Citation:

PANGAEA.927566

Name: Dissolved and particulate carbohydrates and inorganic ions in Antarctic surface seawater samples
Published: 2021-02-05
License: https://creativecommons.org/licenses/by/4.0/
Keywords: Antarctic Peninsula; carbohydrates; chloride; dissolved; DOC; Livingston Island; Monosaccharides; particulate; PI-ICE campaign; POC; SML; sodium; sugars; surface microlayer; Total chlorophyll

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Abstract:

Antarctic sea surface microlayer (SML) and bulk water samples were collected during the PI-ICE campaign from January until March 2019 at the west coast of the Antarctic Peninsula. SML samples were collected using the glass plate technique, corresponding bulk (subsurface) samples were collected by submerging a plastic bottle below the sea surface. Following chemical parameters were determined: dissolved organic carbon (DOC), particulate organic carbon (POC), total chlorophyll-a, main inorganic ions (chloride, sulfate, sodium, etc.), dissolved free carbohydrates (DFCHO), dissolved combined carbohydrates (DCCHO) and particulate combined carbohydrates (PCCHO). DCCHO and DFCHO were measured from filtered (0.2 µm) seawater after a desalination using electro-dialysis and high-performance anion exchange chromatography coupled with pulsed amperometric detection (HPAEC-PAD). PCCHO were measured from filters (0.2 µm polycarbonate membrane). DFCHO, DCCHO and PCCHO were determined as the sum of individual monosaccharides (e.g. arabinose, glucose, galactose, glucosamine, galactosamine, muramic acid, galacturonic acid, etc.). More details about the analytical procedures can be found in the manuscript. These data were collected in order to improve the understanding of the sea-air transfer of carbohydrates in this pristine environment. A corresponding data set for size-resolved aerosol particles can be found under following doi number (doi:10.1594/PANGAEA.927565).

Keyword(s):

Antarctic Peninsula; carbohydrates; chloride; dissolved; DOC; Livingston Island; Monosaccharides; particulate; PI-ICE campaign; POC; SML; sodium; sugars; surface microlayer; Total chlorophyll

Related to:

Zeppenfeld, Sebastian; Fuchs, Susanne; Rödger, Susanne; Dietze, Anett; van Pinxteren, Manuela; Herrmann, Hartmut (2021): Marine carbohydrates and inorganic ions in size-resolved atmospheric particles collected over the Southern Ocean. PANGAEA, https://doi.org/10.1594/PANGAEA.927565

Zeppenfeld, Sebastian; Fuchs, Susanne; van Pinxteren, Manuela; Sotomayor Garcia, Ana; Cabrera Brufau, Miguel; Vaqué, Dolors; Berdalet, Elisa; Dall'Osto, Manuel; Herrmann, Hartmut (2021): Aerosol marine primary carbohydrates and atmospheric transformation in the Western Antarctic Peninsula. ACS Earth and Space Chemistry, https://doi.org/10.1021/acsearthspacechem.0c00351

Project(s):

Arctic Amplification (AC3)

Funding:

German Research Foundation (DFG), grant/award no. 268020496 : TRR 172: ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms

Coverage:

Median Latitude: -64.235721 * Median Longitude: -62.935868 * South-bound Latitude: -67.794600 * West-bound Longitude: -68.878917 * North-bound Latitude: -60.384367 * East-bound Longitude: -60.302750

Date/Time Start: 2019-01-25T00:00:00 * Date/Time End: 2019-03-11T00:00:00

Minimum DEPTH, water: 0.00 m * Maximum DEPTH, water: 0.25 m

Event(s):

PI-ICE_WS1 * Latitude: -66.660667 * Longitude: -68.554000 * Date/Time: 2019-01-25T00:00:00 * Location: Antarctic Peninsula * Campaign: * Basis: * Method/Device: Water sample (WS)

PI-ICE_WS2 * Latitude: -67.794600 * Longitude: -67.331683 * Date/Time: 2019-01-26T00:00:00 * Location: Antarctic Peninsula * Campaign: * Basis: * Method/Device: Water sample (WS)

PI-ICE_WS3 * Latitude: -67.781833 * Longitude: -68.802639 * Date/Time: 2019-01-27T00:00:00 * Location: Antarctic Peninsula * Campaign: * Basis: * Method/Device: Water sample (WS)

Comment:

