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Feltracco, Matteo; Barbaro, Elena; Spolaor, Andrea; Vecchiato, Marco; Callegaro, Alice; Burgay, Francois; Vardè, Massimiliano; Maffezzoli, Niccolò; Dallo, Federico; Scoto, Federico; Turetta, Clara; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2021): Ions and organc acids in aerosol samples from Ny-Alesund, Svalbard Island, 2018 - 2019 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.928106, In: Feltracco, M et al. (2021): Water soluble compounds in size-segregated Arctic aerosol at Gruvebadet, Ny-Ålesund in 2013, 2014, 2015 and 2018-2019 [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.928238

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Abstract:
Ions and organic acids were quantified in 46 aerosol samples collected during the Arctic campaign at Gruvebadet Laboratory in 2018 and 2019. Aerosol samples were collected in quartz fiber filters. They were spiked with isotopically labelled standard solutions (2 - 3 µg/ml) prior extraction. Ion and organic acid content was measured using IC-MS and HPLC-MS.
Keyword(s):
aerosol; amino acids; Arctic; ions; organic acids; sugars
Related to:
Feltracco, Matteo; Barbaro, Elena; Kirchgeorg, Torben; Spolaor, Andrea; Turetta, Clara; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2019): Free and combined L- and D-amino acids in Arctic aerosol. Chemosphere, 220, 412-421, https://doi.org/10.1016/j.chemosphere.2018.12.147
Feltracco, Matteo; Barbaro, Elena; Spolaor, Andrea; Vecchiato, Marco; Callegaro, Alice; Burgay, Francois; Vardè, Massimiliano; Maffezzoli, Niccolò; Dallo, Federico; Scoto, Federico; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2021): Year-round measurements of size-segregated low molecular weight organic acids in Arctic aerosol. Science of the Total Environment, 763, 142954, https://doi.org/10.1016/j.scitotenv.2020.142954
Feltracco, Matteo; Barbaro, Elena; Tedeschi, Silvia; Spolaor, Andrea; Turetta, Clara; Vecchiato, Marco; Morabito, Elisa; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2020): Interannual variability of sugars in Arctic aerosol: Biomass burning and biogenic inputs. Science of the Total Environment, 706, 136089, https://doi.org/10.1016/j.scitotenv.2019.136089
Further details:
Barbaro, Elena; Padoan, Sara; Kirchgeorg, Torben; Zangrando, Roberta; Toscano, Giuseppa; Barbante, Carlo; Gambaro, Andrea (2017): Particle size distribution of inorganic and organic ions in coastal and inland Antarctic aerosol. Environmental Science and Pollution Research, 24(3), 2724-2733, https://doi.org/10.1007/s11356-016-8042-x
Feltracco, Matteo; Barbaro, Elena; Contini, Daniele; Zangrando, Roberta; Toscano, Giuseppa; Battistel, Dario; Barbante, Carlo; Gambaro, Andrea (2018): Photo-oxidation products of α-pinene in coarse, fine and ultrafine aerosol: A new high sensitive HPLC-MS/MS method. Atmospheric Environment, 180, 149-155, https://doi.org/10.1016/j.atmosenv.2018.02.052
Coverage:
Latitude: 78.917500 * Longitude: 11.894167
Date/Time Start: 2018-03-03T00:00:00 * Date/Time End: 2019-02-26T00:00:00
Event(s):
Gruvebadet_Svalbard * Latitude: 78.917500 * Longitude: 11.894167 * Campaign: Joint Arctic Weather Stations * Method/Device: Multiple investigations (MULT) * Comment: Aerosol samples
Comment:
Extraction of ions and organic acids, with exception of pinic and pinonic acids, was done as follows: A quarter of the filter was broken into small pieces and placed in polyethylene tubes, using steel tweezers. Slotted filters were ultrasonically extracted for 30 min with 7 mL of ultra-pure water, while backup filters with 15 mL of ultra-pure water. Extracts were filtrated through a 0.45 μm PTFE filter to remove residues before the analysis. Determination and quantification of major ions and organic acids were performed using an IC-MS system.
For the determination of pinic and pinonic acids a HPLC-MS/MS system was used.
Values below the detection limit of the measurements are indicated (<0.xxxxx).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
DATE/TIMEDate/TimeFeltracco, MatteoGeocode
Size fraction, upper thresholdFraction upperµmFeltracco, Matteo
Size fraction, lower thresholdFraction lowerµmFeltracco, Matteo
Sample IDSample IDFeltracco, Matteo
Sodium ionNa+ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
Ammonium[NH4]+ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
Potassium ionK+ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
Magnesium ionMg2+ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
Calcium ionCa2+ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
10 ChlorideCl-ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
11 Formic acidFormic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
12 Acetic acidAcetic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
13 NitrateNO3ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
14 Glycolic acidGlycolic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
15 BromideBr-ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
16 Oxalic acidOxaic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
17 Methanesulfonic acidMSAng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
18 Sulfate[SO4]2-ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
19 Malonic acidMalonic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
20 Maleic acidMaleic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
21 Fumaric acidFumaric acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
22 Succinic acidSuccinic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
23 Iodine ionI-ng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
24 Glutaric acidGAng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
25 Malic acidMalic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
26 Adipic acidAdipic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
27 Pimelic acidPimelic acidng/m3Feltracco, MatteoIon chromatography Mass Spectrometry (IC-MS)
28 Pinonic acidPinonic acidng/m3Feltracco, MatteoHigh Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
29 Pinic acidPinic acidng/m3Feltracco, MatteoHigh Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
Size:
7682 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Date/Time

