Citation:

PANGAEA.927565

Name: Marine carbohydrates and inorganic ions in size-resolved atmospheric particles collected over the Southern Ocean
Published: 2021-02-05
License: https://creativecommons.org/licenses/by/4.0/
Keywords: aerosol particles; Berner; carbohydrates; chloride; glucose; Hesperides; inorganic ions; Juan Carlos I; Livingston Island; Monosaccharides; PI-ICE; polysaccharides; size-resolved; sodium; Southern Ocean; sugars

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Abstract:

Size-resolved atmospheric particles were collected over the Southern Ocean west of the Antarctic Peninsula during the PI-ICE campaign (2019) using a five-stage low-pressure BERNER impactor. The size of the particles ranged between 50 nm and 10 µm. Sampling was conducted on board the Spanish research vessel B.I.O. Hespérides and at the research station Juan Carlos I located on Livingston Island. These aerosol particle samples were characterized on following chemical parameters: Particle mass concentration, inorganic ions, monosaccharides contained in polysaccharides after acid hydrolysis.

Keyword(s):

aerosol particles; Berner; carbohydrates; chloride; glucose; Hesperides; inorganic ions; Juan Carlos I; Livingston Island; Monosaccharides; PI-ICE; polysaccharides; size-resolved; sodium; Southern Ocean; sugars

Related to:

Zeppenfeld, Sebastian; Fuchs, Susanne; van Pinxteren, Manuela; Sotomayor Garcia, Ana; Cabrera Brufau, Miguel; Vaqué, Dolors; Berdalet, Elisa; Dall'Osto, Manuel; Herrmann, Hartmut (2021): Aerosol marine primary carbohydrates and atmospheric transformation in the Western Antarctic Peninsula. ACS Earth and Space Chemistry, https://doi.org/10.1021/acsearthspacechem.0c00351

Zeppenfeld, Sebastian; Fuchs, Susanne; van Pinxteren, Manuela; Sotomayor Garcia, Ana; Cabrera Brufau, Miguel; Vaqué, Dolors; Berdalet, Elisa; Dall'Osto, Manuel; Herrmann, Hartmut (2021): Dissolved and particulate carbohydrates and inorganic ions in Antarctic surface seawater samples. PANGAEA, https://doi.org/10.1594/PANGAEA.927566

Project(s):

Arctic Amplification (AC3)

Funding:

German Research Foundation (DFG), grant/award no. 268020496 : TRR 172: ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms

Coverage:

Median Latitude: -63.622500 * Median Longitude: -61.848750 * South-bound Latitude: -67.780000 * West-bound Longitude: -68.850000 * North-bound Latitude: -62.660000 * East-bound Longitude: -60.390000

Date/Time Start: 2019-01-25T02:54:00 * Date/Time End: 2019-03-11T20:00:00

Minimum ALTITUDE: 4 m * Maximum ALTITUDE: 18 m

Event(s):

PI-ICE_Berner1 * Latitude: -64.930000 * Longitude Start: -63.310000 * Date/Time Start: 2019-01-25T02:54:00 * Date/Time End: 2019-01-27T15:30:00 * Location: Antarctic Peninsula * Campaign: * Basis: * Method/Device: Five-stage low-pressure BERNER impactor (BERNER)

PI-ICE_Berner2 * Latitude: -67.780000 * Longitude Start: -68.850000 * Date/Time Start: 2019-01-28T05:01:00 * Date/Time End: 2019-01-31T05:04:00 * Location: Antarctic Peninsula * Campaign: * Basis: * Method/Device: Five-stage low-pressure BERNER impactor (BERNER)

PI-ICE_Berner3 * Latitude: -62.970000 * Longitude Start: -60.680000 * Date/Time Start: 2019-02-03T20:03:00 * Date/Time End: 2019-02-06T13:58:00 * Location: Antarctic Peninsula * Campaign: * Basis: * Method/Device: Five-stage low-pressure BERNER impactor (BERNER)

Comment:

#0 = below detection limit, empty cells = not determined

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Event label	Event		Zeppenfeld, Sebastian
2	Sample code/label	Sample label		Zeppenfeld, Sebastian
3	ALTITUDE	Altitude	m	Zeppenfeld, Sebastian		Geocode
4	Aerosol, particle size range	Aerosol size range		Zeppenfeld, Sebastian		in µm
5	Air volume	Air vol	m³	Zeppenfeld, Sebastian
6	DATE/TIME	Date/Time		Zeppenfeld, Sebastian		Geocode – start sampling, UTC
7	LATITUDE	Latitude		Zeppenfeld, Sebastian		Geocode – start sampling
8	LONGITUDE	Longitude		Zeppenfeld, Sebastian		Geocode – start sampling
9	DATE/TIME	Date/Time		Zeppenfeld, Sebastian		Geocode – end sampling, UTC
10	Latitude 2	Latitude 2		Zeppenfeld, Sebastian		end sampling
11	Longitude 2	Longitude 2		Zeppenfeld, Sebastian		end sampling
12	Wind speed	ff	m/s	Zeppenfeld, Sebastian		averaged over sampling time
13	Wind speed, standard deviation	ff std	±	Zeppenfeld, Sebastian		averaged over sampling time
14	Temperature, air	TTT	°C	Zeppenfeld, Sebastian		averaged over sampling time
15	Temperature, air, standard deviation	TTT std dev	±	Zeppenfeld, Sebastian		averaged over sampling time
16	Humidity, relative	RH	%	Zeppenfeld, Sebastian		averaged over sampling time
17	Humidity, relative, standard deviation	RH std	±	Zeppenfeld, Sebastian		averaged over sampling time
18	Short-wave downward (GLOBAL) radiation	SWD	W/m²	Zeppenfeld, Sebastian		averaged over sampling time
19	Short-wave downward (GLOBAL) radiation, standard deviation	SWD std dev	W/m²	Zeppenfeld, Sebastian		averaged over sampling time
20	Aerosols	Aerosol	µg/m³	Zeppenfeld, Sebastian	Microbalance Mettler Toledo XP2U	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
21	Fucose	Fuc	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
22	Galactosamine	GaIN	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
23	Rhamnose	Rha	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
24	Arabinose	Ara	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
25	Glucosamine	GlcN	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
26	Galactose	Gal	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
27	Glucose	Glc	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
28	Xylose	Xyl	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
29	Mannose	Man	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
30	Muramic acid	Mur	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
31	Galacturonic acid	GalA	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
32	Glucuronic acid	GlcA	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
33	Carbohydrates, combined, total	CCHO	pg/m³	Zeppenfeld, Sebastian	High-Perfomrance Anion-Exchange Chromatography coupled with Pulsed Amperometric Detection (Dionex ICS-3000, Thermo Scientific)	Atmospheric aerosol particles after acid hydrolysis (CCHOaer)
34	Chloride	Cl-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
35	Nitrate	[NO3]-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
36	Sulfate	[SO4]2-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
37	Oxalate	[C2O4]2-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
38	Nitrite	[NO2]-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
39	Bromide	Br-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
40	Fluoride	F-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
41	Methane sulfonic acid	MSA	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
42	Phosphate	[PO4]3-	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
43	Sodium	Na+	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
44	Ammonium	[NH4]+	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
45	Potassium	K+	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
46	Magnesium	Mg2+	µg/m³	Zeppenfeld, Sebastian	Ion chromatograph, Dionex Corporation, ICS-6000
47	Comment	Comment		Zeppenfeld, Sebastian

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Size:

