Citation:

PANGAEA.924535

Name: X-Ray Fluorescence Spectrometry Data for IODP Hole 369-U1513D
Published: 2020-11-09
License: https://creativecommons.org/licenses/by/4.0/
Keywords: IODP Expedition 369 Site U1513 Hole D; Naturaliste Plateau basalts and volcaniclastic flows

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Published: 2020-11-09 • DOI registered: 2020-11-18

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Abstract:

Bulk rock composition analysis was conducted by X-Ray Fluorescence spectrometry (WD-XRF) using AXIOS Plus (Panalytical) at University of Oldenburg on shipboard residual sample powders analyzed by ICP-AES [Huber et al., 2019]. Borate glass beads were prepared from the sample powder using di-lithium tetraborate as a flux (700 mg sample, 4.2 g flux). Calibration of the XRF instrument is based on 52 international reference samples and in-house standards. Precision was determined from the pooled standard deviation of several duplicates and is better than 3% for major elements and better than 5% for trace elements when concentration levels are above the limit of quantitation. Accuracy was checked by analyzing international and in-house reference samples that are not included in the calibration and was better than 7% for all elements above the limit of quantitation. Results between XRF and ICP-AES analysis are generally in excellent agreement, except for elements affected by incomplete dissolution in borate digestion, especially Cr, and low-abundance elements like Rb and Nb that were not measured well by ICP-AES.

Keyword(s):

IODP Expedition 369 Site U1513 Hole D; Naturaliste Plateau basalts and volcaniclastic flows

Supplement to:

Harry, Dennis L; Tejada, Maria Luisa G; Lee, Eun Young; Wolfgring, Erik; Wainman, Carmine Christopher; Brumsack, Hans-Jürgen; Schnetger, Bernhard; Kimura, Jun-Ichi; Riquier, Laurent; Borissova, Irina; Hobbs, Richard W; Jiang, Tao; Li, Yong-Xiang; Maritati, Alessandro; Martinez, Mathieu; Richter, Carl; Tagliaro, Gabriel; White, Lloyd T (2020): Evolution of the Southwest Australian Rifted Continental Margin During Breakup of East Gondwana: Results from IODP Expedition 369. Geochemistry, Geophysics, Geosystems, https://doi.org/10.1029/2020GC009144

Related to:

Huber, Brian T; Hobbs, Richard W; Bogus, Kara A; Batenburg, Sietske J; Brumsack, Hans-Jürgen; do Monte Guerra, Rodrigo; Edgar, Kirsty M; Edvardsen, Trine; Tejada, Maria Luisa G; Harry, Dennis L; Hasegawa, Takashi; Haynes, Shannon J; Jiang, Tao; Jones, Matthew M; Kuroda, Junichiro; Lee, Eun Young; Li, Yong-Xiang; MacLeod, Kenneth G; Maritati, Alessandro; Martinez, Mathieu; O'Connor, Lauren K; Petrizzo, Maria Rose; Quan, Tracy M; Richter, C; Riquier, Laurent; Tagliaro, Gabriel; Wainman, Carmine Christopher; Watkins, David K; White, Lloyd T; Wolfgring, Erik; Xu, Zhaokai (2019): Site U1513. In: Proceedings of the International Ocean Discovery Program, International Ocean Discovery Program, 369, https://doi.org/10.14379/iodp.proc.369.104.2019

Further details:

XRF standard measurement ICBM JB-1

Project(s):

Integrated Ocean Drilling Program / International Ocean Discovery Program (IODP)

Coverage:

Latitude: -33.793470 * Longitude: 112.485560

Date/Time Start: 2017-10-24T08:45:00 * Date/Time End: 2017-11-01T17:30:00

Minimum DEPTH, sediment/rock: 693.54 m * Maximum DEPTH, sediment/rock: 756.67 m

Event(s):

369-U1513D * Latitude: -33.793470 * Longitude: 112.485560 * Date/Time Start: 2017-10-24T08:45:00 * Date/Time End: 2017-11-01T17:30:00 * Elevation: -2789.0 m * Campaign: * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL)

Comment:

Borate glass beads were prepared from the sample powder using di-lithium tetraborate as a flux (700 mg sample, 4.2 g flux).

