Citation:

PANGAEA.928238

Name: Ions and organc acids in aerosol samples from Ny-Alesund, Svalbard Island, 2014
Published: 2021-02-16
License: https://creativecommons.org/licenses/by/4.0/
Keywords: aerosol; amino acids; Arctic; ions; organic acids; sugars

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Abstract:

Ions and organic acids were quantified in 16 aerosol samples collected during the Arctic campaign at Gruvebadet Laboratory in 2014. Aerosol samples were collected in quartz fiber filters. They were spiked with isotopically labelled standard solutions (2 - 3 µg/ml) prior extraction. Ion and organic acid content was measured using IC-MS and HPLC-MS.

Keyword(s):

aerosol; amino acids; Arctic; ions; organic acids; sugars

Related to:

Feltracco, Matteo; Barbaro, Elena; Kirchgeorg, Torben; Spolaor, Andrea; Turetta, Clara; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2019): Free and combined L- and D-amino acids in Arctic aerosol. Chemosphere, 220, 412-421, https://doi.org/10.1016/j.chemosphere.2018.12.147

Feltracco, Matteo; Barbaro, Elena; Spolaor, Andrea; Vecchiato, Marco; Callegaro, Alice; Burgay, Francois; Vardè, Massimiliano; Maffezzoli, Niccolò; Dallo, Federico; Scoto, Federico; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2021): Year-round measurements of size-segregated low molecular weight organic acids in Arctic aerosol. Science of the Total Environment, 763, 142954, https://doi.org/10.1016/j.scitotenv.2020.142954

Feltracco, Matteo; Barbaro, Elena; Tedeschi, Silvia; Spolaor, Andrea; Turetta, Clara; Vecchiato, Marco; Morabito, Elisa; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2020): Interannual variability of sugars in Arctic aerosol: Biomass burning and biogenic inputs. Science of the Total Environment, 706, 136089, https://doi.org/10.1016/j.scitotenv.2019.136089

Further details:

Barbaro, Elena; Padoan, Sara; Kirchgeorg, Torben; Zangrando, Roberta; Toscano, Giuseppa; Barbante, Carlo; Gambaro, Andrea (2017): Particle size distribution of inorganic and organic ions in coastal and inland Antarctic aerosol. Environmental Science and Pollution Research, 24(3), 2724-2733, https://doi.org/10.1007/s11356-016-8042-x

Feltracco, Matteo; Barbaro, Elena; Contini, Daniele; Zangrando, Roberta; Toscano, Giuseppa; Battistel, Dario; Barbante, Carlo; Gambaro, Andrea (2018): Photo-oxidation products of α-pinene in coarse, fine and ultrafine aerosol: A new high sensitive HPLC-MS/MS method. Atmospheric Environment, 180, 149-155, https://doi.org/10.1016/j.atmosenv.2018.02.052

Coverage:

Latitude: 78.917500 * Longitude: 11.894167

Date/Time Start: 2014-04-08T00:00:00 * Date/Time End: 2014-06-29T00:00:00

Event(s):

Gruvebadet_Svalbard * Latitude: 78.917500 * Longitude: 11.894167 * Campaign: * Method/Device: Multiple investigations (MULT) * Comment: Aerosol samples

Comment:

Extraction of ions and organic acids, with exception of pinic and pinonic acids, was done as follows: A quarter of the filter was broken into small pieces and placed in polyethylene tubes, using steel tweezers. Slotted filters were ultrasonically extracted for 30 min with 7 mL of ultra-pure water, while backup filters with 15 mL of ultra-pure water. Extracts were filtrated through a 0.45 μm PTFE filter to remove residues before the analysis. Determination and quantification of major ions and organic acids were performed using an IC-MS system.

For the determination of pinic and pinonic acids a HPLC-MS/MS system was used.

Values below the detection limit of the measurements are indicated (<0.xxxxx).

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	DATE/TIME	Date/Time		Feltracco, Matteo		Geocode
2	Size fraction, upper threshold	Fraction upper	µm	Feltracco, Matteo
3	Size fraction, lower threshold	Fraction lower	µm	Feltracco, Matteo
4	Sample ID	Sample ID		Feltracco, Matteo
5	Sodium ion	Na+	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
6	Ammonium	[NH4]+	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
7	Potassium ion	K+	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
8	Magnesium ion	Mg2+	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
9	Calcium ion	Ca2+	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
10	Chloride	Cl-	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
11	Formic acid	Formic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
12	Acetic acid	Acetic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
13	Nitrate	NO3	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
14	Glycolic acid	Glycolic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
15	Bromide	Br-	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
16	Oxalic acid	Oxaic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
17	Methanesulfonic acid	MSA	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
18	Sulfate	[SO4]2-	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
19	Malonic acid	Malonic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
20	Maleic acid	Maleic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
21	Fumaric acid	Fumaric acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
22	Succinic acid	Succinic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
23	Iodine ion	I-	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
24	Glutaric acid	GA	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
25	Malic acid	Malic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
26	Adipic acid	Adipic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
27	Pimelic acid	Pimelic acid	ng/m³	Feltracco, Matteo	Ion chromatography Mass Spectrometry (IC-MS)
28	Pinonic acid	Pinonic acid	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
29	Pinic acid	Pinic acid	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Size:

