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Tanner, Thomas; Hernández-Almeida, Iván; Drury, Anna Joy; Guitián, José; Stoll, Heather M (2020): Organic and inorganic data of ODP Hole 177-1088B [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.924480, In: Tanner, T et al. (2020): New Tie points, organic and inorganic data, growth rate and pCO2 reconstructions for the late Miocene Cooling of ODP Hole 177-1088B [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.924529

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Abstract:
Oxygen and carbon isotopes were measured for several planktonic foraminifera species (Globigerina bulloides, Neogloboquadrina pachyderma sinistral (sin.), Globoconella spp.) and the benthic foraminifera genus Cibicidoides spp. in samples from Ocean Drilling Program (ODP) Site 1088B. Typically, 10-15 planktonic specimen and five benthic specimen larger than 150μm were picked per sample. Foraminifera were crushed, rinsed twice with deionized water and once with MeOH and dried overnight at 50°C. Samples were analyzed at ETH Zurich on a GAS BENCH II system coupled to a Delta V Plus irMS (Thermo Scientific) following procedures described by Breitenbach and Bernasconi (2011). Analytical precision after system calibration by two in-house standards and international standards NBS-19 and NBS-18 was 0.07‰ for both stable isotopes. Values are reported relative to the VPDB standard.
Different alkenone ratios (U_37^k' and C37.2/C38.2) were directly estimated with a Thermo Scientific Trace 1310 Gas Chromatograph (GC) equipped with a flame ionization detector (FID). Lab-sample replicates and in-house alkenone standard were injected every sequence to determine instrument drift and to guarantee long-term validation giving a precision of 0.025 U_37^k' units. Alkenone-derived SST was calculated from U_37^k' using the global calibration from Müller et al. (1998).
Carbon isotopic compositions of C37.2 alkenones were measured on a Thermo Scientific Delta V mass spectrometer interfaced with a Thermo Scientific Trace 1310 Gas Chromatograph (GC-irMS) at ETH Zurich. Replicates, in-house alkenone standard, and known isotopic mixtures A5 and B4 (supplied by Arndt Schimmelmann, Univ. of Indiana) were injected at every sequence to determine the analytical accuracy of the measurement and an uncertainty of 0.4‰ is reported. Carbon isotopes are reported relative to the Vienna PeeDee Belemnite (VPDB) standard.
The isotopic fractionation (εp) during photosynthetic fixation of carbon between [CO2]aq and algal biomass is calculated using the equation originally described by Freeman and Hayes (1992). The carbon isotopic composition of C37.2 alkenones represents the organic part whereas carbon isotopes from the planktonic formaninifera species N. pachyderma sin. are used as an assumption of dissolved inorganic carbon. To carefully include and propagate the uncertainties of each parameter introduced, a full Monte Carlo simulation (n = 10'000) was conducted and the respective 1 sigma confidence intervals are reported in this table.
A quantitative estimation of the mean size of the alkenone producing coccolithophorid Reticulofenestra pseudoumbilicus was carried out using polarized light microscopy and the C-Calcita software (Fuertes et al., 2014).
Keyword(s):
Alkenones; epsilon_p; Foraminifera; SST; Stable isotopes; UK37
Related to:
Tanner, Thomas; Hernández-Almeida, Iván; Drury, Anna Joy; Guitián, José; Stoll, Heather M (in review): Decreasing atmospheric CO2 during the Late Miocene Cooling.
Project(s):
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample code/labelSample labelTanner, Thomas
2DEPTH, sediment/rockDepth sedmTanner, ThomasGeocode
3AGEAgeka BPTanner, ThomasGeocode
4Globigerina bulloides, δ13CG. bulloides δ13C‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
5Globigerina bulloides, δ18OG. bulloides δ18O‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
6Neogloboquadrina pachyderma sinistral, δ13CN. pachyderma s δ13C‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
7Neogloboquadrina pachyderma sinistral, δ18ON. pachyderma s δ18O‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
8Globoconella spp., δ13CGloboconella spp. δ13C‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
9Globoconella spp., δ18OGloboconella spp. δ18O‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
10Cibicidoides spp., δ13CCibicidoides spp. δ13C‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
11Cibicidoides spp., δ18OCibicidoides spp. δ18O‰ PDBTanner, ThomasGas Bench II system coupled to a Delta V Plus irMS (Thermo Fisher Scientific)vs. VPDB
12Alkenone, δ13Cδ13C alkenone‰ PDBTanner, Thomas
13Alkenone, δ13C, standard deviationδ13C alk std dev±Tanner, Thomas
14Isotopic fractionation, during photosynthisεpTanner, Thomas16th percentile of epsilon p
15Isotopic fractionation, during photosynthisεpTanner, Thomas50th percentile of epsilon p
16Isotopic fractionation, during photosynthisεpTanner, Thomas84th percentile of epsilon p
17Alkenone, unsaturation index UK'37UK'37Tanner, Thomas
18Sea surface temperatureSST°CTanner, ThomasCalculated from UK'37 (Müller et al, 1998)
19Alkenone, C37:2/C38:2Et ratioC37:2/C38:2eTanner, Thomas
20Alkenone, C37:2/C38:2Et ratio, standard deviationC37:2/C38:2e std±Tanner, Thomas
21Reticulofenestra pseudoumbilicusR. pseudoumbilicusµmTanner, ThomasLight microscope
Size:
608 data points

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