1540 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Event	2 Sample label	3 Altitude [m]	4 Aerosol size range (in µm)	5 Air vol [m³]	6 Date/Time (start sampling, UTC)	7 Latitude (start sampling)	8 Longitude (start sampling)	9 Date/Time (end sampling, UTC)	10 Latitude 2 (end sampling)	11 Longitude 2 (end sampling)	12 ff [m/s] (averaged over sampling time)	13 ff std [±] (averaged over sampling time)	14 TTT [°C] (averaged over sampling time)	15 TTT std dev [±] (averaged over sampling time)	16 RH [%] (averaged over sampling time)	17 RH std [±] (averaged over sampling time)	18 SWD [W/m²] (averaged over sampling time)	19 SWD std dev [W/m²] (averaged over sampling time)	20 Aerosol [µg/m³] (Atmospheric aerosol particles...)	21 Fuc [pg/m³] (Atmospheric aerosol particles...)	22 GaIN [pg/m³] (Atmospheric aerosol particles...)	23 Rha [pg/m³] (Atmospheric aerosol particles...)	24 Ara [pg/m³] (Atmospheric aerosol particles...)	25 GlcN [pg/m³] (Atmospheric aerosol particles...)	26 Gal [pg/m³] (Atmospheric aerosol particles...)	27 Glc [pg/m³] (Atmospheric aerosol particles...)	28 Xyl [pg/m³] (Atmospheric aerosol particles...)	29 Man [pg/m³] (Atmospheric aerosol particles...)	30 Mur [pg/m³] (Atmospheric aerosol particles...)	31 GalA [pg/m³] (Atmospheric aerosol particles...)	32 GlcA [pg/m³] (Atmospheric aerosol particles...)	33 CCHO [pg/m³] (Atmospheric aerosol particles...)	34 Cl- [µg/m³] (Ion chromatograph, Dionex Cor...)	35 [NO3]- [µg/m³] (Ion chromatograph, Dionex Cor...)	36 [SO4]2- [µg/m³] (Ion chromatograph, Dionex Cor...)	37 [C2O4]2- [µg/m³] (Ion chromatograph, Dionex Cor...)	38 [NO2]- [µg/m³] (Ion chromatograph, Dionex Cor...)	40 F- [µg/m³] (Ion chromatograph, Dionex Cor...)	41 MSA [µg/m³] (Ion chromatograph, Dionex Cor...)	43 Na+ [µg/m³] (Ion chromatograph, Dionex Cor...)	44 [NH4]+ [µg/m³] (Ion chromatograph, Dionex Cor...)	45 K+ [µg/m³] (Ion chromatograph, Dionex Cor...)	46 Mg2+ [µg/m³] (Ion chromatograph, Dionex Cor...)	47 Comment
PI-ICE_Berner1	Berner 1, stage 1	18	0.05-0.14	188	2019-01-25T02:54:00	-64.93	-63.31	2019-01-27T15:30:00	-67.58	-68.13	4.7	3.5	2.2	1.5	68	9	340	250	0.087862528	139.9410454	#0	#0	49.00931901	60.93268575	174.7579004	701.3050128	387.262907	408.2672167	135.4090405	#0	254.8173076	2311.702435	0.002046227	0.001401807	0.016136182	0.000195123	0	0	0.002038525	0	0.007270909	0.000503213	0
PI-ICE_Berner1	Berner 1, stage 2	18	0.14-0.42	188	2019-01-25T02:54:00	-64.93	-63.31	2019-01-27T15:30:00	-67.58	-68.13	4.7	3.5	2.2	1.5	68	9	340	250	0.519595162	148.520119	#0	#0	#0	31.43963885	#0	69.41851435	88.52383406	#0	50.45197885	#0	#0	388.3540851	0.003118111	0.002077876	0.120270349	0.000254222	0	0	0.017997879	0.011170203	0.037126787	0.000786013	0.000843083
