Citation:

PANGAEA.931663

Name: Impact of chemicals on stable carbon and oxygen isotope values of raw pollen
Published: 2021-05-18
License: https://creativecommons.org/licenses/by/4.0/
Keywords: chemical treatment; Pollen; pollen purification protocol; Stable carbon and oxygen isotopes

Always quote citation above when using data! You can download the citation in several formats below.

Published: 2021-05-18 • DOI registered: 2021-07-31

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Abstract:

Purification protocols to extract pollen from lake sediments contain chemicals, which alter the carbon and oxygen pollen-isotope values according to pollen characteristics and family affiliation. Modern (raw) pollen of broad-leaved (Alnus glutinosa, Betula pendula, Carpinus betulus, Corylus avellana, Fagus sylvatica and Quercus robur) and coniferous tree species (Picea abies and Pinus sylvestris) were treated with potassium hydroxide (KOH), hydrofluoric acid (HF), sodium hypochlorite (NaClO) and sulphuric acid (H2SO4) to test the impact on δ13Cpollen and δ18Opollen and assess the applicability in purification protocols. Alterations of δ13Cpollen values vary between +1.0‰ (B. pendula, NaClO-treatment) and -5.0‰ (P. sylvestris, H2SO4-treatment). The impact of chemicals on δ18Opollen are more diverse and offsets range between +1.1‰ (C. avellana, NaClO-treatment) and -17.9‰ (P. sylvestris, H2SO4-treatment). Pollen of broad-leaved and coniferous trees reacted differently to chemicals, but response patterns are generally alike. The usage of isotope-altering chemicals in purification protocols should be brought to a minimum, but the application of KOH and NaClO seems unproblematic.

Keyword(s):

chemical treatment; Pollen; pollen purification protocol; Stable carbon and oxygen isotopes

Related to:

Müller, Carolina; Hennig, Julian; Riedel, Frank; Helle, Gerhard (2021): Quantifying the impact of chemicals on stable carbon and oxygen isotope values of raw pollen. Journal of Quaternary Science, 36(3), 441-449, https://doi.org/10.1002/jqs.3300

Coverage:

Median Latitude: 49.829178 * Median Longitude: 6.089197 * South-bound Latitude: 49.738320 * West-bound Longitude: 4.756920 * North-bound Latitude: 50.063280 * East-bound Longitude: 10.533180

Minimum ELEVATION: 242 m a.s.l. * Maximum ELEVATION: 462 m a.s.l.

Event(s):

pollen_experiment_exctraction * Latitude Start: 49.738320 * Longitude Start: 4.756920 * Latitude End: 50.063280 * Longitude End: 10.533180 * Method/Device: Biological sample (BIOS)

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Comment
1	Species	Species		Müller, Carolina
2	Sample ID	Sample ID		Müller, Carolina
3	LATITUDE	Latitude		Müller, Carolina	Geocode
4	LONGITUDE	Longitude		Müller, Carolina	Geocode
5	ELEVATION	Elevation	m a.s.l.	Müller, Carolina	Geocode – Altitude
6	Treatment	Treat		Müller, Carolina
7	Replicates	Repl	#	Müller, Carolina
8	δ13C, pollen	δ13C pollen	‰	Müller, Carolina
9	δ18O, pollen	δ18O pollen	‰	Müller, Carolina

