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<md:year>2005</md:year>
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<md:orcid>0000-0001-7190-9391</md:orcid>
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<md:title>Ferrozine - A new spectrophotometric reagent for iron</md:title>
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<md:volume>42</md:volume>
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<md:firstName>Eric</md:firstName>
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<md:lastName>van Cappellen</md:lastName>
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<md:eMail>pvc@geo.uu.nl</md:eMail>
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<md:year>2000</md:year>
<md:title>The ferrozine method revisited: Fe(II)/Fe(III) determination in natural waters</md:title>
<md:type id="ref111909.reftype1">journal article</md:type>
<md:source id="ref111909.journal1314" relatedTermIds="33971" type="journal">Applied Geochemistry</md:source>
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<md:URI>http://purl.obolibrary.org/obo/CHEBI_17632</md:URI>
</md:term>
<md:term id="col6.ds14374068.param756.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col6.ds14374068.method14609">
<md:name>Calculated from difference of NOx and NO2</md:name>
</md:method>
<md:PI id="col6.ds14374068.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>[NO3]- [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="###0" id="col7.ds14374069" source="data" type="numeric">
<md:parameter id="col7.ds14374069.param52">
<md:name>Ammonium</md:name>
<md:shortName>[NH4]+</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="8" fragment="1" id="col7.ds14374069.param52.term1073173" semanticURI="http://purl.obolibrary.org/obo/CHEBI_28938" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>ammonium</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_28938</md:URI>
</md:term>
<md:term id="col7.ds14374069.param52.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col7.ds14374069.method13107">
<md:name>SEAL Analytical, continuous flow analyser QuAAtro</md:name>
</md:method>
<md:PI id="col7.ds14374069.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>[NH4]+ [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="###0" id="col8.ds14374070" source="data" type="numeric">
<md:parameter id="col8.ds14374070.param758">
<md:name>Phosphate</md:name>
<md:shortName>[PO4]3-</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col8.ds14374070.param758.term1073484" semanticURI="http://purl.obolibrary.org/obo/CHEBI_26020" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>phosphate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_26020</md:URI>
</md:term>
<md:term id="col8.ds14374070.param758.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col8.ds14374070.method13107">
<md:name>SEAL Analytical, continuous flow analyser QuAAtro</md:name>
</md:method>
<md:PI id="col8.ds14374070.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>[PO4]3- [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="##0" id="col9.ds14374071" source="data" type="numeric">
<md:parameter id="col9.ds14374071.param755">
<md:name>Silicate</md:name>
<md:shortName>Si(OH)4</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col9.ds14374071.param755.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col9.ds14374071.method13107">
<md:name>SEAL Analytical, continuous flow analyser QuAAtro</md:name>
</md:method>
<md:PI id="col9.ds14374071.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Si(OH)4 [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="###0.0" id="col10.ds14374072" source="data" type="numeric">
<md:parameter id="col10.ds14374072.param54">
<md:name>Chloride</md:name>
<md:shortName>Cl-</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="8" fragment="1" id="col10.ds14374072.param54.term1073174" semanticURI="http://purl.obolibrary.org/obo/CHEBI_17996" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>chloride</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_17996</md:URI>
</md:term>
<md:term id="col10.ds14374072.param54.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col10.ds14374072.method9220">
<md:name>Ion chromatograph, Metrohm,  Compact IC 761</md:name>
<md:term id="col10.ds14374072.method9220.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
</md:method>
<md:PI id="col10.ds14374072.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Cl- [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="##0.00" id="col11.ds14374073" source="data" type="numeric">
<md:parameter id="col11.ds14374073.param50">
<md:name>Sulfate</md:name>
<md:shortName>[SO4]2-</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col11.ds14374073.param50.term1073219" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16189" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>sulfate</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16189</md:URI>
</md:term>
<md:term id="col11.ds14374073.param50.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col11.ds14374073.method9220">
<md:name>Ion chromatograph, Metrohm,  Compact IC 761</md:name>
<md:term id="col11.ds14374073.method9220.term68027" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>Chromatographs &amp; spectrometers</md:name>
</md:term>
</md:method>
<md:PI id="col11.ds14374073.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>[SO4]2- [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="12" format="##0" id="col12.ds14374074" source="data" type="numeric">
<md:parameter id="col12.ds14374074.param63">
<md:name>Iron</md:name>
<md:shortName>Fe</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col12.ds14374074.param63.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col12.ds14374074.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col12.ds14374074.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Fe [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="13" format="#0" id="col13.ds14374075" source="data" type="numeric">
<md:parameter id="col13.ds14374075.param15060">
<md:name>Arsenic</md:name>
<md:shortName>As</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col13.ds14374075.param15060.term40847" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>arsenic</md:name>
</md:term>
<md:term id="col13.ds14374075.param15060.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col13.ds14374075.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col13.ds14374075.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>As [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="14" format="##0.0" id="col14.ds14374076" source="data" type="numeric">
<md:parameter id="col14.ds14374076.param105290">
<md:name>Calcium</md:name>
<md:shortName>Ca</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col14.ds14374076.param105290.term38520" semanticURI="http://purl.obolibrary.org/obo/CHEBI_22984" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>calcium</md:name>