Fraction upper [µm]

Fraction lower [µm]

Sample ID

Na+ [ng/m3]

[NH4]+ [ng/m3]

K+ [ng/m3]

Mg2+ [ng/m3]

Ca2+ [ng/m3]
10 
Cl- [ng/m3]
11 
Formic acid [ng/m3]
12 
Acetic acid [ng/m3]
13 
NO3 [ng/m3]
14 
Glycolic acid [ng/m3]
15 
Br- [ng/m3]
16 
Oxaic acid [ng/m3]
17 
MSA [ng/m3]
18 
[SO4]2- [ng/m3]
19 
Malonic acid [ng/m3]
20 
Maleic acid [ng/m3]
21 
Fumaric acid [ng/m3]
22 
Succinic acid [ng/m3]
23 
I- [ng/m3]
24 
GA [ng/m3]
25 
Malic acid [ng/m3]
26 
Adipic acid [ng/m3]
27 
Pimelic acid [ng/m3]
28 
Pinonic acid [ng/m3]
29 
Pinic acid [ng/m3]
2018-03-0310.007.20c1_st1241.4187882004.2945243077.81542342534.07885758014.383704390382.8815517001.0840691890.11118394436.7173715500.3312743970.7591773911.6993312610.381921516110.8631167000.1692012640.1152784620.0095475120.0831248190.1584363900.0480250420.0512442500.2441824200.0137218270.0133919160.093493370
2018-03-037.203.00c1_st214.2682364301.0819611090.3740828712.7501074462.59322613720.303936900<0.050675000<0.0009800005.3127701270.0617943200.3636576200.8749361840.19949543320.7511929600.0688108970.045544248<0.0001030000.0099014130.0460684390.0211605040.0191861400.0956366240.0067218050.0104741910.024038089
2018-03-033.001.50c1_st32.2867314200.7739071030.1437008100.4764994531.4218179313.937170171<0.050675000<0.0009800001.4140945550.0228224610.1293404450.3695799120.0783429666.5727220050.0216319740.015003085<0.0001030000.0017496150.0172521780.0172457430.0057193920.1006489630.0093326810.0101624960.014017554
2018-03-031.500.95c1_st45.7161170601.7420768340.3280064590.9704211891.8165315664.377035085<0.050675000<0.0009800003.6351772540.0815003680.3008847490.8551195650.15955932020.4525860000.0601915980.033168898<0.0001030000.0056988060.0466237290.0113113840.0180306730.0689777930.0078970230.0085165310.021656050
2018-03-030.950.49c1_st55.9580239315.1306708930.4201592830.9312210512.2112452011.532322514<0.050675000<0.0009800001.4973458860.1410241040.4955032541.1312919350.37861708844.1037885000.0970319140.0657422290.0093120420.0345616680.0591939130.0337566650.0606345000.1253485500.0128622000.0086069710.036702066
2018-03-03<0.49c1_st67.01326642316.2108705201.0735804021.2880045283.7393205277.296232170<0.0506750000.4733242973.3634323410.2331538621.3993837322.4408367520.99788835897.7276043800.1430765390.1915757740.0114612620.0831510030.1648533530.0309525150.1333097610.2080157990.0221992890.0470929920.085002579
2018-03-0910.007.20c2_st156.3302904604.0344764321.5255491287.2969483698.84424395773.3128351000.9374261290.30245629820.1063977100.2410634240.3382236301.0342873020.47724009066.1165155600.2023426710.0669649730.0102040990.0890127060.1583719660.0390906520.0639196810.0998308560.0063562740.0041610410.070109457
2018-03-097.203.00c2_st24.2711294522.1277504950.1566189241.0596750642.2662280551.457362939<0.0506750000.1544797482.9857713790.1009804480.1638969900.5479934490.22036494224.8028556100.1078502140.0395613850.0037399710.0214397300.0487002840.0120187320.0330995390.0396471320.0025766330.0039397880.030553972