2672 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Date/Time	2 Fraction upper [µm]	3 Fraction lower [µm]	4 Sample ID	5 Na+ [ng/m³]	6 [NH4]+ [ng/m³]	7 K+ [ng/m³]	8 Mg2+ [ng/m³]	9 Ca2+ [ng/m³]	10 Cl- [ng/m³]	11 Formic acid [ng/m³]	12 Acetic acid [ng/m³]	13 NO3 [ng/m³]	14 Glycolic acid [ng/m³]	15 Br- [ng/m³]	16 Oxaic acid [ng/m³]	17 MSA [ng/m³]	18 [SO4]2- [ng/m³]	19 Malonic acid [ng/m³]	20 Maleic acid [ng/m³]	21 Fumaric acid [ng/m³]	22 Succinic acid [ng/m³]	23 I- [ng/m³]	24 GA [ng/m³]	25 Malic acid [ng/m³]	26 Adipic acid [ng/m³]	27 Pimelic acid [ng/m³]	28 Pinonic acid [ng/m³]	29 Pinic acid [ng/m³]
2014-04-08	10.00	7.20	C1 ST1	14.542125290	1.107695806	0.149861728	2.255382925	3.100548858	29.643652030	0.099553627	0.019494514	1.160772869	0.018690222	0.265245496	0.064241398	0.030485478	10.593583650	0.006304339	0.001769838	<0.000103000	0.001200602	0.008184028	0.001114550	0.001333557	<0.001755000	<0.000495000	0.014325935	0.010347129
2014-04-08	7.20	3.00	C1 ST2	47.041514650	1.523546285	1.277950018	6.120296447	5.623582672	79.629947450	0.130790076	0.049621371	8.564962814	0.046350686	0.358664860	0.101565118	0.035647822	22.923955770	0.016742361	0.001300182	<0.000103000	0.003070866	0.027636698	0.002486020	0.002031843	0.005836875	<0.000495000	0.018633664	0.042508030
2014-04-08	3.00	1.50	C1 ST3	102.736064200	5.075205305	2.729233247	16.616180350	8.463079155	164.796121500	0.091504976	0.055804781	19.615672100	0.079471579	0.602461223	0.287608743	0.323625126	69.258302680	0.067971744	0.003721158	0.000995581	0.019340078	0.086875576	0.009396208	0.014930710	0.001302533	0.000285198	0.018887678	0.058895497
2014-04-08	1.50	0.95	C1 ST4	49.150513190	8.104266512	1.815605303	8.570030204	4.460515024	52.981232530	0.115700508	0.052132666	12.018230520	0.108195519	0.925373837	0.504201266	0.262034782	124.270167300	0.080796814	0.006573909	0.003447248	0.032033713	0.082898277	0.004962171	0.037125677	0.000802730	0.000295539	0.017784781	0.087902672
2014-04-08	0.95	0.49	C1 ST5	37.837124190	17.423454140	2.697687725	6.673828110	5.047962972	<0.148225000	0.256015586	0.062535561	<0.043148000	0.273982994	2.577523680	0.835264589	0.575429291	350.568473600	0.185206338	0.013272526	0.013491632	0.058907826	0.118042302	0.013289067	0.139602245	<0.001755000	0.000370116	0.009026945	0.063930967
2014-04-08	<0.49		C1 BACK	25.364347780	25.138242830	1.563543005	4.521456243	12.374197410	7.356993646	0.320933064	0.350350016	3.764127899	0.456948030	5.847504627	2.007953141	0.934393208	427.538684800	0.296017566	0.046410376	0.046729389	0.123143744	0.226307502	0.033049906	0.274833312	0.032468795	0.005826992	0.041312729	0.065002725
2014-04-14	10.00	7.20	C2 ST1	8.579165012	0.611020136	0.093839113	0.639613656	0.764526734	15.241192630	0.121136268	0.030138774	1.016824719	0.011487145	0.095222263	0.084215442	0.044013660	4.203665641	0.010223289	0.002525793	<0.000103000	0.000413770	0.015426592	0.001549535	0.002895179	0.001188099	0.000563066	0.019997395	0.010404287
2014-04-14	7.20	3.00	C2 ST2	59.656339160	2.552419074	1.268763284	8.043438588	5.208828323	97.121545480	0.085100755	0.061186025	13.582059740	0.051345595	0.251283926	0.292055361	0.377291811	33.303579820	0.069572461	0.007276499	0.001591828	0.010652733	0.105163555	0.006723522	0.018346805	0.003008373	0.000337137	0.023656947	0.019843741
2014-04-14	3.00	1.50	C2 ST3	19.769733500	2.517913024	0.327186968	3.631067350	2.625467601	26.300416810	0.058528032	0.037086286	8.329336674	0.026790084	0.267712414	0.665069175	0.498651788	29.889743670	0.140617119	0.007424752	0.003898233	0.011800345	0.118985987	0.006707931	0.035712562	0.010213987	0.000445102	0.031734796	0.029716493
2014-04-14	1.50	0.95	C2 ST4	22.495804710	10.990904290	0.947790049	3.765805285	2.758953095	4.610561222	0.086250526	0.100514234	4.980872754	0.104865237	0.964785151	1.515396846	0.743056469	127.385409300	0.150422572	0.014339376	0.013321584	0.037672089	0.184154843	0.014989135	0.103432294	0.014161377	0.001471858	0.029806926	0.036351514
2014-04-14	0.95	0.49	C2 ST5	9.547184193	16.046592470	1.174225779	2.276014734	2.864813150	0.716234645	0.070876624	0.052026710	0.649565405	0.131324901	1.291900758	0.859215288	0.860749270	169.412568800	0.162110690	0.015010529	0.012716543	0.045704120	0.130057068	0.014625623	0.147029769	0.005680622	0.001323811	0.016036783	0.034839450
2014-04-14	<0.49		C2 BACK	12.275786510	26.034857360	0.940731532	2.470170689	4.180487151	6.151649882	0.122120253	0.881148253	4.085369883	0.289515164	2.499910917	1.944220111	1.779294530	234.797116300	0.249855877	0.035654006	0.023628212	0.094185143	0.351562911	0.025744597	0.232977479	0.016639088	0.004546531	0.113659787	0.100735292