PI-ICE_Berner1	Berner 1, stage 3	18	0.42-1.2	188	2019-01-25T02:54:00	-64.93	-63.31	2019-01-27T15:30:00	-67.58	-68.13	4.7	3.5	2.2	1.5	68	9	340	250	0.607403274	193.3692472	#0	#0	#0	14.14748814	#0	13.12246433	#0	#0	#0	#0	541.9779983	762.6171979	0.157751892	0.006223537	0.06744065	0.000619245	0	0.000012955	0.023399151	0.111541742	0.005842663	0.00256248	0.011949605
PI-ICE_Berner1	Berner 1, stage 4	18	1.2-3.5	188	2019-01-25T02:54:00	-64.93	-63.31	2019-01-27T15:30:00	-67.58	-68.13	4.7	3.5	2.2	1.5	68	9	340	250	2.293810092	160.9636018	#0	#0	37.748773	38.80253249	48.80371057	1734.175879	274.7585152	71.51267218	166.401167	#0	#0	2533.166851	0.835362202	0.01381057	0.094482849	0.001503409	0	0.000037319	0.009822804	0.458179844	0.003667891	0.015737812	0.04188753
PI-ICE_Berner1	Berner 1, stage 5	18	3.5-10	188	2019-01-25T02:54:00	-64.93	-63.31	2019-01-27T15:30:00	-67.58	-68.13	4.7	3.5	2.2	1.5	68	9	340	250	1.872406627	98.1797957	89.81668408	#0	#0	67.05206207	106.9849557	185.0344525	23.60975503	#0	70.99398954	#0	334.0598477	975.7315424	0.699708874	0.00414557	0.070474689	0.001201927	0	0.000043183	0.000854064	0.369807392	0.003111577	0.013698614	0.045975522
PI-ICE_Berner2	Berner 2, stage 1	18	0.05-0.14	216	2019-01-28T05:01:00	-67.78	-68.85	2019-01-31T05:04:00	-62.58	-59.73	4.8	3.0	1.4	0.7	92	5	150	110	0.087600415	#0	2.621277931	9.977239123	11.47181435	12.5250612	10.74814697	199.3469484	107.5212693	8.140110528	52.01106033	#0	15.70979523	430.0727234	0.008612238	0.001449894	0.008440217	0.000169787	0	0.000002234	0.002113405	0.00122649	0.003143299	0.000882447	0.000332873
PI-ICE_Berner2	Berner 2, stage 2	18	0.14-0.42	216	2019-01-28T05:01:00	-67.78	-68.85	2019-01-31T05:04:00	-62.58	-59.73	4.8	3.0	1.4	0.7	92	5	150	110	0.339832363	#0	#0	#0	#0	39.31042712	#0	265.144518	177.2486214	35.04778322	194.7584214	691.9968705	93.00046359	1496.507105	0.01486938	0.001701121	0.058853922	0.001121594	0	0.000017628	0.020948902	0.023108356	0.018868776	0.001148036	0.002404045
PI-ICE_Berner2	Berner 2, stage 3	18	0.42-1.2	216	2019-01-28T05:01:00	-67.78	-68.85	2019-01-31T05:04:00	-62.58	-59.73	4.8	3.0	1.4	0.7	92	5	150	110	0.819747540	#0	#0	#0	#0	18.30009051	#0	484.4711195	48.11171308	#0	68.62899555	423.2374545	63.34767711	1106.09705	0.281961155	0.012037058	0.048080596	0.001048367	0	0.000040582	0.008583083	0.161148681	0.002468735	0.005005108	0.019652938
PI-ICE_Berner2	Berner 2, stage 4	18	1.2-3.5	216	2019-01-28T05:01:00	-67.78	-68.85	2019-01-31T05:04:00	-62.58	-59.73	4.8	3.0	1.4	0.7	92	5	150	110	2.077268000	#0	#0	#0	19.33534295	26.9757958	3.692642271	305.5854068	188.0207609	#0	130.0181527	173.3438855	24.88049168	871.8524786	0.756251745	0.012935845	0.080161882	0.000783991	0	0.000083502	0.00263727	0.403824761	0.003943148	0.014081678	0.037121261
PI-ICE_Berner2	Berner 2, stage 5	18	3.5-10	216	2019-01-28T05:01:00	-67.78	-68.85	2019-01-31T05:04:00	-62.58	-59.73	4.8	3.0	1.4	0.7	92	5	150	110	0.638690594	#0	#0	#0	#0	7.675941185	#0	109.0695725	44.94061478	#0	88.09692105	#0	#0	249.7830495	0.221706056	0.002219065	0.022856574	0.000993673	0	0.00009394	0.000156566	0.116512374	0.001095963	0.004333752	0.013986578
