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Wu, Jiawang; Liu, Zhifei; Yu, Xun (2022): Strontium and Nd isotope compositions of hydrothermally altered basaltic rocks in IODP Hole 368-U1502B (Dataset S4) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.946143, In: Wu, J et al. (2022): Geochemistry of IODP Hole U1502B at the South China Sea rifted margin [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.946146

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Published: 2022-07-08DOI registered: 2022-08-30

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Keyword(s):
Hydrothermal alteration; IODP Exp. 367/368; IODP Hole U1502B; Mid-ocean ridge basalt (MORB); plagioclase; South China Sea; Sr isotopes
Related to:
Wu, Jiawang; Liu, Zhifei; Yu, Xun (2021): Plagioclase-regulated hydrothermal alteration of basaltic rocks with implications for the South China Sea rifting. Chemical Geology, 585, 120569, https://doi.org/10.1016/j.chemgeo.2021.120569
Funding:
China Postdoctoral Science Foundation, grant/award no. 2018M640418
China Postdoctoral Science Foundation, grant/award no. 2019T120352
National Natural Science Foundation of China (NSFC), grant/award no. 41530964
National Natural Science Foundation of China (NSFC), grant/award no. 41806064
National Natural Science Foundation of China (NSFC), grant/award no. 41906051
Shanghai Association for Science and Technology (SAST), grant/award no. 20590780200: Shanghai Science and Technology Innovation Action Plan
Coverage:
Latitude: 18.464663 * Longitude: 116.230682
Date/Time Start: 2017-04-29T19:30:00 * Date/Time End: 2017-05-13T20:50:00
Minimum DEPTH, sediment/rock: 733.75 m * Maximum DEPTH, sediment/rock: 917.41 m
Event(s):
368-U1502B * Latitude: 18.464663 * Longitude: 116.230682 * Date/Time Start: 2017-04-29T19:30:00 * Date/Time End: 2017-05-13T20:50:00 * Elevation: -3763.6 m * Campaign: Exp368 * Basis: Joides Resolution * Method/Device: Core drilling (CDRILL) * Comment: Drill in casing to 723.7 mbsf
Comment:
a Six sample-types are distinguished (see Section 4); note that the fully altered samples and the breccia sample are taken as endmembers of the hydrothermal alteration and associated brecciation, respectively.
b Normalized to the NBS-SRM 987 value of 87Sr/86Sr = 0.710248 (Thirlwall, 1991), with 2SE internal errors in brackets; the 2SD external errors are <18 ppm; the 2σ uncertainties in 87Sr/86Sr from BHVO-2 and AGV-2 standards are 0.703467 ± 0.000010 (n=2) and 0.703959 ± 0.000015 (n=3), respectively.
c Normalized to the JNdi-1 value of 143Nd/144Nd = 0.512115 (Tanaka et al., 2000), with 2SE internal errors in brackets; εNd = [(143Nd/144Nd) measured / (143Nd/144Nd) CHUR – 1] × 104, while CHUR is 0.512638 (Jacobson and Wasserburg, 1980); the 2SD external errors are <19 ppm (i.e. <0.4 εNd-unit); the 2σ uncertainties in 143Nd/144Nd from BHVO-2 and AGV-2 standards are 0.512997 ± 0.000028 (n=2) and 0.512802 ± 0.000038 (n=3), respectively.
d Degree of alteration in natural hydrothermal system can be estimated (cf. Kawahata et al., 2001; Delacour et al., 2008): Sr isotope exchange = (εSrfrock – εSrirock) / (εSriwater – εSrirock), where the subscripts (water) and (rock) refer to the hydrothermal fluid and altered rock, respectively; and the superscripts (i) and (f) identify the initial and final values of Sr isotope ratios, respectively.
e Assuming the final equilibrium of Sr isotope, the water–rock interaction can be quantified by simple mass balance equations, respectively, for closed system (cf. Berndt et al., 1988; Kawahata et al., 2001) and for open system (cf. Albarède, 1995; Delacour et al., 2008); W/R ratio (close system) = (εSrirock – εSrfrock) / (εSrfrock – εSriwater) * (Srrock / Srwater); W/R ratio (open system) = ln [(εSrirock – εSrfrock) / (εSrfrock – εSriwater) +1] * (Srrock / Srwater); where W is the mass of hydrothermal fluid, R is the mass of rock being altered; εSrirock and εSrfrock is the initial and final isotopic ratio of rock, respectively; εSriwater and εSrfwater is the initial (i.e. seawater) and final isotopic ratio of fluid, respectively; note that εSrfrock is equal to εSrfwater; Srrock and Srwater is the Sr concentration of unaltered rock and of seawater, respectively. The values of εSrirock (87Sr/86Sr: 0.70309) and Srrock (Sr: 168 ppm) after the mean values of Site U1500 basalts (Yu and Liu, 2020) and SCS seafloor basalts (i.e. Sites U1431, U1433, and U1434; Zhang et al., 2018), and the values of εSrfwater (87Sr/86Sr: 0.70780; McArthur et al., 2012) and Srwater (Sr: 12 ppm; Antonelli et al., 2017) after the global seawater estimates of the late-Eocene age.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample code/labelSample labelWu, Jiawang
2DEPTH, sediment/rockDepth sedmWu, JiawangGeocode – mbsf
3Sample typeSamp typeWu, Jiawang
4StrontiumSrmg/kgWu, Jiawanggiven in ppm
5NeodymiumNdmg/kgWu, Jiawanggiven in ppm
6Strontium-87/Strontium-86 ratio87Sr/86SrWu, Jiawangb
7Strontium-87/Strontium-86 ratio, standard deviation87Sr/86Sr std dev±Wu, Jiawang2σ, b
8Neodymium-143/Neodymium-144 ratio143Nd/144NdWu, Jiawang
9Neodymium-143/Neodymium-144 ratio, standard deviation143Nd/144Nd std dev±Wu, Jiawang2σ, c
10ε-Neodymiumε-NdWu, Jiawangc
11ε-Neodymium, standard deviationε-Nd std dev±Wu, Jiawang
12Strontium isotope exchangeSr ex%Wu, Jiawangd
13Water/rock ratioW/R ratioWu, Jiawangclosed, e
14Water/rock ratioW/R ratioWu, Jiawangopen, e
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
401 data points

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