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Vasil'chuk, Yurij K; Belik, Anna D; Budantseva, Nadine A; Vasil'chuk, Alla Constantinovna; Vasil'chuk, Jessica Yurevna; Zavgordnyaya, Juliya A; Ginzburg, Alexander P; Bludushkina, Liubov (2021): Polycyclic aromatic Hydrocarbons (PAH) content in the peat of a palsa near Eletsky settlement (Bol'shezemel'skaya Tundra) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.937482

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Abstract:
The total content of polycyclic aromatic hydrocarbons (PAHs) in the peat of a palsa near Eletsky settlement, Vorkuta urban district, Komi Republic, varies from 11 to 360 ppb, with an average of 63 ppb. Heavy compounds, such as benzo(a)anthracene and benzofluoranthenes, are prevalent among PAHs. Benzo(a)anthracene decreases with depth, while benzofluoranthenes increases. The presence of PAHs in the peat is determined by three main factors: technogenic impact, wildfires, and biogeochemical soil processes. The prevalence of benzo(a)anthracene in the upper part of the palsa down to the bottom of the active layer suggests an anthropogenic impact (the influence of transport and domestic fuel combustion). Two sharp peaks of PAHs content (260 and 360 ppb) are observed; they coincide with a local increase of carbon isotope values, most likely resulting from wildfires. The minimums in PAHs content are presumably determined by the biogeochemical factor and the input of polyarenes generated by decomposition of plant residues.
Keyword(s):
PAHs; paleoenvironment; Palsa; peat; Vorkuta
Related to:
Budantseva, Nadine A; Chizhova, Julia Nikolaevna; Bludushkina, Liubov; Vasil'chuk, Yurij K (2017): Stable oxygen, hydrogen and carbon isotopes and the age of the palsa near Eletsky village, northeast of the Bolshezemelskaya tundra. Arktika i Antarktika (Arctic and Antarctic), 4, 38-56, https://doi.org/10.7256/2453-8922.2017.4.25087
Budantseva, Nadine A; Chizhova, Julia Nikolaevna; Vasil'chuk, Yurij K (2016): Reflection in the isotopic composition of the peat development phases of palsa landscapes of the Bolshezemelskaya tundra [in Russian]. Arktika i Antarktika (Arctic and Antarctic), 1, 124-138, https://doi.org/10.7256/2453-8922.2016.1.21420
Khaustov, A P; Redina, M M (2017): Geochemical markers based on concentration ratios of PAH in oils and oil-polluted areas. Geochemistry International, 55(1), 98-107, https://doi.org/10.1134/S0016702916120041
Vasil'chuk, Yurij K; Belik, Anna D; Budantseva, Nadine A; Gennadiev, Alexander N; Vasil'chuk, Alla Constantinovna; Vasil'chuk, Jessica Yurevna; Zavgordnyaya, Juliya A; Ginzburg, Alexander P; Bludushkina, Liubov (2021): Polycyclic Aromatic Hydrocarbons and Carbon Isotopes in a Palsa Peat (Bol'shezemel'skaya Tundra). Eurasian Soil Science, 54(7), 999-1006, https://doi.org/10.1134/S1064229321070139
Further details:
Belik, Anna D; Vasil'chuk, Yurij K; Gennadiev, Alexander N; Budantseva, Nadine A; Zhidkin, A P; Kovach, R G; Koshovskii, T S (2020): The Isotopic Composition of Carbon in Soil Lipids in the Oil and Gas Development Area in Volgograd Oblast, Russia. Eurasian Soil Science, 53(12), 1735-1742, https://doi.org/10.1134/S1064229320120030
Chizhova, Julia Nikolaevna; Vasil'chuk, Yurij K (2020): Use of stable water isotopes to identify water as a source for palsa ice core formation [in Russian]. Ice and Snow, 60(3), 395-408, https://doi.org/10.31857/S2076673420030047
Vasil'chuk, Yurij K; Belik, Anna D; Budantseva, Nadine A; Vasil'chuk, Jessica Yurevna; Gennadiev, Alexander N (2020): Carbon Isotope Signatures and Polyarenes in the Pedogenic Material of Ice Wedges of the Batagay Yedoma (Yakutia). Eurasian Soil Science, 53(2), 187-196, https://doi.org/10.1134/S1064229320020143
