de.pangaea.dataset944390 und dataset PANGAEA
info@pangaea.de
https://www.pangaea.de/ information pointOfContact 2026-04-30T21:33:37Z https://doi.pangaea.de/10.1594/PANGAEA.944390 <gco:CharacterString>Determination of inorganic and organic pollutants in a dated sediment core of the Skagerrak (North Sea)</gco:CharacterString> 2022-05-19T13:21:08 publication https://doi.org/10.1594/PANGAEA.944390 Logemann, Anna Elisabeth
anna.logemann@studium.uni-hamburg.de
author Reininghaus, Mathias
mathias.reininghaus@haw-hamburg.de
author Schmidt, Maike M
maike.schmidt@hereon.de
author Ebeling, Anna
anna.ebeling@hereon.de
https://orcid.org/0000-0002-9449-5723 information author Zimmermann, Tristan
tristan.zimmermann@hereon.de
https://orcid.org/0000-0002-2302-7519 information author Wolschke, Hendrik
hendrik.wolschke@hereon.de
author Friedrich, Jana
jana.friedrich@hereon.de
http://www.hzg.de/institute/coastal_research/structure/biogeochemistry_in_coastal_seas/ecosystem_and_cycles/staff/031731/index_0031731.html.de information author Brockmeyer, Berit
berit.brockmeyer@bsh.de
author Pröfrock, Daniel
daniel.proefrock@hereon.de
author Witt, Gesine
gesine.witt@haw-hamburg.de
author PANGAEA
info@pangaea.de
https://www.pangaea.de/ information publisher tableDigital We investigated 90 contaminants covering inorganic and organic pollutants analyzed in a set of sediment cores taken in the North Sea (Skagerrak). The cores were taken by the German Federal Maritime and Hydrographic Agency (BSH) in August 2017 on the RV CelticExplorer (Cruise CE17013a) using a multi corer (MUC, Oktopus, Kiel, Germany) at 57° 49.8 N and 7° 59.9 E at 520 m water depth. Samples were radiometrically dated and analyzed for the mass fractions of eight elements, as well as Pb isotope ratios by (MC) ICP-MS. Analysis of 61 HOCs was carried out using accelerated solvent extraction followed by GC–MS/MS analysis. Determination of 21 PFAS was carried out following DIN 38414-14, 2011, using LC-MS/MS. Furthermore, concentrations of 12 PAHs and 7 PCBs in porewaters were determined using equilibrium passive sampling and GC-MS analysis. Determined mass fractions decreased towards more recent deposited sediment for most analyzed contaminants. These trends could be linked to the time of introductions of restrictions and bans. Therefore, our results confirm, amongst possible other factors, the effectiveness of environmental legislation by revealing a successive change in contamination levels over the decades. completed Logemann, Anna Elisabeth
anna.logemann@studium.uni-hamburg.de
principalInvestigator copyright copyright CC-BY-4.0: Creative Commons Attribution 4.0 International textTable und geoscientificInformation 7.9977 7.9977 57.8298 57.8298 2017-08-23T11:26:00 2017-08-23T11:26:00 0.01 0.49 DEPTH, sediment/rock physicalMeasurement m m Age physicalMeasurement a AD/CE a AD/CE Age, uncertainty physicalMeasurement ± ± AGE physicalMeasurement ka BP ka BP Chromium physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 2.3 Milligram per kilogram, limit of quantification: 6.2 Milligram per kilogram mg/kg mg/kg Chromium, uncertainty physicalMeasurement ± ± Nickel physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 0.6 Milligram per kilogram, limit of quantification: 1 Milligram per kilogram mg/kg mg/kg Nickel, uncertainty physicalMeasurement ± ± Copper physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 1 Milligram per kilogram, limit of quantification: 3 Milligram per kilogram mg/kg mg/kg Copper, uncertainty physicalMeasurement ± ± Zinc physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 18 Milligram per kilogram, limit of quantification: 59 Milligram per kilogram mg/kg mg/kg Zinc, uncertainty physicalMeasurement ± ± Cadmium physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 0.019 Milligram per kilogram, limit of quantification: 0.062 Milligram per kilogram mg/kg mg/kg Cadmium, uncertainty physicalMeasurement ± ± Lead physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 1.6 Milligram per kilogram, limit of quantification: 4.1 Milligram per kilogram mg/kg mg/kg Lead, uncertainty physicalMeasurement ± ± Arsenic physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 0.71 Milligram per kilogram, limit of quantification: 2.4 Milligram per kilogram mg/kg mg/kg Arsenic, uncertainty physicalMeasurement ± ± Titanium physicalMeasurement Element analysis grain size fraction <20 microns via ICP-MS (total digest); measured in sediment, total, limit of detection: 80 Milligram per kilogram, limit of quantification: 260 Milligram per kilogram mg/kg mg/kg Titanium, uncertainty physicalMeasurement ± ± Lead-206/Lead-204 ratio thematicClassification Multi-collector ICP-MS (MC-ICP-MS), Nu Plasma II; measured in sediment, total Lead-206/Lead-204 ratio, uncertainty physicalMeasurement ± ± Lead-208/Lead-204 ratio thematicClassification Multi-collector ICP-MS (MC-ICP-MS), Nu Plasma II; measured in sediment, total Lead-208/Lead-204 ratio, uncertainty physicalMeasurement ± ± Lead-208/Lead-206 ratio thematicClassification