<?xml version="1.0" encoding="UTF-8"?><resource xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.3/metadata.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4"><identifier identifierType="DOI">10.1594/PANGAEA.935586</identifier><creators><creator><creatorName>Gensel, Julia</creatorName><givenName>Julia</givenName><familyName>Gensel</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-8948-2231</nameIdentifier></creator><creator><creatorName>Humphries, Marc</creatorName><givenName>Marc</givenName><familyName>Humphries</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-4047-1451</nameIdentifier></creator><creator><creatorName>Zabel, Matthias</creatorName><givenName>Matthias</givenName><familyName>Zabel</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0003-4681-1821</nameIdentifier></creator><creator><creatorName>Sebag, David</creatorName><givenName>David</givenName><familyName>Sebag</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-6446-6921</nameIdentifier></creator><creator><creatorName>Hahn, Annette</creatorName><givenName>Annette</givenName><familyName>Hahn</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-3647-473X</nameIdentifier></creator><creator><creatorName>Schefuß, Enno</creatorName><givenName>Enno</givenName><familyName>Schefuß</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-5960-930X</nameIdentifier></creator></creators><titles><title>Bulk organic matter composition, n-alkane distribution patterns, and compound-specific stable isotope compositions of modern surface sediments and plants of South Africa's largest freshwater wetland</title></titles><publisher>PANGAEA</publisher><publicationYear>2021</publicationYear><subjects><subject>d13C</subject><subject>dD</subject><subject>n-alkanes</subject><subject>organic matter</subject><subject>plant waxes</subject><subject>Rock-Eval</subject><subject>South Africa</subject><subject>wetland</subject><subject subjectScheme="Parameter">Event label</subject><subject subjectScheme="Parameter">Latitude of event</subject><subject subjectScheme="Parameter">Longitude of event</subject><subject subjectScheme="Parameter">DEPTH, sediment/rock</subject><subject subjectScheme="Parameter">Sample type</subject><subject subjectScheme="Parameter">Sample comment</subject><subject subjectScheme="Parameter">Species</subject><subject subjectScheme="Parameter">n-Alkane C16</subject><subject subjectScheme="Parameter">n-Alkane C17</subject><subject subjectScheme="Parameter">n-Alkane C18</subject><subject subjectScheme="Parameter">n-Alkane C19</subject><subject subjectScheme="Parameter">n-Alkane C20</subject><subject subjectScheme="Parameter">n-Alkane C21</subject><subject subjectScheme="Parameter">n-Alkane C22</subject><subject subjectScheme="Parameter">n-Alkane C23</subject><subject subjectScheme="Parameter">n-Alkane C24</subject><subject subjectScheme="Parameter">n-Alkane C25</subject><subject subjectScheme="Parameter">n-Alkane C26</subject><subject subjectScheme="Parameter">n-Alkane C27</subject><subject subjectScheme="Parameter">n-Alkane C28</subject><subject subjectScheme="Parameter">n-Alkane C29</subject><subject subjectScheme="Parameter">n-Alkane C30</subject><subject subjectScheme="Parameter">n-Alkane C31</subject><subject subjectScheme="Parameter">n-Alkane C32</subject><subject subjectScheme="Parameter">n-Alkane C33</subject><subject subjectScheme="Parameter">n-Alkane C34</subject><subject subjectScheme="Parameter">n-Alkane C35</subject><subject subjectScheme="Parameter">n-Alkane C23, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C23, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C25, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C25, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C27, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C27, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C29, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C29, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C31, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C31, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C33, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C33, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C35, δ13C</subject><subject subjectScheme="Parameter">n-Alkane C35, δ13C, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C25, δD</subject><subject subjectScheme="Parameter">n-Alkane C25, δD, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C27, δD</subject><subject subjectScheme="Parameter">n-Alkane C27, δD, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C29, δD</subject><subject subjectScheme="Parameter">n-Alkane C29, δD, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C31, δD</subject><subject subjectScheme="Parameter">n-Alkane C31, δD, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C33, δD</subject><subject subjectScheme="Parameter">n-Alkane C33, δD, standard deviation</subject><subject subjectScheme="Parameter">n-Alkane C35, δD</subject><subject subjectScheme="Parameter">n-Alkane C35, δD, standard deviation</subject><subject subjectScheme="Parameter">Carbon, organic, total</subject><subject subjectScheme="Parameter">Nitrogen, total</subject><subject subjectScheme="Parameter">δ13C, bulk carbonate</subject><subject subjectScheme="Parameter">Carbon/Nitrogen ratio</subject><subject subjectScheme="Parameter">Hydrogen index</subject><subject subjectScheme="Parameter">I-index</subject><subject subjectScheme="Parameter">R-Index</subject><subject subjectScheme="Project">Tracing Human and Climate impacts in South Africa (TRACES)</subject></subjects><resourceType resourceTypeGeneral="Dataset">Dataset</resourceType><relatedIdentifiers><relatedIdentifier relatedIdentifierType="DOI" relationType="References">10.5194/bg-19-2881-2022</relatedIdentifier></relatedIdentifiers><sizes><size>2231 data points</size></sizes><formats><format>text/tab-separated-values</format></formats><rightsList><rights rightsURI="https://creativecommons.org/licenses/by/4.0/" schemeURI="https://spdx.org/licenses/" rightsIdentifierScheme="SPDX" rightsIdentifier="CC-BY-4.0">Creative Commons Attribution 4.0 International</rights></rightsList><descriptions><description descriptionType="Abstract">Surface sediments (n=41) reflecting modern times (uppermost 10 cm) were collected during a November/December 2018 field campaign along the course of the Mkhuze River and a transect into Lake St. Lucia (KwaZulu Natal Province, South Africa). In addition, plant species (n=10) were collected based on previous reports of dominant vegetation communities and local occurrences. All samples were extracted soon after with a mixture of dichloromethane and methanol (9:1), purified, and fractionated. The apolar fraction was finally analyzed for its n-alkane concentrations and corresponding compound-specific carbon and hydrogen isotope compositions. Sub-samples of the surface sediments were also analyzed for (i) organic matter content (total organic carbon) and composition (d13C, carbon-to-nitrogen ratio) after decalcification, and (ii) for thermal indices (Hydrogen Index, R-index, I-index) using Rock-Eval analyses. The study's objective was to evaluate the most extensive freshwater wetland system in South Africa regarding its current condition and functioning by identifying the origin and transport pathways of sedimentary organic matter.</description></descriptions><geoLocations><geoLocation><geoLocationBox><westBoundLongitude>32.01755</westBoundLongitude><eastBoundLongitude>32.561083</eastBoundLongitude><southBoundLatitude>-27.9457</southBoundLatitude><northBoundLatitude>-27.5839166</northBoundLatitude></geoLocationBox></geoLocation><geoLocation><geoLocationPlace>Mkuze River</geoLocationPlace></geoLocation></geoLocations><fundingReferences><fundingReference><funderName>Federal Ministry of Education and Research</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100002347</funderIdentifier><awardNumber awardURI="https://foerderportal.bund.de/foekat/jsp/SucheAction.do?actionMode=view&amp;fkz=03F0798A">03F0798A</awardNumber><awardTitle>Tracing Human and Climate impacts in South Africa</awardTitle></fundingReference></fundingReferences></resource>