Vasil'chuk, Yurij K; Vasil'chuk, Alla Constantinovna; Budantseva, Nadine A; Chizhova, Julia Nikolaevna (2008): Palsa of frozen peat mires. Editor: Member of the Russian Academy of Natural Sciences, Professor Yurij K.Vasil'chuk. Moscow. Moscow University Press. [In Russian], 571
Vasil'chuk, Yurij K; Vasil'chuk, Alla Constantinovna; Budantseva, Nadine A; Chizhova, Julia Nikolaevna (2011): Palsas in the northern European Russia: the southern and northern limits of the areal and the modern dynamic [in Russian]. Engineering Geology, 2, 56-72
Vasil'chuk, Yurij K; Vasil'chuk, Alla Constantinovna; Budantseva, Nadine A; Sulerzhitsky, Leopold D; Chizhova, Julia Nikolaevna; Jungner, Höegne (2002): Radiocarbon age and Holocene dynamics of palsa in the Usa River valley. Doklady Earth Sciences, 4, 442-447
Vasil'chuk, Yurij K; Vasil'chuk, Alla Constantinovna; Jungner, Höegne; Budantseva, Nadine A; Chizhova, Julia N (2013): RADIOCARBON CHRONOLOGY OF HOLOCENE PALSA OF BOL'SHEZEMEL'SKAYA TUNDRA IN RUSSIAN NORTH. Geography, Environment, Sustainability, 6(3), 38-59, https://doi.org/10.24057/2071-9388-2013-6-3-38-59
Vasil'chuk, Yurij K; Vasil'chuk, Alla Constantinovna; Sulerzhitsky, Leopold D; Budantseva, Nadine A; Volkova, Ye M; Chizhova, Julia Nikolaevna (2003): Radiocarbon chronology of palsa in the Bol'shaya Zemlya tundra. Doklady Earth Sciences, 393(8), 1160-1164
Vasil'chuk, Yurij K; Vasil'chuk, Jessica Yurevna; Budantseva, Nadine A; Vasil'chuk, Alla Constantinovna; Belik, Anna D; Bludushkina, Liubov; Ginzburg, Alexander P; Krechetov, Pavel P; Terskaya, Elena V (2020): Major and trace elements, δ13C, and polycyclic aromatic hydrocarbons in the Late Pleistocene ice wedges: A case-study of Batagay yedoma, Central Yakutia. Applied Geochemistry, 120, 104669, https://doi.org/10.1016/j.apgeochem.2020.104669
Funding:
Russian Foundation for Basic Research, grant/award no. 18-05-60272: Arctic
Russian Science Foundation, grant/award no. 19-17-00126: Verification and validation of Late Pleistocene paleotemperature scenario based on the stable isotope data in syngenetic ice wedges in Siberia using independent paleoclimatic models
Coverage:
Latitude: 67.039292 * Longitude: 64.249392
Date/Time Start: 2019-09-01T00:00:00 * Date/Time End: 2019-09-30T00:00:00
Minimum DEPTH, sediment/rock: 0.00 m * Maximum DEPTH, sediment/rock: 1.44 m
Event(s):
Bolshezemelskaya_Tundra * Latitude: 67.039292 * Longitude: 64.249392 * Date/Time Start: 2019-09-01T00:00:00 * Date/Time End: 2019-09-30T00:00:00 * Location: Komi, Russia
Comment:
PAHs were analyzed by high performance liquid chromatography. The preparation of samples started from the extraction with dichloromethane (20 mL per 1 g dry peat). The resulting extract was filtered, evaporated, re-extracted with hexane, and purified using modified silica gel Diapak-C cartridges. The air-evaporation was performed to dryness. The purified extracts were also evaporated and re-extracted with acetonitrile. PAHs were analyzed in an Agilent 1260 at the Analytical center of the Faculty of Soil Science, Moscow State University.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1LocationLocationVasil'chuk, Yurij K
2Sample IDSample IDVasil'chuk, Yurij K
3DEPTH, sediment/rockDepth sedmVasil'chuk, Yurij KGeocode – from
4DEPTH, sediment/rockDepth sedmVasil'chuk, Yurij KGeocode – to
5Polycyclic aromatic hydrocarbonsPAHng/gVasil'chuk, Yurij KHigh performance liquid chromatography (HPLC) using an Agilent 1260 HPLC
6Phenanthrene/anthracene ratioPhenanthrene/anthraceneVasil'chuk, Yurij KCalculatedindicator ratio
7Fluoranthene/(Fluoranthene + Pyrene) ratioFluoranthene/(Fluoranthene + Pyrene)Vasil'chuk, Yurij KCalculatedFluoranthene/(fluoranthene + pyrene) ratio
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
84 data points

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