169388.7967254435.40488970.006223568-0.021795520-0.0077918710.0202883770.034171973-0.082993180-0.460762242-0.2853276250.1197612260.2946784550.3795995100.0372168030.1889791620.5713901480.745716381
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-1,111-112.5169.110190.09173916802.5701862.1505063850.740000000
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-2,67-68.5170.170190.35777786815.4920632.3336856010.890000000
154-926C1994-02-25T19:003.7188-42.9084154-926C-18H-6,41-44169.910190.42538466818.775824
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-2,111-112.5170.610190.58500006826.5151522.3212843900.695369872
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-3,31.5-33171.315192.32500006930.8571433.0900323083.55224344890.89217999133.6197511026.163717470.518.070.4017.281.1617.670.78351.539.80.3118880002500001.0272432.1205953395.5982336412.1984210452.0284172468.07332138.5840038418.5647305958.5733874448.5954857288.6053907220.0000000.0000000.0000000.0000000.0000000.0275893830.0268192970.0271587200.0280245140.0284139340.0000010.0000010.0000010.0000010.0000020.0000000.0000000.0000000.0000000.0000008.0125775317.8863215117.9469618238.0766091228.125804537390.2673392244.1677701299.3704883481.2213080580.5514495-0.043203844-0.160204594-0.0973906270.0111661510.0604701990.573915934-0.793377088-0.2056935551.3730250912.1919072900.451682982-0.751963530-0.2392597261.1582796291.891747887Single C. wuellerstorfii run for stable isotopes [B] = 4 ppb, large error, excluded from statistical analysis
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-3,116-117.5172.160193.17000006973.6000002.3222804881.151398557
154-926B1994-02-21T10:303.7191-42.9084154-926B-19H-4,2.5-4172.525193.53500006995.5000002.2296434640.912860475