2018-03-093.001.50c2_st30.9711916570.7294848080.0805672460.2767808001.2469508310.705680358<0.050675000<0.0009800001.2707271870.0293189950.0711207860.1045265430.0514622048.0706400890.0403211040.0234934710.0015438150.0065023780.0191115220.0104795670.0109042970.0249423560.0009031450.0033467910.014006584
2018-03-091.500.95c2_st42.7796984912.5998921550.3657610390.4838272172.4028322191.1907378100.8345374520.2244909942.7109494830.0888876330.1660622040.3886178400.19980670521.7116925300.0724469710.031049146<0.0001030000.0191553230.0413957170.0143866860.0343872410.0532722750.0052606530.0033203400.023861053
2018-03-090.950.49c2_st52.4978532706.0319988420.4037868780.5938206263.5692216210.476608064<0.0506750000.1807229200.9051622120.1571434410.2488522140.6442009320.46873614457.2701780400.1112283880.0536880970.0061945410.0524241480.0623935830.0172330370.0859920320.0378972490.0039137670.0023649590.033813280
2018-03-09<0.49c2_st654.05388701013.7286861700.7230341671.7839267169.1430968399.8397368892.4346942121.47521290512.3954582800.4462379241.0112885452.3855429741.067809831131.0196747000.2874790100.4256090580.0085783760.2147462380.3348022460.0491748540.2179739930.1468345580.0151990390.0176368400.134071777
2018-03-1510.007.20c3_st146.7835588701.3870723931.0150198017.1875096637.26721274079.707932100<0.050675000<0.00098000011.6685922200.1150873810.1820318551.4106437960.30769826132.0878522200.0931290900.0376609290.0038605840.0239310560.1052742010.0130854970.0238067090.0721252940.0061189630.0055478460.014262887
2018-03-157.203.00c3_st24.2359216970.7679365540.1570551891.1729266021.4717071723.543251199<0.050675000<0.0009800002.6249051480.0451309500.1039131320.9381896910.17895543414.5157098600.0721616830.018111404<0.0001030000.0029296090.042207314<0.0004430000.0193458920.0232921840.0019189830.0040303830.007723910
2018-03-153.001.50c3_st30.8443580360.2580599800.1189234280.2840400010.6603363921.047818240<0.050675000<0.0009800000.9856799940.0192059470.0410416760.4009630490.0396514464.0568254800.0238169880.006144687<0.000103000<0.0000871000.010558132<0.0004430000.005857059<0.0017550000.0016020480.0037627480.003382540
2018-03-151.500.95c3_st41.4096186471.0957143510.0807916680.2256459900.7130228060.540698062<0.050675000<0.0009800000.6372959010.0322523070.0814993770.5434554200.09509042710.3362114100.0468750810.011059385<0.0001030000.0028098560.024007970<0.0004430000.0181289670.0175502020.0016289130.0047222740.005490251
2018-03-150.950.49c3_st51.4920524863.2626897900.2523845900.4138044681.5665427170.356176611<0.0506750000.0994470670.8114879480.0749799310.1814235830.5496483870.24207642621.0827689800.0756511050.0165257750.0065147660.0130053040.0342153660.0124181230.0421216550.0255717200.0030995010.0057124280.009997342