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

2208 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Species	2 Sample ID	3 Latitude	4 Longitude	5 Elevation [m a.s.l.]	6 Treat	7 Repl [#]	8 δ13C pollen [‰]	9 δ18O pollen [‰]
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	All	1	-34.8	17.2
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	All	2	-34.3	18.0
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	All	3	-34.7	17.8
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	H2SO4	1	-34.0	21.6
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	H2SO4	2	-34.0	22.6
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	H2SO4	3	-33.5	21.2
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	KOH	1	-33.6	20.1
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	KOH	2	-34.3	19.9
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	KOH	3	-33.7	19.7
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	NaClO	1	-31.7	21.3
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	NaClO	2	-32.0	21.0
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	NaClO	3	-31.3	21.1
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	raw	1	-30.7	21.7
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	raw	2	-30.3	20.9
Alnus glutinosa	ARD3_Alder11	49.74229	5.67883	405	raw	3	-30.3	21.0
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	H2SO4	1	-34.7	20.6
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	H2SO4	2	-33.9	21.0
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	H2SO4	3	-33.3	20.9
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	KOH	1	-34.1	20.3
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	KOH	2	-31.2	21.5
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	KOH	3	-36.5	12.5
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	NaClO	1	-31.1	23.5
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	NaClO	2	-31.5	22.6
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	NaClO	3	-30.9	22.7
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	raw	1	-31.0	22.0
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	raw	2	-31.0	22.4
Alnus glutinosa	ARD3_Alder15	49.74182	5.67972	390	raw	3	-31.2	22.8
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	All	1	-35.1	17.0
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	All	2	-34.5	19.0
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	All	3	-34.2	19.2
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	H2SO4	1	-33.9	19.9
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	H2SO4	2	-32.3	21.0
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	KOH	1	-33.6	19.7
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	KOH	2	-33.8	19.0
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	KOH	3	-31.7	19.2
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	NaClO	1	-31.1	22.1
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	NaClO	2	-31.2	20.8
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	NaClO	3	-31.2	20.5
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	raw	1	-30.1	21.4
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	raw	2	-30.0	21.4
Alnus glutinosa	ARD3_Alder20	49.75604	5.66175	430	raw	3	-30.2	20.9
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	All	1	-27.2	17.4
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	All	2	-27.3	17.6
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	All	3	-27.4	17.5
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	H2SO4	1	-28.1	20.8
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	H2SO4	2	-27.8	20.3
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	H2SO4	3	-27.6	20.5
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	KOH	1	-24.4	25.4
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	KOH	2	-24.2	25.6
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	KOH	3	-24.8	25.1
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	NaClO	1	-22.7	28.0
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	NaClO	2	-22.6	28.1
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	NaClO	3	-22.5	28.0
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	raw	1	-23.4	24.6
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	raw	2	-23.6	24.9
Betula pendula	ARD4_Bet12	49.83259	5.65819	454	raw	3	-23.4	24.6
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	All	1	-29.5	17.2
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	All	2	-29.3	16.9
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	All	3	-30.0	16.9
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	H2SO4	1	-28.4	20.1
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	H2SO4	2	-29.1	20.7
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	H2SO4	3	-29.1	20.7
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	KOH	1	-26.3	25.6
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	KOH	2	-26.6	25.3
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	KOH	3	-26.5	25.7
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	NaClO	1	-24.0	28.3
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	NaClO	2	-23.7	28.3
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	NaClO	3	-24.0	28.4
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	raw	1	-25.0	24.8
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	raw	2	-24.9	25.1
