Citation:

PANGAEA.928238

Name: Combined amino acids in aerosol samples from Ny-Alesund, Svalbard Island, 2015
Published: 2021-02-16
License: https://creativecommons.org/licenses/by/4.0/
Keywords: aerosol; amino acids; Arctic; ions; organic acids; sugars

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Abstract:

Combined amino acids (CAA) were quantified in 7 aerosol samples collected during the Arctic campaign at Gruvebadet Laboratory in 2015. Combined amino acids (CAA) refer to amino acids contained in peptides, polipeptides and proteins.

Aerosol samples were collected in quartz fiber filters. They were spiked with isotopically labelled standard solutions (2 - 3 µg/ml) prior extraction. CAA content was measured using HPLC-MS.

Keyword(s):

aerosol; amino acids; Arctic; ions; organic acids; sugars

Related to:

Feltracco, Matteo; Barbaro, Elena; Kirchgeorg, Torben; Spolaor, Andrea; Turetta, Clara; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2019): Free and combined L- and D-amino acids in Arctic aerosol. Chemosphere, 220, 412-421, https://doi.org/10.1016/j.chemosphere.2018.12.147

Feltracco, Matteo; Barbaro, Elena; Spolaor, Andrea; Vecchiato, Marco; Callegaro, Alice; Burgay, Francois; Vardè, Massimiliano; Maffezzoli, Niccolò; Dallo, Federico; Scoto, Federico; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2021): Year-round measurements of size-segregated low molecular weight organic acids in Arctic aerosol. Science of the Total Environment, 763, 142954, https://doi.org/10.1016/j.scitotenv.2020.142954

Feltracco, Matteo; Barbaro, Elena; Tedeschi, Silvia; Spolaor, Andrea; Turetta, Clara; Vecchiato, Marco; Morabito, Elisa; Zangrando, Roberta; Barbante, Carlo; Gambaro, Andrea (2020): Interannual variability of sugars in Arctic aerosol: Biomass burning and biogenic inputs. Science of the Total Environment, 706, 136089, https://doi.org/10.1016/j.scitotenv.2019.136089

Further details:

Barbaro, Elena; Zangrando, Roberta; Vecchiato, Marco; Piazza, R; Cairns, Warren R L; Capodaglio, G; Barbante, Carlo; Gambaro, Andrea (2015): Free amino acids in Antarctic aerosol: potential markers for the evolution and fate of marine aerosol. Atmospheric Chemistry and Physics, 15(10), 5457-5469, https://doi.org/10.5194/acp-15-5457-2015

Feltracco, Matteo; Barbaro, Elena; Contini, Daniele; Zangrando, Roberta; Toscano, Giuseppa; Battistel, Dario; Barbante, Carlo; Gambaro, Andrea (2018): Photo-oxidation products of α-pinene in coarse, fine and ultrafine aerosol: A new high sensitive HPLC-MS/MS method. Atmospheric Environment, 180, 149-155, https://doi.org/10.1016/j.atmosenv.2018.02.052

Coverage:

Latitude: 78.917500 * Longitude: 11.894167

Date/Time Start: 2015-04-14T00:00:00 * Date/Time End: 2015-06-13T00:00:00

Event(s):

Gruvebadet_Svalbard * Latitude: 78.917500 * Longitude: 11.894167 * Campaign: * Method/Device: Multiple investigations (MULT) * Comment: Aerosol samples

Comment:

For the analysis of CAAs, in a 1.5 mL vial, 500 mL of each sample extract was mixed with 500 mL of 12M HCl and 5 mL of ascorbic acid at a concentration of 1 ng/mL to avoid oxidation of the amino acids. The vial was flushed with a stream of nitrogen before sealing and placed in a heat-block at 110 °C for 24 h with a Liebig prototype glass condenser used to condense compounds in the vapor (gas) phase back down to the liquid phase under boiling conditions through heat exchange with the environment. The hydrolysis products were freeze-dried to eliminate traces of HCl. The dry residues were subsequently dissolved in 500 mL of ultrapure water and diluted 1:10 before analysis for total amino acids (TAAs). The extracts of the field blank filters were also hydrolyzed so all TAAs concentrations could be blank corrected. The concentrations of the CAAs were calculated as the difference between the TAAs and free amino acids (FAAs) concentrations.

Values below the detection limit of the measurements are indicated (<0.xxxxx).

