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Matsuoka, Atsushi; Juhls, Bennet; Bécu, Guislain; Oziel, Laurent; Leymarie, Edouard; Lizotte, Martine; Ferland, Joannie; Béguin, Marine; Laberge-Carignan, Audrey; Guilmette, Caroline; Maury, Juliette; Hilborn, Andrea; Tisserand, Lucas; Devred, Emmanuel; Doxaran, David; Bossé-Demers, Thomas; Gonçalves-Araujo, Rafael; Stedmon, Colin A; Babin, Marcel (2021): Fluorescent dissolved organic matter (FDOM) intensity (Parafac components and FDOM indices) in the surface water of the Mackenzie Delta Region during 4 expeditions from spring to fall in 2019 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.937582, In: Juhls, Bennet; Lizotte, Martine; Matsuoka, Atsushi; Mével, Gaëlle; Bécu, Guislain; Overduin, Pier Paul; Devred, Emmanuel; Doxaran, David; Ferland, Joannie; Forget, Marie-Hélène; Hilborn, Andrea; Leymarie, Edouard; Maury, Juliette; Oziel, Laurent; Tisserand, Lucas; Miles, Dillon; Anikina, David Obie James; Guilmette, Caroline; Béguin, Marine; Couture, Raoul-Marie; Bossé-Demers, Thomas; Laberge-Carignan, Audrey; Chaillou, Gwénaëlle; Bélanger, Simon; Bruyant, Flavienne; Babin, Marcel (2021): Hydrographical, biogeochemical and biooptical water properties in the Mackenzie Delta Region during 4 expeditions from spring to fall in 2019 [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.937587

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Abstract:
Fluorescent dissolved organic matter intensity was measured with an Aqualog®. Measurements were corrected for inner-filter effects and for the Raman and Rayleigh scattering (Murphy et al., 2013; doi:10.1039/C3AY41160E). The different fluorescent components of DOM were isolated from combined signal by PARAFAC modeling using the “drEEM Toolbox” and following the recommendation of Murphy et al. (2013; doi:10.1039/C3AY41160E). The DOM components derived from PARAFAC modeling were compared with PARAFAC components from other studies through the OpenFluor database (Murphy et al., 2014; doi:10.1039/C3AY41935E). The coble-peaks indicate major fluorescent components (Coble 1996; doi:10.1016/0304-4203(95)00062-3) in marine FDOM EEMs (Excitation-Emission-Matrix). Peaks T represents protein-like compounds (tyrosine and tryptophane), peaks A and C are indicators of humic-like components whereas peak M was associated to marine humic-like fluorescence. The fluorescence index (FI) is calculated as the ratio of fluorescence at emission 450 nm and 500 nm, at fixed excitation of 370 nm. The HIX index is the ratio of the areas of two spectral wavelength regions in the emission spectra for an excitation at 254 nm and it is obtained as: HIX = H∕L, where H is the area between 435 and 480 nm in the emission spectra and L is the area in the emission spectra between 300 and 345 nm (Zsolnay et al., 1999; doi:10.1016/S0045-6535(98)00166-0). The BIX index is obtained by calculating the ratio of the emission at 380 and 430 nm, excited at 310 nm: BIX = IEm380∕IEm430 (Huguet et al., 2009; doi:10.1016/j.orggeochem.2009.03.002).
Keyword(s):
biogeochemistry; Biooptics; Coastal waters; hydrographic data; Mackenzie
Related to:
Juhls, Bennet; Matsuoka, Atsushi; Lizotte, Martine; Mével, Gaëlle; Bécu, Guislain; Overduin, Pier Paul; El-Kassar, Jan; Devred, Emmanuel; Doxaran, David; Ferland, Joannie; Forget, Marie-Hélène; Hilborn, Andrea; Leymarie, Edouard; Maury, Juliette; Oziel, Laurent; Tisserand, Lucas; Babin, Marcel (accepted): Seasonal dynamics of dissolved organic matter of the Mackenzie Delta, Canadian Arctic waters: implications for ocean colour remote sensing.
Funding:
Horizon 2020 (H2020), grant/award no. 773421: NUNATARYUK, Permafrost thaw and the changing Arctic coast, science for socioeconomic adaptation
Coverage:
Median Latitude: 69.101251 * Median Longitude: -134.991317 * South-bound Latitude: 68.264050 * West-bound Longitude: -138.135120 * North-bound Latitude: 69.648520 * East-bound Longitude: -133.031410
Date/Time Start: 2019-04-20T15:34:00 * Date/Time End: 2019-09-08T12:00:00
Minimum DEPTH, water: 0.30 m * Maximum DEPTH, water: 1.66 m
Event(s):
NunaWP4Mackenzie19_1_STN0a (1_STN0a) * Latitude: 68.504830 * Longitude: -134.147960 * Date/Time: 2019-04-20T15:34:00 * Location: Mackenzie Delta, Canada * Method/Device: Multiple investigations (MULT)
NunaWP4Mackenzie19_1_STN0b (1_STN0b) * Latitude: 68.319030 * Longitude: -133.678190 * Date/Time: 2019-04-20T20:49:00 * Location: Mackenzie Delta, Canada * Method/Device: Multiple investigations (MULT)
NunaWP4Mackenzie19_1_STN01 (1_STN01) * Latitude: 68.318910 * Longitude: -133.677500 * Date/Time: 2019-04-23T19:48:00 * Location: Mackenzie Delta, Canada * Method/Device: Multiple investigations (MULT)
Comment:
Empty cells = NA
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventJuhls, Bennet
2Cruise/expeditionExpeditionJuhls, Bennet
3LATITUDELatitudeJuhls, BennetGeocode
4LONGITUDELongitudeJuhls, BennetGeocode
5DATE/TIMEDate/TimeJuhls, BennetGeocode
6Station labelStationJuhls, Bennet
7DEPTH, waterDepth watermJuhls, BennetGeocode
8Intensity fluorescent dissolved organic matter, component 1IFDOM C1RUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonPARAFAC-derived component
9Intensity fluorescent dissolved organic matter, component 2IFDOM C2RUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonPARAFAC-derived component
10Intensity fluorescent dissolved organic matter, component 3IFDOM C3RUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonPARAFAC-derived component
11Fluorescence, dissolved organic matter, A coble-peakFDOM A-peakRUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonEx:260, Em:380-460
12Fluorescence, dissolved organic matter, C coble-peakFDOM C-peakRUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonEx:350, Em:420-480
13Fluorescence, dissolved organic matter, M coble-peakFDOM M-peakRUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonEx:312, Em:380-420
14Fluorescence, dissolved organic matter, T coble-peakFDOM T-peakRUMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonEx:275, Em:340
15Fluorescence, dissolved organic matter, fluorescence indexfDOM FIMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonFI=Em450, 500/Ex370
16Fluorescence, dissolved organic matter, humification indexfDOM HIMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonHIX = H∕L (Zsolnay et al., 1999)
17Fluorescence, dissolved organic matter, biological indexfDOM BIMatsuoka, AtsushiFluorescence spectrometer, AquaLog, HORIBA JobinYvonBIX = IEm380/IEm430 (Huguet et al., 2009)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1702 data points

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