Betula pendula	ARD4_Bet15	49.83259	5.65819	454	raw	3	-25.2	25.2
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	All	1	-30.9	16.3
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	All	2	-30.8	16.3
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	All	3	-31.0	16.9
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	H2SO4	1	-28.6	19.8
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	H2SO4	2	-29.0	20.6
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	H2SO4	3	-29.0	19.6
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	KOH	1	-27.7	24.0
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	KOH	2	-27.8	23.9
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	KOH	3	-27.8	24.2
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	NaClO	1	-24.5	27.3
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	NaClO	2	-24.5	27.6
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	NaClO	3	-24.5	27.6
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	raw	1	-25.5	24.6
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	raw	2	-25.2	24.6
Betula pendula	ARD4_Bet5	49.83263	5.66144	462	raw	3	-25.5	24.8
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	All	1	-30.7	17.6
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	All	2	-31.0	17.8
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	All	3	-31.0	17.6
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	H2SO4	1	-29.7	21.5
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	H2SO4	2	-29.9	21.3
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	H2SO4	3	-29.5	20.9
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	KOH	1	-28.4	26.9
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	KOH	2	-28.1	27.0
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	KOH	3	-28.7	26.4
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	NaClO	1	-26.6	28.7
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	NaClO	2	-26.2	28.9
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	NaClO	3	-26.8	28.9
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	raw	1	-27.3	27.6
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	raw	2	-26.9	27.1
Carpinus betulus	Ste1_Carp1	49.86620	10.53169	444	raw	3	-27.1	27.4
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	All	1	-28.8	17.6
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	All	2	-28.7	17.2
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	All	3	-29.1	17.4
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	H2SO4	1	-27.3	20.6
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	H2SO4	2	-28.4	20.7
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	H2SO4	3	-27.6	20.6
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	KOH	1	-26.8	25.2
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	KOH	2	-26.2	25.4
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	KOH	3	-26.3	25.1
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	NaClO	1	-24.1	28.2
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	NaClO	2	-24.3	28.5
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	NaClO	3	-24.2	28.3
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	raw	1	-24.9	27.4
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	raw	2	-24.8	27.3
Carpinus betulus	Ste1_Carp6	49.86331	10.53318	436	raw	3	-24.8	27.1
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	All	1	-28.8	17.0
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	All	2	-29.3	16.6
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	All	3	-28.5	16.9
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	H2SO4	1	-28.4	20.2
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	H2SO4	2	-28.4	20.1
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	KOH	1	-28.5	21.7
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	KOH	2	-28.2	22.3
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	KOH	3	-28.1	22.2
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	NaClO	1	-24.9	26.7
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	NaClO	2	-25.2	26.8
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	NaClO	3	-24.9	26.9
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	raw	1	-26.0	24.7
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	raw	2	-26.2	24.7
Carpinus betulus	Ste1_Carp7	49.85999	10.52233	385	raw	3	-26.0	24.9
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	All	1	-33.5	15.5
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	All	2	-33.4	15.5
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	All	3	-33.5	15.3
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	H2SO4	1	-31.2	20.9
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	H2SO4	2	-32.5	20.5
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	H2SO4	3	-32.4	20.0
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	HF	1	-29.6	23.0
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	HF	2	-29.7	22.4
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	HF	3	-29.8	22.0
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	KOH	1	-32.4	20.2
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	KOH	2	-32.9	21.2
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	KOH	3	-32.7	21.0
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	NaClO	1	-29.5	22.8