Multi-collector ICP-MS (MC-ICP-MS), Nu Plasma II; measured in sediment, total Lead-208/Lead-206 ratio, uncertainty physicalMeasurement ± ± Lead-207/Lead-206 ratio thematicClassification Multi-collector ICP-MS (MC-ICP-MS), Nu Plasma II; measured in sediment, total Lead-207/Lead-206 ratio, uncertainty physicalMeasurement ± ± Lead-207/Lead-204 ratio thematicClassification Multi-collector ICP-MS (MC-ICP-MS), Nu Plasma II; measured in sediment, total Lead-207/Lead-204 ratio, uncertainty physicalMeasurement ± ± Carbon, organic, total physicalMeasurement Carbon and nitrogen and sulfur (CNS) element analyzer, Elementar, Vario EL; measured in sediment, total. The TOC analysis was carried out with a VarioEL (Elementar, Germany) in CN mode at 950 degC. The dried and homogenized samples were weighted in silver capsules, acidified with 200 microL of 2 M HCl (32%) and placed in an oven for 3 h at 110 degC to remove the inorganic carbon. % % 1,2,8-Trimethylphenanthrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.012 Nanogram per gram, limit of quantification: 0.037 Nanogram per gram ng/g ng/g 1-Methylpyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.35 Nanogram per gram ng/g ng/g 5-Methylchrysene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.036 Nanogram per gram, limit of quantification: 0.11 Nanogram per gram ng/g ng/g Dimethylated Naphthalenes, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.017 Nanogram per gram, limit of quantification: 0.043 Nanogram per gram ng/g ng/g Trimethylated Naphthalenes, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.029 Nanogram per gram, limit of quantification: 0.075 Nanogram per gram ng/g ng/g Methylated Phenantrenes, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.029 Nanogram per gram, limit of quantification: 0.074 Nanogram per gram ng/g ng/g Dimethylated Phenantrenes, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.052 Nanogram per gram, limit of quantification: 0.132 Nanogram per gram ng/g ng/g Trimethylated Phenantrenes, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; sum, measured in sediment, total, limit of detection: 0.012 Nanogram per gram, limit of quantification: 0.03 Nanogram per gram ng/g ng/g Hexachlorobenzene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.01 Nanogram per gram, limit of quantification: 0.03 Nanogram per gram ng/g ng/g alpha-Hexachlorocyclohexane (Lindane), per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0067 Nanogram per gram, limit of quantification: 0.02 Nanogram per gram ng/g ng/g beta-Hexachlorocyclohexane, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.014 Nanogram per gram, limit of quantification: 0.041 Nanogram per gram ng/g ng/g gamma-Hexachlorocyclohexane (Lindane), per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.012 Nanogram per gram, limit of quantification: 0.035 Nanogram per gram ng/g ng/g Dieldrin, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.026 Nanogram per gram, limit of quantification: 0.08 Nanogram per gram ng/g ng/g 1,1-Dichloro-2,2-bis-(p-chlorophenyl)ethene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.011 Nanogram per gram, limit of quantification: 0.033 Nanogram per gram ng/g ng/g 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethane, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.015 Nanogram per gram, limit of quantification: 0.046 Nanogram per gram ng/g ng/g 1,1,1-Trichloro-2,2-bis-(p-chlorophenyl)-ethane, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0078 Nanogram per gram, limit of quantification: 0.024 Nanogram per gram ng/g ng/g 2,4,4'-Trichlorobiphenyl/2,4',5-Trichlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.016 Nanogram per gram, limit of quantification: 0.05 Nanogram per gram ng/g ng/g 2,2',5,5'-Tetrachlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.016 Nanogram per gram, limit of quantification: 0.048 Nanogram per gram ng/g ng/g 2,2',4,5,5'-Pentachlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.012 Nanogram per gram, limit of quantification: 0.038 Nanogram per gram ng/g ng/g 2,3',4,4',5-Pentachlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.011 Nanogram per gram, limit of quantification: 0.034 Nanogram per gram ng/g ng/g 2,2',4,4',5,5'-Hexachlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.013 Nanogram per gram, limit of quantification: 0.039 Nanogram per gram ng/g ng/g 2,2',3,4,4',5'-Hexachlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.011 Nanogram per gram, limit of quantification: 0.034 Nanogram per gram ng/g ng/g 2,2',3,4,4',5,5'-Heptachlorobiphenyl, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.016 Nanogram per gram, limit of quantification: 0.048 Nanogram per gram ng/g ng/g 2,4,4'-tribromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0041 Nanogram per gram, limit of quantification: 0.013 Nanogram per gram ng/g ng/g 2,2',4,4'-tetrabromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0027 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g 2,3',4,4'-tetrabromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0034 