Calibration of the XRF instrument is based on 52 international reference samples and in-house standards. Precision was determined from the pooled standard deviation of several duplicates and is better than 3% for major elements and better than 5% for trace elements when concentration levels are above the limit of quantitation. Accuracy was checked by analyzing international and in-house reference samples that are not included in the calibration and was better than 7% for all elements above the limit of quantitation.

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Sample code/label	Sample label		Tejada, Maria Luisa G	DSDP/ODP/IODP sample designation
2	DEPTH, sediment/rock	Depth sed	m	Tejada, Maria Luisa G		Geocode – mbsf
3	Unit	Unit		Tejada, Maria Luisa G
4	Silicon dioxide	SiO2	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
5	Titanium dioxide	TiO2	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
6	Aluminium oxide	Al2O3	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
7	Iron oxide, Fe2O3	Fe2O3	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %, total Fe as Fe2O3
8	Manganese oxide	MnO	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
9	Magnesium oxide	MgO	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
10	Calcium oxide	CaO	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
11	Sodium oxide	Na2O	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
12	Potassium oxide	K2O	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
13	Phosphorus pentoxide	P2O5	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
14	Elements, total	Total	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)	wt. %
15	Loss on ignition	LOI	%	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
16	Rubidium	Rb	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
17	Barium	Ba	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
18	Niobium	Nb	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
19	Strontium	Sr	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
20	Zirconium	Zr	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
21	Vanadium	V	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
22	Yttrium	Y	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
23	Gallium	Ga	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
24	Chromium	Cr	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
25	Zinc	Zn	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
26	Copper	Cu	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
27	Cobalt	Co	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)
28	Nickel	Ni	mg/kg	Tejada, Maria Luisa G	X-ray fluorescence (XRF)

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Size:

648 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Sample label	2 Depth sed [m]	3 Unit	4 SiO2 [%]	5 TiO2 [%]	6 Al2O3 [%]	7 Fe2O3 [%]	8 MnO [%]	9 MgO [%]	10 CaO [%]	11 Na2O [%]	12 K2O [%]	13 P2O5 [%]	14 Total [%]	15 LOI [%]	16 Rb [mg/kg]	17 Ba [mg/kg]	18 Nb [mg/kg]	19 Sr [mg/kg]	20 Zr [mg/kg]	21 V [mg/kg]	22 Y [mg/kg]	23 Ga [mg/kg]	24 Cr [mg/kg]	25 Zn [mg/kg]	26 Cu [mg/kg]	27 Co [mg/kg]	28 Ni [mg/kg]
369-U1513D-66R-3W,66-69	693.54	Unit 3	49.5	0.54	21.39	6.36	0.118	8.5	10.90	2.51	0.03	0.04	99.8	3.0	<3	16	<3.0	148	32	166	12	15	833	51	55	95	283
369-U1513D-66R-4W,43-46	694.37	Unit 3	49.4	0.33	25.18	6.48	0.149	11.6	4.25	1.51	0.97	0.01	99.9	9.0	6	36	3.0	132	21	87	7	10	665	35	29	66	264
369-U1513D-67R-1W,25.5-28.5	695.61	dike A	48.7	0.53	18.81	8.45	0.155	11.6	9.32	2.29	0.03	0.04	99.8	3.7	<3	13	2.6	119	32	171	16	13	889	56	53	66	324
369-U1513D-67R-3W,17.5-20.5	697.31	Unit 3	48.2	0.57	21.87	7.06	0.180	9.9	9.50	2.50	0.03	0.04	99.8	4.8	<3	15	2.1	151	34	182	11	15	876	66	35	110	331
369-U1513D-67R-4W,62-65	698.41	volcaniclastic flow	40.0	2.36	31.62	22.30	0.072	1.1	1.45	0.52	0.17	0.16	99.8	11.0	<3	170	10.0	101	175	307	23	26	579	56	925	50	389
369-U1513D-68R-1W,28-30	700.09	dike B	45.6	1.16	23.73	10.90	0.153	14.6	1.98	0.62	0.50	0.52	99.7	13.0	12	13	<3.0	95	62	265	204	26	1058	402	20	424	808
369-U1513D-68R-4W,123-126	705.42	Unit 5	49.4	1.52	20.34	13.20	0.291	9.8	3.13	1.73	0.52	0.09	99.9	10.0	6	29	4.1	158	87	388	25	19	249	78	12	88	59
369-U1513D-69R-1W,74-76	710.15	Unit 7	48.4	1.81	21.15	21.40	0.139	3.1	2.31	1.11	0.41	0.01	99.9	8.6	3	40	4.0	161	105	228	17	20	71	100	72	96	40
369-U1513D-69R-2W,66-68	711.43	Unit 7	46.9	1.39	18.13	13.90	0.282	10.1	6.09	2.59	0.36	0.12	99.9	6.5	7	46	4.2	150	81	414	23	21	75	114	34	95	34
369-U1513D-69R-4W,59-61	713.80	Unit 7	51.5	1.37	19.36	11.70	0.170	7.9	4.70	2.38	0.85	0.05	99.9	5.3	15	33	4.2	172	79	310	20	19	100	82	74	53	34
369-U1513D-70R-1W,69.5-71.5	719.71	Unit 7	52.3	1.23	17.30	15.40	0.172	8.3	2.45	1.36	1.42	0.08	99.9	6.5	26	29	2.6	146	73	269	28	17	84	91	24	55	32
369-U1513D-70R-3W,2-5	721.60	dike B	51.3	1.21	15.57	12.00	0.208	7.2	9.87	2.12	0.40	0.08	99.9	2.5	5	38	2.6	134	74	330	28	16	79	76	33	74	30
369-U1513D-71R-2W,105-107	725.23	Unit 7	50.0	1.22	18.24	10.50	0.155	8.0	8.55	2.97	0.23	0.10	99.9	2.7	3	33	3.6	175	71	333	22	20	84	83	31	81	33
369-U1513D-71R-3W,125-127	726.89	Unit 7	56.0	1.08	16.86	15.30	0.185	5.2	2.44	1.14	1.66	0.02	100.0	8.1	34	26	<3.0	166	66	111	54	20	112	68	31	47	36
369-U1513D-72R-1W,10-12	728.71	Unit 7	50.7	1.66	18.33	12.10	0.281	8.3	5.09	2.83	0.53	0.11	99.9	5.1	7	41	4.0	173	96	352	25	23	72	69	26	76	27
369-U1513D-73R-1W,76-79	738.98	dike B	51.0	1.22	15.27	11.50	0.160	7.8	9.97	2.72	0.22	0.09	99.9	1.9	<3	37	3.1	151	73	328	26	18	67	86	25	86	29
369-U1513D-73R-4W,25-28	741.88	dike B	50.8	1.16	14.86	11.40	0.259	7.6	11.00	2.71	0.10	0.10	99.9	0.9	<3	28	2.5	149	71	323	28	17	67	89	81	71	29
369-U1513D-74R-1W,53-55	743.53	dike B	50.8	1.01	13.63	12.80	0.299	8.6	10.10	2.47	0.20	0.08	99.9	1.6	4	23	3.1	144	60	292	25	16	57	87	67	171	29
369-U1513D-74R-2W,19-21	744.70	dike B	50.8	1.20	15.31	11.00	0.281	7.2	11.20	2.74	0.07	0.11	99.9	1.1	<3	33	3.6	155	73	324	28	19	65	92	61	106	27
369-U1513D-74R-3W,17-19	746.14	dike B	49.5	1.34	16.82	11.50	0.207	7.7	9.35	3.11	0.20	0.10	99.9	2.4	<3	37	3.6	175	78	364	37	20	74	88	93	120	28
369-U1513D-75R-3W,52-54	750.41	volcaniclastic flow	43.5	2.07	31.70	19.90	0.066	0.7	1.27	0.43	0.10	0.07	99.9	10.0	<3	139	12.0	102	207	390	20	31	449	70	20	37	137
369-U1513D-75R-4W,98-100	752.29	Unit 9	39.2	2.63	27.36	26.40	0.300	0.9	2.03	0.61	0.35	0.05	99.8	11.0	<3	23	7.4	113	159	610	59	41	333	228	53	124	90
369-U1513D-75R-7W,65-67	756.06	Unit 9	50.3	2.30	21.28	17.70	0.168	2.4	2.84	1.02	1.58	0.25	99.9	8.0	23	32	6.0	160	142	251	65	30	170	101	47	75	54
369-U1513D-75R-7W,126-128	756.67	Unit 9	49.5	2.35	18.99	14.20	0.555	6.2	3.61	2.70	1.54	0.24	99.9	6.3	24	130	7.1	157	145	364	45	28	169	291	25	191	65