PI-ICE_Berner3	Berner 3, stage 1	18	0.05-0.14	206	2019-02-03T20:03:00	-62.97	-60.68	2019-02-06T13:58:00	-62.20	-58.94	9.1	4.8	3.2	1.6	89	10	220	210	1.311548929	#0	4.682857626	9.714661424	10.65604065	56.75877305	6.865798774	260.7396024	91.12495896	#0	47.06659638	#0	40.99884888	528.6081382	0.024659521	0.000742291	0.03398148	0.000629894	0	0.000004683	0.005378684	0.016417045	0.010113424	0.001065434	0.001892023
PI-ICE_Berner3	Berner 3, stage 2	18	0.14-0.42	206	2019-02-03T20:03:00	-62.97	-60.68	2019-02-06T13:58:00	-62.20	-58.94	9.1	4.8	3.2	1.6	89	10	220	210	1.098362240	3.196518547	3.893254887	103.934585	182.85826	56.99872995	57.66869873	281.2424226	4548.417335	#0	1032.005051	#0	48.48053129	6318.695387	0.137023017	0.001572853	0.069623592	0.001175598	0	0.000020787	0.025276517	0.107037179	0.011998493	0.003385908	0.011617405
PI-ICE_Berner3	Berner 3, stage 3	18	0.42-1.2	206	2019-02-03T20:03:00	-62.97	-60.68	2019-02-06T13:58:00	-62.20	-58.94	9.1	4.8	3.2	1.6	89	10	220	210	3.224979167	2.291428259	#0	#0	#0	71.11686353	8.813301809	57.82529045	85.51021496	18.31173349	13.38192329	474.1019419	79.59266999	810.9453677	1.120047612	0.00836068	0.124422428	0.001576194	0	0.000082709	0.020854439	0.614122466	0.005324085	0.021846945	0.059989891
PI-ICE_Berner3	Berner 3, stage 4	18	1.2-3.5	206	2019-02-03T20:03:00	-62.97	-60.68	2019-02-06T13:58:00	-62.20	-58.94	9.1	4.8	3.2	1.6	89	10	220	210	6.967111524	21.87983071	10.68666719	45.23133713	20.21285001	72.94278845	37.16386372	111.112253	59.41146601	21.98275076	35.63403609	#0	38.65579928	474.9136424	2.500726316	0.008620973	0.230160033	0.001264215	0	0.000133715	0.011446006	1.359072261	0.006486394	0.052056476	0.138876429
PI-ICE_Berner3	Berner 3, stage 5	18	3.5-10	206	2019-02-03T20:03:00	-62.97	-60.68	2019-02-06T13:58:00	-62.20	-58.94	9.1	4.8	3.2	1.6	89	10	220	210	1.882777070	#0	7.803365972	20.70638003	27.96856481	41.33474366	11.31067066	2202.595051	196.5740736	34.7588571	606.5287314	#0	34.98641577	3184.566854	0.669512609	0.001363164	0.064307204	0.001144358	0	0.000094087	0.000363219	0.448723812	0.001918932	0.012380067	0.042505333
PI-ICE_Berner4	Berner 4, stage 1	4	0.05-0.14	340	2019-02-21T19:26:00	-62.66	-60.39	2019-02-24T23:00:00	-62.66	-60.39	2.5	1.0	1.1	1.0	69	5	170	230	0.179003539	#0	#0	#0	#0	1.70948991	#0	19.23071369	5.091980866	#0	23.45684507	98.24385704	49.44192107	197.1748076	0.015322337	0.004154346	0.031941137	0.0004109	0	0.000011335	0.005158926	0.008888203	0.01348037	0.001117933	0.001130685
PI-ICE_Berner4	Berner 4, stage 2	4	0.14-0.42	340	2019-02-21T19:26:00	-62.66	-60.39	2019-02-24T23:00:00	-62.66	-60.39	2.5	1.0	1.1	1.0	69	5	170	230	0.388206026	#0	#0	#0	#0	3.910346202	#0	6.636521582	#0	#0	32.78074678	#0	#0	43.32761457	0.043453764	0.006555868	0.070445884	0.00042625	0.000037319	0.000013975	0.006438475	0.031358041	0.028915138	0.001031386	0.003143071
