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Elling, Felix J; Hemingway, Jordon D; Kharbush, Jenan; Becker, Kevin W; Polik, Catherine Ann; Pearson, Ann (2021): Table S5, Abundance of crenarchaeol, bacteriohopanetetrol I (BHT-I), bacteriohopanetetrol II (BHT-II), as well as C5 and C6 heterocyst glycolipids (HGs) in ODP cores at sites 964 and 967 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.936834, In: Elling, FJ et al. (2021): Mediterranean sapropel bulk organic matter and biomarker concentrations and carbon isotope compositions [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.937082

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Published: 2021-10-07DOI registered: 2021-11-16

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Abstract:
Carbon-normalized abundance of individual bacteriohopanetetrol (BHP) and heterocyst glycolipid (HG) compounds, as well as the relative abundance of BHT-I vs. BHT-II and HG-C5 compounds vs. HG-C6 compounds in ODP cores at sites 964 and 967. Concentration data for BHPs and HGs were generated using ultra high-performance liquid chromatography coupled to triple quadrupole mass spectrometry following Kusch et al. (2018) and Wörmer et al. (2012), respectively.
This work was supported by the Gordon and Betty Moore Foundation.
Keyword(s):
anoxia; Bacteriohopanepolyols; Biomarkers; d13C; d15N; GDGTs; heterocyst glycolipids; Mediterranean Sea; nitrogen cycle; organic matter; sapropels
Related to:
Elling, Felix J; Hemingway, Jordon D; Kharbush, Jenan; Becker, Kevin W; Polik, Catherine Ann; Pearson, Ann (2021): Linking diatom-diazotroph symbioses to nitrogen cycle perturbations and deep-water anoxia: Insights from Mediterranean sapropel events. Earth and Planetary Science Letters, 571, 117110, https://doi.org/10.1016/j.epsl.2021.117110
Kusch, Stephanie; Shah Walter, Sunita R; Hemingway, Jordon D; Pearson, Ann (2018): Improved chromatography reveals multiple new bacteriohopanepolyol isomers in marine sediments. Organic Geochemistry, 124, 12-21, https://doi.org/10.1016/j.orggeochem.2018.07.010
Wörmer, Lars; Cirés, Samuel; Velázquez, David; Quesada, Antonio; Hinrichs, Kai-Uwe (2012): Cyanobacterial heterocyst glycolipids in cultures and environmental samples: Diversity and biomarker potential. Limnology and Oceanography, 57(6), 1775-1788, https://doi.org/10.4319/lo.2012.57.6.1775
Project(s):
Funding:
National Science Foundation (NSF), grant/award no. EAR-1349126: A window on ancient systems: Understanding the environmental distributions of hopanoids using compound-specific multi-isotope analysis and metagenomics
National Science Foundation (NSF), grant/award no. OCE-1702262: Beyond ocean temperature: Extracting new dimensions of paleoclimatic information from archaeal lipids and their isotopic compositions
National Science Foundation (NSF), grant/award no. OCE-1843285: Carbon isotope fractionation in Archaea using the 3HP/4HB pathway: Prospects for paleo-geochemistry and paleo-barometry
Coverage:
Median Latitude: 35.164850 * Median Longitude: 25.237650 * South-bound Latitude: 34.068300 * West-bound Longitude: 17.749700 * North-bound Latitude: 36.260800 * East-bound Longitude: 32.725600
Date/Time Start: 1995-03-17T20:14:00 * Date/Time End: 1995-04-03T21:15:00
Minimum Elevation: -3661.0 m * Maximum Elevation: -2552.0 m
Event(s):
160-964A * Latitude: 36.260300 * Longitude: 17.749700 * Date/Time Start: 1995-03-17T20:14:00 * Date/Time End: 1995-03-18T21:30:00 * Elevation: -3658.0 m * Penetration: 101.8 m * Recovery: 106.12 m * Location: Eastern Basin * Campaign: Leg160 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 11 core; 101.8 m cored; 0 m drilled; 104.2 % recovery
160-964D * Latitude: 36.260600 * Longitude: 17.750000 * Date/Time Start: 1995-03-20T02:00:00 * Date/Time End: 1995-03-20T16:45:00 * Elevation: -3660.0 m * Penetration: 108.6 m * Recovery: 112.2 m * Location: Eastern Basin * Campaign: Leg160 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 12 cores; 108.6 m cored; 0 m drilled; 103.3 % recovery