2018-03-15<0.49c3_st64.08804548415.4448377900.6841927320.9825023964.7654861702.1836831600.7700887440.5574280412.6609320740.1986745970.8022398022.7663415840.92682163268.6188339000.1950077300.1206548490.0073133830.0640867030.1338058670.0359559870.1715092890.1571603460.0189403090.0170417800.033417807
2018-03-2110.007.20c4_st188.8372166605.6013349113.01236947413.81014181011.110669350135.4221874000.3125939750.21522247419.6047774600.2669215270.2232946903.3620641190.46911138571.9189511500.1968884500.0467578150.0145197080.0619752600.1016959190.0167589700.0763346810.0997635130.0089177630.0056698310.031128452
2018-03-217.203.00c4_st26.4272619323.7782440350.3709126031.6585584442.532579042<0.148225000<0.0506750000.1154457302.7898840940.1074367970.1200925761.9627685520.18531922729.7209600400.1152101860.0233238040.0070707860.0126464240.035599491<0.0004430000.0360322280.0273349860.0028546400.0041464040.012445164
2018-03-213.001.50c4_st31.6041359681.1633056070.1781055320.5300096651.466977762<0.148225000<0.050675000<0.0009800001.4108814250.0389613550.0590719920.9787892290.0526316929.7042435760.0455772980.014083872<0.0001030000.0017914680.016776854<0.0004430000.0171931120.0198256070.0022166840.0045332480.007295530
2018-03-211.500.95c4_st43.4976594954.7542421800.2166669460.8252695202.479298978<0.148225000<0.0506750000.1687409870.9626069630.1012251970.1336464791.2991931370.19296471929.2852289700.0846078460.0201003240.0056775330.0094948340.037166535<0.0004430000.0380875650.0233244440.0029024200.0041393490.011347015
2018-03-210.950.49c4_st52.9736655639.5789877310.6022810880.9499347923.2465319000.6483417630.2625773850.2080005380.5866348340.1907913930.2227799501.5990667430.32937129851.4934164100.1492650770.0252113650.0091300190.0549508290.0424518270.0155150290.0812644570.0477291610.0058503360.0036219610.017244182
2018-03-21<0.49c4_st63.23243009918.3548158001.2152354241.0638728105.3672053040.8786003330.6459336100.8123703901.6439390730.2616699700.5869768763.5780188070.55059412588.3755983000.2486368330.0622301120.0197160720.0756361440.1355755320.0336892650.1709456190.0961024410.0125201850.0209852180.050005105
2018-03-2710.007.20c5_st1125.8866474006.1300435654.19153848217.5542826609.231423617194.829745600<0.0506750000.12001207519.4623511300.1945397290.3394786741.1884305850.452883874100.2045027000.1935013470.0520706060.0075327960.0923602340.0740314800.0396615230.0633925610.0954043460.0050263900.0053233730.062757697
2018-03-277.203.00c5_st29.2377217893.7086344280.3886878292.0704641682.0239073635.641223493<0.050675000<0.0009800003.5124487430.0460483990.1843305270.6171733640.15537804536.3570402400.0942825950.0171865250.0040032410.0160362380.0200929230.0077872370.0284595300.0308519560.0014428280.0045009080.024367766
2018-03-273.001.50c5_st33.1757263681.6724494710.1005930820.6979011101.2914793491.986836069<0.050675000<0.0009800001.0387734050.0316653480.0927272410.2052838760.04891286016.5018109200.0394920720.008747341<0.0001030000.0069671070.009358315<0.0004430000.012087950<0.001755000<0.0004950000.0048789080.013728795