2014-04-20	10.00	7.20	C3 ST1	37.074584990	0.768568908	0.481209471	5.267148881	2.881524450	66.048707120	0.025583697	<0.000980000	1.615358121	0.004456796	0.047261365	0.297636517	0.028549895	19.281961060	0.021898920	0.003971687	0.000653513	0.003853431	0.011045159	0.002797893	0.004906362	<0.001755000	0.000243122	0.024080454	0.009365605
2014-04-20	7.20	3.00	C3 ST2	170.254025200	2.001859378	3.320351753	23.359778920	11.258659850	279.056945000	0.062933144	0.024941868	12.754919000	0.062561088	0.600675067	0.524184254	0.332406261	79.442797450	0.117331376	0.005886621	0.002661128	0.022292704	0.043118575	0.006617680	0.029227428	0.005628130	0.000250661	0.032297056	0.028600385
2014-04-20	3.00	1.50	C3 ST3	101.206545800	3.929579723	2.431241066	15.935360570	7.324884993	156.007178800	0.087655271	0.055122605	14.803603350	0.053396531	0.776981751	0.690556990	0.395264512	89.598160270	0.138386641	0.006945263	0.002916392	0.036248456	0.105395571	0.008721750	0.036132148	0.009656835	0.000340196	0.034141678	0.037516802
2014-04-20	1.50	0.95	C3 ST4	82.913532320	13.247354080	3.042305386	13.192965970	5.981262437	35.534322050	0.111886591	0.068540167	7.949869609	0.114251049	1.823496549	2.455249517	0.645788348	262.428126600	0.326014943	0.018402210	0.017384073	0.050336633	0.202967109	0.009697336	0.188464843	0.001059197	0.001721572	0.042324545	0.059422755
2014-04-20	0.95	0.49	C3 ST5	31.654349220	21.852727170	2.977422779	5.988810025	3.913583474	0.235231344	0.251854550	0.081428978	0.303841170	0.268240520	2.180052506	1.538253024	1.012906220	348.306525000	0.333153413	0.014296010	0.022398676	0.077528225	0.095904609	0.007434771	0.277000496	0.022082528	0.002300189	0.012869784	0.026890196
2014-04-20	<0.49		C3 BACK	24.033694910	23.448363960	1.499782628	4.610294258	5.604370051	9.405870673	0.241151210	0.409806687	2.111830986	0.367163405	3.732309054	2.020853714	1.489826205	317.604401000	0.423509087	0.036468123	0.033931941	0.115023785	0.161878930	0.027644439	0.338293752	0.028717618	0.003484617	0.098313066	0.041064662
2014-04-23	10.00	7.20	C4 ST1	18.537173380	0.518974838	0.076957194	3.289713198	2.279326368	31.322014520	0.116698508	0.015878777	0.523233927	0.008066477	0.199795196	0.106320748	0.050183864	12.654524700	0.016735172	0.003935316	<0.000103000	0.000978253	0.013025333	0.002394428	0.003246055	<0.001755000	<0.000495000	0.018611145	0.008498024
2014-04-23	7.20	3.00	C4 ST2	139.441902300	2.828796583	2.533892318	22.342151760	13.055557150	218.518222200	0.033639110	<0.000980000	21.229881200	0.051574449	0.398271725	0.853605042	0.904648251	75.163496280	0.203609209	0.008361277	0.002206607	0.013718884	0.078523765	0.006728402	0.024627205	0.003892640	<0.000495000	0.030550357	0.036813177
2014-04-23	3.00	1.50	C4 ST3	54.379698590	4.977127115	0.821149203	9.660378364	5.947139718	52.853689890	0.107475094	0.042167492	19.008149440	0.062008280	0.687625576	1.649486600	0.656241424	100.455647900	0.281724769	0.012444983	0.010122561	0.039425973	0.206564553	0.015036377	0.085934648	0.008397433	0.000775283	0.024071364	0.034435461
2014-04-23	1.50	0.95	C4 ST4	47.649191000	18.076604460	1.971768460	8.169719883	5.727291042	1.411526761	0.184712824	0.115195757	2.229781506	0.188355459	1.611318737	2.729828252	1.217171096	257.428686800	0.294959629	0.014729241	0.021186401	0.076611695	0.192727619	0.021247193	0.214430475	<0.001755000	0.001495088	0.023159006	0.039072324
2014-04-23	0.95	0.49	C4 ST5	21.065469020	24.989646860	2.153555207	5.501722388	6.527080588	0.412459118	0.217626282	0.135660120	0.429320146	0.399746140	2.947016881	2.082044547	1.987557393	329.792992600	0.501604008	0.027562242	0.031541570	0.107382017	0.154234544	0.014730142	0.380267564	<0.001755000	0.000683232	0.013129280	0.037491185
2014-04-23	<0.49		C4 BACK	12.607540830	29.850338400	1.061810567	5.224305174	10.194981290	1.894346510	0.182181528	0.987558938	1.585336052	0.561069386	4.686792289	2.073362312	2.473841271	336.604781800	0.488196958	0.049973763	0.053236557	0.151612993	0.238654779	0.040240406	0.407718186	0.020291095	0.002188386	0.101883768	0.075429673
2014-04-24	10.00	7.20	C5 ST1	4.413127760	0.080621711	0.190263253	0.165752991	<0.088877000	6.600445296	<0.050675000	<0.000980000	<0.043148000	<0.002700000	<0.000605000	<0.011181000	<0.000262000	8.983748978	<0.000124000	<0.000215000	<0.000103000	<0.000087100	0.004674910	<0.000443000	<0.000168000	<0.001755000	<0.000495000	0.017958982	0.009345307
2014-04-24	7.20	3.00	C5 ST2	44.784850760	1.619321736	0.411661969	6.679828993	8.892390385	89.427307210	<0.050675000	<0.000980000	5.153474147	<0.002700000	0.045637784	0.149156075	0.071877476	34.381592900	0.022310187	<0.000215000	<0.000103000	<0.000087100	0.012328551	<0.000443000	<0.000168000	<0.001755000	<0.000495000	0.023472711	0.020147756