<0 = below detection limit, empty cells = not determined

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Comment
1	Event label	Event		Zeppenfeld, Sebastian
2	Sample code/label	Sample label		Zeppenfeld, Sebastian
3	DATE/TIME	Date/Time		Zeppenfeld, Sebastian	Geocode
4	LATITUDE	Latitude		Zeppenfeld, Sebastian	Geocode
5	LONGITUDE	Longitude		Zeppenfeld, Sebastian	Geocode
6	DEPTH, water	Depth water	m	Zeppenfeld, Sebastian	Geocode
7	Carbon, organic, dissolved	DOC	µmol/l	Zeppenfeld, Sebastian
8	Carbon, organic, particulate	POC	µmol/l	Zeppenfeld, Sebastian
9	Chlorophyll a	Chl a	µg/l	Zeppenfeld, Sebastian
10	Chlorophyll a allomers	Chl a allom	µg/l	Zeppenfeld, Sebastian
11	Chlorophyll a allomers	Chl a allom	µg/l	Zeppenfeld, Sebastian
12	Chlorophyll a, epimer	Chl a'	µg/l	Zeppenfeld, Sebastian
13	Chlorophyll a, epimer	Chl a'	µg/l	Zeppenfeld, Sebastian
14	Chlorophyll a, total	TChl a	µg/l	Zeppenfeld, Sebastian
15	Fucose	Fuc	µg/l	Zeppenfeld, Sebastian	DFCHO
16	Rhamnose	Rha	µg/l	Zeppenfeld, Sebastian	DFCHO
17	Arabinose	Ara	µg/l	Zeppenfeld, Sebastian	DFCHO
18	Galactose	Gal	µg/l	Zeppenfeld, Sebastian	DFCHO
19	Glucose	Glc	µg/l	Zeppenfeld, Sebastian	DFCHO
20	Xylose	Xyl	µg/l	Zeppenfeld, Sebastian	DFCHO
21	Mannose	Man	µg/l	Zeppenfeld, Sebastian	DFCHO
22	Fructose	Fru	µg/l	Zeppenfeld, Sebastian	DFCHO
23	Carbohydrates, dissolved, neutral free	DFCHO	µg/l	Zeppenfeld, Sebastian
24	Fucose	Fuc	µg/l	Zeppenfeld, Sebastian	DCCHO
25	Galactosamine	GalN	µg/l	Zeppenfeld, Sebastian	DCCHO
26	Rhamnose	Rha	µg/l	Zeppenfeld, Sebastian	DCCHO
27	Arabinose	Ara	µg/l	Zeppenfeld, Sebastian	DCCHO
28	Glucosamine	GlcN	µg/l	Zeppenfeld, Sebastian	DCCHO
29	Galactose	Gal	µg/l	Zeppenfeld, Sebastian	DCCHO
30	Glucose	Glc	µg/l	Zeppenfeld, Sebastian	DCCHO
31	Xylose	Xyl	µg/l	Zeppenfeld, Sebastian	DCCHO
32	Mannose	Man	µg/l	Zeppenfeld, Sebastian	DCCHO
33	Muramic acid	Mur	µg/l	Zeppenfeld, Sebastian	DCCHO
34	Galacturonic acid	GalA	µg/l	Zeppenfeld, Sebastian	DCCHO
35	Glucuronic acid	GlcA	µg/l	Zeppenfeld, Sebastian	DCCHO
36	Carbohydrates, dissolved combined	DCCHO	µg/l	Zeppenfeld, Sebastian
37	Fucose	Fuc	µg/l	Zeppenfeld, Sebastian	PCCHO
38	Galactosamine	GalN	µg/l	Zeppenfeld, Sebastian	PCCHO
39	Rhamnose	Rha	µg/l	Zeppenfeld, Sebastian	PCCHO
40	Arabinose	Ara	µg/l	Zeppenfeld, Sebastian	PCCHO
41	Glucosamine	GlcN	µg/l	Zeppenfeld, Sebastian	PCCHO
42	Galactose	Gal	µg/l	Zeppenfeld, Sebastian	PCCHO
43	Glucose	Glc	µg/l	Zeppenfeld, Sebastian	PCCHO
44	Xylose	Xyl	µg/l	Zeppenfeld, Sebastian	PCCHO
45	Mannose	Man	µg/l	Zeppenfeld, Sebastian	PCCHO
46	Muramic acid	Mur	µg/l	Zeppenfeld, Sebastian	PCCHO
47	Galacturonic acid	GalA	µg/l	Zeppenfeld, Sebastian	PCCHO
48	Glucuronic acid	GlcA	µg/l	Zeppenfeld, Sebastian	PCCHO
49	Carbohydrates, particulate hydrolyzable	PCCHO	µg/l	Zeppenfeld, Sebastian
50	Chloride	Cl-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
51	Nitrate	[NO3]-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
52	Sulfate	[SO4]2-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
53	Oxalate	[C2O4]2-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
54	Nitrite	[NO2]-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
55	Bromide	Br-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
56	Fluoride	F-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
57	Formic acid	Formic acid	mg/l	Zeppenfeld, Sebastian	Inorganic ions
58	Phosphate	[PO4]3-	mg/l	Zeppenfeld, Sebastian	Inorganic ions
59	Sodium	Na+	mg/l	Zeppenfeld, Sebastian	Inorganic ions
60	Ammonium	[NH4]+	mg/l	Zeppenfeld, Sebastian	Inorganic ions
61	Potassium	K+	mg/l	Zeppenfeld, Sebastian	Inorganic ions
62	Magnesium	Mg2+	mg/l	Zeppenfeld, Sebastian	Inorganic ions
63	Calcium	Ca2+	mg/l	Zeppenfeld, Sebastian	Inorganic ions