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	NaClO	2	-29.9	22.4
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	NaClO	3	-29.7	22.2
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	raw	1	-29.5	22.3
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	raw	2	-29.0	21.8
Corylus avellana	ARD3_Hazel18	49.78055	5.69954	431	raw	3	-28.9	22.0
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	All	1	-33.0	16.1
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	All	2	-33.4	15.8
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	All	3	-33.1	15.7
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	H2SO4	1	-30.7	21.8
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	H2SO4	2	-33.3	21.3
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	H2SO4	3	-31.9	21.4
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	HF	1	-30.6	22.0
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	HF	2	-31.0	22.2
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	HF	3	-30.5	21.9
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	KOH	1	-32.7	20.6
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	KOH	2	-32.1	20.8
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	KOH	3	-32.7	20.6
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	NaClO	1	-30.1	23.3
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	NaClO	2	-30.0	22.3
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	NaClO	3	-30.1	22.6
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	raw	1	-28.5	21.3
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	raw	2	-28.4	21.7
Corylus avellana	ARD3_Hazel4	49.75593	5.66205	420	raw	3	-28.3	21.2
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	All	1	-32.4	16.4
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	All	2	-32.5	16.5
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	All	3	-32.6	16.7
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	H2SO4	1	-32.5	20.0
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	H2SO4	2	-32.5	20.1
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	H2SO4	3	-32.6	20.3
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	HF	1	-28.6	21.8
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	HF	2	-29.5	21.5
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	HF	3	-29.2	21.8
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	KOH	1	-32.0	20.5
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	KOH	2	-32.2	20.3
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	KOH	3	-32.0	20.6
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	raw	1	-27.4	20.5
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	raw	2	-27.7	20.7
Corylus avellana	ARD3_Hazel6	49.74008	5.68151	411	raw	3	-27.6	21.1
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	All	1	-29.4	17.0
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	All	2	-29.5	17.7
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	All	3	-29.3	18.2
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	H2SO4	1	-29.6	21.9
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	H2SO4	2	-28.9	22.0
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	H2SO4	3	-28.7	21.9
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	KOH	1	-28.1	22.2
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	KOH	2	-27.8	22.6
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	KOH	3	-28.0	22.4
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	raw	1	-27.9	23.8
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	raw	2	-28.0	23.2
Fagus sylvatica	ARD4_Fagus5	49.74115	5.67451	404	raw	3	-28.0	23.2
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	All	1	-30.5	18.2
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	All	2	-30.5	17.4
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	All	3	-30.4	17.9
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	H2SO4	1	-30.8	21.7
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	H2SO4	2	-30.5	21.7
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	H2SO4	3	-29.3	22.1
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	KOH	1	-29.4	22.1
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	KOH	2	-29.8	21.9
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	KOH	3	-29.9	22.0
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	raw	1	-29.4	23.1
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	raw	2	-29.3	23.2
Fagus sylvatica	ARD4_Fagus7	49.74140	5.67621	402	raw	3	-29.1	23.1
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	All	1	-29.7	16.4
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	All	2	-29.5	15.9
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	All	3	-29.9	16.0
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	H2SO4	1	-29.0	20.9
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	H2SO4	2	-29.1	21.1
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	H2SO4	3	-29.4	20.9
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	KOH	1	-28.0	22.8
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	KOH	2	-28.1	22.4
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	KOH	3	-28.1	22.2
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	raw	1	-27.5	23.6
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	raw	2	-27.9	23.3