160-964E * Latitude: 36.260800 * Longitude: 17.750000 * Date/Time Start: 1995-03-20T16:45:00 * Date/Time End: 1995-03-21T00:45:00 * Elevation: -3661.0 m * Penetration: 85.5 m * Recovery: 54.32 m * Location: Eastern Basin * Campaign: Leg160 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 6 cores; 53 m cored; 0 m drilled; 102.5 % recovery
Comment:
The biomarker abundance data is normalized to g TOC. Fractional abundances of BHT-II [fBHT-II = BHT-I/(BHT-I + BHT-II)] and C5 HGs [fHG-C5 = HG-C5/(HG-C5 + HG-C6)] are given.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventElling, Felix J
2SiteSiteElling, Felix J
3Sapropel layerSapropelElling, Felix J
4CoreCoreElling, Felix J
5Depth, top/minDepth topmElling, Felix J
6Depth, bottom/maxDepth botmElling, Felix J
7Bacteriohopanetetrol I (peak area), per unit mass total organic carbonBHT-I peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
8Bacteriohopanetetrol II (peak area), per unit mass total organic carbonBHT-II peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
9Bacteriohopanetetrol II, fractional abundancefBHT-IIElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
10Crenarchaeol (peak area), per unit mass total organic carbonCren peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
111-(O-ribose)-3,29,31-dotriacontanetriol (peak area), per unit mass total organic carbonC5 HG32 triol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
121-(O-ribose)-3,29-triacontanediol (peak area), per unit mass total organic carbonC5 HG30 diol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
131-(O-ribose)-3,27,29-triacontanetriol (peak area), per unit mass total organic carbonC5 HG30 triol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
141-(O-hexose)-3,29,31-dotriacontanetriol (peak area), per unit mass total organic carbonC6 HG32 triol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
151-(O-hexose)-3,25-hexacosanediol (peak area), per unit mass total organic carbonC6 HG26 diol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
161-(O-hexose)-3-keto-29,31-dotriacontanediol (peak area), per unit mass total organic carbonC6 HG32 keto-diol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
171-(O-hexose)-3-keto-25-hexacosanol (peak area), per unit mass total organic carbonC6 HG26 keto-ol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
181-(O-hexose)-3-keto-27-octacosanol (peak area), per unit mass total organic carbonC6 HG28 keto-ol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
191-(O-hexose)-3,27-octacosanediol (peak area), per unit mass total organic carbonC6 HG28 diol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
201-(O-hexose)-3,25,27-octacosanetriol (peak area), per unit mass total organic carbonC6 HG28 triol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
211-(O-hexose)-3,27,29-triacontanetriol (peak area), per unit mass total organic carbonC6 HG30 triol peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
22C5 heterocyst glycolipids (peak area), per unit mass total organic carbonC5 HGs peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)Sum
23C6 heterocyst glycolipids (peak area), per unit mass total organic carbonC6 HGs peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)Sum
24Heterocyst glycolipids (peak area), per unit mass total organic carbonHGs peak area/TOC1/gElling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)Sum C5+C6 HGs
25C5 heterocyst glycolipids, fractional abundancefHG-C5Elling, Felix JAgilent 1290 ultrahigh performance liquid chromatograph coupled to an Agilent 6410 triple-quadrupole mass spectrometer (UPLC-QqQ-MS)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2468 data points

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