2014-04-24	3.00	1.50	C5 ST3	22.659704760	2.261620668	<0.005221000	6.367252018	5.296710122	15.481693500	<0.050675000	<0.000980000	7.364428356	<0.002700000	0.122417629	0.374688846	0.170992849	70.796982140	0.045967399	<0.000215000	<0.000103000	<0.000087100	0.037356695	<0.000443000	0.006019797	<0.001755000	<0.000495000	0.027038134	0.031269417
2014-04-24	1.50	0.95	C5 ST4	36.830232470	17.307054110	0.563767028	9.794837347	8.075828949	<0.148225000	<0.050675000	<0.000980000	1.902070900	0.029150759	0.250389967	0.625494400	0.340947150	184.028051900	0.048091717	0.002603506	<0.000103000	0.005475236	0.054097248	<0.000443000	0.029261883	<0.001755000	<0.000495000	0.031247441	0.022393516
2014-04-24	0.95	0.49	C5 ST5	14.566571680	35.885488320	1.684521915	8.297472781	16.641965220	<0.148225000	<0.050675000	<0.000980000	0.894135893	0.104933145	0.747395341	0.540909190	0.832329654	366.742897400	0.122052411	0.007234247	0.012050710	0.018696224	0.069285695	<0.000443000	0.076523567	<0.001755000	<0.000495000	0.016552431	0.022779245
2014-04-24	<0.49		C5 BACK	65.294580410	150.517146900	7.986428938	24.094015400	40.879547500	14.247026510	0.039841857	0.536967957	6.910144972	0.387186104	4.504649747	1.910315750	3.155229565	1601.886779000	0.523561799	0.020368441	0.051897142	0.101991358	0.412803814	0.004118994	0.321614673	0.009653166	<0.000495000	0.112297067	0.086796932
2014-04-30	10.00	7.20	C6 ST1	27.230800950	0.432476748	0.262239177	3.417221702	4.542068600	45.762030680	0.044628533	0.017786048	1.552087114	0.012266148	0.202514896	0.145476714	0.063572905	16.211364050	0.014924621	0.001349953	0.000387496	0.000542476	0.012063971	0.001099408	0.001613293	<0.001755000	<0.000495000	0.031016515	0.011120121
2014-04-30	7.20	3.00	C6 ST2	79.237697480	1.134357424	1.513600172	10.715345020	7.907420828	118.865878500	0.037255153	0.026858446	16.379993220	0.047253860	0.285860103	0.456796872	0.333474080	47.450443880	0.105041496	0.003517507	0.001914563	0.018308536	0.067540294	0.005666569	0.013090674	<0.001755000	<0.000495000	0.028897535	0.019236745
2014-04-30	3.00	1.50	C6 ST3	19.922611830	2.410005774	0.370208285	3.105614580	2.160934337	14.143576280	0.022702968	0.038242357	11.261325840	0.034639710	0.477841949	0.686530600	0.438575426	49.210005370	0.123676145	0.004132997	0.003033465	0.018055814	0.106193393	0.006083495	0.024857579	0.001137285	<0.000495000	0.031775385	0.020249288
2014-04-30	1.50	0.95	C6 ST4	24.409241050	10.948579160	1.306345799	3.763077996	2.547803029	0.372100131	0.082301403	0.070998251	1.535342606	0.109294951	0.994322343	0.987895909	0.878657649	138.539572400	0.221123156	0.005668735	0.007900238	0.052064958	0.103089985	0.006574610	0.099849757	0.006298538	<0.000495000	0.025809753	0.015312476
2014-04-30	0.95	0.49	C6 ST5	13.781519930	16.231531030	1.735404806	3.000847007	3.198118577	<0.148225000	0.103687654	0.109786798	0.247303507	0.235142017	1.859482064	1.181529340	1.667167096	208.597573500	0.381773243	0.011036622	0.017192449	0.067683183	0.087715046	0.004861565	0.222892519	0.011958939	0.000794531	0.011200490	0.008832049
2014-04-30	<0.49		C6 BACK	2.240223709	6.401545964	0.191912918	0.604809401	1.226575781	0.707308729	0.025602032	0.219335007	0.650604430	0.109630697	0.770070004	0.472162761	0.603496653	69.633716420	0.094333553	0.011457198	0.001251755	0.032649554	0.049879775	0.013151922	0.051353686	0.003461701	0.000896734	0.079939670	0.028308102
2014-05-06	10.00	7.20	C7 ST1	17.750282020	0.419560673	0.182239515	3.134687478	2.182848290	29.559954240	0.043084605	0.023342663	1.171791388	0.007118085	0.223179714	0.088563943	0.073757308	11.123029240	0.011870806	0.001718318	0.000137666	0.001241179	0.007829831	0.001635635	0.001157711	<0.001755000	<0.000495000	0.018267351	0.004544726
2014-05-06	7.20	3.00	C7 ST2	71.338521780	0.931320105	0.942289995	10.002153430	4.986970190	113.777735500	<0.050675000	0.015431879	7.041049792	0.013784532	0.232835216	0.285766263	0.262461174	36.968953240	0.086913836	0.001709555	0.000960982	0.001340691	0.021749852	<0.000443000	0.006747747	<0.001755000	<0.000495000	0.027010493	0.007985779
2014-05-06	3.00	1.50	C7 ST3	25.403797480	0.851010329	0.281786701	3.772659222	2.114272501	33.682085520	0.013351007	0.051094219	6.827294440	0.017157103	0.261902337	0.337662069	0.328747451	25.757034580	0.079822615	0.003010406	0.000992042	0.008702291	0.084877835	0.003036659	0.011508718	<0.001755000	<0.000495000	0.032033516	0.008794012
2014-05-06	1.50	0.95	C7 ST4	14.827903180	3.674098122	0.262533195	2.053448672	1.182525413	4.489101507	<0.050675000	0.070719143	2.737613727	0.040373262	0.516460986	0.779444649	0.619799236	55.827233250	0.095634070	0.004786496	0.004741191	0.019120394	0.062155037	0.003912879	0.044396800	0.004743476	0.000346604	0.030228632	0.007082497