PI-ICE_Berner4	Berner 4, stage 3	4	0.42-1.2	340	2019-02-21T19:26:00	-62.66	-60.39	2019-02-24T23:00:00	-62.66	-60.39	2.5	1.0	1.1	1.0	69	5	170	230	0.360435955	#0	#0	#0	#0	#0	#0	38.80170614	7.966997708	#0	33.53667346	138.3030812	#0	218.6084585	0.075936578	0.011121807	0.0242941	0.000491888	0	0.000018589	0.002997083	0.051866974	0.006709118	0.001075289	0.006055651
PI-ICE_Berner4	Berner 4, stage 4	4	1.2-3.5	340	2019-02-21T19:26:00	-62.66	-60.39	2019-02-24T23:00:00	-62.66	-60.39	2.5	1.0	1.1	1.0	69	5	170	230	0.476325568	#0	#0	#0	#0	3.563023904	7.730467572	32.40030989	#0	#0	#0	#0	34.39004525	78.08384661	0.082603201	0.007670976	0.014445715	0.000350347	0	0.000019011	0.001811486	0.054629735	0.001527677	0.0015915	0.006184037
PI-ICE_Berner4	Berner 4, stage 5	4	3.5-10	340	2019-02-21T19:26:00	-62.66	-60.39	2019-02-24T23:00:00	-62.66	-60.39	2.5	1.0	1.1	1.0	69	5	170	230	0.377651493	#0	2.783253842	#0	#0	0.985534197	9.460784314	128.4025389	45.29156429	#0	43.73008704	112.0238474	20.26603074	362.9436407	0.068173187	0.003146675	0.008497789	0.000392783	0	0.000015447	0.000797702	0.042778016	0.000476635	0.001386876	0.004846895
PI-ICE_Berner5	Berner 5, stage 1	4	0.05-0.14	397	2019-02-25T19:45:00	-62.66	-60.39	2019-03-01T12:00:00	-62.66	-60.39	2.6	1.2	-0.1	1.3	67	12	110	180	0.318692471	#0	#0	#0	#0	8.519742577	#0	39.58748528	10.31894525	#0	28.41308006	#0	#0	86.83925317	0.086666451	0.0032676	0.03648	0.001264719	0	0.000004921	0.002218179	0.055615637	0.005954512	0.003775702	0.006872295
PI-ICE_Berner5	Berner 5, stage 2	4	0.14-0.42	397	2019-02-25T19:45:00	-62.66	-60.39	2019-03-01T12:00:00	-62.66	-60.39	2.6	1.2	-0.1	1.3	67	12	110	180	1.261246057	78.9496985	#0	345.0861257	#0	261.3823881	32.57690253	872.8440577	307.7759967	#0	341.1674681	#0	8.058926799	2247.841564	0.192887581	0.00492482	0.068690831	0.001538704	0	0.000003632	0.002213021	0.117546791	0.013443984	0.006732283	0.01388223
PI-ICE_Berner5	Berner 5, stage 3	4	0.42-1.2	397	2019-02-25T19:45:00	-62.66	-60.39	2019-03-01T12:00:00	-62.66	-60.39	2.6	1.2	-0.1	1.3	67	12	110	180	0.731979412	#0	#0	#0	#0	#0	#0	16.602601	17.22567083	#0	#0	#0	#0	33.82827183	0.204577148	0.003311945	0.034612433	0.000890699	0	0.000020601	0.001660214	0.116623371	0.003818492	0.003954218	0.014685017
PI-ICE_Berner5	Berner 5, stage 4	4	1.2-3.5	397	2019-02-25T19:45:00	-62.66	-60.39	2019-03-01T12:00:00	-62.66	-60.39	2.6	1.2	-0.1	1.3	67	12	110	180	0.919420837	#0	#0	#0	#0	#0	#0	20.86848332	#0	#0	#0	#0	#0	20.86848332	0.237865156	0.002633016	0.028374762	0.000766418	0	0.000019779	0.001159516	0.133553232	0.000766418	0.005111512	0.017078754
PI-ICE_Berner5	Berner 5, stage 5	4	3.5-10	397	2019-02-25T19:45:00	-62.66	-60.39	2019-03-01T12:00:00	-62.66	-60.39	2.6	1.2	-0.1	1.3	67	12	110	180	0.712428271	#0	#0	#0	#0	5.870471342	#0	#0	5.947843882	#0	#0	#0	#0	11.81831522	0.201367328	0.001080869	0.021854278	0.000649367	0	0.000037016	0.001060774	0.112205175	0.000667347	0.003676223	0.014015335