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	DATE/TIME	Date/Time		Feltracco, Matteo		Geocode
2	Size fraction, upper threshold	Fraction upper	µm	Feltracco, Matteo
3	Size fraction, lower threshold	Fraction lower	µm	Feltracco, Matteo
4	Sample ID	Sample ID		Feltracco, Matteo
5	L-Alanine	L-Ala	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
6	D-Alanine	D-Ala	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
7	Glycine	Gly	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
8	L-Arginine	L-Arg	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
9	D-Arginine	D-Arg	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
10	L-Threonine	L-Thr	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
11	D-Threonine	D-Thr	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
12	Serine	Ser	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)	L & D
13	Histidine	His	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)	L & D
14	Ornithine	Ornithine	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)	L & D
15	L-Aspartic acid	L-Asp	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
16	D-Aspartic acid	D-Asp	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
17	L-Glutamic acid	L-Glu	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
18	D-Glutamic acid	D-Glu	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
19	L-Leucine and Isoleucine	L-Leu and L-Ile	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
20	D-Leucine and Isoleucine	D-Leu and D-Ile	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
21	L-Phenylalanine	L-Phe	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
22	D-Phenylalanine	D-Phe	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
23	L-Proline	L-Pro	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
24	L-Hydroxyproline	L-Hyp	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
25	D-Hydroxyproline	D-Hyp	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
26	L-Valine	L-Val	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)
27	D-Valine	D-Val	ng/m³	Feltracco, Matteo	High Performance Liquid Chromatography tandem mass spectrometry (HPLC-MS/MS)

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Size:

1085 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Date/Time	2 Fraction upper [µm]	3 Fraction lower [µm]	4 Sample ID	5 L-Ala [ng/m³]	6 D-Ala [ng/m³]	7 Gly [ng/m³]	8 L-Arg [ng/m³]	9 D-Arg [ng/m³]	10 L-Thr [ng/m³]	11 D-Thr [ng/m³]	12 Ser [ng/m³]	13 His [ng/m³]	14 Ornithine [ng/m³]	15 L-Asp [ng/m³]	16 D-Asp [ng/m³]	17 L-Glu [ng/m³]	18 D-Glu [ng/m³]	19 L-Leu and L-Ile [ng/m³]	20 D-Leu and D-Ile [ng/m³]	21 L-Phe [ng/m³]	22 D-Phe [ng/m³]	23 L-Pro [ng/m³]	24 L-Hyp [ng/m³]	25 D-Hyp [ng/m³]	26 L-Val [ng/m³]	27 D-Val [ng/m³]
2015-04-14	10.00	7.20	C1 ST1	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	0.033813052	<0.00274	<0.004567000	<0.002877000	<0.000060900	<0.000311000	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-04-14	7.20	3.00	C1 ST2	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.111277152	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	0.019500539	<0.00003
2015-04-14	3.00	1.50	C1 ST3	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	0.044892396	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.075758226	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	0.027457806	<0.00003
2015-04-14	1.50	0.95	C1 ST4	<0.000952000	<0.000196000	0.184574090	0.129242853	<0.00000	<0.000565000	0.006313602	<0.008938000	<0.000239000	<0.001269000	<0.00274	0.102582349	0.211128451	0.016638510	0.155412686	<0.00005	<0.001950000	0.003638092	0.026107228	<0.00021	<0.00000	0.068138355	<0.00003
2015-04-14	0.95	0.49	C1 ST5	<0.000952000	<0.000196000	0.111173445	<0.001098000	<0.00000	<0.000565000	0.000716991	<0.008938000	<0.000239000	0.013400990	<0.00274	0.181170404	<0.002877000	0.024327312	<0.000311000	<0.00005	<0.001950000	0.000443677	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-04-14	<0.49		C1 BACK	<0.000952000	<0.000196000	0.216802467	0.007414217	<0.00000	0.018447039	0.000979993	<0.008938000	<0.000239000	0.049049273	<0.00274	0.151921463	<0.002877000	0.033593197	0.167706824	<0.00005	0.056972382	0.001298545	0.023801008	<0.00021	<0.00000	0.051681277	<0.00003
2015-04-24	10.00	7.20	C2 ST1	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.026931806	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-04-24	7.20	3.00	C2 ST2	<0.000952000	<0.000196000	0.147121721	0.020331237	<0.00000	0.014101547	<0.000020700	<0.008938000	<0.000239000	0.011063643	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.082834889	<0.00005	0.020316327	<0.000002630	0.009841892	<0.00021	<0.00000	0.019713416	<0.00003
2015-04-24	3.00	1.50	C2 ST3	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.029092813	<0.00005	<0.001950000	<0.000002630	0.000104944	<0.00021	<0.00000	0.009451410	<0.00003
2015-04-24	1.50	0.95	C2 ST4	<0.000952000	<0.000196000	0.157706554	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	0.008823679	0.034238335	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	0.053086523	<0.00003
2015-04-24	0.95	0.49	C2 ST5	<0.000952000	<0.000196000	0.141789822	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	0.048037647	<0.002877000	0.032204107	<0.000311000	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-04-24	<0.49		C2 BACK	<0.000952000	0.012390780	0.407515013	0.030236907	<0.00000	0.007368425	<0.000020700	<0.008938000	0.022339600	<0.001269000	<0.00274	0.013301212	<0.002877000	0.041159864	0.038014374	<0.00005	0.101027011	<0.000002630	0.013688994	<0.00021	<0.00000	0.021688878	<0.00003
2015-05-04	10.00	7.20	C3 ST1	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	<0.000311000	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-04	7.20	3.00	C3 ST2	0.020846961	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	<0.000311000	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	0.027239202	<0.00003
2015-05-04	3.00	1.50	C3 ST3	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	<0.000311000	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	0.015466863	<0.00003
2015-05-04	1.50	0.95	C3 ST4	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	<0.000311000	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-04	0.95	0.49	C3 ST5	0.095328260	<0.000196000	0.140008451	0.071510525	<0.00000	<0.000565000	<0.000020700	0.157752884	<0.000239000	0.011270457	<0.00274	0.083456923	<0.002877000	0.005170799	0.091596114	<0.00005	0.023599158	<0.000002630	0.043842446	<0.00021	<0.00000	0.046670772	<0.00003
2015-05-04	<0.49		C3 BACK	0.033387265	0.023970441	0.213433599	0.068363400	<0.00000	0.028618860	<0.000020700	0.036756543	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	0.015253459	0.067225290	<0.00005	0.116743891	<0.000002630	0.043343832	<0.00021	<0.00000	0.032103515	<0.00003
2015-05-14	10.00	7.20	C4 ST1	<0.000952000	<0.000196000	0.040200784	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.008342269	<0.001269000	<0.00274	<0.004567000	0.035886003	<0.000060900	0.019600760	<0.00005	<0.001950000	<0.000002630	0.003251304	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-14	7.20	3.00	C4 ST2	<0.000952000	<0.000196000	0.099346976	0.015773871	<0.00000	0.008057316	<0.000020700	<0.008938000	0.012665573	<0.001269000	<0.00274	<0.004567000	0.031853332	<0.000060900	0.027219503	<0.00005	<0.001950000	<0.000002630	0.003614608	<0.00021	<0.00000	0.011636693	<0.00003
2015-05-14	3.00	1.50	C4 ST3	0.016270539	<0.000196000	0.084603345	0.044265111	<0.00000	0.023045749	<0.000020700	<0.008938000	0.026487965	<0.001269000	<0.00274	<0.004567000	0.141761781	<0.000060900	0.045845702	<0.00005	<0.001950000	<0.000002630	0.009012455	<0.00021	<0.00000	0.025097270	<0.00003
