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Tzedakis, Polychronis C; Margari, Vasiliki; Skinner, Luke C; Menviel, Laurie; Capron, Emilie; Rhodes, Rachael H; Mleneck-Vautravers, Maryline J; Ezat, Mohamed M; Martrat, Belén; Grimalt, Joan O; Hodell, David A (2020): Alkenone sea surface temperatures Uk'37-SST from sediment core MD01-2444 on the Portuguese Margin, Marine Isotope Stage 3 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.919841, In: Tzedakis, PC et al. (2020): Palaeoceanographic, sediment and pollen data from sediment core MD01-2444 on the Portuguese Margin, Marine Isotope Stage 3 [dataset bundled publication]. PANGAEA, https://doi.org/10.1594/PANGAEA.919846

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Abstract:
Alkenone SST: Sediment samples (2.5 to 2.57 g) were freeze-dried and extracted by sonication using dichloromethane. The extracts were dried under nitrogen and hydrolysed with 7% potassium hydroxide in methanol. Extraction with hexane yielded a fraction enriched in neutral compounds, which was cleaned with ultra-pure water. The purified extracts were derivatised with BSTFA. Samples were injected diluted in toluene. They were then analysed with a Varian gas chromatograph Model 3400 equipped with a septum programmable injector and a flame ionisation detector. Absolute concentration errors were below 10%. Reproducibility tests showed that the uncertainty in the Uk'37 determinations was lower than 0.015 (ca. ±0.5ºC). The SST reconstruction (Uk'37-SST) was obtained from the relative composition of C37 unsaturated alkenones [Uk'37 = C37:2/(C37:2+C37:3)], using the calibration equation Uk'37 = 0.033*SST+0.044. The record was generated by B. Martart and J.O. Grimalt.
Age model: The age model was developed by aligning the abrupt transitions of d18O record of G. bulloides in core MD01-2444 to warming and cooling events in the NGRIP d18Oice record, presented on: (i) the GICC05 timescale [Svensson, A. et al. A 60,000 year Greenland stratigraphic ice core chronology. Clim. Past 4, 47–57 (2008)]; and (ii) the WD2014: modified timescale, whereby NGRIP GICC05 ice ages 31.2–67.2 ka are multiplied by 1.0063. [Buizert, C. et al. The WAIS Divide deep ice core WD2014 chronology – Part 1: Methane synchronization (68–31 ka BP) and the gas age–ice age difference. Clim. Past 11, 153-173 (2015)].
Keyword(s):
Heinrich Stadials; Interstadials; MIS 3; Portuguese Margin
Supplement to:
Margari, Vasiliki; Skinner, Luke C; Menviel, Laurie; Capron, Emilie; Rhodes, Rachael H; Mleneck-Vautravers, Maryline J; Ezat, Mohamed M; Martrat, Belén; Grimalt, Joan O; Hodell, David A; Tzedakis, Polychronis C (2020): Fast and slow components of interstadial warming in the North Atlantic during the last glacial. Communications Earth & Environment, 1(1), https://doi.org/10.1038/s43247-020-0006-x
Further details:
Buizert, Christo; Cuffey, Kurt M; Severinghaus, Jeffrey P; Baggenstos, Daniel; Fudge, Tyler J; Steig, Eric J; Markle, Bradley R; Winstrup, Mai; Rhodes, Rachael H; Brook, Edward J; Sowers, Todd A; Clow, Gary D; Cheng, Hai; Edwards, Ross L; Sigl, Michael; McConnell, Joseph R; Taylor, Kendrick C (2015): The WAIS Divide deep ice core WD2014 chronology - Part 1: Methane synchronization (68–31 ka BP) and the gas age–ice age difference. Climate of the Past, 11(2), 153-173, https://doi.org/10.5194/cp-11-153-2015
Coverage:
Latitude: 37.565000 * Longitude: -10.134000
Minimum DEPTH, sediment/rock: 9.00 m * Maximum DEPTH, sediment/rock: 13.66 m
Event(s):
MD01-2444 * Latitude: 37.565000 * Longitude: -10.134000 * Elevation: -2656.0 m * Campaign: MD123 (GEOSCIENCES, MARMARCORE) * Basis: Marion Dufresne (1995) * Method/Device: Calypso Corer (CALYPSO)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1DEPTH, sediment/rockDepth sedmTzedakis, Polychronis CGeocode
2Age modelAge modelkaTzedakis, Polychronis CAge model, GICC05
3Age modelAge modelkaTzedakis, Polychronis CAge model, WD2014
4Sea surface temperatureSST°CTzedakis, Polychronis CCalculated from UK'37
Size:
462 data points

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