PI-ICE_Berner6	Berner 6, stage 1	4	0.05-0.14	315	2019-03-02T14:00:00	-62.66	-60.39	2019-03-05T12:00:00	-62.66	-60.39	4.4	2.2	3.0	1.7	86	4	80	120	0.388429650														0.016797339	0.001032213	0.00842409	0.000155602	0	0.000003081	0.001064566	0.007302521	0.002489636	0.001106162	0.000898179	atmsospheric carbohydrates could not be analyzed from these samples due to lack of sample material
PI-ICE_Berner6	Berner 6, stage 2	4	0.14-0.42	315	2019-03-02T14:00:00	-62.66	-60.39	2019-03-05T12:00:00	-62.66	-60.39	4.4	2.2	3.0	1.7	86	4	80	120	0.224545455														0.026216667	0.001122024	0.033447143	0.000246071	0	0.000015476	0.001035357	0.01593119	0.012144167	0.000512262	0.001688452	atmsospheric carbohydrates could not be analyzed from these samples due to lack of sample material
PI-ICE_Berner6	Berner 6, stage 3	4	0.42-1.2	315	2019-03-02T14:00:00	-62.66	-60.39	2019-03-05T12:00:00	-62.66	-60.39	4.4	2.2	3.0	1.7	86	4	80	120	0.255223881														0.055180621	0.001997516	0.009983106	0.000478509	0	0.000004472	0.000667826	0.030211677	0.001645714	0.001472795	0.00329441	atmsospheric carbohydrates could not be analyzed from these samples due to lack of sample material
PI-ICE_Berner6	Berner 6, stage 4	4	1.2-3.5	315	2019-03-02T14:00:00	-62.66	-60.39	2019-03-05T12:00:00	-62.66	-60.39	4.4	2.2	3.0	1.7	86	4	80	120	0.256956116														0.070865411	0.00135987	0.01003645	0.001186883	0	0.000014416	0.000887359	0.04566697	0.000334762	0.001588918	0.00513355	atmsospheric carbohydrates could not be analyzed from these samples due to lack of sample material
PI-ICE_Berner6	Berner 6, stage 5	4	3.5-10	315	2019-03-02T14:00:00	-62.66	-60.39	2019-03-05T12:00:00	-62.66	-60.39	4.4	2.2	3.0	1.7	86	4	80	120	0.184249084														0.056650667	0.000777333	0.005088	0.000408	0	0.000006667	0.000622667	0.030952	0.000133333	0.001138667	0.003129333	atmsospheric carbohydrates could not be analyzed from these samples due to lack of sample material
PI-ICE_Berner7	Berner 7, stage 1	4	0.05-0.14	302	2019-03-05T14:00:00	-62.66	-60.39	2019-03-08T13:00:00	-62.66	-60.39	3.0	1.8	0.5	1.8	78	7	60	90	0.264470312	7.600873899	45.10138595	133.4600942	20.85000341	67.96323445	100.0920553	285.6373215	138.2715252	23.15286407	107.5747111	200.5393596	26.07496416	1156.318393	0.034298763	0.001792409	0.008889467	0.000247719	0	0.000004733	0.001172324	0.016849595	0.001693006	0.001435821	0.001999104
PI-ICE_Berner7	Berner 7, stage 2	4	0.14-0.42	302	2019-03-05T14:00:00	-62.66	-60.39	2019-03-08T13:00:00	-62.66	-60.39	3.0	1.8	0.5	1.8	78	7	60	90	0.492267277	#0	24.59616542	141.9647571	21.15963507	34.72922295	43.89624724	618.890304	184.4754473	#0	38.99425997	#0	#0	1108.706039	0.075404006	0.002343009	0.019010212	0.000581396	0	0.000006337	0.001501807	0.042036332	0.005592171	0.00235093	0.004557698