<md:optionalName>Ca</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:22984</md:URI>
</md:term>
<md:term id="col14.ds14374076.param105290.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col14.ds14374076.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col14.ds14374076.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Ca [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="15" format="#0" id="col15.ds14374077" source="data" type="numeric">
<md:parameter id="col15.ds14374077.param1874">
<md:name>Copper</md:name>
<md:shortName>Cu</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col15.ds14374077.param1874.term40561" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>copper</md:name>
</md:term>
<md:term id="col15.ds14374077.param1874.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col15.ds14374077.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col15.ds14374077.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Cu [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="16" format="##0" id="col16.ds14374078" source="data" type="numeric">
<md:parameter id="col16.ds14374078.param60">
<md:name>Magnesium</md:name>
<md:shortName>Mg</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col16.ds14374078.param60.term40665" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>magnesium</md:name>
</md:term>
<md:term id="col16.ds14374078.param60.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col16.ds14374078.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col16.ds14374078.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Mg [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="17" format="#0" id="col17.ds14374079" source="data" type="numeric">
<md:parameter id="col17.ds14374079.param64">
<md:name>Manganese</md:name>
<md:shortName>Mn</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col17.ds14374079.param64.term38521" semanticURI="http://purl.obolibrary.org/obo/CHEBI_18291" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>manganese</md:name>
<md:optionalName>Mn</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18291</md:URI>
</md:term>
<md:term id="col17.ds14374079.param64.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col17.ds14374079.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col17.ds14374079.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Mn [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="18" format="#0" id="col18.ds14374080" source="data" type="numeric">
<md:parameter id="col18.ds14374080.param18452">
<md:name>Molybdenum</md:name>
<md:shortName>Mo</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="10" fragment="1" id="col18.ds14374080.param18452.term40560" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>molybdenum</md:name>
</md:term>
<md:term id="col18.ds14374080.param18452.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col18.ds14374080.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col18.ds14374080.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Mo [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="19" format="#0" id="col19.ds14374081" source="data" type="numeric">
<md:parameter id="col19.ds14374081.param722">
<md:name>Barium</md:name>
<md:shortName>Ba</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col19.ds14374081.param722.term40966" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>barium</md:name>
</md:term>
<md:term id="col19.ds14374081.param722.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col19.ds14374081.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col19.ds14374081.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Ba [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="20" format="##0" id="col20.ds14374082" source="data" type="numeric">
<md:parameter id="col20.ds14374082.param62">
<md:name>Strontium</md:name>
<md:shortName>Sr</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col20.ds14374082.param62.term40663" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>strontium</md:name>
</md:term>
<md:term id="col20.ds14374082.param62.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col20.ds14374082.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col20.ds14374082.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Sr [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="21" format="#0.0" id="col21.ds14374083" source="data" type="numeric">
<md:parameter id="col21.ds14374083.param57">
<md:name>Potassium</md:name>
<md:shortName>K</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col21.ds14374083.param57.term40134" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>potassium</md:name>
<md:optionalName>K</md:optionalName>
</md:term>
<md:term id="col21.ds14374083.param57.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col21.ds14374083.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col21.ds14374083.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>K [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="22" format="##0" id="col22.ds14374084" source="data" type="numeric">
<md:parameter id="col22.ds14374084.param2212">
<md:name>Lithium</md:name>
<md:shortName>Li</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col22.ds14374084.param2212.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col22.ds14374084.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col22.ds14374084.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Li [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="23" format="###0" id="col23.ds14374085" source="data" type="numeric">
<md:parameter id="col23.ds14374085.param49320">
<md:name>Silicon</md:name>
<md:shortName>Si</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col23.ds14374085.param49320.term38478" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27573" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>silicon</md:name>
<md:optionalName>Si</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27573</md:URI>
</md:term>
<md:term id="col23.ds14374085.param49320.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col23.ds14374085.method13587">
<md:name>ICP-OES, Thermo Fisher iCAP 7400</md:name>
</md:method>
<md:PI id="col23.ds14374085.pi56517">
<md:lastName>Friedrich</md:lastName>
<md:firstName>Michael W</md:firstName>
<md:eMail>michael.friedrich@uni-bremen.de</md:eMail>
<md:orcid>0000-0002-8055-3232</md:orcid>
</md:PI>
<md:caption>Si [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="24" format="###0" id="col24.ds14374086" source="data" type="numeric">
<md:parameter id="col24.ds14374086.param92377">
<md:name>Phosphorus</md:name>
<md:shortName>P</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="10" fragment="1" id="col24.ds14374086.param92377.term39985" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>phosphorus</md:name>
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