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Size:

2011 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Event	2 Sample label	3 Date/Time	4 Latitude	5 Longitude	6 Depth water [m]	7 DOC [µmol/l]	8 POC [µmol/l]	9 Chl a [µg/l]	10 Chl a allom [µg/l]	11 Chl a allom [µg/l]	12 Chl a' [µg/l]	13 Chl a' [µg/l]	14 TChl a [µg/l]	15 Fuc [µg/l] (DFCHO)	16 Rha [µg/l] (DFCHO)	17 Ara [µg/l] (DFCHO)	18 Gal [µg/l] (DFCHO)	19 Glc [µg/l] (DFCHO)	20 Xyl [µg/l] (DFCHO)	21 Man [µg/l] (DFCHO)	22 Fru [µg/l] (DFCHO)	23 DFCHO [µg/l]	24 Fuc [µg/l] (DCCHO)	25 GalN [µg/l] (DCCHO)	26 Rha [µg/l] (DCCHO)	27 Ara [µg/l] (DCCHO)	28 GlcN [µg/l] (DCCHO)	29 Gal [µg/l] (DCCHO)	30 Glc [µg/l] (DCCHO)	31 Xyl [µg/l] (DCCHO)	32 Man [µg/l] (DCCHO)	33 Mur [µg/l] (DCCHO)	34 GalA [µg/l] (DCCHO)	35 GlcA [µg/l] (DCCHO)	36 DCCHO [µg/l]	37 Fuc [µg/l] (PCCHO)	38 GalN [µg/l] (PCCHO)	39 Rha [µg/l] (PCCHO)	40 Ara [µg/l] (PCCHO)	41 GlcN [µg/l] (PCCHO)	42 Gal [µg/l] (PCCHO)	43 Glc [µg/l] (PCCHO)	44 Xyl [µg/l] (PCCHO)	45 Man [µg/l] (PCCHO)	46 Mur [µg/l] (PCCHO)	47 GalA [µg/l] (PCCHO)	48 GlcA [µg/l] (PCCHO)	49 PCCHO [µg/l]	50 Cl- [mg/l] (Inorganic ions)	51 [NO3]- [mg/l] (Inorganic ions)	52 [SO4]2- [mg/l] (Inorganic ions)	53 [C2O4]2- [mg/l] (Inorganic ions)	54 [NO2]- [mg/l] (Inorganic ions)	55 Br- [mg/l] (Inorganic ions)	56 F- [mg/l] (Inorganic ions)	57 Formic acid [mg/l] (Inorganic ions)	58 [PO4]3- [mg/l] (Inorganic ions)	59 Na+ [mg/l] (Inorganic ions)	60 [NH4]+ [mg/l] (Inorganic ions)	61 K+ [mg/l] (Inorganic ions)	62 Mg2+ [mg/l] (Inorganic ions)	63 Ca2+ [mg/l] (Inorganic ions)
PI-ICE_WS1	Bulk 1	2019-01-25T00:00	-66.660667	-68.554000	0.25	57.430	12.536	0.016	<0.000	<0.000	0.011	<0.000	0.026	<0.00	<0	<0.00	<0.00	2.11	<0.00	<0	<0.00	2.11	1.96	0.60	1.60	1.11	1.99	3.61	7.84	2.32	<0.00	1.02	10.27	1.27	33.60	1.23	0.41	1.29	0.88	0.66	4.95	19.08	5.17	1.19	0.52	0.61	0.41	36.40	21706.5	<0	2910.5	<0	<0.0	<0	<0.0	<0.0	<0	12139.0	<0.0	285.0	1081.5	238.0
PI-ICE_WS1	SML 1	2019-01-25T00:00	-66.660667	-68.554000	0.00									<0.00	<0	<0.00	0.17	6.44	<0.00	<0	<0.00	6.61	2.69	0.90	2.58	1.78	2.32	5.50	21.72	4.44	0.54	2.78	16.82	2.28	64.34	1.86	0.52	1.84	1.85	1.05	6.32	20.02	5.28	1.52	0.45	1.83	0.83	43.36	16111.0	<0	1085.5	<0	<0.0	<0	6.0	<0.0	<0	9077.0	16.0	219.5	616.5	162.5