PI-ICE_Berner7	Berner 7, stage 3	4	0.42-1.2	302	2019-03-05T14:00:00	-62.66	-60.39	2019-03-08T13:00:00	-62.66	-60.39	3.0	1.8	0.5	1.8	78	7	60	90	0.675863539	2.795552175	#0	#0	#0	#0	#0	34.85127135	4.987057346	8.377930911	#0	#0	#0	51.01181178	0.164740734	0.003664842	0.021157442	0.000724668	0	0.000011173	0.000692745	0.094052052	0.001442952	0.003441376	0.011661733
PI-ICE_Berner7	Berner 7, stage 4	4	1.2-3.5	302	2019-03-05T14:00:00	-62.66	-60.39	2019-03-08T13:00:00	-62.66	-60.39	3.0	1.8	0.5	1.8	78	7	60	90	0.813709232	#0	#0	#0	#0	8.79818048	7.053140678	117.9814168	53.93289183	#0	35.2485183	#0	#0	223.0141481	0.19400986	0.002722705	0.022660199	0.000624197	0	0.000011714	0.00048028	0.110508005	0.000922071	0.003621348	0.013603483
PI-ICE_Berner7	Berner 7, stage 5	4	3.5-10	302	2019-03-05T14:00:00	-62.66	-60.39	2019-03-08T13:00:00	-62.66	-60.39	3.0	1.8	0.5	1.8	78	7	60	90	0.597014925	#0	9.328202375	15.15601694	9.256010978	5.784083903	10.78485771	53.65586236	#0	#0	4.940441646	#0	#0	108.9054759	0.182010448	0.002260199	0.020763184	0.001760448	0	0.000020896	0.000384826	0.103124627	0.00195199	0.003736816	0.012673134
PI-ICE_Berner8	Berner 8, stage 1	4	0.05-0.14	356	2019-03-08T13:00:00	-62.66	-60.39	2019-03-11T20:00:00	-62.66	-60.39	1.6	0.6	0.5	0.2	71	1	140	20	0.244673647	#0	#0	#0	#0	7.589916307	3.923220974	14.54418212	7.555486523	#0	28.81540559	#0	22.37055485	84.79876636	0.031544054	0.001633625	0.007635479	0.000319861	0	0.000004118	0.000738563	0.015553753	0.001383776	0.001341219	0.001905438
PI-ICE_Berner8	Berner 8, stage 2	4	0.14-0.42	356	2019-03-08T13:00:00	-62.66	-60.39	2019-03-11T20:00:00	-62.66	-60.39	1.6	0.6	0.5	0.2	71	1	140	20	0.645122859	#0	#0	#0	#0	#0	#0	#0	11.17893279	#0	11.69452172	#0	#0	22.87345451	0.062310105	0.001838429	0.013077854	0	0	0.000004122	0.000967305	0.039324245	0.002690317	0.001137683	0.004365239
PI-ICE_Berner8	Berner 8, stage 3	4	0.42-1.2	356	2019-03-08T13:00:00	-62.66	-60.39	2019-03-11T20:00:00	-62.66	-60.39	1.6	0.6	0.5	0.2	71	1	140	20	1.213837350	#0	#0	#0	#0	#0	#0	16.74275782	#0	#0	3.956017432	#0	#0	20.69877526	0.144552338	0.002672257	0.017567317	0.000638959	0	0.000014891	0.000559089	0.082144163	0.000839311	0.002534177	0.010208456
PI-ICE_Berner8	Berner 8, stage 4	4	1.2-3.5	356	2019-03-08T13:00:00	-62.66	-60.39	2019-03-11T20:00:00	-62.66	-60.39	1.6	0.6	0.5	0.2	71	1	140	20	1.415074046	#0	#0	#0	#0	#0	#0	17.52499149	#0	#0	2.388247645	#0	#0	19.91323913	0.145057883	0.001795359	0.016227771	0.000540736	0	0.000012773	0.00032359	0.081817261	0.00083878	0.003059916	0.010062524
PI-ICE_Berner8	Berner 8, stage 5	4	3.5-10	356	2019-03-08T13:00:00	-62.66	-60.39	2019-03-11T20:00:00	-62.66	-60.39	1.6	0.6	0.5	0.2	71	1	140	20	1.070756248	#0	#0	#0	#0	#0	#0	64.88001783	#0	#0	22.70634798	#0	#0	87.5863658	0.168268776	0.001246414	0.018013924	0.000674895	0	0.000011814	0.000217089	0.094319831	0.001081013	0.002932911	0.011671097