Nanogram per gram, limit of quantification: 0.01 Nanogram per gram ng/g ng/g 2,2',4,4',6-pentabromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0059 Nanogram per gram, limit of quantification: 0.018 Nanogram per gram ng/g ng/g 2,2',4,4',5-pentabromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0053 Nanogram per gram, limit of quantification: 0.016 Nanogram per gram ng/g ng/g 2,2',4,4',5,6'-hexabromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0055 Nanogram per gram, limit of quantification: 0.017 Nanogram per gram ng/g ng/g 2,2',4,4',5,5'-hexabromodiphenyl ether, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.0059 Nanogram per gram, limit of quantification: 0.018 Nanogram per gram ng/g ng/g Naphthalene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.13 Nanogram per gram, limit of quantification: 0.41 Nanogram per gram ng/g ng/g Acenaphthylene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.32 Nanogram per gram ng/g ng/g Acenaphthene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.069 Nanogram per gram, limit of quantification: 0.21 Nanogram per gram ng/g ng/g Fluorene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.077 Nanogram per gram, limit of quantification: 0.23 Nanogram per gram ng/g ng/g Dibenzothiophene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.34 Nanogram per gram ng/g ng/g Phenanthrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.32 Nanogram per gram ng/g ng/g Anthracene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.34 Nanogram per gram ng/g ng/g Fluoranthene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.034 Nanogram per gram, limit of quantification: 0.1 Nanogram per gram ng/g ng/g Pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.065 Nanogram per gram, limit of quantification: 0.2 Nanogram per gram ng/g ng/g 11H-Benzo(a)fluorene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.12 Nanogram per gram, limit of quantification: 0.36 Nanogram per gram ng/g ng/g Cyclopenta(c,d)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.036 Nanogram per gram, limit of quantification: 0.11 Nanogram per gram ng/g ng/g Benz(a)anthracene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.34 Nanogram per gram ng/g ng/g Chrysene/Triphenylene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.39 Nanogram per gram, limit of quantification: 1.2 Nanogram per gram ng/g ng/g Benzo(b)fluoranthene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.32 Nanogram per gram ng/g ng/g Benzo(k)fluoranthene/Benzo(j)fluoranthene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.2 Nanogram per gram, limit of quantification: 0.61 Nanogram per gram ng/g ng/g Benzo(e)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.11 Nanogram per gram, limit of quantification: 0.34 Nanogram per gram ng/g ng/g Benzo(a)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.2 Nanogram per gram, limit of quantification: 0.6 Nanogram per gram ng/g ng/g Perylene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.13 Nanogram per gram, limit of quantification: 0.4 Nanogram per gram ng/g ng/g Indeno(1,2,3-cd)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.099 Nanogram per gram, limit of quantification: 0.3 Nanogram per gram ng/g ng/g Dibenz(a,h)anthracene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.16 Nanogram per gram, limit of quantification: 0.48 Nanogram per gram ng/g ng/g Benzo(g,h,i)perylene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.093 Nanogram per gram, limit of quantification: 0.28 Nanogram per gram ng/g ng/g Indeno(1,2,3-cd)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.04 Nanogram per gram, limit of quantification: 0.12 Nanogram per gram ng/g ng/g Dibenzo(a,e)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.043 Nanogram per gram, limit of quantification: 0.13 Nanogram per gram ng/g ng/g Dibenzo(a,i)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.039 Nanogram per gram, limit of quantification: 0.12 Nanogram per gram ng/g ng/g Dibenzo(a,h)pyrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.024 Nanogram per gram, limit of quantification: 0.072 Nanogram per gram ng/g ng/g 2-Methylnaphthalene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.026 Nanogram per gram, limit of quantification: 0.078 Nanogram per gram ng/g ng/g 1-Methylnaphthalene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.12 Nanogram per gram, limit of quantification: 0.38 Nanogram per gram ng/g ng/g 2,6-Dimethylnaphthalene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.044 Nanogram per gram, limit of quantification: 0.13 Nanogram per gram ng/g ng/g 2,3,5-Trimethylnaphthalene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.098 Nanogram per gram, limit of quantification: 0.3 Nanogram per gram ng/g ng/g 2-Methylphenanthrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.088 Nanogram per gram, limit of quantification: 0.27 Nanogram per gram ng/g ng/g 3,6-Dimethylphenanthrene, per unit sediment mass physicalMeasurement GC–MS/MS system (7890B GC-System, 7000C GC/MS Triple