PI-ICE_WS2	Bulk 2	2019-01-26T00:00	-67.794600	-67.331683	0.25	62.630	18.529	0.219	0.093	<0.000	0.047	<0.000	0.358	0.44	<0	<0.00	0.13	4.18	<0.00	<0	<0.00	4.75	4.62	1.03	4.99	2.20	2.00	6.31	74.45	4.04	<0.00	<0.00	<0.00	1.26	100.90	5.21	0.69	15.05	3.51	1.88	18.52	152.98	9.15	14.85	2.59	6.16	1.71	236.07	20356.5	<0	2838.5	<0	<0.0	<0	3.0	10.5	<0	11437.0	<0.0	271.5	1041.0	262.0
PI-ICE_WS2	SML 2	2019-01-26T00:00	-67.794600	-67.331683	0.00									<0.00	<0	<0.00	0.21	5.59	<0.00	<0	<0.00	5.79	5.02	0.88	4.89	1.67	2.06	5.27	22.73	4.02	<0.00	<0.00	<0.00	<0.00	46.55	3.22	0.63	5.88	2.55	1.50	8.88	28.03	8.16	6.05	0.65	4.77	1.21	71.54	14566.5	<0	1431.5	<0	<0.0	<0	1.5	28.5	<0	8146.0	<0.0	217.5	622.5	134.5
PI-ICE_WS3	Bulk 3	2019-01-27T00:00	-67.781833	-68.802639	0.25	55.640	34.964	0.046	0.009	<0.000	0.009	0.007	0.070	<0.00	<0	<0.00	<0.00	5.70	<0.00	<0	<0.00	5.70	3.21	0.91	2.86	1.55	2.83	4.94	0.08	2.30	<0.00	<0.00	<0.00	<0.00	18.68	2.83	0.90	1.43	0.89	1.92	12.76	14.69	4.51	3.03	0.89	1.73	0.87	46.46	20108.5	<0	1438.0	<0	<0.0	<0	13.5	<0.0	<0	11148.5	50.5	272.0	856.5	261.5
PI-ICE_WS3	SML 3	2019-01-27T00:00	-67.781833	-68.802639	0.00									<0.00	<0	<0.00	0.26	6.48	<0.00	<0	<0.00	6.74	2.51	0.76	2.37	1.08	1.72	3.29	0.01	2.81	<0.00	<0.00	<0.00	<0.00	14.55	4.61	1.51	2.61	2.11	3.19	22.06	18.06	6.80	5.60	0.98	1.45	1.27	70.26	27492.0	<0	3480.5	<0	<0.0	<0	3.0	22.5	<0	15325.0	<0.0	313.5	1470.0	290.5
PI-ICE_WS4	Bulk 4	2019-01-27T00:00	-67.770139	-68.873944	0.25	59.040	40.189	0.192	0.033	<0.000	0.036	0.006	0.268	<0.00	<0	<0.00	<0.00	1.35	<0.00	<0	<0.00	1.35	2.52	0.97	2.25	1.46	2.73	4.70	3.27	2.15	<0.00	<0.00	<0.00	<0.00	20.05	3.20	1.19	1.34	0.90	2.32	14.72	19.59	5.79	2.49	0.94	0.69	0.68	53.84	21297.0	<0	2766.5	<0	7.5	<0	3.0	30.0	<0	11914.0	<0.0	303.0	1075.5	260.5
PI-ICE_WS4	SML 4	2019-01-27T00:00	-67.770139	-68.873944	0.00									<0.00	<0	<0.00	0.26	8.20	<0.00	<0	<0.00	8.46	3.36	1.19	2.75	1.25	2.05	4.81	9.29	2.40	<0.00	<0.00	<0.00	1.33	28.45	3.71	1.35	1.89	1.19	2.68	15.25	28.99	11.65	4.23	2.00	1.91	0.94	75.79	16921.5	<0	1760.0	<0	<0.0	<0	1.5	18.0	<0	9421.0	<0.0	246.0	763.5	212.5
PI-ICE_WS5	Bulk 5	2019-01-27T00:00	-67.775833	-68.878917	0.25	147.630	42.531	0.215	0.171	<0.000	0.154	0.012	0.552	<0.00	<0	<0.00	<0.00	1.08	<0.00	<0	<0.00	1.08	2.70	0.83	2.32	1.53	1.42	3.84	4.96	2.56	<0.00	<0.00	<0.00	<0.00	20.17	2.83	0.94	1.10	0.60	1.71	11.73	17.75	3.55	3.76	0.66	3.64	0.45	48.70	20793.0	<0	2628.5	<0	<0.0	<0	3.0	30.0	<0	11635.0	<0.0	276.0	1008.0	271.0