Fagus sylvatica	ARD4_Fagus8	49.74140	5.67621	402	raw	3	-27.5	23.5
Picea abies	ARD4_Picea10	49.74501	5.68633	394	All	1	-31.1	15.6
Picea abies	ARD4_Picea10	49.74501	5.68633	394	All	2	-31.1	13.1
Picea abies	ARD4_Picea10	49.74501	5.68633	394	All	3	-31.3	13.7
Picea abies	ARD4_Picea10	49.74501	5.68633	394	H2SO4	1	-29.3	15.9
Picea abies	ARD4_Picea10	49.74501	5.68633	394	H2SO4	2	-30.1	14.7
Picea abies	ARD4_Picea10	49.74501	5.68633	394	H2SO4	3	-29.2	15.4
Picea abies	ARD4_Picea10	49.74501	5.68633	394	HF	1	-27.6	22.7
Picea abies	ARD4_Picea10	49.74501	5.68633	394	HF	2	-27.2	23.2
Picea abies	ARD4_Picea10	49.74501	5.68633	394	HF	3	-27.4	24.1
Picea abies	ARD4_Picea10	49.74501	5.68633	394	KOH	1	-27.6	24.4
Picea abies	ARD4_Picea10	49.74501	5.68633	394	KOH	2	-27.3	24.7
Picea abies	ARD4_Picea10	49.74501	5.68633	394	KOH	3	-27.7	24.4
Picea abies	ARD4_Picea10	49.74501	5.68633	394	NaClO	1	-27.0	22.8
Picea abies	ARD4_Picea10	49.74501	5.68633	394	NaClO	2	-27.2	22.8
Picea abies	ARD4_Picea10	49.74501	5.68633	394	NaClO	3	-27.0	22.9
Picea abies	ARD4_Picea10	49.74501	5.68633	394	raw	1	-27.3	25.8
Picea abies	ARD4_Picea10	49.74501	5.68633	394	raw	2	-27.3	25.6
Picea abies	ARD4_Picea10	49.74501	5.68633	394	raw	3	-27.8	25.3
Picea abies	ARD4_Picea11	49.74501	5.68633	394	All	1	-30.9	13.9
Picea abies	ARD4_Picea11	49.74501	5.68633	394	All	2	-31.2	12.8
Picea abies	ARD4_Picea11	49.74501	5.68633	394	All	3	-30.9	13.2
Picea abies	ARD4_Picea11	49.74501	5.68633	394	H2SO4	1	-29.4	15.7
Picea abies	ARD4_Picea11	49.74501	5.68633	394	H2SO4	2	-29.8	14.6
Picea abies	ARD4_Picea11	49.74501	5.68633	394	H2SO4	3	-29.9	14.4
Picea abies	ARD4_Picea11	49.74501	5.68633	394	HF	1	-27.1	22.2
Picea abies	ARD4_Picea11	49.74501	5.68633	394	HF	2	-26.7	22.4
Picea abies	ARD4_Picea11	49.74501	5.68633	394	HF	3	-27.2	23.0
Picea abies	ARD4_Picea11	49.74501	5.68633	394	KOH	1	-27.1	23.9
Picea abies	ARD4_Picea11	49.74501	5.68633	394	KOH	2	-26.8	24.3
Picea abies	ARD4_Picea11	49.74501	5.68633	394	KOH	3	-27.0	23.9
Picea abies	ARD4_Picea11	49.74501	5.68633	394	NaClO	1	-26.9	23.3
Picea abies	ARD4_Picea11	49.74501	5.68633	394	NaClO	2	-26.9	23.0
Picea abies	ARD4_Picea11	49.74501	5.68633	394	NaClO	3	-26.6	23.2
Picea abies	ARD4_Picea11	49.74501	5.68633	394	raw	1	-26.8	26.0
Picea abies	ARD4_Picea11	49.74501	5.68633	394	raw	2	-26.7	26.1
Picea abies	ARD4_Picea11	49.74501	5.68633	394	raw	3	-26.5	26.0
Picea abies	ARD4_Picea9	49.74303	5.68061	400	All	1	-30.9	16.1
Picea abies	ARD4_Picea9	49.74303	5.68061	400	All	2	-31.0	13.2
Picea abies	ARD4_Picea9	49.74303	5.68061	400	All	3	-31.8	13.7
Picea abies	ARD4_Picea9	49.74303	5.68061	400	H2SO4	1	-31.2	15.5
Picea abies	ARD4_Picea9	49.74303	5.68061	400	H2SO4	2	-31.2	14.0
Picea abies	ARD4_Picea9	49.74303	5.68061	400	H2SO4	3	-31.4	13.8
Picea abies	ARD4_Picea9	49.74303	5.68061	400	HF	1	-29.3	21.2
Picea abies	ARD4_Picea9	49.74303	5.68061	400	HF	2	-28.7	23.5
Picea abies	ARD4_Picea9	49.74303	5.68061	400	HF	3	-28.9	22.6
Picea abies	ARD4_Picea9	49.74303	5.68061	400	KOH	1	-28.4	23.6
Picea abies	ARD4_Picea9	49.74303	5.68061	400	KOH	2	-28.2	23.8
Picea abies	ARD4_Picea9	49.74303	5.68061	400	KOH	3	-28.0	25.3
Picea abies	ARD4_Picea9	49.74303	5.68061	400	NaClO	1	-28.6	22.2
Picea abies	ARD4_Picea9	49.74303	5.68061	400	NaClO	2	-28.6	22.2
Picea abies	ARD4_Picea9	49.74303	5.68061	400	NaClO	3	-28.2	22.9
Picea abies	ARD4_Picea9	49.74303	5.68061	400	raw	1	-28.7	24.3
Picea abies	ARD4_Picea9	49.74303	5.68061	400	raw	2	-28.3	24.3
Picea abies	ARD4_Picea9	49.74303	5.68061	400	raw	3	-28.1	24.0
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	All	1	-31.6	11.6
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	All	2	-32.1	10.7
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	All	3	-31.8	11.0
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	H2SO4	1	-31.3	11.0
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	H2SO4	2	-31.2	10.1
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	H2SO4	3	-31.1	10.4
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	HF	1	-26.9	27.6
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	HF	2	-26.6	28.2
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	HF	3	-26.7	27.9
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	KOH	1	-26.9	25.3
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	KOH	2	-27.2	25.1
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	NaClO	1	-26.4	28.9
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	NaClO	2	-26.1	29.0
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	NaClO	3	-26.2	28.9
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	raw	1	-26.2	30.0
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	raw	2	-26.1	30.1
Pinus sylvestris	ARD4_Pine10	50.06328	4.76259	252	raw	3	-26.0	30.1
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	All	1	-30.9	11.6
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	All	2	-31.4	10.2
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	H2SO4	1	-29.6	12.0
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	H2SO4	2	-30.3	11.0
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	H2SO4	3	-29.0	11.8
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	HF	1	-25.4	28.3
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	HF	2	-25.4	28.7
