Joerss, Hanna; Xie, Zhiyong; Ebinghaus, Ralf (2021): Per- and polyfluoroalkyl substances (PFASs) in water samples from POLARSTERN cruise PS114 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.929509
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Abstract:
Legacy and emerging per- and polyfluoroalkyl substances (PFASs) were measured in water samples from the Polarstern expedition PS114 (ARK-XXXII/1), which took place from July 11th to August 3rd 2018. Using the ship's seawater intake system, surface water samples were collected along a latitudinal transect from the European continent to the Arctic (57°N to 79°N at ∼5°E) and a longitudinal and latitudinal transect within Fram Strait (9°E to 18°W at ∼79°N and 78°N to 80°N at ∼0°EW). Additionally, water was collected from different depths of the water column (5 to 3117 m) at seven stations in Fram Strait. Samples were prepared using solid-phase extraction (SPE) and analysed by liquid chromatography coupled to a triple quadrupole tandem mass spectrometer (LC-MS/MS). More information can be found in Joerss et al. (2020). The aim of the study was to investigate occurrence, distribution, transport and sources of legacy and emerging PFAS in the Atlantic gateway to the Arctic Ocean.
Related to:
Joerss, Hanna; Xie, Zhiyong; Wagner, Charlotte C; von Appen, Wilken-Jon; Sunderland, Elsie M; Ebinghaus, Ralf (2020): Transport of Legacy Perfluoroalkyl Substances and the Replacement Compound HFPO-DA through the Atlantic Gateway to the Arctic Ocean—Is the Arctic a Sink or a Source? Environmental Science & Technology, 54(16), 9958-9967, https://doi.org/10.1021/acs.est.0c00228
Project(s):
Coverage:
Median Latitude: 76.858020 * Median Longitude: -0.532173 * South-bound Latitude: 57.137000 * West-bound Longitude: -17.840000 * North-bound Latitude: 80.855000 * East-bound Longitude: 9.300000
Date/Time Start: 2018-07-11T09:29:00 * Date/Time End: 2018-07-29T13:38:00
Minimum DEPTH, water: 5 m * Maximum DEPTH, water: 3117 m
Event(s):
PS114_9-1 * Latitude: 78.606670 * Longitude: 5.041320 * Date/Time: 2018-07-17T18:53:00 * Elevation: -2347.0 m * Campaign: PS114 * Basis: Polarstern * Method/Device: CTD/Rosette (CTD-RO)
PS114_9-4 * Latitude: 78.607350 * Longitude: 5.046980 * Date/Time: 2018-07-18T00:37:00 * Elevation: -2344.0 m * Campaign: PS114 * Basis: Polarstern * Method/Device: CTD/Rosette (CTD-RO)
PS114_12-1 * Latitude: 79.011740 * Longitude: 7.034590 * Date/Time: 2018-07-18T10:41:00 * Elevation: -1277.0 m * Campaign: PS114 * Basis: Polarstern * Method/Device: CTD/Rosette (CTD-RO)
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Event label | Event | Joerss, Hanna | |||
| 2 | Station label | Station | Joerss, Hanna | |||
| 3 | Sample code/label | Sample label | Joerss, Hanna | |||
| 4 | LATITUDE | Latitude | Joerss, Hanna | Geocode | ||
| 5 | LONGITUDE | Longitude | Joerss, Hanna | Geocode | ||
| 6 | DEPTH, water | Depth water | m | Joerss, Hanna | Geocode | |
| 7 | DATE/TIME | Date/Time | Joerss, Hanna | Geocode – URC | ||
| 8 | Perfluorohexanoic acid | PFHxA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 12 pg/l, limit of quantification: 27 pg/l |
| 9 | Perfluoroheptanoic acid | PFHpA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 12 pg/l, limit of quantification: 21 pg/l |
| 10 | Perfluorooctanoic acid | PFOA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 16 pg/l, limit of quantification: 29 pg/l |
| 11 | Perfluorononanoic acid | PFNA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 6.3 pg/l, limit of quantification: 21 pg/l |
| 12 | Perfluorodecanoic acid | PFDA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 6.4 pg/l, limit of quantification: 21 pg/l |
| 13 | Perfluoroundecanoic acid | PFUnDA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 3.7 pg/l, limit of quantification: 12 pg/l |
| 14 | Perfluorododecanoic acid | PFDoDA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 3.3 pg/l, limit of quantification: 11 pg/l |
| 15 | Perfluorotridecanoic acid | PFTrDA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 4.6 pg/l, limit of quantification: 15 pg/l |
| 16 | Perfluorotetradecanoic acid | PFTeDA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 8.8 pg/l, limit of quantification: 29 pg/l |
| 17 | Perfluorobutane sulfonic acid | PFBS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 13 pg/l, limit of quantification: 45 pg/l |
| 18 | Perfluorohexane sulfonic acid | PFHxS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 18 pg/l, limit of quantification: 61 pg/l |
| 19 | Perfluoroheptane sulfonic acid | PFHpS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 27 pg/l, limit of quantification: 90 pg/l |
| 20 | Perfluorooctane sulfonic acid | PFOS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 21 pg/l, limit of quantification: 44 pg/l |
| 21 | Perfluorodecane sulfonic acid | PFDS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 32 pg/l, limit of quantification: 93 pg/l |
| 22 | Perfluoro-4-ethylcyclohexane sulfonic acid | PFECHS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 43 pg/l, limit of quantification: 140 pg/l |
| 23 | 2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3,3,-heptafluoropropoxy)-propanoic acid | HFPO-DA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 6 pg/l, limit of quantification: 20 pg/l |
| 24 | Hexafluoropropylene oxide trimer acid | HFPO-TrA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 44 pg/l, limit of quantification: 150 pg/l |
| 25 | Hexafluoropropylene oxide tetramer acid | HFPO-TeA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 75 pg/l, limit of quantification: 250 pg/l |
| 26 | 2,2,3-trifluoro-3-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]propanoic acid | DONA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 7.5 pg/l, limit of quantification: 25 pg/l |
| 27 | 9-chlorohexadecafluoro-3-oxanonane-1-sulfonic acid | 9Cl-PF3ONS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 6.9 pg/l, limit of quantification: 23 pg/l |
| 28 | 11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid | 11Cl-PF3OUdS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 6.8 pg/l, limit of quantification: 23 pg/l |
| 29 | Bis(perfluorohexyl)phosphinic acid | 6:6PFPiA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 4.9 pg/l, limit of quantification: 16 pg/l |
| 30 | Perfluorohexylperfluorooctylphosphinic acid | 6:8PFPiA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 8.7 pg/l, limit of quantification: 29 pg/l |
| 31 | Perfluorooctane sulfonamide | FOSA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 8 pg/l, limit of quantification: 27 pg/l |
| 32 | 4:2 fluorotelomer sulfonic acid | 4:2FTSA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 30 pg/l, limit of quantification: 100 pg/l |
| 33 | 6:2 fluorotelomer sulfonic acid | 6-2FTS | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 61 pg/l, limit of quantification: 150 pg/l |
| 34 | 8:2 fluorotelomer sulfonic acid | 8:2FTSA | pg/l | Joerss, Hanna | Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS) | measured in water column, limit of detection: 36 pg/l, limit of quantification: 120 pg/l |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
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2803 data points
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