PI-ICE_WS5	SML 5	2019-01-27T00:00	-67.775833	-68.878917	0.00									<0.00	<0	<0.00	<0.00	3.60	<0.00	<0	<0.00	3.60	2.83	0.86	1.98	1.19	0.72	4.21	4.22	2.31	1.09	<0.00	<0.00	<0.00	19.41	3.42	1.04	1.49	1.00	2.18	11.35	19.77	5.66	3.47	0.22	3.61	1.87	55.09	20482.5	<0	2144.0	<0	<0.0	<0	1.5	37.5	<0	11384.5	<0.0	271.5	967.5	248.5
PI-ICE_WS6	Bulk 6	2019-01-29T00:00	-64.814639	-63.772556	0.25	48.500	12.240	0.017	<0.000	0.074	0.023	0.005	0.120	<0.00	<0	<0.00	<0.00	2.41	<0.00	<0	<0.00	2.41	1.62	0.64	1.29	0.83	1.38	3.13	4.93	1.15	<0.00	<0.00	<0.00	2.58	17.53	3.11	0.70	4.03	0.70	1.04	9.33	21.49	3.83	1.45	<0.00	<0.00	<0.00	45.67	19998.0	<0	2526.5	<0	<0.0	<0	3.0	22.5	<0	11536.0	<0.0	259.5	895.5	190.0
PI-ICE_WS6	SML 6	2019-01-29T00:00	-64.814639	-63.772556	0.00									<0.00	<0	0.14	0.23	7.61	0.36	<0	1.38	9.72	2.26	0.92	2.62	1.81	1.88	5.84	16.10	3.76	<0.00	<0.00	<0.00	<0.00	35.18	4.26	0.86	4.45	1.70	1.82	11.69	30.08	7.72	3.49	1.42	<0.00	1.80	69.30	14395.5	<0	1392.5	<0	<0.0	<0	1.5	9.0	<0	8074.0	<0.0	222.0	604.5	169.0
PI-ICE_WS7	Bulk 7	2019-01-30T00:00	-64.015250	-60.987500	0.25	57.470	15.198	0.058	0.064	<0.000	0.048	0.012	0.182	<0.00	<0	<0.00	<0.00	2.73	<0.00	<0	<0.00	2.73	1.50	0.56	1.70	1.04	1.52	2.93	0.90	1.20	<0.00	<0.00	6.23	1.44	19.02	1.11	0.35	1.71	0.82	0.86	6.59	11.17	3.99	0.56	0.68	<0.00	0.27	28.11	17649.0	<0	2081.0	<0	<0.0	<0	3.0	22.5	<0	10054.0	<0.0	244.5	781.5	188.5
PI-ICE_WS7	SML 7	2019-01-30T00:00	-64.015250	-60.987500	0.00	64.430								<0.00	<0	<0.00	<0.00	3.71	<0.00	<0	<0.00	3.71	1.64	0.75	1.35	0.86	1.55	2.67	5.76	1.45	<0.00	<0.00	<0.00	<0.00	16.02	1.45	0.52	2.02	0.89	0.96	6.54	23.19	4.53	0.91	0.46	<0.00	0.61	42.07	17506.5	<0	1799.0	<0	<0.0	<0	<0.0	9.0	<0	9737.5	<0.0	235.5	784.5	224.5
PI-ICE_WS8	Bulk 8	2019-01-30T00:00	-64.153833	-60.973056	0.25	47.940	18.525	0.073	0.078	<0.000	0.046	0.011	0.208	<0.00	<0	<0.00	<0.00	1.38	<0.00	<0	<0.00	1.38	1.42	0.58	1.47	0.76	1.29	1.69	4.07	1.24	<0.00	<0.00	9.20	0.97	22.69	1.17	0.42	1.77	0.87	0.92	5.75	15.85	5.18	1.13	1.38	<0.00	0.56	35.00	18190.5	<0	2091.5	<0	6.0	<0	1.5	43.5	<0	10226.5	<0.0	262.5	861.0	202.0
PI-ICE_WS8	SML 8	2019-01-30T00:00	-64.153833	-60.973056	0.00									<0.00	<0	<0.00	<0.00	1.99	<0.00	<0	<0.00	1.99	1.56	0.68	1.96	0.77	1.46	3.07	10.04	1.69	<0.00	<0.00	<0.00	0.70	21.92	4.13	1.32	4.33	1.62	2.37	11.88	26.73	7.39	2.40	0.98	<0.00	1.50	64.64	16407.0	<0	1695.5	<0	<0.0	<0	1.5	30.0	<0	9137.5	<0.0	235.5	720.0	172.0