2014-05-06	0.95	0.49	C7 ST5	7.733306741	11.126438600	0.554113847	1.313905274	1.837057119	0.460597901	0.018154750	0.138862130	0.303893151	0.092368525	0.912140333	0.507178549	1.082471251	95.113237340	0.142712612	0.006680217	0.007316954	0.034686164	0.043442587	0.005437237	0.096370622	0.010132686	0.000309023	0.021337273	0.005513179
2014-05-06	<0.49		C7 BACK	7.204261951	17.335147360	0.340105771	0.936847939	1.957346717	5.978719359	0.054063416	0.564542114	2.797175737	0.175165596	2.201275469	1.195441816	1.777993243	98.029663560	0.199023432	0.018030299	0.011190129	0.068853461	0.096049275	0.010374864	0.111224931	0.018350257	0.002430699	0.202183558	0.039749184
2014-05-12	10.00	7.20	C8 ST1	57.713065500	0.313099963	0.873176179	9.010581696	4.438905320	93.199490220	0.040907447	<0.000980000	2.437669598	0.011302956	0.211637347	0.313547070	0.148685475	23.703166810	0.017325699	0.001560425	0.000291406	0.001046874	0.014036965	0.000697127	0.001842451	<0.001755000	<0.000495000	0.013895586	0.011354531
2014-05-12	7.20	3.00	C8 ST2	245.349518900	0.310881225	4.145145026	32.097857100	17.593236690	394.854366700	0.020918066	<0.000980000	23.820103350	0.068505138	0.463602545	0.687479822	0.593784173	89.057811090	0.154621490	0.003524082	0.001534126	0.025618405	0.041604159	0.004884734	0.018758113	0.004421058	<0.000495000	0.020592320	0.014436874
2014-05-12	3.00	1.50	C8 ST3	58.766318040	0.717447291	0.996097478	9.670615328	6.663761936	85.057463040	<0.050675000	<0.000980000	14.825720970	0.017570207	0.520479173	0.631100283	0.491267534	33.755518980	0.095432185	0.002735939	0.001094498	0.006078158	0.174598685	0.002166010	0.009629139	0.002122869	<0.000495000	0.020033427	0.012266091
2014-05-12	1.50	0.95	C8 ST4	31.434788160	2.472850583	0.592974300	5.433927232	3.662043016	25.093161900	0.015675232	0.012687877	11.420456300	0.041043701	0.736997079	1.121412872	0.876932490	58.874540810	0.104606559	0.004576823	0.004013558	0.013765766	0.282269866	0.003228026	0.041291076	<0.001755000	0.000516663	0.023041623	0.012566600
2014-05-12	0.95	0.49	C8 ST5	16.323445730	12.566596160	1.106471847	3.841329654	4.013092420	0.502982374	0.022381442	0.033851094	0.392964708	0.088508436	0.893436680	0.669204504	1.493541938	128.468324300	0.123492313	0.005241783	0.007872957	0.021340021	0.125240068	0.002634501	0.117597880	0.008100963	0.000770447	0.016780896	0.007596480
2014-05-12	<0.49		C8 BACK	11.330984510	23.090978310	0.871363539	2.372273041	5.545122857	4.008333616	0.048734785	0.409021408	2.042272799	0.255229584	2.540420308	1.347766776	3.491037763	160.864211900	0.205413262	0.019715448	0.015619998	0.054246127	0.247411939	0.006663001	0.206941096	0.018884300	0.002451335	0.102285097	0.028165170
2014-05-18	10.00	7.20	C9 ST1	14.260164520	0.354763241	0.163978961	3.154780364	5.038581684	37.316196680	0.048660152	0.079101939	1.412543737	0.015851953	0.182640607	0.507189079	0.165608829	5.451212979	0.017937566	0.000683010	<0.000103000	<0.000087100	0.005316994	<0.000443000	0.002210908	<0.001755000	<0.000495000	0.013426396	0.005968110
2014-05-18	7.20	3.00	C9 ST2	73.822433270	0.936032536	1.146724567	12.254519970	7.532465234	116.302357500	<0.050675000	0.012784729	11.261401080	0.019668949	0.219894575	0.509686760	0.494968845	36.528944520	0.058316393	0.001446105	0.000714291	0.006634180	0.025012316	0.001337184	0.006951253	0.001194077	<0.000495000	0.021146608	0.008892515
2014-05-18	3.00	1.50	C9 ST3	23.277104200	0.765915357	0.259386435	4.764700325	3.155656565	33.335591190	<0.050675000	0.052026953	7.859871124	0.022129063	0.243977532	0.315100483	0.494801490	22.000762250	0.048473400	0.001821814	0.001403010	0.007114160	0.089853100	0.002317065	0.007053024	0.002604428	<0.000495000	0.019191738	0.006536238
2014-05-18	1.50	0.95	C9 ST4	17.640027560	3.026155475	0.254445864	3.353152078	2.060120257	5.409898191	<0.050675000	0.040572853	4.925726964	0.032022601	0.430737604	0.775275350	0.910511781	58.981589850	0.092606378	0.003214054	0.004813837	0.009329380	0.098739400	0.002337083	0.030914338	0.003645666	<0.000495000	0.020475476	0.007200832
2014-05-18	0.95	0.49	C9 ST5	9.774337505	8.416887753	0.501746704	2.728433560	2.504964177	0.459325002	0.024821030	0.123604418	0.179164555	0.084146515	0.971151807	0.709622321	1.902784337	92.829109910	0.154470788	0.005389288	0.010707695	0.035436483	0.058874482	0.004492492	0.089369896	0.011235231	0.000415869	0.013994529	0.004170454
2014-05-18	<0.49		C9 BACK	10.281980850	17.862886610	0.569568863	1.748267617	2.792142615	2.762932368	0.032415713	0.768935625	2.202608662	0.217747084	2.477548828	1.167031754	3.748489552	162.327511200	0.220709366	0.019188328	0.017198058	0.080270836	0.124293300	0.010750434	0.154411921	0.011907902	0.001609012	0.082327498	0.017518761