2015-05-14	1.50	0.95	C4 ST4	0.012827923	0.055217693	0.114650466	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.004075652	<0.001269000	<0.00274	<0.004567000	<0.002877000	0.021540453	0.015914296	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-14	0.95	0.49	C4 ST5	<0.000952000	<0.000196000	0.073191173	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.007654488	<0.001269000	<0.00274	<0.004567000	<0.002877000	0.002994574	0.013663157	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-14	<0.49		C4 BACK	0.022432768	0.026548890	0.172348960	0.024828465	<0.00000	0.014489084	<0.000020700	<0.008938000	0.020930954	<0.001269000	<0.00274	<0.004567000	0.146420447	0.035931652	0.054036630	<0.00005	0.036672111	<0.000002630	0.014531584	<0.00021	<0.00000	0.017141497	<0.00003
2015-05-24	10.00	7.20	C5 ST1	<0.000952000	<0.000196000	0.020288093	0.011573123	<0.00000	0.005772135	<0.000020700	<0.008938000	0.006615102	<0.001269000	<0.00274	<0.004567000	0.029361866	<0.000060900	0.018698974	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-24	7.20	3.00	C5 ST2	<0.000952000	<0.000196000	0.034349253	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.003398609	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.012508165	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-24	3.00	1.50	C5 ST3	<0.000952000	<0.000196000	0.025599020	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.010062969	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	0.008650154	<0.00003
2015-05-24	1.50	0.95	C5 ST4	<0.000952000	<0.000196000	0.056340110	0.024937326	<0.00000	0.014629702	<0.000020700	<0.008938000	0.013366240	<0.001269000	<0.00274	<0.004567000	0.083918059	0.007540469	0.024649373	<0.00005	<0.001950000	<0.000002630	0.007656636	<0.00021	<0.00000	0.009253761	<0.00003
2015-05-24	0.95	0.49	C5 ST5	<0.000952000	<0.000196000	0.039445927	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	0.005689333	0.013731915	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-05-24	<0.49		C5 BACK	0.022118340	<0.000196000	0.104455354	0.021862792	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	0.065999785	0.008678740	0.032806934	<0.00005	0.013200755	<0.000002630	0.006762465	<0.00021	<0.00000	0.009344356	<0.00003
2015-06-03	10.00	7.20	C6 ST1	<0.000952000	<0.000196000	0.037811711	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.006536039	<0.001269000	<0.00274	0.090393348	<0.002877000	<0.000060900	0.016171862	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-03	7.20	3.00	C6 ST2	<0.000952000	<0.000196000	0.075480361	0.022784757	<0.00000	0.006919215	<0.000020700	<0.008938000	0.003022606	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.033047240	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-03	3.00	1.50	C6 ST3	<0.000952000	<0.000196000	0.036783401	0.020303877	<0.00000	0.007320767	<0.000020700	<0.008938000	0.007229056	<0.001269000	<0.00274	<0.004567000	0.049468534	<0.000060900	0.031477979	<0.00005	<0.001950000	<0.000002630	0.003141597	<0.00021	<0.00000	0.005997457	<0.00003
2015-06-03	1.50	0.95	C6 ST4	<0.000952000	<0.000196000	0.042581143	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.005279957	<0.001269000	<0.00274	<0.004567000	0.043909898	0.005900146	0.019958349	<0.00005	<0.001950000	<0.000002630	0.002883849	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-03	0.95	0.49	C6 ST5	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	0.006424376	0.009378045	<0.00005	<0.001950000	<0.000002630	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-03	<0.49		C6 BACK	0.026062977	<0.000196000	0.115773918	0.006829931	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	0.067185240	0.011688453	0.021274579	<0.00005	0.014211896	<0.000002630	0.005002029	<0.00021	<0.00000	0.004514868	<0.00003
2015-06-13	10.00	7.20	C7 ST1	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.001644271	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.016039899	<0.00005	<0.001950000	0.006396378	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-13	7.20	3.00	C7 ST2	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.019940429	<0.00005	<0.001950000	0.008137046	<0.000281000	<0.00021	<0.00000	0.040558690	<0.00003
2015-06-13	3.00	1.50	C7 ST3	<0.000952000	<0.000196000	0.048159487	0.024824767	<0.00000	0.017118511	<0.000020700	<0.008938000	0.009852221	<0.001269000	<0.00274	<0.004567000	0.043803859	<0.000060900	0.038245487	<0.00005	<0.001950000	0.017059787	0.006054669	<0.00021	<0.00000	0.014353484	<0.00003
2015-06-13	1.50	0.95	C7 ST4	<0.000952000	<0.000196000	0.035147443	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	<0.000239000	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.006482779	<0.00005	<0.001950000	0.005156018	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-13	0.95	0.49	C7 ST5	<0.000952000	<0.000196000	<0.002554000	<0.001098000	<0.00000	<0.000565000	<0.000020700	<0.008938000	0.003789906	<0.001269000	<0.00274	<0.004567000	<0.002877000	<0.000060900	0.010219814	<0.00005	<0.001950000	0.007421088	<0.000281000	<0.00021	<0.00000	<0.000540000	<0.00003
2015-06-13	<0.49		C7 BACK	<0.000952000	<0.000196000	0.086413891	0.020123924	<0.00000	0.011678812	<0.000020700	0.031595082	<0.000239000	<0.001269000	<0.00274	<0.004567000	0.086249927	<0.000060900	0.025857787	<0.00005	0.017106752	0.022148699	0.007655904	<0.00021	<0.00000	0.010885951	<0.00003