PI-ICE_WS13	Bulk 13	2019-02-22T00:00	-62.651500	-60.637567	0.25	52.890	25.845	0.853	0.446	<0.000	0.239	<0.000	1.537	<0.00	<0	<0.00	<0.00	3.20	<0.00	<0	<0.00	3.20	1.08	0.69	1.10	0.74	0.19	3.02	11.46	2.42	<0.00	<0.00	<0.00	10.62	31.33	1.95	0.86	2.21	0.63	1.31	13.39	57.15	4.97	0.96	5.85	3.80	2.37	95.45	25829.5	<0	2179.0	<0	<0.0	<0	15.0	<0.0	<0	14361.5	26.5	303.5	1311.0	332.0
PI-ICE_WS13	SML 13	2019-02-22T00:00	-62.651500	-60.637567	0.00	121.950		1.149	0.487	<0.000	0.286	0.059	1.981	<0.00	<0	<0.00	<0.00	1.57	<0.00	<0	<0.00	1.57	2.12	0.87	1.80	1.26	1.82	4.97	25.30	3.16	<0.00	4.89	22.15	1.87	70.21	7.03	2.19	6.08	2.73	4.16	27.78	105.10	16.44	5.79	7.92	10.56	6.79	202.56	22722.0	<0	2934.5	<0	<0.0	<0	1.5	24.0	<0	12586.0	<0.0	285.0	1111.5	398.5
PI-ICE_WS14	Bulk 14	2019-02-22T00:00	-60.384367	-60.384367	0.25	64.720	28.605	0.781	0.163	<0.000	0.069	<0.000	1.013	<0.00	<0	<0.00	<0.00	3.74	<0.00	<0	<0.00	3.74	1.95	0.97	0.69	0.50	1.21	5.54	52.39	1.89	<0.00	<0.00	<0.00	<0.00	65.14	2.66	1.10	2.75	0.85	1.50	14.99	43.13	5.85	2.24	5.68	2.47	2.57	85.79	19707.0	<0	2219.0	<0	<0.0	<0	<0.0	61.5	<0	10996.0	<0.0	262.5	958.5	254.5
PI-ICE_WS14	SML 14	2019-02-22T00:00	-60.384367	-60.384367	0.00	105.160		0.223	0.265	<0.000	0.076	0.080	0.644	<0.00	<0	<0.00	0.63	16.85	<0.00	<0	<0.00	17.48	1.49	1.02	1.04	0.74	0.94	3.84	10.61	1.98	<0.00	4.95	<0.00	4.30	30.91	2.53	1.15	3.46	1.07	1.76	12.75	48.64	9.71	2.30	2.97	4.23	3.19	93.75	18564.0	<0	1905.5	<0	<0.0	<0	3.0	9.0	<0	10357.0	<0.0	246.0	877.5	163.0
PI-ICE_WS15	Bulk 15	2019-02-25T00:00	-62.662833	-60.442278	0.25	63.770	44.453	1.504	0.462	<0.000	0.235	0.027	2.228	<0.00	<0	<0.00	<0.00	3.22	<0.00	<0	<0.00	3.22	1.81	0.78	1.48	0.68	1.32	4.98	31.19	2.18	<0.00	5.09	<0.00	3.82	53.34	1.89	1.16	2.34	0.85	1.67	22.54	127.63	5.22	1.60	10.72	2.09	3.03	180.73	23022.0	<0	2748.5	<0	<0.0	<0	1.5	21.0	<0	12767.5	<0.0	282.0	1147.5	512.5
PI-ICE_WS15	Bulk 15 B	2019-02-25T00:00	-62.662833	-60.442278	0.25			0.681	0.207	<0.000	0.155	0.034	1.077	<0.00	<0	<0.00	0.33	9.23	<0.00	<0	<0.00	9.55	2.04	1.00	1.43	1.37	2.03	8.31	53.11	3.55	1.51	<0.00	<0.00	0.89	75.25	2.20	1.25	2.65	0.85	2.11	33.37	169.33	8.97	4.11	14.51	4.01	4.25	247.62	19293.0	<0	2150.0	<0	<0.0	<0	1.5	34.5	<0	10724.5	<0.0	279.0	936.0	245.5
PI-ICE_WS15	SML 15	2019-02-25T00:00	-62.662833	-60.442278	0.00	129.370		0.567	0.427	<0.000	0.228	0.089	1.311	<0.00	<0	<0.00	0.34	11.96	<0.00	<0	<0.00	12.30	2.67	0.85	1.79	1.79	2.51	11.08	209.45	3.02	<0.00	16.61	38.23	6.32	294.31	3.08	1.75	4.36	1.12	2.79	29.63	128.07	11.93	4.00	12.88	4.24	5.46	209.31	17178.0	<0	1743.5	<0	<0.0	<0	1.5	24.0	<0	9485.5	<0.0	238.5	813.0	227.5