2014-05-24	10.00	7.20	C10 ST1	19.037301300	0.211660125	0.159449316	3.999116859	13.564393080	43.895307820	<0.050675000	<0.000980000	6.428273968	<0.002700000	0.032381175	0.169849972	0.058894726	24.072833300	0.007377253	<0.000215000	0.000210348	0.001189807	0.002191722	<0.000443000	0.000832994	<0.001755000	<0.000495000	0.017704726	0.012578966
2014-05-24	7.20	3.00	C10 ST2	42.168480840	0.291097295	0.516632407	7.082733615	21.858764320	81.586569500	<0.050675000	<0.000980000	16.036879270	0.005007094	0.067979194	0.317636679	0.170526115	39.843201830	0.028485728	0.000701706	0.000261713	0.004595459	0.005532134	<0.000443000	0.004740482	<0.001755000	<0.000495000	0.026419161	0.018292632
2014-05-24	3.00	1.50	C10 ST3	36.931438400	1.298195174	0.693996721	7.720116015	18.830406570	50.271300830	<0.050675000	<0.000980000	18.651616120	0.008558866	0.105047890	0.437973824	0.328482997	72.202753460	0.057222224	0.000671551	0.000649395	0.004792178	0.022199586	0.000780770	0.008141669	<0.001755000	<0.000495000	0.023753416	0.015852600
2014-05-24	1.50	0.95	C10 ST4	15.378569350	7.230283492	0.529898206	4.114521261	8.768715301	0.880672534	<0.050675000	<0.000980000	0.279546704	0.008333076	0.163031710	0.345117524	0.460265260	105.497013400	0.069828202	0.001002721	0.001929020	0.011719700	0.029331708	0.001532359	0.022921885	<0.001755000	<0.000495000	0.019695668	0.007565509
2014-05-24	0.95	0.49	C10 ST5	15.272663740	10.826077580	0.901340570	3.375134636	4.071060467	<0.148225000	0.020639751	0.052239135	<0.043148000	0.066703731	0.748412426	<0.011181000	1.633769183	168.320246000	0.115599748	0.004177605	0.007316574	0.034131753	0.045248331	0.005050181	0.102282931	0.016348783	0.000355336	0.010567352	0.005095467
2014-05-24	<0.49		C10 BACK	<0.033976000	16.703904060	0.495818619	1.826531512	2.851169249	2.114406908	0.042297849	0.940261492	1.383948672	0.139119826	1.579063657	0.796876021	3.065796127	217.951348000	0.176483258	0.009979066	0.009645450	0.060482109	0.108464625	0.010225131	0.117453951	0.001488532	0.002095125	0.074271370	0.028072608
2014-05-30	10.00	7.20	C11 ST1	30.131926330	0.288830475	0.410938371	3.172515263	3.081677756	37.073546170	<0.050675000	<0.000980000	3.966172775	0.007623435	0.096044352	0.129651080	0.301983836	35.765086190	0.014131615	0.000801228	0.000142255	0.000978547	0.008239735	0.002088443	0.002046787	0.001603779	<0.000495000	0.010804138	0.004682612
2014-05-30	7.20	3.00	C11 ST2	135.444050400	0.886972291	2.351944506	19.069075000	18.503013730	208.427168400	0.032384979	0.039483291	29.023726610	0.057523316	0.151404037	0.693327175	1.094060167	69.268081790	0.124611608	0.002318202	0.001650427	0.034518298	0.034717352	0.012176168	0.024636847	0.008115932	0.000833583	0.014827005	0.008819077
2014-05-30	3.00	1.50	C11 ST3	42.487157330	1.054157041	0.698125329	6.526014682	5.727952162	47.793360680	<0.050675000	<0.000980000	10.895197570	0.014584560	0.136186803	0.920684398	0.828092247	61.012916040	0.120485873	0.002188926	0.001474417	0.012172606	0.074461983	0.007897062	0.022250463	0.004880475	0.000785565	0.014263224	0.006901065
2014-05-30	1.50	0.95	C11 ST4	31.802955910	10.276160600	0.927092786	4.507833673	4.412320497	0.592749263	<0.050675000	0.031573457	0.411259649	0.034941389	0.337359882	0.951453880	1.563714632	152.077559000	0.108928557	0.003678676	0.003633160	0.038847112	0.036579263	0.014228807	0.064196055	0.010457948	0.001480956	0.017552387	0.007138578
2014-05-30	0.95	0.49	C11 ST5	13.558721390	10.446808870	0.755925162	2.681876742	3.787888162	<0.148225000	<0.050675000	0.030526451	0.134964467	0.075815220	0.662334534	0.617682400	2.363074694	152.152807800	0.107156902	0.005634467	0.007917107	0.054159451	0.041934062	0.015185495	0.114600614	0.013676548	0.001158721	0.008618399	0.004914943
2014-05-30	<0.49		C11 BACK	10.002731590	20.342766200	0.799468974	1.492938750	3.189318143	0.832329571	0.009272616	0.297137938	1.518948007	0.113502241	1.100160984	0.616614306	3.998166822	177.012725200	0.151796833	0.012665891	0.006193604	0.080520411	0.073178441	0.019407455	0.139572953	0.006423484	0.002918767	0.049944152	0.021318250
2014-06-05	10.00	7.20	C12 ST1	25.754128020	0.285816082	0.496351165	3.065358101	2.061112598	28.922388570	0.028091013	0.020384152	2.160501241	0.006017919	0.068365051	0.041084831	0.191392951	24.391836740	0.003309415	0.000590483	<0.000103000	0.000498977	0.006036853	0.001173931	<0.000168000	<0.001755000	<0.000495000	0.017460110	0.008883058
2014-06-05	7.20	3.00	C12 ST2	87.072408340	0.462649492	2.129759109	10.473768800	6.376688676	128.195800800	<0.050675000	<0.000980000	17.523785180	0.016096556	0.083204315	0.248191412	0.749982676	40.590909160	0.057234627	0.001180934	0.000347752	0.008458583	0.031287717	0.005676051	0.006095824	0.001585585	<0.000495000	0.018319737	0.009477669