Quad, Agilent Technologies) coupled to an Gerstel MPS robotic pro autosampler with Gerstel KAS 4 injector; measured in sediment, total, limit of detection: 0.093 Nanogram per gram, limit of quantification: 0.28 Nanogram per gram ng/g ng/g Perfluorodecanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorooctane sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorononanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorooctanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorohexane sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluoroheptanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorohexanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorobutane sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluoropentanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorobutanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluoroheptane sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g 6:2 fluorotelomer sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g 4:2 fluorotelomer sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g 2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g 8:2 fluorotelomer sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluoropentane sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Henicosalfluorodecane sulfonic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluoroundecanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorododecanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorotridecanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Perfluorotetradecanoic acid, per unit sediment mass physicalMeasurement LC–MS/MS system (LC: Agilent 1260 pump, Agilent 1200 oven, MS: Sciex QTrap 5500, Agilent Technologies and Sciex); measured in sediment, total, limit of detection: 0.025 Nanogram per gram, limit of quantification: 0.0083 Nanogram per gram ng/g ng/g Fluorene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Phenanthrene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Anthracene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Fluoranthene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Pyrene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Benz(a)anthracene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Chrysene/Triphenylene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Benzo(k)fluoranthene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Benzo(a)pyrene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Indeno(1,2,3-cd)pyrene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Dibenz(a,h)anthracene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l Benzo(g,h,i)perylene physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l 2,4,4'-Trichlorobiphenyl/2,4',5-Trichlorobiphenyl, per unit sediment mass physicalMeasurement measured in porewater ng/g ng/g 2,2',5,5'-Tetrachlorobiphenyl physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l 2,2',4,5,5'-Pentachlorobiphenyl physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l 2,3',4,4',5-Pentachlorobiphenyl physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l 2,2',4,4',5,5'-Hexachlorobiphenyl physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l 2,2',3,4,4',5'-Hexachlorobiphenyl physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l 2,2',3,4,4',5,5'-Heptachlorobiphenyl physicalMeasurement Gas chromatography/mass spectrometry system (GC 7890B/ MS 5977A, Agilent Technologies); measured in porewater pg/l pg/l text/tab-separated-values unknown https://doi.pangaea.de/10.1594/PANGAEA.944390?format=textfile download dataset The data set was checked for completeness, correctness, and consistency of metainformation. Validity of used methods was checked and - if applicable - precision and range of data. EVENT LABEL: CE17013_40 * LATITUDE: 57.829800 * LONGITUDE: 7.997700 * DATE/TIME: 2017-08-23T11:26:00 * ELEVATION: -520.0 m * CAMPAIGN: CE17013 * BASIS: Celtic Explorer * METHOD/DEVICE: MultiCorer 2017-08-23T11:26:00 Related to <gco:CharacterString>Assessing the chemical anthropocene – Development of the legacy pollution fingerprint in the North Sea during the last century</gco:CharacterString> 2022-01-01 publication https://doi.org/10.1016/j.envpol.2022.119040 Logemann, Anna Elisabeth
anna.logemann@studium.uni-hamburg.de
author Reininghaus, Mathias
mathias.reininghaus@haw-hamburg.de
author Schmidt, Maike M
maike.schmidt@hereon.de
author Ebeling, Anna
anna.ebeling@hereon.de
https://orcid.org/0000-0002-9449-5723 information author Zimmermann, Tristan
tristan.zimmermann@hereon.de
https://orcid.org/0000-0002-2302-7519 information author Wolschke, Hendrik
hendrik.wolschke@hereon.de
author Friedrich, Jana
jana.friedrich@hereon.de
http://www.hzg.de/institute/coastal_research/structure/biogeochemistry_in_coastal_seas/ecosystem_and_cycles/staff/031731/index_0031731.html.de information author Brockmeyer, Berit
berit.brockmeyer@bsh.de
author Pröfrock, Daniel
daniel.proefrock@hereon.de
author Witt, Gesine
gesine.witt@haw-hamburg.de
author documentDigital Environmental Pollution 302 119040