PI-ICE_WS16	Bulk 16	2019-03-02T00:00	-63.033639	-60.595417	0.25	192.380	13.251	0.325	0.156	<0.000	0.054	0.022	0.557	<0.00	<0	<0.00	<0.00	2.66	<0.00	<0	<0.00	2.66	0.96	0.52	1.08	0.43	0.93	2.47	4.07	1.65	<0.00	<0.00	<0.00	2.21	14.32	0.82	0.38	1.07	0.43	0.51	5.11	22.92	2.96	0.95	1.33	<0.00	0.56	37.04	19560.0	<0	2166.5	<0	<0.0	<0	1.5	10.5	<0	10936.0	<0.0	255.0	964.5	179.5
PI-ICE_WS16	SML 16	2019-03-02T00:00	-63.033639	-60.595417	0.00	252.837		0.510	0.133	<0.000	0.046	0.018	0.706	<0.00	<0	<0.00	0.36	11.27	<0.00	<0	<0.00	11.63	1.24	0.77	1.30	1.47	1.91	5.71	18.12	1.44	<0.00	<0.00	<0.00	2.04	34.00	1.89	0.85	2.16	1.24	1.17	9.43	34.77	4.40	1.19	2.59	3.09	1.50	64.29	16110.0	<0	1560.5	<0	<0.0	<0	1.5	7.5	<0	8942.5	<0.0	225.0	700.5	122.5
PI-ICE_WS16	SML 16 bis	2019-03-02T00:00	-63.033639	-60.595417	0.00			0.514	<0.000	0.084	0.021	0.018	0.637	<0.00	<0	<0.00	<0.00	2.27	<0.00	<0	1.45	3.73	1.16	0.58	1.39	0.39	1.08	3.62	7.34	1.32	<0.00	<0.00	<0.00	<0.00	16.88	1.67	0.81	2.35	0.83	1.26	9.75	46.32	5.68	1.02	2.03	5.83	1.74	79.29	14247.0	<0	1826.0	<0	<0.0	<0	1.5	42.0	<0	8441.5	<0.0	222.0	520.5	166.0
PI-ICE_WS17	Bulk 17	2019-03-03T00:00	-63.150944	-60.520583	0.25	131.110	7.853	0.068	0.014	<0.000	<0.000	0.010	0.092	<0.00	<0	<0.00	<0.00	6.71	<0.00	<0	<0.00	6.71	1.78	0.63	1.47	0.95	0.45	4.20	10.32	2.10	<0.00	2.97	17.68	2.06	44.61	0.92	0.39	0.92	0.44	0.60	3.04	13.46	2.06	0.64	0.49	<0.00	0.45	23.40	17085.0	<0	1874.0	<0	<0.0	<0	1.5	22.5	<0	9554.5	<0.0	247.5	816.0	191.5
PI-ICE_WS17	SML 17	2019-03-03T00:00	-63.150944	-60.520583	0.00	157.700	15.639	0.069	0.009	<0.000	<0.000	<0.000	0.078	<0.00	<0	<0.00	<0.00	2.19	<0.00	<0	<0.00	2.19	1.26	0.52	1.19	1.03	0.20	3.39	8.08	1.92	<0.00	2.09	22.75	2.83	45.25	1.15	0.49	0.94	0.64	0.78	3.55	11.69	3.00	0.75	0.43	<0.00	0.95	24.37	18887.5	<0	1388.5	<0	<0.0	<0	1.5	<0.0	<0	10604.0	14.5	225.5	814.5	245.0
PI-ICE_WS18	Bulk 18	2019-03-05T00:00	-62.642694	-60.431056	0.25	236.650	11.316	0.347	0.041	<0.000	0.014	0.009	0.411	<0.00	<0	<0.00	<0.00	1.61	<0.00	<0	<0.00	1.61	1.35	0.94	2.66	1.64	1.11	2.72	4.65	1.86	<0.00	<0.00	3.32	0.46	20.71	0.80	0.34	0.78	0.29	0.51	4.03	12.53	1.48	0.89	0.57	0.76	0.64	23.63	17248.5	<0	1862.0	<0	<0.0	<0	1.5	13.5	<0	9647.5	<0.0	262.5	787.5	232.0