2014-06-05	3.00	1.50	C12 ST3	24.936583940	0.596198512	0.412933767	2.948155853	1.922076199	15.886529500	<0.050675000	<0.000980000	7.594565693	0.008880016	0.110659025	0.326896046	0.743273399	42.020203120	0.050445604	0.001013042	0.000391696	0.005421295	0.042797979	0.005713695	0.007828247	<0.001755000	<0.000495000	0.019421330	0.009681493
2014-06-05	1.50	0.95	C12 ST4	15.630950100	4.979189324	0.479694155	1.295584239	1.000661628	1.163915989	<0.050675000	0.029299594	1.313716000	0.024432425	0.205985508	0.727766685	1.534925159	58.002864050	0.067569255	0.002103632	0.002561877	0.018381852	0.045251841	0.008369790	0.033964092	<0.001755000	0.000538878	0.019473115	0.007869185
2014-06-05	0.95	0.49	C12 ST5	9.171943457	13.100777550	0.628151410	0.636047690	1.261034740	2.602491517	<0.050675000	0.045789250	0.137555278	0.045379832	0.391605227	0.357250275	1.983812019	106.702785100	0.065401396	0.004274814	0.003211162	0.025869733	0.047059366	0.010454302	0.075159053	0.000821699	0.000605557	0.014306867	0.005834047
2014-06-05	<0.49		C12 BACK	7.639982399	23.494830340	0.685714024	0.645488202	1.893015198	5.079454901	<0.050675000	0.324431411	1.372990301	0.132778473	0.988943089	0.822328308	4.510112619	125.403390500	0.204086590	0.015492526	0.007294578	0.076154970	0.145895580	0.025360029	0.136969703	0.004879146	0.002655051	0.076808025	0.035330296
2014-06-11	10.00	7.20	C13 ST1	7.955467418	0.523693674	0.186665057	1.715392742	1.337697942	12.342239290	<0.050675000	<0.000980000	2.759730117	0.010520954	0.048135573	0.109545612	0.354795917	5.826413332	0.012445942	0.001394416	<0.000103000	0.000868269	0.007868569	0.002544306	0.000998621	0.001280187	0.000398829	0.015237340	0.008111836
2014-06-11	7.20	3.00	C13 ST2	45.419705400	0.792433431	1.039648893	6.667425847	4.600203832	54.399585210	<0.050675000	0.008215148	18.869842490	0.015145188	0.086451821	0.396084400	1.489041195	36.808823420	0.096484638	0.001820949	0.000840455	0.013912664	0.037830143	0.010708516	0.014400857	0.002239930	0.000615016	0.019199294	0.009785393
2014-06-11	3.00	1.50	C13 ST3	13.174986810	1.258714145	0.315131338	1.894350548	1.678393164	5.696653146	<0.050675000	<0.000980000	7.704455266	0.013967730	0.067573141	0.442831105	1.577121735	26.082229980	0.076951880	0.001811225	0.001197964	0.013894866	0.027894311	0.011465797	0.016255908	0.001633425	0.000900649	0.018735174	0.008177482
2014-06-11	1.50	0.95	C13 ST4	8.022376081	6.536531135	0.338055665	1.230221219	1.311737442	3.487160732	<0.050675000	0.020790765	0.251681376	0.020289526	0.099673745	0.339237528	2.256230708	43.968782090	0.051995745	0.002642654	0.001436007	0.020671299	0.023564953	0.014478414	0.033228920	0.002367815	0.000908300	0.017537628	0.006960720
2014-06-11	0.95	0.49	C13 ST5	3.109113124	13.148995980	0.344527755	0.511412462	1.021994143	10.250065060	<0.050675000	0.024079537	0.199091238	0.052770203	0.322902519	0.658856342	3.626309232	103.942837800	0.124776109	0.005062774	0.004426652	0.038579734	0.039601301	0.019740552	0.091278718	0.001321223	0.001206021	0.016614665	0.006894130
2014-06-11	<0.49		C13 BACK	5.748676983	27.219917160	0.508521293	0.360829007	1.659283117	18.009051970	<0.050675000	0.262237071	1.289851188	0.108852434	0.827398986	1.106692249	7.084518842	132.524404900	0.242198525	0.019870782	0.007142694	0.089506357	0.156509469	0.037306637	0.167220586	0.008254432	0.004698651	0.061264097	0.027449017
2014-06-17	10.00	7.20	C14 ST1	13.833163930	0.352097741	0.189631396	2.945945753	3.127920028	24.899008640	<0.050675000	<0.000980000	0.612427192	0.004823314	0.069209191	0.109069138	0.091023653	19.111122990	0.004068207	0.000580246	<0.000103000	0.000418676	0.003797559	0.000985593	<0.000168000	<0.001755000	<0.000495000	0.026185759	0.006791883
2014-06-17	7.20	3.00	C14 ST2	109.286097400	0.016438476	4.789641930	8.877122162	5.588777385	131.182289400	1.446201238	0.183044669	5.123189007	0.044003935	0.514611869	0.212420992	<0.000262000	21.101633850	0.034293498	0.007625558	0.000243315	0.020770238	0.012850858	0.006773485	0.005998350	0.000971607	0.000508267	0.013536526	0.007172695
2014-06-17	3.00	1.50	C14 ST3	54.443007780	0.107225085	3.793680088	6.618938750	5.615897185	41.447261050	0.400280223	0.183363308	4.052750027	0.039244197	0.620051962	0.237885774	0.668674901	7.000702768	<0.000124000	0.011536658	0.000528315	0.027433323	0.013361440	0.005456208	0.006339977	0.001000686	<0.000495000	0.022745096	0.005477441
2014-06-17	1.50	0.95	C14 ST4	34.860911560	0.020170416	3.052806032	4.275051302	5.943225288	15.601233110	0.428553220	0.174340326	3.465186332	0.039893074	0.506350516	0.522953475	0.758067967	14.802998210	0.067807219	0.012143613	0.000926634	0.030074325	0.011686664	0.004042301	0.021654174	<0.001755000	0.000995631	0.030190791	0.013039764