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	HF	3	-25.2	28.6
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	KOH	1	-25.6	28.1
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	KOH	2	-25.8	28.0
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	KOH	3	-25.5	27.8
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	NaClO	1	-25.0	29.4
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	NaClO	2	-25.0	29.7
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	NaClO	3	-25.2	29.5
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	raw	1	-25.2	30.0
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	raw	2	-24.0	30.3
Pinus sylvestris	ARD4_Pine14	50.06322	4.76239	252	raw	3	-23.6	31.6
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	All	1	-30.7	11.5
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	All	2	-30.7	10.7
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	All	3	-30.8	11.0
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	H2SO4	1	-28.8	15.2
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	H2SO4	2	-28.6	14.9
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	H2SO4	3	-28.7	14.4
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	HF	1	-24.6	28.0
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	HF	2	-24.6	29.7
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	HF	3	-24.3	29.1
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	KOH	1	-25.0	28.7
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	KOH	2	-24.8	28.4
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	KOH	3	-24.8	28.3
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	NaClO	1	-24.0	30.2
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	NaClO	2	-24.3	30.5
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	NaClO	3	-24.2	30.6
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	raw	1	-24.3	30.6
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	raw	2	-24.5	30.5
Pinus sylvestris	ARD4_Pine9	50.06328	4.76259	252	raw	3	-24.1	30.8
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	All	1	-28.1	18.1
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	All	2	-28.3	18.4
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	All	3	-28.0	18.7
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	H2SO4	1	-27.6	23.9
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	H2SO4	2	-27.3	23.7
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	H2SO4	3	-27.0	24.0
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	KOH	1	-25.1	29.5
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	KOH	2	-25.9	29.3
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	KOH	3	-26.2	29.3
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	NaClO	1	-25.3	30.3
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	NaClO	2	-25.5	29.5
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	NaClO	3	-25.8	30.8
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	raw	1	-25.7	25.2
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	raw	2	-25.1	28.5
Quercus robur	ARD4_Quercus13	49.74303	5.68061	400	raw	3	-25.5	28.1
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	All	1	-30.8	18.5
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	All	2	-30.1	19.0
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	All	3	-30.6	19.3
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	H2SO4	1	-29.1	21.3
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	H2SO4	2	-29.6	21.8
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	H2SO4	3	-29.0	20.8
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	KOH	1	-27.9	29.1
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	KOH	2	-27.5	30.2
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	KOH	3	-27.5	29.8
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	NaClO	1	-26.9	30.3
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	NaClO	2	-27.1	30.7
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	NaClO	3	-27.1	30.5
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	raw	1	-27.3	29.5
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	raw	2	-27.2	29.1
Quercus robur	ARD4_Quercus15	49.73832	5.66935	381	raw	3	-27.4	29.2
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	All	1	-30.0	17.6
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	All	2	-30.2	17.6
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	All	3	-30.2	17.5
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	H2SO4	1	-29.0	23.3
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	H2SO4	2	-28.7	22.9
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	H2SO4	3	-28.4	22.7
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	KOH	1	-29.0	25.2
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	KOH	2	-27.4	27.7
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	KOH	3	-28.7	25.6
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	NaClO	1	-26.9	28.4
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	NaClO	2	-27.4	28.1
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	NaClO	3	-26.9	29.2
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	raw	1	-27.0	27.5
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	raw	2	-26.7	27.8
Quercus robur	ARD4_Quercus6	50.06114	4.75692	242	raw	3	-27.2	27.8