PI-ICE_WS18	SML 18	2019-03-05T00:00	-62.642694	-60.431056	0.00	456.210	22.049	0.425	0.077	<0.000	0.032	0.016	0.550	<0.00	<0	<0.00	<0.00	2.08	<0.00	<0	<0.00	2.08	1.29	0.59	1.37	0.56	1.07	3.36	30.20	1.69	<0.00	<0.00	<0.00	<0.00	40.13	1.36	0.61	1.62	0.57	0.84	4.97	27.73	3.78	1.34	1.03	2.17	1.29	47.32	18132.0	<0	1910.0	<0	<0.0	<0	1.5	16.5	<0	10019.5	<0.0	256.5	787.5	572.5
PI-ICE_WS19	Bulk 19	2019-03-09T00:00	-62.687861	-60.302750	0.25	266.090	5.717	0.089	<0.000	<0.000	0.014	0.004	0.107	<0.00	<0	<0.00	<0.00	3.52	<0.00	<0	0.84	4.36	1.14	0.40	0.88	0.66	0.85	3.22	13.87	1.14	<0.00	<0.00	<0.00	<0.00	22.17	0.45	0.20	0.60	0.45	0.47	1.68	13.64	2.27	<0.00	<0.00	<0.00	<0.00	19.75	19281.0	<0	1983.5	<0	<0.0	<0	3.0	37.5	<0	10757.5	<0.0	259.5	894.0	206.5
PI-ICE_WS19	SML 19	2019-03-09T00:00	-62.687861	-60.302750	0.00	274.030	22.825	0.283	0.010	<0.000	0.009	<0.000	0.301	<0.00	<0	<0.00	1.10	3.15	<0.00	<0	<0.00	4.25	1.50	0.78	1.98	1.50	1.29	7.03	18.87	2.13	<0.00	<0.00	<0.00	<0.00	35.07	0.95	0.46	1.34	0.64	0.90	4.07	17.25	2.87	0.97	0.89	<0.00	0.65	30.99	15931.5	<0	1653.5	<0	<0.0	<0	1.5	39.0	<0	8825.5	<0.0	226.5	694.5	187.0
PI-ICE_WS20	Bulk 20	2019-03-09T00:00	-62.763944	-60.418250	0.25	670.620	13.948	0.266	<0.000	0.072	0.045	<0.000	0.384	<0.00	<0	<0.00	<0.00	1.00	<0.00	<0	<0.00	1.00	1.55	0.62	0.81	0.59	1.18	3.06	6.03	1.87	<0.00	<0.00	<0.00	<0.00	15.70	0.73	0.37	0.78	0.41	0.42	3.86	23.76	1.10	1.25	0.56	<0.00	0.30	33.53	17874.0	<0	1890.5	<0	<0.0	<0	1.5	24.0	<0	10006.0	<0.0	250.5	834.0	196.0
PI-ICE_WS20	SML 20	2019-03-09T00:00	-62.763944	-60.418250	0.00	206.040	23.071	0.122	0.016	<0.000	0.006	<0.000	0.144	<0.00	<0	<0.00	<0.00	6.04	<0.00	<0	<0.00	6.04	1.80	0.64	2.24	3.42	1.28	7.64	15.02	4.26	<0.00	<0.00	<0.00	<0.00	36.31	1.00	0.48	0.97	0.50	0.65	4.73	22.33	4.43	0.39	0.50	<0.00	0.75	36.72	14637.0	86	1419.5	<0	<0.0	<0	1.5	21.0	<0	8168.5	<0.0	243.0	589.5	173.5
PI-ICE_WS21	Bulk 21	2019-03-11T00:00	-62.650167	-60.420222	0.25	561.460	11.194	0.252	0.048	<0.000	0.034	0.005	0.338	<0.00	<0	<0.00	<0.00	1.11	<0.00	<0	<0.00	1.11	1.40	0.53	1.02	0.76	0.85	2.35	8.16	3.83	<0.00	<0.00	<0.00	<0.00	18.91	0.76	0.38	1.05	0.31	0.45	4.02	16.60	1.85	1.11	0.44	<0.00	0.36	27.34	19386.0	<0	1995.5	<0	<0.0	<0	1.5	19.5	<0	10820.5	<0.0	262.5	894.0	206.5
PI-ICE_WS21	SML 21	2019-03-11T00:00	-62.650167	-60.420222	0.00	421.850	18.177							<0.00	<0	<0.00	<0.00	1.14	<0.00	<0	<0.00	1.14	1.45	0.54	0.89	0.49	0.83	4.84	5.86	2.67	<0.00	<0.00	<0.00	<0.00	17.58	0.50	0.14	0.46	0.23	0.34	1.56	7.05	2.06	0.82	<0.00	<0.00	<0.00	13.15	13821.0	<0	1277.0	<0	<0.0	<0	1.5	27.0	<0	7720.0	<0.0	208.5	549.0	116.5