2014-06-17	0.95	0.49	C14 ST5	31.572579050	0.223805139	3.118308168	3.383501439	5.377715576	4.809810804	0.168539964	0.148421435	1.791480396	0.051836327	0.631534812	0.511666325	1.708809572	35.866913780	0.082809368	0.010938013	0.001339091	0.025323887	0.020431377	0.005785883	0.052737435	0.003384942	0.001290150	0.020397069	0.008671192
2014-06-17	<0.49		C14 BACK	2.002393476	0.276976591	0.325172019	0.940575558	1.349439104	0.284821629	0.089101809	0.036015370	0.602105346	0.023685021	<0.000605000	0.138080102	<0.000262000	5.672691111	0.004687243	0.006400651	<0.000103000	0.002063694	0.000520945	0.000930683	0.001624702	0.002394281	0.000814690	0.079030672	0.023442554
2014-06-23	10.00	7.20	C15 ST1	38.681031110	<0.000426000	2.779644481	0.661534957	0.448205058	9.461944072	0.368497675	0.186931560	0.900474243	0.028552329	0.141212996	0.180414070	0.191154525	5.105261940	0.031543234	0.013315508	0.000513029	0.022975813	0.005942270	0.003107030	0.004551675	<0.001755000	0.000875299	0.017689991	0.003272184
2014-06-23	7.20	3.00	C15 ST2	75.100186030	<0.000426000	3.827345438	4.760248577	3.049568787	64.669590030	0.328624279	0.155409819	10.676334090	0.045072224	0.262844470	0.492543505	1.084166349	17.252274980	0.106791494	0.010994674	0.000752987	0.047999180	0.015269208	0.016998622	0.016576337	0.002651566	0.001736057	0.023815396	0.008046132
2014-06-23	3.00	1.50	C15 ST3	37.026003540	<0.000426000	2.616869060	2.591392769	2.978225761	14.459816600	0.431787571	0.157771675	8.141944935	0.039220499	0.254655411	0.392320835	0.971367390	5.740415782	0.113717104	0.016417816	0.000442106	0.044694415	0.012913103	0.010963137	0.017965692	0.001411401	0.001351856	0.022769737	0.005997848
2014-06-23	1.50	0.95	C15 ST4	38.639508060	<0.000426000	2.784235534	2.334578478	2.586152308	5.584379454	0.293327749	0.142455089	5.235811882	0.048921864	0.220158909	0.578660889	1.399493045	21.465948840	0.133737745	0.016375233	0.000717177	0.042325170	0.015822040	0.010241877	0.041729471	<0.001755000	0.001723203	0.026124218	0.012885694
2014-06-23	0.95	0.49	C15 ST5	39.600169380	2.325087400	4.152143648	3.718743493	5.332221640	3.371955197	0.040297658	0.135181946	1.976773304	0.069526778	0.427857497	0.888755809	2.626290645	58.469135600	0.177308896	0.013405155	0.002619578	0.042852262	0.027866960	0.018808905	0.088233043	0.003190361	0.002831335	0.015588297	0.008679836
2014-06-23	<0.49		C15 BACK	3.757348058	22.727140500	0.140392692	4.509829149	8.854530161	1.631270819	<0.050675000	0.238675347	1.081104874	0.092694467	0.871476864	1.441166220	0.227347199	103.971248800	0.214913904	0.014357949	0.011177176	0.072286191	0.170952026	0.064413457	0.145341021	0.013758305	0.007350990	0.089479111	0.032828352
2014-06-29	10.00	7.20	C16 ST1	39.173572990	<0.000426000	3.436756631	0.859196819	1.029738120	7.444697439	0.669999737	0.224383660	1.811078869	0.030487359	0.113426908	0.244918573	0.384153331	5.605801508	0.039557553	0.015874970	0.001129050	0.030877351	0.003953698	0.004493359	0.009494957	0.002940356	0.000839141	0.016901301	0.002512571
2014-06-29	7.20	3.00	C16 ST2	60.465955220	<0.000426000	4.028989221	4.100514569	4.987960958	26.147353650	0.376936613	0.147642281	8.297207921	0.046239336	0.245945537	0.679901942	0.075175855	26.364908050	0.180607043	0.011024251	0.001566375	0.073522117	0.008114464	0.021454065	0.035988279	<0.001755000	0.001557003	0.020777152	0.006989036
2014-06-29	3.00	1.50	C16 ST3	45.630490100	<0.000426000	3.230443866	4.407171625	7.467430890	13.357501560	0.307254645	0.137734076	7.056067133	0.043302463	0.203735007	0.776882679	1.649173774	20.453141160	0.193295935	0.013123073	0.000830275	0.063323407	0.007529974	0.020107848	0.036446083	<0.001755000	0.001790307	0.020151691	0.008038050
2014-06-29	1.50	0.95	C16 ST4	34.912775460	0.061991111	3.473596112	2.575168737	3.676803620	6.466515765	0.142697403	0.179062499	4.163534001	0.038153380	0.149392264	0.665427327	1.770504482	21.109724630	0.134263718	0.013911335	0.000934014	0.041929278	0.008598100	0.015485206	0.043865418	<0.001755000	0.001676158	0.026078630	0.016248798
2014-06-29	0.95	0.49	C16 ST5	35.938230280	1.085775387	4.021170070	4.348329803	6.524689070	3.974813355	0.030751450	0.135451468	2.092802248	0.048056715	0.312546500	0.896136037	2.951536933	44.780690830	0.137676457	0.017847902	0.002481934	0.057580275	0.025641930	0.026566195	0.098531915	0.003821512	0.002956276	0.022090916	0.015281095
2014-06-29	<0.49		C16 BACK	5.246365214	19.970528010	0.910872707	4.696594515	<0.088877000	3.307259284	0.008928804	0.272301240	1.865937274	0.054863453	0.526106541	1.168536412	5.397962337	90.107732730	0.106438578	0.015403569	0.007886272	0.060637652	0.122151631	0.055992632	0.110490320	0.015006647	0.006941959	0.135544673	0.050566846