2018-03-271.500.95c5_st45.8567654396.3134836510.2734499301.3122864792.0345222610.844998061<0.050675000<0.0009800000.7677036350.0979266810.2107237450.9162039360.15306554147.1802019500.0889862680.0154855090.0033543520.0219129490.0204617140.0086732340.0403646410.0235115470.0016143420.0044885140.028502043
2018-03-270.950.49c5_st59.29703681311.3764300301.0032899551.4168627122.7351055790.326555554<0.0506750000.1299426691.1199633840.1930023900.4094259281.2896825270.368526075112.0042767000.1719342500.0303191510.0142548950.0807973760.0343600730.0179939330.1621097920.0423609090.0057212960.0034998350.030445137
2018-03-27<0.49c5_st65.61798010120.7866443901.3065782691.4939461853.413069053<0.148225000<0.0506750000.6388003770.8958491090.3241853450.9069375503.3675581010.772862976226.6324032000.2736589100.0757497740.0459228710.1367490310.0875053470.0284035720.282805609<0.0017550000.0111103590.0075653900.077963751
2018-04-0210.007.20c6_st157.7555156103.0647514881.5226037138.5946082845.107259382132.7373528000.1391303260.12181637118.8236084100.1872951470.4061800961.5685330880.60764236461.7988929200.2149473980.0449792280.0143434820.1020714820.1235017940.0344422170.0634732520.1073050000.0078057340.0055109640.020333241
2018-04-027.203.00c6_st24.5825469112.3395436170.1221204530.7911301521.2651579852.0073848750.1857003860.0270498531.0791189760.0549335840.1874258220.6187445010.12810362524.6096009500.0581883150.0127934340.0040061340.0165473740.0284212650.0144411630.0208022320.0418461120.0029606620.0057680970.008741614
2018-04-023.001.50c6_st31.5497492050.5829289940.0715005760.2169227830.7336051211.2447563650.2124327950.0242111940.9755787760.0334762760.0882425670.2249783670.0337624309.4014583920.0206705280.008869619<0.0001030000.0061534230.0081732060.0079918730.0083220150.0365449440.0029580100.0054383300.004922919
2018-04-021.500.95c6_st43.2068448592.3073121560.1052471610.3891849940.9574168531.6518988980.3471689480.0834653941.5807137240.0541519310.1754028600.4478036780.10372821424.7868049700.0543316060.0125255100.0031530900.0171969250.0197727240.0128394220.0299047300.0388746760.0036743780.0040312850.007336467
2018-04-020.950.49c6_st51.1849797224.9019447630.1389937450.4064112150.9480913641.4247211410.2610268860.0743420881.0779685300.0970018330.2798395430.8638378830.22063387752.3319363300.1016917490.0220875180.0096091030.0402661560.0257143620.0160103790.0715528010.0389446550.0039596100.0039024150.010621453
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2018-04-0810.007.20c7_st158.1278154806.8353887771.6091513898.5844516248.63335854572.5045913900.3019238330.20023043317.9134270300.1833311390.2904283881.7191396610.56808024983.6943390500.3951106400.0325487520.0146623000.1113488870.0768683750.0460857190.1306702680.1269788740.0070867440.0062389980.068444584
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